Decane
(what is the formula?
______________)
Catalyst (broken clay pot or
aluminium oxide (Al2O3)
water
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Decane
(what is the formula?______________)
What is the Structural formula - Draw in your jotter)
H H H H H H H H H H
H C C C C C C C C C C H
H H H H H H H H H H
H H H H H H H H H H
H C C C C C C C C C C H
H H H H H H H H H H
Decane
Draw 4 isomers of decane
c c
c c c c c c c cc c c c c c c c c c
c
c c
c c c c c c c c c c c c c c c
c c
When we “crack” DECANE what are the possible products formed?
How do you prove you have formed these products?
H H H H H H H H H H
H C C C C C C C C C C H
H H H H H H H H H H
H H H H H H H H
H
H
H C C C H c c C C C C C H
H
H H H H H H H H
Annapurna
Alkanes
Saturated
(Single Bonds)
Cycloalkanes
Can be
Can be
Hydrocarbons Unsaturated
(Double Bond)
Ethene
CH2=CH2
Pentene Alkenes
CH3CH2CH2CH=CH2
Saturated or
Unsaturated?
H H H H Saturate
Saturate d
H H
H C d
C C C H
C
H C C H
H H H H
H H H H H
CH2 CH2
CH2 CH2
C C C H
Saturate Unsaturat CH2CHCH3
d
Hed H Unsaturat
ed
Bromine Water
Double Bonds
Br Br
Undergo
H Addition Reactions
H C C C H
In Addition Reactions
H H H The double bond
Breaks and bromine atoms
are added to both sides
of the double bond
Addition of Hydrogen
(H2)
The double bond
H H
Breaks and Hydrogen atoms
H are added to both sides
of the double bond
H C C C H
H H H
Propene
Propane
+ Hydrogen
Alkenes into Alkanes
Now write this
1. Hexene + reactions using
Hexane
Hydrogen the Structural
C6H12 + H2 Formulae
C6H14
H H H H H H H H H
H H
H C C C H
H C C C C H
C C H H C C C H
H
H HH H H H HH H
Alkenes into Alkanes
2. Octene + Hydrogen Octane
C8H16 + H2 C8H18
H H
H H H H H H H HH H H H H
H C C C C C H H C C C C H
C C C H C C C C H
H H H H HH HH H
H HH HH H
Saturated?
C2H6 C10H20 ?
C4H10 C4H8 ?
C H 8?
C7H14 ?
4
C8H18
C20H42 C11H22 ?
C60H122 C15H30
?
Alkenes and Cycloalkanes
Isomers from different Homologous
Series
Unsaturate
d
Alkenes C4H8
CnH2n
Cyclo-
alkanes
C4H8
Saturated
C 4H 8
Unsaturated Saturated
H H H H CH2 CH2
CH2 CH2
C C C C H Cyclobutane
H H H
Unreactive
Butene
No Reaction with
Reacts with Bromine
Bromine
C5H10
A B
Penten Cyclopentan
e e
► Describe how you could find out, which
test tube contained pentene and which
test tube contained cyclopentane
►Only Tube A decolourised bromine water.
Bromine Water
► Alkenesreact with Bromine water.
► The bromine water changes from brown to
clear.
► Tube A must contain Pentene
Alkene
Alkane
Bromin
e
Water