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Inert Gas Composition and Safety Protocols

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0% found this document useful (0 votes)
19 views47 pages

Inert Gas Composition and Safety Protocols

Uploaded by

nareshh62
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPT, PDF, TXT or read online on Scribd

INERT GAS - BASIC

Prepared by: C/E Naresh Sharma

Please switch off your mobile phones.

1
IMO-MARPOL/SOLAS PROTOCOL 1978
REQUIRES:

 Where any explosive mixtures can be


formed inside cargo spaces, due to the
presence of oxygen from air , air should
replaced by inert gas.

2
INERT GASES

• HELIUM
• ARGON
• KRYPTON TRUE INERT GASES
• NEON
• RADON
• XENON

These are ruled out of the petroleum trade


due to prohibitive cost.
3
 The Sámi-inert gases :

 Nitrogen :

 is employed with certain cargos;


 however this gas is also expensive to
produce.

4
• Carbon Dioxide :

• It has the disadvantage of generating


an intense electrostatic field when
injecting into a compartment and when
dissolved with water produces a weak
corrosive acid.

5
THE PURPOSE OF INERT GAS

To prevent a flammable atmosphere

in the tank where hydrocarbon

gases are present.

6
THE PURPOSE OF INERT GAS

• Purging tanks prior to gas freeing (if required).

• Purging tanks prior to loading (if required).

• Replacing cargo during discharge.

• Blanketing usage spaces.

• Topping up during voyage.

7
GAS REQUIREMENTS

• Oxygen content

< 1% - LNG, LPG, Chemical tankers.

< 5% - Crude oil tankers, Combination


carriers, Product carriers.

8
• THE DESIGN OF ANY I.G. PLANT
Must posses the following safety precautions:

• Prevent the passage of hot, unwashed and wet


gases to the deck main.

• Prevent the return of H/C vapors to the safe zone.

• Be capable of maintaining a positive pressure in


the cargo tanks, regardless of cargo or ballast
discharge rate.

• Be incapable of over pressurizing the cargo tanks.


9
Fundamental design principles:
Basic requirements;

• I.G. Source,

• Boiler flue valve at the uptake,

• Scrubbing tower
(Cooling 140-900, 90-600, cleaning So2-90%)
(spray nozzles, trays of packed stones or plastic chippings, perforated
impingement plates, venture nozzles and slots).

• Demister unit.
polypropylene mattresses or cyclone dryers.
10
• Two electric or steam driven IG blowers
(together 125% of the max. rate of cargo discharge capacity, by
volume).
with isolating valves & water washing system,

• Means of;
 stabilizing plant on start up,
 maintaining min. I.G. flow through scrubber (venting / re-
circulating),

• A liquid non return device.

• A mechanical non return device.


11
• Deck main & branches
to deliver I.G. to various tanks.

With;
 (A) isolating valves for each tank.

 (B) drains at suitable locations.

 (C) vent line & valve between regulating &


N/R valve.

12
• Means to prevent excessive pressure or
vacuum build up.

• ‘U’ – Seals and siphon breakers


(scrubber tower effluent line, deck seal
drain line and any other line)

13
14
15
16
17
Sources:
• up take from ships main or auxiliary boilers;

• an independent inert gas generator;


• a gas turbine plant when equipped with an
afterburner.
• a diesel engine fitted with after burner.

Quality:
• A good combustion control to achieve O2 content
below 5% by volume.

18
Methods of gas replacement:

1. inerting 2. purging 3. gas freeing

• In each case one or two processes can


predominate:

• dilution – dilution process;

• displacement – layering process

19
20
22
Inert Gas Generator:

• was originally developed to supplement the CO2


flooding system.

• In tankers it is used as an independent unit for inerting


the cargo tanks.

• The cylindrical shaped, brick lined, horizontally


arranged, furnace is surrounded by a water jacket.

• This is connected to vertical combustion chamber,


where the gas flow is baffled, cleaned and cooled.
23
• Usually a water cooled engine is arranged, to drive fuel pump ,
air blower & an electric generator for s/w pump, which is usually
located at the fwd end of the shaft tunnel.

• This pump can be connected to deck fire line & used


as emergency fire pump.

• Cooling water can also be supplied from ballast &


general service pump in the engine room.

• the control panel has CO2 recorder, water & fuel pr


ggs & alarms.

• Approximate analysis of gas:-


O2--- 0-1%, CO--- Nil, CO2--- 14-15%, N2--- 85%24
Cargo tank atmosphere control:

• tanks shell be in inert condition whenever they


contain cargo residuals or ballast,

• O2 < 8% by volume, with +ve pressure.

