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0% found this document useful (0 votes)
14 views35 pages

Solution

The document consists of a series of physics and chemistry questions covering topics such as motion, optics, and molecular structure. It includes multiple-choice questions with options related to various physical phenomena and chemical principles. The questions are structured in sections, each focusing on different concepts and scenarios.

Uploaded by

ggoda3654
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

08-02-2026

1001CJA101021260005 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A particle moves in xy-plane due to the force , where Vx = x-component of velocity


at any time t, Vy = y-component of velocity at any time t. Given mass of the particle = 1kg. At t = 0, x
= 0 and y = 0 and has velocity m/s. Select correct options.

(A) Motion of the particle along x-axis is SHM.


(B) Motion of the particle along y-axis is SHM.
(C) Path of the particle in xy-plane is straight line.
(D) Path of the particle in xy-plane is circle.

2) A bird is flying downward with constant velocity 6 cm/s towards a fixed container filled with a
liquid of refractive index 4/3. A fish is moving upward with constant speed 4 cm/s towards the
surface of liquid. Surface of liquid is also moving downward with constant velocity 2 cm/s as shown

in the figure. The bottom of container is silvered, then :-

(A) Speed of fish as seen by bird only after refraction is 9 cm/sec.


(B) Speed of fish as seen by bird only after refraction is 8.5 cm/sec.
(C) Speed of fish as seen by bird after reflection and then refraction is 3 cm/sec.
(D) Speed of fish as seen by bird after reflection and then refraction is 2.5 cm/sec.

3) In the arrangement shown in figure pulleys and strings are ideal. End A of string connected to
pulley P1 is moved upwards with acceleration aA = 2m/s2 while end B of another string shown in
figure is moved up with acceleration aB = 1 m/s2. Block C of mass 1 kg is moving up with
acceleration 1 m/s2. The block D to which strings are connected moves symmetrically such that its
orientations remains same and the tension in the two strings connected to it always remain equal.
(assume g = 10 m/s2)

(A)
acceleration of block D is upwards.
(B) end A is pulled with force of 22 N.

(C)
mass of block E is .

(D)
acceleration of block E is upwards.

4) On a wide river, two boats move with constant velocities. The velocity of the water in the river is
constant across the whole area depicted in the figure, and parallel to the coastline. The figure is
based on a photo which was taken from air, the camera being directed straight down. The positions
of the boats at some instant are marked with a square and a triangle, and the positions of trash
fallen from the boats — with pentagrams. One of the boats departed from the point A; it is known
that the boats did meet with each other at a certain moment. The figure is drawn to scale. Choose

the correct statement(s).

The triangular boat dropped two pieces of trash and the square boat dropped one piece of
(A)
trash.
(B) The triangular boat as well as the square boat departed from the coast marked with A.
(C) The river flows towards right.
(D) The boats met after dropping their respective pieces of trash.

5) A combination of two thin convex lenses of equal focal lengths, is kept separated along the optical
axis by a distance of 20 cm between them. The combination behaves as a lens system of infinite focal
length :-

If an object is kept on the common optic axis at a distance of 10 cm from the first lens, its
(A)
final image will be formed at a distance of 10 cm from the next lens.
If an object is kept on the common optic axis at a distance of 10 cm from the first lens, its
(B)
final image will be formed at a distance of 30 cm from the next lens.
If an object is kept on the common optic axis at a distance of 30 cm from the first lens, its
(C)
final image will be formed at a distance of 10 cm from the next lens.
If an object is kept on the common optic axis at a distance of 30 cm from the first lens, its
(D)
final image will be formed at a distance of 20 cm from the next lens.

SECTION-I (ii)

Common Content for Question No. 1 to 2


A block is attached to a spring and is placed on a horizontal smooth surface as shown, in which
spring is unstreched. Now the spring is given an initial compression 2x0 and block is released from
rest. Collision with the wall PQ are elastic.

1) If coefficient of restitution e = 1/2 in the collision between block and the wall then select the
correct statement(s).

(A) New maximum compression in the spring is x0.

(B) 0
New maximum compression in the spring is x .

(C)
New angular frequency after collision is .

(D)
New angular frequency after collision is .

2) Find the time period of motion of the block. (For e = 1)

(A)

(B)

(C)

(D)

Common Content for Question No. 3 to 4


Mr. Saransh having mass 50kg is standing on a platform of mass 10 kg which oscillates up & down
(doing SHM) of frequency 0.5 sec–1 & amplitude 0.4 m. Platform has a weighing machine fitted in it
(which is massless) on which person is standing. (Take π2 = 10 & g = 10 m/s2). Assume that at t = 0
(platform + man) is at their highest point of oscillation.

3) Which of the following will be correct for reading of weighing machine?

(A) Maximum reading of weighing machine will be 70 kg.


(B) Maximum reading will be at mean position.
(C) Maximum reading will be at lower extreme position.
(D) Maximum reading will be at upper extreme position.

4) Which of the following is correct for compression or extension of spring?

(A) When reading is 55 kg, then compression will be 1.1 m.


