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Basic Chemistry Concepts and Bonding

The document provides an overview of basic chemistry concepts including: 1) It defines key terms like elements, compounds, molecules, atoms, protons, neutrons, electrons and isotopes. 2) It describes the structure of an atom including the nucleus containing protons and neutrons, and electrons in shells. 3) It explains electron configuration and the octet rule where atoms gain, lose or share electrons to have 8 in their outer shell.

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0% found this document useful (0 votes)
19 views55 pages

Basic Chemistry Concepts and Bonding

The document provides an overview of basic chemistry concepts including: 1) It defines key terms like elements, compounds, molecules, atoms, protons, neutrons, electrons and isotopes. 2) It describes the structure of an atom including the nucleus containing protons and neutrons, and electrons in shells. 3) It explains electron configuration and the octet rule where atoms gain, lose or share electrons to have 8 in their outer shell.

Uploaded by

corygunther6451
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPT, PDF, TXT or read online on Scribd

Basic Chemistry

Chemistry Warm-Up
a. Compound 1. negatively charged sub-atomic particle
2. A charged particle
b. Molecule 3. Positively charged sub-atomic particle
c. Proton 4. Contains protons and neutrons
d. Neutron 5. 2 or more atoms bonded together
6. Atoms of different elements bonded
e. Electron together
f. Ion 7. Neutral sub-atomic particle
g. Isotope 8. Atoms with equal # of protons, but different
# of neutrons
h. Atom 9. The smallest particle of an element
i. Element 10. Substance composed of 1 type of atom
j. Nucleus
Matching Answers
a. Compound - Atoms of different elements bonded together (6)
b. Molecule - 2 or more atoms bonded together (5)
c. Proton - Positively charged sub-atomic particle (3)
d. Neutron - Neutral sub-atomic particle (7)
e. Electron - negatively charged sub-atomic particle (1)
f. Ion - A charged particle (2)
g. Isotope - Atoms with equal # of protons, but different # of
neutrons (8)
h. Atom - The smallest particle of an element (9)
i. Element - Substance composed of 1 type of atom (10)
j. Nucleus - Contains protons and neutrons (4)
Atom – the smallest unit of matter “indivisible”

Helium
atom

Contains 3 sub-atomic
particles
Protons ( p+): Mass = 1
Neutrons (N0): Mass = 1
Electrons (e-): Mass = 0
Atom
Atomic Number - # of
protons in an atom
Atomic Mass - # of protons
and neutrons in an atom.

Atomic #
6

C
Carbon
Chemical Symbol
Atomic mass 12.001
Learning Check
• Look at your Periodic Table and determine
the number of protons, neutrons, and
electrons for the following atoms:
• Nitrogen
• Lithium
• Hydrogen
• Fluorine
What are living things made of?
Why do we need these?

These atoms make up the molecules of life. Many act as


vitamins and minerals, help our cells carry out important
reactions.
Isotopes – Who Cares?!

• Same # protons (same element, same exact chemical


behavior)
• different # neutrons
• Some isotopes are radioactive – Nucleus is unstable.
Spontaneously gives off energy (radiation)
Isotopes
• Medical Uses
• Tracers and Labels
• Ex: Iodine 131 – Behaves exactly like I127.
Moves through human body and accumulates in
thyroid. Half-life of 8 days. Gives off energy,
so presence can be detected.
• Ex: PET scan
Isotopes
• Half-Life: Time it
takes for ½ atoms
in a sample to
decay
• Can be used to
determine age of
rocks, fossils, etc.
• Carbon-14 is
radioactive. ½ Life
= 5,730 years.
Electron Shells
a) Atomic number = number of Electrons

b) Electrons vary in the amount of energy


they possess, and they occur at certain
energy levels or electron shells.

c) Electron shells determine how an atom


behaves when it encounters other atoms
Electrons are placed in shells
according to rules:
1) The 1st shell can hold up to two electrons,
and each shell thereafter can hold up to 8
electrons.
2) “The Octet Rule”: Atoms will gain or lose
electrons in order to have a filled outer
shell. (Most stable state)
Predict: How many electrons will these atoms lose/gain?
Octet Rule = atoms tend to gain, lose or share electrons so
as to have 8 electrons
C would like to Gain 4 electrons
N would like to Gain 3 electrons
O would like to Gain 2 electrons
Why are electrons important?
1) Elements have different electron configurations
 different electron configurations mean different
levels of bonding (and different chemical properties)
Electron Dot Structures
Symbols of atoms with dots to represent the valence-
shell electrons

1 2 13 14 15 16 17 18
H He:
      