• the tank atmosphere transition from inert to gas-


free condition, should be without passing through
flammable condition.
Purging

26
SULPHUR DIOXIDE (SO2)
• SO2 combines with water (H2O) and forms
Sulphurous acid (H2SO3) when hot, and causes.

• SO2 + H2O = H2SO3

• Sulphor trioxide (SO3) at temperature 90oC & 140 oC


combines with water to form Sulphuric acid.

• SO3 + H20 = H2SO4 (Sulphuric acid)


Which is not only corrosive, but a very stable
acid and unlike Sulphurous acid which decomposes
back in to SO2 & H2O when it cools.

• Therefore the amount of water required, depends


up on the amount of SO2 & SO3 gases produced. It
varies from about, 11-14 lts /m3 of gas to be
dessolved.
Non return devices:
 to prevent back flow of cargo vapor to machinery
space, specially when I.G. plant is shut down,

 Water supply must be maintained all the time in deck


water seal,

 A low level alarm shell be provided, before the seal


is rendered ineffective.

 Regular operation & maintenance of mechanical N/R


valve is important.
Drawback;
carry over of water droplet, leads to increased
corrosion. 29
30
Better design
31
Risk of automation failure
Liquid filled P-V valves:
• These are fitted if other P-V valves are not of adequate
capacity, to prevent excessive pressure or vacuum in the
tanks & I.G. pipes.

• The correct level & density of liquid is important.

• Suitable oil or fresh water & glycol mixture to be used to


prevent freezing.

• In heavy weather the liquid p-v valve may get blown out
due to pressure surge caused by motion of liquid cargo.

• The level or pressure setting should be in accordance with


low & high I.G. pressure alarm setting.
34
35
FLAME SCREENS:
Fitted on p/v valves and at the inlets & outlets of any relief
devices.

For flame screens to be effective:


- Mesh holes shall not be larger than original one.

- must be properly mounted on its support, without any


gaps around the edges.

- The matting surfaces must be free of dirt, scale &


corrosion.
OPERATIONS – [Link]
• Start-up procedures: Ensure;

• Boiler producing sufficient flue gas with less than 5%


oxygen content.

• Power available to all controls, alarms and auto shut-


down operations.

• Deck seal & scrubber water lines are prepared and


supply is adequate. Ttest the alarms & shut- down.

• Gas freeing fresh air inlet valves (if fitted) are shut and
the blanks in position are secured.

• Air to any air sealing arrangements for the flue gas


isolating valve is shut off.
• Open flue gas isolating valve.

• Open selected blower suction valve, ensure other blower


suc. & disch. vvs are shut unless both blowers are to be
run.

• Start the blower & test blower failure alarm.

• Open blower discharge valve.

• Open re-circulating valve to stabilize the plant.

• Open flue gas regulating vv, vent the gas to atmosphere till
oxygen in flue gases reached below 5%. ( some O2
analyzer may take 2 hrs to stabilize).

• Shut the vent vv b/w gas reg. vv & deck isolating vv.
Deck
• Open drain cocks in I.G. deck lines to drain
condensates.

• Check P/V vvs, free movement and correct


adjustment.

• Check P/V breakers liquid level is correct.

• Check deck seal water level and ensure o/b vv is


fully opened.

• System is now ready to deliver inert gas to cargo


tanks.
Shut down procedures:
• When all tank atmosphere have reached to less than 8% of
oxygen and have adequate pressure, shut deck isolating/
non return valve.

• Open the vent b/w gas pr. reg. vv & deck isolating / n/r vv.

• Shut gas pr. reg. vv.

• Stop the blower, shut suction & disch. vv, check drains are
clear and carry out blower water wash with fresh water.

• Shut flue gas isolating vv, open air sealing system.

• Keep full water supply to the scrubber in accordance to the


instructions, flush through the scrubber with fresh water
after stopping scrubber pump.
Possible failure and actions to be taken:
High oxygen contents:-
• Poor combustion control (low load condition).

• Air drawn down from boiler up take, lower gas pr. to blower demand
(low load conditions).

• Air leak b/w boiler up take & blower.

• Faulty operation or calibration of oxygen analyzer.

• Plant running on re-circulation mode.

• Air entering through PV vv, mast risers, etc., due to maul- operation.

