Chemical Names and
Formulas
Overview
•Metals and Non-Metals
•Ions and Ionic Charges
•Types of Compounds
•Systematic Names
-Writing Names and Formulas
Naming Compounds Tutorial
General Information
Binary Ionic Compounds
Ternary Ionic Compounds/Poly-atomic Ions
Naming w/metals that have more than 1 cha
rge (Transition Metals)
Molecular Compounds
Naming Acids
Metals and Nonmetals
Stairway Of Division on Periodic Table
C, P, Se, I, Rn and to the right are non-
metals
B, Si, As, Ge, Sb, Te, Po, At are semi-
metals
All others are metals
Ions
Cations Anions
Positively Negatively
Charged Charged
Atoms Atoms
i.e. Na+ -
i.e. Cl
IONIC CHARGES
Group I -> 1+
Group II -> 2+
Group III -> 3+
Group IV -> 4+
IONIC CHARGES
Group V -> 3-
Group VI -> 2-
Group VII -> 1-
Group VIII -> Noble Gases
TYPES OF COMPOUNDS
Ionic Compounds
• composed of positive and
negative ions.
• usually formed from a metal and
non-metal.
• these elements are not attached
to one another.
TYPES OF
COMPOUNDS
Ionic Compounds con’t
• Examples
NaCl
CaBr2
KI
CHEMICAL FORMULAS
Definition
• shows the kind and numbers of
atoms in the smallest
representative unit of the
substance.
i. e.
NaCl
IONIC COMPOUNDS
A formula unit is the lowest
whole number ratio of ions in an
ionic compound.
i.e.
i.e. Na2Cl2 -> NaCl
There is no such thing as a
molecule of NaCl!!!!!!!!!
IONIC COMPOUNDS
If charges cancel, just write the symbols
Na+1 Cl-1 NaCl
If charges do not cancel, criss-cross:
Ca+2 Cl-1 CaCl2
***Do not move the charge, only the
number
***Do not write the 1
NAMING
COMPOUNDS
Your ability to name compounds
and write formula’s hinges on
your ability to recognize whether
a compound is Ionic or
Molecular.
BINARY IONIC
COMPOUNDS
Binary means 2 elements
Ionic means a metal and a non-
metal (or cation and anion)
Writing Formulas
• charges must balance so
compound charge is neutral.
BINARY IONIC
COMPOUNDS
Writing Formulas from Names
• 1st word = CATION
• 2nd word = ANION name
with ide
ending.
BINARY IONIC
COMPOUNDS
NaBr Sodium
Bromide
MgF2 Magnesium
Fluoride
BINARY IONIC
COMPOUNDS
Potassium
K+Cl- -> KCl
Chloride
Aluminum
Al23+O32- ->
Oxide
Al2O3
• notice ending
of name is ide!
Polyatomic Ions
Definition •tightly bound
groups of atoms that behave as
a unit and carry a charge.
2-
Example SO3 , NO2 , ClO2
- -
TERNARY IONIC
COMPOUNDS
Ternary means 3 different
elements
Usually contain Poly-atomic
Ions
Ionic means cation and anion
TERNARY IONIC
COMPOUNDS:Writing
Formulas
Ca2+CO 2-
Calcium
3
CaCO3 Carbonate
Charges canceled.
Just write the symbols
TERNARY IONIC
COMPOUNDS: Naming
Calcium Ca+2 (NO3)-1
Nitrate
Notice the charges didn’t
cancel so they criss crossed
Ca(NO3)2
Naming with Transition
Metals
First word = CATION
Second word = ANION
– The Roman numeral will tell you the
charge of the transition metal
– Silver (Ag) is an exception. It’s
charge is +1
Naming Transition
Metals
Copper (I) Cu+1 O-2
Oxide
Cu O
2
Writing Formulas with
Transition Metals
FeCl Iron (III)
3
Fe Cl+3 -1 Chloride
FeCl Iron (II)
2
Fe +2
Cl -1 Chloride
*Backwards criss-cross to know the charge/Roman numeral
TYPES OF
COMPOUNDS
Molecular Compounds
• composed of molecules in
which elements share
electrons.
• usually composed of 2
nonmetals.
• these elements are attached
MOLECULAR
FORMULA
Definition
• shows the numbers and
kinds of atoms present in a
molecule of a compound.
i. e.
CO
TYPES OF
COMPOUNDS
Molecular Compounds con’t
•Examples
CS2
SiO2
BF3
BINARY MOLECULAR
COMPOUNDS
Binary means 2 elements
Molecular means 2 non-
metals
NO ionic charges are
present
Naming Binary
Molecular Compounds
Prefixes are used to show how
many atoms are present in each
molecule.
Covalent Prefixes
Mono (or no prefix) – Hexa – 6
1 Hepta – 7
Di – 2 Octa – 8
Tri – 3 Nona – 9
Tetra – 4 Deca – 10
Penta – 5
Writing Binary
Molecular Compounds
CO
2
Carbon
Dioxide
•no mono • Di means 2
prefix is used on oxygens!!
first element
Naming Binary
Molecular Compounds
2 ways it’s done!
• (prefix + element name)
i.e. N2O
dinitrogen monoxide
Naming Binary
Molecular Compounds
• (prefix + element root + ide)
i.e. PCl3
Phosphorous Trichloride
All binary compounds end in
ide!!!