CHAPTER –
4
1. Introduction
Source
2. Models
Flow of Liquid
1. through a hole
2. through pipes
3. 2-K Method,
4. Flow of Vapor through holes
5. Flow of gases through pipes
1. Adiabatic Flows,
2. Isothermal Flows,
6. Flashing Liquids,
7. Liquid Pool Evaporation or
Boiling,
8. Realistic and Worst-Case
Releases.
4.1
Introduction
▶ Most accidents in chemical plants result in spills of toxic,
flammable,
and explosive materials.
▶ Accidents begins with an incident which usually results in the
loss of materials from the process
▶ Typical incidents might include the rupture or break of a
pipeline, a hole formation in a tank or pipe, runaway reaction
(increase in reaction rate & liberate heat or pressure), fire
external to the vessel etc..
▶ Once the incidents are known, source models are selected to
describe how materials are discharged from the process
▶ Source models are an important part of the consequence
modeling
procedure
▶ This model describes rate of discharged, total quantity
discharge, and state of the discharge
▶ Source models are constructed from fundamental or empirical
equations representing the physico-chemical processes
occurring during the release of materials
▶ Release mechanisms are
classified into wide
and limited aperture
releases
▶ In wide aperture case, large hole
release large quantity in short time
eg. Explosion of storage tank
▶ Limited aperture releases slowly
for long time
▶ The following figure
conceptualized limited aperture
release
▶ For these releases material is
ejected from holes and cracks in
tanks
and pipes, leaks in flanges, valves,
and pumps, or ruptured pipes.
▶ Relief systems, designed to
prevent the over pressuring of tanks.
• For gases or vapors stored in a
tank, a leak leads to a jet of gas
or vapor.
• For liquids, a leak below the
liquid level in the tank causes a
stream of escaping liquid.
• If the liquid is stored under
pressure above its atmospheric
boiling point:
• A leak below the liquid level will
result in a stream of liquid that
partially flashes into vapor.
• Small liquid droplets or aerosols
might form from the flashing
stream.
• Wind currents can transport
these droplets or aerosols away
from the leak.