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Distillation Technology Overview

Distillation technology involves separating liquid mixtures into fractions based on differences in boiling points and volatility. The process utilizes various types of distillation columns, including tray and packed columns, and different tray designs to enhance efficiency. Key methods include atmospheric and multi-pressure distillation, which optimize energy use and component separation.

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0% found this document useful (0 votes)
12 views24 pages

Distillation Technology Overview

Distillation technology involves separating liquid mixtures into fractions based on differences in boiling points and volatility. The process utilizes various types of distillation columns, including tray and packed columns, and different tray designs to enhance efficiency. Key methods include atmospheric and multi-pressure distillation, which optimize energy use and component separation.

Uploaded by

rupawer56
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPT, PDF, TXT or read online on Scribd

DISTILLATION TECHNOLOGY

Definition…….

Separation of liquid mixture(s) of


different components into a number of fractions
of different compositions or into its Pure
Components
Distillation How It Works ?

Distillation is based on the fact that the vapor of a


boiling mixture will be richer in the components that
have lower boiling points. Therefore, when this vapor
is cooled and condensed, the condensate will contain
more volatile components.

 Boiling points difference


 Vapor pressure difference
 ‘Boil’ :vapor pressure = surrounding pressure
 Volatility
Distillation – How it works?

In Alcohol Water mixture Alcohol Vaporizes first and


then Water.

From the mixture of Alcohol & Water ,Water condenses


on the Tray, While condensing it liberates Latent Heat.

Alcohol Present on the tray absorbs the Latent heat


from condensing water and gets vaporized.

This makes Alcohol enrichment in Vapor and Water is


enriched at base.
Distillation – How it works?
Low Boiling
Point Component

Tray X+2

Tray X+1

High Boiling
Point Component
Tray X
[Link]
Types of distillation

 Batch distillation

 Continuous distillation

Binary
Multi-component
Extractive
Azeotropic
Components of
Distillation Column
 Vertical shell

 Column internals

 Reboiler

 Condenser

 Reflux drum
Types of Distillation Column

 Tray Column
 Packed Column
Types of Distillation Column

 Tray Column
 Packed Column
Tray Column Internals

Vapor

Liquid

Liquid Vapor flows Liquid, Vapor flows


inside a column across a tray
Tray Types : Based on
Liquid Flow
Single pass Double Pass

Three pass
Tray Types : Bubble Cap Trays
Used in low liquid flow operation
• Advantage
– Maximise gas liquid contact
– Better efficiency
– Wide range of operation
– Good turn down ratio

• Disadvantage
– Very high pressure drop
– High Fouling Tendency
Tray Types : Bubble Cap Trays
Type Of Trays : Sieve Trays

• Sieve trays
Sieve trays are simply
metal plates with holes
in them. Vapor passes
straight upward through
the liquid on the plate.
The arrangement,
number and size of the
holes are design
parameters.
Type Of Trays : Sieve Trays

 Advantage
– Simple in Operation
– Good Vapour Liquid Contact
– Good Efficiency

 Disadvantage
– Not suitable for variable loads
Type Of Trays :
Rh_GRID ~ Hyperstat Tray
 Minimization of
deposition of
scale on trays
due to Lateral
Sweeping
Action

Rh-Grid - Sweeping Action


Type Of Trays :
Rh_GRID ~ Hyperstat Tray
 Advantage
– Rugged construction
– Better Heat & Mass Transfer
– Useful for handling Mash with
suspended matters
– Minimization of deposition of scale on
trays due to Lateral Sweeping Action
 Disadvantage
– Lower efficiency
– Low Turndown
Basic Terminology of
Distillation Column
 Feed
 Rectification zone
 Stripping zone
 Reflux
 Feed tray
 Overflow weir
 Down-comer
 Calming Zone
 Dripping Zone/
Drip Holes
TECHNOLOGIES……

 ATMOSPHERIC DISTILLATION

 MULTIPRESSURE DISTILLATION
Atmospheric Distillation

Separation of Liquid Mixture(s) of


Different Components into its pure
components at (close to) atmospheric
pressure
Atmospheric Distillation
Vent to Atm
CWR
CWS

