Microelectronics I
Chapter 5: Carrier Transport
Phenomena
Transport; the process by which charged particles (electrons
and holes) move
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Understanding of electrical properties ( I-V characteristics)
Basic current equation;
I ∝ e⋅ µ ⋅ n⋅ E
e; electronic charged (constant, 1.6 x 10-19 C)
u; mobility ( figure of merit that reflect the speed)
n; carrier concentration
E; Electric field
Carrier concentration (electron, no and hole, po)
Chapter 4
Carrier transport (current)
This chapter
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Carrier Transport
“Drift” “Diffusion”
The movement of carrier due The flow of carrier due to density
to electric field (E) gradients (dn/dx)
electron divider
E
+ -
electron
V
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5.1 Carrier Drift
Drift current density
Consider a positively charged hole,
When electric field, E, is applied, the hole accelerates
F = m*p a = eE
m*p; effective mass of hole, a; acceleration, e; electronic charge
However, hole collides with ionized impurity atoms and with thermally vibrating
lattice atom
Lattice atom
hole
E
Ionized impurity atom
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Lattice atom
hole
E
Ionized impurity atom
Gain average drift velocity, vdp
Holes accelerates
due to E vdp = µ p E
µp; Hole mobility (unit; cm2/Vs)
Involves in collision
(“Scattering Process”) Describes how well a carrier move due to E
Loses most of energy
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Drift current density, Jdrf (unit; A/cm2) due to hole
J p|drf = epvdp
J p|drf = eµ p pE
Drift current density due to electron
J n|drf = eµ n nE
Total drift current;
J drf = e( µ n n + µ p p ) E
The sum of the individual electron and hole drift current densities
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Mobility is important parameter to determine the conductivity of material
Mobility effects
eτ cp eτ cn
µp = µn =
m*p mn*
τ; mean time between collisions
If τ=10-15 s, in average, every 10-15 s, carrier involves in collision @ scattering
Two dominant scattering mechanism
[Link] or lattice scattering
[Link] scattering
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1. Lattice scattering or phonon scattering
At temperature, T > 0 K, atoms randomly vibrate. This thermal vibrations cause a
disruption of the periodic potential function. This resulting in an interaction
between carrier and the vibrating lattice atoms.
Mobility due to lattice scattering, µL
µ L ∝ T −3 / 2
As temperature decreases, the probability of a scattering event decreases. Thus,
mobility increases
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electron hole
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2. Ionized Ion scattering
Coulomb interaction between carriers and ionized impurities produces scattering
or collusion. This alter the velocity characteristics of the carriers.
Mobility due to ionized ion scattering, µI
T 3/ 2
µL ∝
NI Total ionized impurity concentration
If temperature increases, the random thermal velocity of a carrier increases,
reducing the time the carrier spends in the vicinity of the ionized impurity center.
This causes the scattering effect decreases and mobility increases.
If the number of ionized impurity centers increases, then the probability of a
carrier encountering an ionized impurity centers increases, thus reducing
mobility
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The net mobility is given by
1 1 1
= +
µ µL µI
Due to phonon scattering Due to ionized ion scattering
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Conductivity
Drift current
electron
J drf = e( µ n n + µ p p) E = σE
hole
σ; conductivity [(Ω.cm)-1 ]
σ = e( µ n n + µ p p )
Function of electron and hole concentrations and mobolities
Ρ; resistivity [Ω.cm]
1 1
ρ= =
σ e( µ n n + µ p p )
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Bar of semiconductor
L I
+
- V
Area, A
I V
Current density, J = Electric field, E =
A L
J = σE
Resistance, R is a function of resistivity, or
I V conductivity, as well as the geometry of the
=σ semiconductor
A L
L ρL
V = I = I = IR
σA A
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Consider p-type semiconductor with an acceptor doping Na (Nd=0) in which Na>>ni
σ = e( µ n n + µ p p ) ≈ eµ n p
Assume complete ionization
1
σ ≈ eµ n N a ≈
ρ
Function of the majority carrier
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ex.;
Consider compensated n-type Silicon at T=300 K with a conductivity of σ=16
(Ωcm)-1 and an acceptor doping concentration of 1017 cm-3 . Determine the donor
concentration and the electron mobility.
Solution;
At T=300 K, we can assume complete ionization. (Nd-Na >>ni)
σ ≈ eµ n n = eµ n ( N d − N a )
16 = (1.6 × 10 −19 ) µ n ( N d − 1017 )
To determine µn and Nd, we can use figure mobility vs. impurity concentration
with trial and error
10 20 = µ n ( N d − 1017 )
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If Nd=2 x 1017 cm-3 , impurity
concentration, NI= Nd++Na-=3 x 1017
cm-3 . from the figure, µn= 510
cm2/Vs. so σ=8.16 (Ωcm)-1 .
If Nd=5 x 1017 cm-3 , impurity
concentration, NI= Nd++Na-=6x 1017
cm-3 . from the figure, µn= 325
cm2/Vs. so σ=20.8 (Ωcm)-1 .
Nd should be between 2 x 1017 and 5 x
1017 cm-3 . after trial and error.