(B) When reading is 50 kg, then compression will be 1.0 m.
(C) When reading is 50 kg, then compression will be 1.1 m.
(D) When reading is 55 kg, then compression will be 1.0 m

SECTION-I (iii)

1) Provided sketches in list–I are made on the basis of satellite images, preserving proportions. They
represent tractors, together with their smoke trails. The tractors were moving along the roads in the
direction indicated by the arrows. The velocity of all the tractors was v0 = 30km/h. In each case,
match with possible wind velocity in list–II.

List–I List–II

(P) (1)

(Q) (2)

(R) (3)
(S) (4)

(5)

(A) P → 1;Q → 1;R → 5;S → 4


(B) P → 3;Q → 3;R → 3;S → 1
(C) P → 1;Q → 2;R → 4;S → 5
(D) P → 5;Q → 1;R → 1;S → 5

2)

A particle is moving along x-axis. Its position is given by x = (where t is time in


second), then :-

List-I List-II
(P) for 0 < t < 1 second (1) particle speeds up.
(Q) for 1 < t < 2 second (2) particle retards
(R) for t > 2 second (3) particle is moving towards origin
(S) at t = 1 second (4) particle changes its direction of motion
(5) None of these
(A) P → 1;Q → 2;R → 4;S → 3
(B) P → 4;Q → 2;R → 1;S → 3
(C) P → 2;Q → 3;R → 1;S → 4
(D) P → 2;Q → 3;R → 4;S → 1

3)

List-I List-II

Particle must change its direction


(P) (1)
during the subsequent motion

Particle may return to its initial


(Q) (2) position
during subsequent motion
Acceleration vector of a particle must
(R) (3)
be constant throughout the motion

Particle come to rest at least once


(S) (4)
during its motion

(5) Initial velocity of particle is zero.

(A) P → 1,2,4;Q → 1,2,4;R → 3;S → 5


(B) P → 1,2,3,4;Q → 2,4;R → 2;S → 2,4
(C) P → 1,3,4;Q → 1,4;R → 2;S → 2,3
(D) P → 2,3,4;Q → 2,4;R → 3;S → 2,5

SECTION-II

1) A body P of mass 1kg and a body Q of mass 5kg are connected to a spring as shown in the figure.
P is given a velocity 1.73 m/s when spring is relaxed. Find ratio of maximum and minimum reading

of weighing machine. Spring constant = 100 N/m.

2) For the combination of one prism and 2 lenses shown. Find the size (in mm) of final image when
the object whose length is 1 cm is located as shown in figure.
3) Consider an arrangement shown in the figure. The block of mass m3 is constrained to move in the
vertical direction only. The wedge of mass m4 moves in the horizontal direction. The slider 's' of mass
m2 moves on a fixed horizontal rod. The friction between all the contact surfaces is negligible. At a
particular instant the string connecting the slider 's' to the block of mass m1 is making angle θ with
the rod. Find the acceleration (in m/s2) of the block of mass m1 at this instant ? The acceleration due
to gravity is g. Given that m1 = m2 = m3 = m4 and θ = 60°, α = 30°. (Take : g = 9.8 m/s2)

4) In the situation shown in figure, a rod slides on a fixed inclined plane and a wedge is moving
horizontally with acceleration a0 towards right so that the rod is always horizontal. The magnitude of
acceleration of the rod is x a0. Value of x is.

5) The path of a ray of light passing through an equilateral prism ABC is shown in the figure. The ray
of light is incident on face BC at an angle just greater than the critical angle for total internal
reflection to take place. The total angle of deviation after the refraction at face AC is 120°
(anticlockwise). The value of refractive index of material of prism is . The value of x is:
PART-2 : CHEMISTRY

SECTION-I (i)

1) Select correct statement about X2 if electronic configuration of X2 is given


(σ1s2, σ*1s2) , (σ2s2, σ*2s2) , (π2p2x = π2p2y)

(A) Two molecular orbitals are gerade.


(B) CaX2 : is ionic in nature.
(C) Ionization energy of X is less than X2
(D) Total four orbital contain nodal plane in XY plane or parallel to XY plane

2) A metal exists in two allotropic forms, α-form is BCC and β-form is FCC. The distance between
nearest neighbours is same in both forms. Which of the following is/are INCORRECT information(s)
related with these two forms of the metal ?

(A) Next nearest neighbours are at same distance in both forms.


(B) Percentage void space in α -form is greater than that in β -form.
The diameter of largest sphere which may be fitted in both the crystals of metal, without
(C)
disturbing the distance between nearest neighbours, is same in both forms.
(D) The edge length is greater for the unit cell of β-form.

3) Which of the following are incorrect ?

(A) ClO3 , NO2 , CH3 , CF3 (all are paramagnetic species)


(B) B2H6 , Al2(CH3)6 , Al2Cl6 (all are having 3c – 2e¯ bond)

(C)
, , NCl3 , Be2H4 (all are non planar species)
(D) B2Cl4 > B2F4 > B2(OR)4 > B2(NR)2 (Relative stability order)

4) Identify the major product


(A)

+ Enantiomer

(B)

+ Enantiomer

(C)

(D)

+ Enantiomer

5) In which of the following carbonyl compound (Aldehyde or ketone) is formed as major product.