Li Be  B  C  N  O :F :Ne :


    

      

Na Mg   Al  Si   P  S :Cl  :Ar :


    
Learning Check

A. X would be the electron dot formula for
1) Na 2) K 3) Al

B. X would be the electron dot formula

1) B 2) N 3) P
The Periodic Table of the Elements

Dmitri Mendeleev
The Periodic Table
• A map of the building block of matter.
1 18
IA VIIIA
1 H
1 2
IIA
Periodic Table 13
IIIA
14
IVA
15
VA
16
VIA
17
VIIA He
2

1.00797 4.0026
3 4 5 6 7 8 9 10
2 Li Be B C N O F Ne
6.939 9.0122 10.811 12.0112 14.0067 15.9994 18.9984 20.179
11 12 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
3 Na Mg IIIB IVB VB VIB VIIB VIIIB IB IIB Al Si P S Cl Ar
22.9898 24.305 26.9815 28.086 30.9738 32.064 35.453 39.948
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.102 40.08 44.956 47.90 50.942 51.996 54.9380 55.847 58.9332 58.71 63.54 65.37 65.37 72.59 74.9216 78.96 79.909 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.905 91.22 92.906 95.94 [99] 101.07 102.905 106.4 107.870 112.40 114.82 118.69 121.75 127.60 126.904 131.30
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.905 137.34 138.91 178.49 180.948 183.85 186.2 190.2 192.2 195.09 196.967 200.59 204.37 207.19 208.980 [210] [210] [222]
87 88 89 104 105 106 107 108 109
7 Fr Ra Ac Ku [Link]
[223] [226] [227] [260]
Layout of the Periodic Table:
Metals vs. nonmetals

1 18
IA VIIIA
2 13 14 15 16 17
1 IIA IIIA IVA VA VIA VIIA

3 4 5 6 7 8 9 10 11 12
3 IIIB IVB VB VIB VIIB VIIIB IB IIB

4
Nonmetals
5 Metals
6

7
Across the Periodic Table
Periods: Horizontal rows (1-7)
These elements have the same number of valence shells.
1 18
IA VIIIA
2 13 14 15 16 17
1 IIA IIIA IVA VA VIA VIIA

2
2nd Period
3 4 5 6 7 8 9 10 11 12
3 IIIB IVB VB VIB VIIB VIIIB IB IIB

4
4th Period
5
All of these have 4 energy levels

7
Down the Periodic Table
•Family: Are arranged vertically down the periodic table
(columns or group, 1- 18 or 1-8 A,B)
•These elements have the same number of valence electrons

1 18
Alkali
IA VIIIA
2 Alkali
AlkaliFamily:
Family: 13 14 15 16 17
Halogen
1 IIA IIIA IVA VA VIA VIIA
11e-e-ininthe
thevalence
valenceshell
shell
2

3 4 5 6 7 8 9 10 11 12
3 IIIB IVB VB VIB VIIB VIIIB IB IIB

4
Halogen
HalogenFamily:
Family:
5 77e-e- ininthe
thevalence
valenceshell
shell

7
Periodic Table: electron behavior
• Elements in the periodic table can be classified by the behavior of their electrons

West (South) Mid-plains East (North)


METALS METALLOID NON-METALS
Alkali Noble gas
Metals
Alkaline Metaloids Non-Metals Halogens
Transition Calcogens
These elements These elements These elements
-
tend to give up will give up e or tend to accept
e - and form accept e -
e - and form
1
CATIONS ANIONS 18
IA VIIIA
2 13 14 15 16 17
1 IIA IIIA IVA VA VIA VIIA

3 4 5 6 7 8 9 10 11 12
3 IIIB IVB VB VIB VIIB VIIIB IB IIB

7
Learning Check

A. Number of valence electrons in aluminum


1) 1 e- 2) 2 e- 3) 3 e-

B. Change in electrons for octet


1) lose 3e- 2) gain 3 e- 3) gain 5 e-

C. Ionic charge of aluminum


1) 3- 2) 5- 3) 3+
Atomic Bonding
• Atoms can form several types of
bonds
• Covalent
• Ionic
• Hydrogen
• Molecules - Atoms covalently
bonded together
• Compounds – Atoms of different
elements bonded together
Ionic Bond
• Between metals and nonmetals
• Bond formed by transfer of electrons
• Produce charged ions
• Examples; NaCl, CaCl2, K2O
1). Ionic bond – electron from Na is transferred to Cl,
this causes a charge imbalance in each atom. The Na
becomes (Na+) and the Cl becomes (Cl-), charged
particles or ions.
I want more
electrons
Covalent Bond
• Between 2 nonmetals
No I want
• Formed by sharing electron more
electrons!
pairs
• Examples; O2, CO2, C2H6,
H2O, SiC Let’s share
2. Covalent bonds- Two atoms share one or more pairs of
outer-shell electrons.

