Procedure for
Testing Chloride
Ions
PRESENTED BY: M. KHURRM RASHEED
Materials Required
- Silver nitrate (AgNO₃) solution (0.0141 M)
- Potassium chromate (K₂CrO₄) solution (5% w/v)
- Burette, stand, and conical flask
- Measuring cylinder and pipette
- Distilled water
- Water samples
Simple Procedure
1. Collect and filter water samples.
2. Rinse and fill the burette with silver nitrate.
3. Pipette 25.0 mL of the sample into a conical
flask.
4. Add 2-3 drops of potassium chromate
(indicator).
5. Titrate with silver nitrate until the solution turns
reddish-brown.
6. Record the volume of silver nitrate used.
Calculation
Use the formula:
Chloride (mg/L) = [(Volume of AgNO₃ (mL) ×
Mᴀɢɴᴏ₃ × 35.45) / 25.0] × 1000
Example: If 12.5 mL of AgNO₃ is used:
Chloride (mg/L) = [(12.5 × 0.0141 × 35.45) /
25.0] × 1000 = 249.9 mg/L
Precautions
- Use clean glassware to avoid contamination.
- Perform multiple titrations for accurate results.
- Avoid over-titration and record observations
carefully.
Conclusion
- Chloride concentration reflects water quality.
- Mohr's Method provides reliable results.
- Regular testing ensures environmental and
public health safety.