POPUlATIONlNVE
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-What is Meant by Populationlnversion??
./ It is the condition required for light amplification.
./ Non-Equilibrium distribution of atoms among
various energy levels of the atomic system.
./ The Boltzmann distribution which
applies to the system in thermal equilibrium is.,
N . = gjN 0 exp (-Ej lkT)
1
Lg; exp(-E; l k T)
Where., Nj =Population Intensity of the
j1h energy level
If Ei increases Ni decreases with
constant tempurature
Populations oftwo level
energy systems
"At thermal equ ilibrium After population
!..
•
1 inversion 11as
been produced
Pumping
• If the energy difference between E 1 and E2 is equals to
kT(nearly 0.025eV at roo1n temp).
• Then the popu lation inversion of the upper level wou
ld be I/e(0.37) of that of the lower level.
• For large energy difference then visible radiation
wi ll be(2.0eV).tben popu lation of the upper level is
negligible.
• So to achieve popu lation inversion we need to supply
large an1ount of energy to excite atoms into E2.
This process n amed as "PUMPING".
Cont.
• This pwnping energy can be supplied by
using laser techno logies.
• Pumping produ ces the non-eqttilibrium
situation.
Attainment of population
• Main method usedinversion
to achieve this population
inversion is "stimulated absorption"
• The energy levels are pumped by intense
irradiation of the system.
• Assume g1 = g2 .then further absorption and
emissions are equal.(two level)
• For three level system proposed by
bloembergen. Initially it obeys boltzmann's law.
• If the collection of atoms is illumination the
electrons can be excited(i.e pumped) into E2 form E0 .
Cont.
• From E2 electrons decay by non-
radiative processes to the level E1 and
inversion created b/w E1 and E0 .
Population
Bohzn1ann distribution distribution after pumping
before pumping and the transitions
Cont.
• E2 to E1 =rapid transition.
• E1 to E0 =slow transition.(E1 is metastable
state)
• This will create the built-up of atoms in E1 then
population inversion achieved b/w E1 and E0 .
( N1 > No )
• Examples :ruby -requires very high pump
powers.
Four level system
Before pumping After pumping
Cont.
• It has less pumping requirements.
• If ( E1 - E0 ) is very large compare to kT then
populations at E1 , E2 and E3 are very small at
thermal equilibrium.
• If atoms pumped to E3 from ground state from
rapid transition occur to E2. population inversion
achieved b/w E2 and E1 .
• If lifetime is short between E3 -7 E2 and E1 -7 E0
are short population inversion maintained between
E2 &E1 .
Otherways to achieve
• Optical pumping pumping
• Electrical discharge or electron bombardment.
• The release of chemical energy.
• The passage of current.