Oxygen Molecule (O2)


Water Molecule (H2O)
There are other ways of representing covalent
bonds.
Quick Check Question
• For each of the following element pairs,
determine whether a covalent bond or an
ionic bond is likely to form.
• K and S
• Be and F
• Li and I
• O and O
Any Questions?
• Next we will make some paper molecules.
Each group will make a different molecule
or compound so that we can see a variety.
• CO2, H2O, CH4, O2, N2, NH3, H2, LiF, HCl
• Step 1: Determine the type of bond in each
molecule/compound
• Step 2: Cut out the atoms and electrons you
will need and glue them onto construction
paper
• Color and label
NONPOLAR
COVALENT BONDS
when electrons are shared equally

H2 or Cl2
2. Covalent bonds- Two atoms share one or more pairs of
valence electrons.

Oxygen Molecule (O2)


Aside from single covalent bonds, double, or
triple covalent bonds can form.

A double bond… how many electrons are shared?


4e-

A triple bond…. How many electrons here? 6e-


POLAR COVALENT
BONDS
when electrons are shared
but shared unequally

H2O
- water is a polar molecule because oxygen is more
electronegative than hydrogen, and therefore electrons
are pulled closer to oxygen.
Hydrogen Bonds

Partially charged ends of polar molecules are attracted to


neighboring molecules. Gives water its special properties.
Water and Living Things
• Water is the most abundant molecule in
living things.
• Water has special traits that make it
important to life.
Properties of Water
• Hydrogen bonding between polar
molecules causes water to “stick together”
• Adhesion
• Cohesion
• Capillary Action
• Surface Tension
• Excellent Solvent
• High Specific Heat
• Frozen water is less dense so ice floats
Properties of Water

Adhesion

Surface Tension

Cohesion
Capillary action helps carry water to the tops of tall trees
Water expands as it freezes
Why is this important for life?

Ice Water Steam


Water as a Solvent
Chemical Reactions
• Involves making and breaking chemical
bonds
• Necessary for cells
• Build molecules for growth and maintenance
• Store/release energy
• metabolism
Chemical Reactions
• Forming and breaking of bonds.
• Necessary for cells
• Build molecules for growth and maintenance
• Store/release energy
Reactants Products
Breakdown of H2O:
Electrical energy
Balanced equations:
2H2O 2H2 + O2 represents conservation
of matter!
Photosynthesis:
Light energy
6H2O + 6CO2 C6H12O6 + 6O2
Ions
• Salts dissociate in water – result is ions
• NaCl  Na+ and Cl-
• Polar H2O molecules attract, dissolve ions
pH
• Ionization: non-polar
molecules are converted
to ions
H2O  H+ and OH-

• In a sample of water, a
small percent of
molecules are always
ionized
pH
• Levels of H+ and OH in solution rated using
pH scale.

• Equal H+ and OH-  pH of 7 (ex: pure


water)
• Logarithmic scale – each level has 10x
more H+ or OH- than previous
• Acids are molecules that release
hydrogen ions in solution.

HCl  H+ + Cl-
• Bases are molecules that either take up
hydrogen ions or give off hydroxide ions
in solution.

NaOH  Na+ + OH-


• Water dissociates and releases hydrogen
ions (H+) and hydroxide ions (OH-).

An equal number of H+ and OH-


So that’s why water is neutral!
pH
• Crucial to living things.
• Enzyme Function
• Acidic stomach, Alkaline intestine
• Blood pH = 7.4
• Buffers in living things help resist pH change
• Buffers are substances that help to resist change
in pH.

Common questions

Powered by AI

The electron configuration of an atom, which refers to the distribution of electrons in an atom's electron shells, significantly influences its chemical properties. Different electron configurations result in different levels of bonding and therefore variation in chemical reactivity . The Periodic Table is arranged in such a way that elements with similar electron configurations, particularly those with the same number of valence electrons, are grouped together in columns known as groups or families. This means that elements in the same group typically exhibit similar chemical properties .

The concept of electron shell filling explains the formation of ions and chemical bonding through the tendency of atoms to achieve a full outer shell, typically conforming to the 'octet rule,' which states that atoms are most stable with eight valence electrons . Atoms will gain, lose, or share electrons to achieve this stable configuration. For example, metals will often lose electrons to empty their outer shell, forming positively charged ions, while nonmetals tend to gain electrons to fill their outer shell, forming negatively charged ions. This electron transfer or sharing results in the formation of ionic or covalent bonds, respectively .