Nd= 3.5 x 1017 cm-3
µn=400 cm2/Vs
σ= 16 (Ωcm)-1
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Ex 2.; designing a semiconductor resistor with a specified resistance to
handle a given current density
A Si semiconductor at T=300 K is initially doped with donors at a concentration of
Nd=5 x 1015 cm-3 . Acceptors are to be added to form a compensated p-type
material. The resistor is to have a resistance of 10 kΩ and handle a current
density of 50 A/cm2 when 5 V is applied.
Solution;
When 5 V is applied to 10 kΩ resistor, the current, I
V 5
I= = 4 = 0.5mA
R 10
If the current density, J is limited to 50 A/cm2, the cross-sectional area, A is
I 0.5 ×10 −3
A= = = 10 −5 cm 2
J 50
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Consider that electric field, E is limited to 100 V/cm. Then the length of the
resistor, L is
V 5
L= = = 5 × 10 − 2 cm
E 100
The conductivity, σ of the semiconductor is
L 5 × 10 −2
σ= = 4 = 0 .5( Ωcm ) −1
RA 10 × 10 −5
The conductivity of the compensated p-type semiconductor is
σ ≈ eµ p p = eµ p ( N a − N d )
Here, the mobility is function of total ionized impurity concentration Na+Nd
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Using trial and error, if Na=1.25x1016 cm-3 , then Na+Nd=1.75x1016 cm-3 , and the
hole mobility, from figure mobility versus impurity concentration, is approximately
µp=410 cm2/Vs. The conductivity is then,
σ = eµ p ( N a − N d ) = 1.6 ×10 −19 × 410 × ((12.5 − 5) × 1015 ) = 0.492
This is very close to the value we need. From the calculation
L=5x10-2 cm
A=10-5 cm2
Na=1.25x1016 cm-3
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Velocity Saturation
vd = µE
Drift velocity increase linearly with applied electric field.
At low electric field,
vd increase linearly
with applied E.
slope=mobility
At high electric field,
vd saturates
Constant value
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Carrier diffusion
Diffusion; process whereby particles from a region of high concentration toward
a region of low concentration.
Carrier divider
Electron concentration, n
Electron flux
dn
J nx|dif = (−e) Dn −
dx
Electron diffusion dn
current density J nx|dif = eDn
dx
Position x
Dn; electron diffusion coefficient
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dp
J px|dif = eD p −
Hole centration, p
dx
Hole flux
dp
J px|dif = −eD p
dx
Hole diffusion
current density
Dp; hole diffusion coefficient
Position x
Diffusion coefficient; indicates how well carrier move as a result of
density gradient.
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Total Current Density
Total Current
Density
Electron drift hole drift Electron diffusion hole diffusion
current current current current
1-D
J = J n|drf + J nx|dif + J p|drf + J px|dif
dn dp
J = enµ n E x + epµ p E x + eDn − eD p
dx dx
3-D
J = enµ n E + epµ p E + eDn ∇n − eD p ∇p
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Mobility,µ; indicates how well carrier moves due to electrical field
Diffusion coefficient, D; how well carrier moves due to density gradient
Here, we derive relationship between mobility and diffusion
coefficient using nonuniformly doped semiconductor model
“Einstein relation”
Graded impurity distribution
EC
electron Energy-band diagram
EF
x Ev
nonuniformly doped semiconductor
x
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EC Doping concentration decreases as x increases
Electron diffuse in +x direction
EF The flow of electron leaves behind positively
charged donor
Ev
Induce electrical field, Ex, given by
x
kT 1 dN d ( x)
E x = − …eq.1
e N d ( x) dx
Since there are no electrical connections, there is no current(J=0)
dN d ( x)
Electron current J = eµ n N d ( x) E x + eDn =0 …eq.2
dx
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From eq.1 and 2,
Dn kT
=
µn e
Hole current must also be zero. We can show that
Dp kT
=
µp e
Dn D p kT
= =
µn µ p e
Diffusion coefficient and mobility are not independent parameters.
The relationship between this 2 parameter “Einstein relation”
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The Hall effect
Using the effect, we can determine
The type of semiconductor
Carrier concentration
mobility
Magnetic field
Force on charged particle
in magnetic field (“Lorentz
force”)
F = qv × B
Applied electrical field
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the Lorentz force on electron
and hole is in –y direction
There will be buildup of negative
charge (n-type) or positive charge
(p-type) at y=0
As a results, an electrical field
called “Hall field, EH” is induced.
Hall field produces “Hall voltage,
VH”
Polarity of VH is used to determine the type of semiconductor
In y-direction, Lorentz force will be balanced by force due to Hall field
VH
qv x × Bz = q (p-type)
W
VH = v xWBz
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For p-type Ix
vx =
(ep)(Wd )
I x Bz
VH =
epd
I B
p= x z Can calculate the hole concentration in p-type
eVH d
For n-type I x Bz
VH = −
end Note that VH is negative for n-type
I B
n=− x z
eVH d
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When we know the carrier concentration, we can calculate carrier mobility
Ix epµ p E x
=
J x = epµ p E x Wd L
IxL
µp =
epVxWd
Similar with n-type, mobility is determined from
IxL
µn =
enVxWd