All cargo operations to be suspended unless the fault is identified,


repaired and O2 obtained less than 5% in system and 8% in the cargo
tanks.
Monitoring

No. Failure Automatic Comments


Alar
shutdown of
m
system
High content of O2
1 X 8 % by volume
in the inert gas main
Low gas pressure in
2 X 100 mm W.G
the inert gas main
High gas pressure, in
3 X
the inert gas main
Automatic stop
High water level in Of scrubber sea
4 X X
the gas scrubber water pump
included
Monitoring

No. Failure Automatic Comments


Alar
shutdown of
m
system
Failure in water
5 supply to gas X X
scrubber
High temperature
6 X X
after gas scrubber
Loss of sealing
7 X
water In water seal
Failure of Inert gas Closing of the
8 X
blower/s Control valve
Instrumentation
9 X X
Power failure
Some incidences
1. Flooding of scrubber and flue gas uptake;
• Reason: failure of opening overboard vv.
• Damages: electrical switch board and transformer were
blown off.
• Loss: repair and off hire.

2. Water in cargo tanks through I.G. main;


• Reasons;
• (a) Deck seal o/board was blocked.
• (b) Blower auto f/w wash solenoid vv was leaking.

3. Fire in scrubber;
• Reason; Demister burnt due to hot gases as water
nozzles were blocked.
• 4. High O2 %,
• (a) Air was being sucked in from I.G. inlet pipe to
scrubber, as a large dia hole was created due to
internal corrosion.
• (b) Poor combustion due to low atomizing steam
and that was due to worn out fuel pump as it
was used for burning the sludge.
• 5. Low O2 %,
• Reason; Blocked sampling line / filters.

• 6. High H2S, Reason was high sulpher content


in fuel oil. Boiler was changed over to diesel oil
and problem was solved.
47

Common questions

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Key measures for ensuring inert gas quality include implementing good combustion control for low oxygen content, conducting regular equipment maintenance to prevent leaks or failures, and using distinctly designed non-return devices and scrubber systems to remove unwanted gas components and maintain pressure levels .

Inert gases minimize the risk of explosive mixtures in cargo spaces by displacing oxygen, a required component for combustion, thereby preventing flammable atmospheres. By maintaining an oxygen content below certain thresholds (e.g., <1% for LNG, LPG tankers; <5% for crude oil tankers), the inert gas system ensures that the tank environment remains safe .

Starting up an inert gas system involves ensuring a sufficient flue gas supply with less than 5% oxygen, adequate power, and water line preparations. Procedures include opening specific valves, starting blowers, and stabilizing gas flow. For shutdown, it involves ensuring oxygen levels in tanks are adequate, closing specific valves, stopping blowers, and performing maintenance like water washes .

Automation failures in inert gas systems can lead to unmanaged oxygen levels, incorrect valve operations, and insufficient gas delivery, potentially resulting in flammable atmospheres. These failures necessitate backup systems and regular maintenance to mitigate safety hazards .

Maintaining optimal inert gas composition involves challenges like controlling combustion processes to ensure low oxygen content, preventing air ingress, and dealing with equipment malfunctions. Accurate monitoring and quick rectifications are critical, as deviations can lead to increased explosion risks or corrosion due to high O2 levels or SOx content .

Carbon dioxide poses challenges when used as an inert gas due to its tendency to generate an intense electrostatic field during injection and to form a weak corrosive acid when dissolved in water, which can complicate maintenance and equipment integrity .

Liquid-filled P/V valves are used to prevent excess pressure or vacuum in tanks and inert gas pipes. The correct level and density of liquid, typically oil or a glycol mixture, is crucial to function effectively and prevent freezing. These valves are particularly important in heavy weather to absorb pressure surges and prevent system disruption .

An effective inert gas plant must prevent the passage of hot, wet gases to the deck, prevent hydrocarbon vapor return, maintain positive tank pressure, and avoid over-pressurizing tanks. It should include components like a scrubber tower for cooling and cleaning gases, demisters, non-return devices, blowers, and a deck main with isolating valves for each tank. Safety features also include preventing excessive pressure or vacuum build-up, and ensuring reliable operation through devices like 'U' seals and siphon breakers .

The design of an inert gas generator, including components such as a water-jacketed furnace, vertical combustion chamber, and baffle systems for cleaning gases, directly impacts its efficiency in producing low-oxygen gas. The generator must handle heat dissipation and corrosion resistance, critical to effective tanker operations .

Failures in inert gas systems can lead to dangerous conditions like high oxygen content or pressure issues. Common failures include poor combustion, air leaks, faulty oxygen analyzers, and equipment breakdowns such as blower or scrubber malfunctions. The consequences can include unsafe tank conditions, risk of explosion, physical damage, and operational shutdowns .

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