Valence electrons, the electrons in the outermost shell of an atom, play a crucial role in determining both the placement of elements in the Periodic Table and their chemical reactivity. Elements are arranged in groups based on the number of valence electrons, which dictates their chemical behavior and tendency to form certain bonds . For example, elements in the same group, such as the alkali metals with one valence electron, exhibit similar reactive properties and are placed vertically in the table. The chemical reactivity of an element is largely determined by its desire to achieve a stable electron configuration, often leading to gaining, losing, or sharing electrons to fulfill the octet rule .

Isotopes play a significant role in medical applications, particularly in imaging and treatment. An example is Iodine-131, which behaves like the more common Iodine-127 but has a radioactive component that allows for tracking within the human body. It accumulates in the thyroid gland and can be used as a tracer to diagnose thyroid conditions due to its detectable radiation . Additionally, isotopes like Carbon-14 and those used in PET scans provide critical insights into bodily functions and structures, allowing for advanced diagnostic capabilities in medicine . Their applications stem from isotopes' ability to emit radiation, making them valuable in both tracking and treatment scenarios. Furthermore, isotopes are used in cancer treatments to target and destroy tumor cells while minimizing damage to surrounding healthy tissues.

The Periodic Table plays a crucial role in predicting chemical reactions and bonding patterns by categorizing elements based on their atomic number, electron configurations, and valence electrons. Elements in the same group exhibit similar valence electron configurations, leading to predictable bonding patterns and chemical reactivity. For instance, alkali metals in Group 1 have one valence electron, making them highly reactive and prone to losing that electron to form ionic bonds, typically with halogens, which need one additional electron to achieve an octet . The table also helps identify elements that might form covalent bonds, as nonmetals tend to share electrons to achieve stable configurations . By observing trends across periods and groups, chemists can predict how an element will likely react or bond with others.

Water's unique properties that are crucial for life include cohesion, adhesion, surface tension, high specific heat, and its status as an excellent solvent. These properties are primarily influenced by hydrogen bonding, which occurs because water molecules are polar, with the oxygen atom being more electronegative and attracting shared electrons more than hydrogen atoms . Cohesion allows water molecules to stick together, evidenced by surface tension, while adhesion helps them stick to other surfaces, both essential for capillary action in plants . High specific heat allows water to stabilize temperatures, supporting life in various climates, while its ability as a solvent facilitates numerous biochemical reactions within living organisms .

The concept of half-life, the time it takes for half of the atoms in a radioactive sample to decay, is fundamental to radiometric dating. This method measures the remaining amount of a radioactive isotope to estimate the age of materials. For example, Carbon-14, with a half-life of 5730 years, is commonly used for dating organic materials and fossils, as its decay can be traced over thousands of years . In geological contexts, isotopes with longer half-lives, like Uranium-238, are used to date rocks and the Earth itself. The predictability of decay rates allows scientists to backtrack and determine when a particular rock or organism was formed based on the isotope levels .

pH levels are critical in influencing enzyme activity, as each enzyme has an optimal pH range in which it operates most efficiently. Deviations from this range can result in denaturation, altering the enzyme's structure and reducing its activity or effectiveness in catalyzing reactions. For instance, pepsin, which operates in the acidic environment of the stomach, functions best at a low pH, while enzymes in the alkaline conditions of the intestine require a higher pH . Maintaining pH balance is crucial for the overall functioning of biological systems; blood pH, for instance, is tightly regulated around 7.4. Buffers in living organisms help resist changes in pH, ensuring that metabolic processes, such as enzymatic reactions, proceed smoothly without harmful fluctuations .

Ionic and covalent bonds significantly influence the physical properties of compounds. Ionic compounds, which form from the transfer of electrons between metals and nonmetals, generally have high melting and boiling points due to the strong electrostatic forces between ions. They also tend to conduct electricity when dissolved in water or melted, as their ions are free to move . In contrast, covalent compounds, where nonmetals share electron pairs, usually have lower melting and boiling points and do not conduct electricity, as they do not have free-moving charged particles. Their hardness varies widely, from soft substances like wax to hard materials like diamonds, depending on the nature of the covalent bonds and the molecular structure .

Ionic bonds involve the transfer of electrons from one atom to another, resulting in the formation of charged ions. These bonds typically form between metals and nonmetals, such as NaCl, where the metal loses electrons and the nonmetal gains them . In contrast, covalent bonds involve the sharing of electron pairs between atoms, usually between nonmetals. Examples include molecules like O2 and H2O .

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