Distillation Column
FEED(H+T+P) Heads (H)
Alcohol (P)

Steam

Steam
Tails (T) Condensate
Multi-Pressure (MPR) Distillation

Separation of components with the


use of Pressure Cascading concept
to achieve Energy Saving by means
of Thermal Integration / Coupling
of Distillation Columns
Typical Ethanol Water X-Y Diagram

Common questions

Powered by AI

The efficiency of gas-liquid interaction in a distillation column is affected by the tray type due to differences in design and operational functionality. Bubble cap trays and Rh_GRID trays provide different mechanisms for interacting gas with liquid. Bubble cap trays offer simplicity and good contact, which results in efficient vapor-liquid mixing. Rh_GRID trays enhance heat and mass transfer with a rugged construction and are particularly beneficial for handling mash with suspended solids. On the contrary, sieve trays may be preferred for operations where simplicity and cost are priorities despite potential inefficiencies under variable loads .

Volatility relates to the separation of alcohol and water in a distillation column as it determines which component vaporizes initially. Alcohol is more volatile than water, meaning it has a lower boiling point and will vaporize first. This principle allows the distillation process to enrich alcohol in the vapor phase while water condenses, enabling effective separation based on the inherent volatility difference .

Tray columns are integral to the efficiency and performance of a distillation column by affecting contact and separation between the vapor and liquid phases. Different tray designs, such as bubble cap, sieve, and Rh_GRID, provide various benefits including maximized contact efficiency, accommodation of suspended solids, and handling of variable loads. Their design parameters, such as hole size and number, significantly influence vapor flow and, hence, the overall separation efficiency and throughput of the distillation process .

The latent heat of condensation is significant in the distillation process because it is the source of energy that facilitates the re-vaporization of more volatile components. For example, when water condenses on a tray, it releases latent heat, which is absorbed by alcohol, promoting its vaporization. This energy exchange enhances the efficiency of separation by progressively increasing the concentration of volatile components in the vapor phase, thus facilitating thorough separation in mixtures like alcohol and water .

The pressure difference in multi-pressure distillation allows for the separation of mixtures by exploiting the pressure cascading concept, which achieves energy savings through thermal integration and coupling of distillation columns. This technique maintains efficiency in separation by manipulating the pressure to enhance vapor-liquid equilibrium without significantly increasing system energy demand .

The Rh_GRID tray system offers benefits such as rugged construction, improved heat and mass transfer, and the ability to handle mixtures with suspended solids due to its sweeping action that minimizes scale deposition. However, it also has drawbacks, including lower efficiency and low turndown capability compared to other tray types .

Tray design significantly affects pressure drop and fouling within a distillation column. Tray types like bubble cap trays can induce a high pressure drop and are susceptible to fouling due to the intricate design and small passages. In contrast, sieve trays offer lower pressure drops because of their straightforward design but might not be suitable for variable loads, impacting operational versatility. Designs such as Rh_GRID trays minimize fouling through lateral sweeping action, maintaining operational efficiency despite potentially higher pressure drops compared to simpler tray designs .

Atmospheric distillation operates at or near atmospheric pressure, separating components based on differences in boiling points in a straightforward manner. It is typically used in scenarios where pressure manipulation is not required. In contrast, multi-pressure distillation utilizes pressure differences to enhance separation efficiency and achieve energy savings through thermal integration and coupling over multiple distillation columns. While atmospheric distillation may be less complex, multi-pressure distillation can offer better energy efficiency and improved separation in complex mixtures requiring more precise control .

The separation of components in distillation is facilitated by the differences in boiling points because the vapor of a boiling mixture is richer in components with lower boiling points. As the vapor is cooled and condensed, the resulting condensate contains more of the volatile components. In a mixture such as alcohol and water, alcohol has a lower boiling point and vaporizes first. As the vapor is cooled on the tray, water condenses, liberating latent heat. This heat is absorbed by the alcohol, causing further vaporization and enriching the vapor phase with alcohol while water enriches in the liquid phase at the base .

Bubble cap trays have several advantages, including good vapor-liquid contact and handling variable loads efficiently. However, they also present disadvantages such as higher cost compared to other tray types and a significant pressure drop across the tray .

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