(A)

(B)

(C)

(D)

SECTION-I (ii)

Common Content for Question No. 1 to 2


Spinel is an important class of oxide having two types of metal ions. A type of spinel have ccp
arrangement to O2– ions in which Fe2+ cation occupy 1/8th of tetrahedral voids and Fe3+ cation
occupies half of the octahedral voids. If 'a' be the edge of unit cell then.

1) What is the minimum internuclear distance between Fe2+ ion & Fe3+ ion in spinel -

(A)

(B)

(C)

(D) a

2) What is formula of spinel -

(A) Fe2O3
(B) Fe3O4
(C) FeO
(D) Fe4O5

Common Content for Question No. 3 to 4


Hybrid orbitals are directed in space in some prefered directional to have minimum repulsion
between electron pairs. The type of hybridisation indicates shape of molecule
Consider the following conditions.
Condition (1) → d-orbitals of central atom involved in bonding
Condition (2) → All bond lengths are same
Condition (3) → All adjacent bond angles are same

3) Select the pair of compounds in which atleast one molecule satisfy condition (3) but no molecule
satisfy condition (1)

(A) CO2 , SO2


(B) PCl5 , PCl3
(C) IF3 , BrF3
(D) NF3 , NCl3

4) Select the pair of compounds in which both molecules satisfy either condition (1) or condition (3)
but not condition (2)

(A) XeF2 , CF4


(B) SF4 , IF7
(C) XeO3 , XeO4
(D) SO2F2 , BrF5

SECTION-I (iii)

1) Match the List :


[Atomic mass : Mg = 24, S = 32, Na = 23]
List-I List-II

(P) 6.3 gm HNO3 in 100 kg of solution (1)


Xsolvent = (X = mole fraction)

(Q) 4 gm MgO and 360 gm water (2)


%

(R) 2M H2SO4 (dsolution = 1.996 gm/mL) (3) 12 M

(S) 40% NaOH solution (4) 1 m


(dsolution = 1.2 gm/mL)

(5) 63 ppm
(A) P → 5;Q → 1;R → 2;S → 3
(B) P → 5;Q → 3;R → 1;S → 4
(C) P → 4;Q → 2;R → 5;S → 1
(D) P → 1;Q → 2;R → 3;S → 4

2) Consider MOT for following list type question in which List-I have characteristics of molecular
orbitals of diatomic molecule and List-II have type of molecular orbital in diatomic molecule

List-I List-II
(Characteristics) (Notation of M.O.)

Orbitals are localised on only one atom and do not


(P) (1) σ (bonding)
affect bonding.

Electrons in these molecular orbitals lower the


energy of the molecule, and are delocalised
(Q) (2) σ* (antibonding)
between two nuclei in two lobes which are above
and below the joining line of nucleus.

Electrons in these molecular orbitals raise the


energy of the molecule, these orbitals have no
(R) (3) Non-bonding
nodal plane along the axis between the two
adjacent nuclei.

These molecular orbitals have lobes on opposite


(S) side of the joining line of nucleus and a nodal plane (4) π (bonding)
perpendicular to joining line of the nuclei.

(5) π* (antibonding)
The correct option is :
(A) P → 4;Q → 3;R → 5;S → 2
(B) P → 1;Q → 5;R → 2;S → 4
(C) P → 3;Q → 5;R → 1;S → 5
(D) P → 3;Q → 4;R → 2;S → 5

3)

List-I List-II
(P) (1) Major product is Saytzeff's alkene
Major product

Major product exists as diastereomeric form or


(Q) Ph–CH2–CH=CH2 Major product (2)
enantiomeric form

(R) (3) White ppt is formed


Major product

(S) (4) Alcohol is formed as a major product.


Major product

(5) Carbocation is formed as intermediate

Choose the correct combination considering List-I and List-II


(A) P → 1,2;Q → 3,4;R → 2,3;S → 4,5
(B) P → 1,5;Q → 2,5;R → 3,5;S → 4,5
(C) P → 1,3,5;Q → 2,4;R → 3,5;S → 3,4,5
(D) P → 1,3,4;Q → 2,4;R → 2,5;S → 1,3,5

SECTION-II

1) 0.5 g mixture of K2Cr2O7 and KMnO4 was treated with excess of KI in acidic medium. Iodine so
liberated required 100 ml of 0.15 N solution of sodium thiosulphate for titration. The percentage of
K2Cr2O7 in the mixture is ?
(Molecular weight of K2Cr2O7 = 294 gm/mol and KMnO4 = 158 gm/mol)

2) A compound AB has zinc blende structure with 'A' atoms at corners and face centres of the unit
cell. If all the atoms present in one body diagonal are removed, the empirical formula of the
compound becomes AxBy. Then sum (x + y) is :

3) Calculate the value of (x + y + z) based on the following parameters for Al(BH4)3 :


x = Number of 3c – 2e¯ (three center, two-electron) bonds
y = number of 2c – 2e¯ (two center, two-electron) bonds
z = (n1 + n2), where the hybridization of Aluminium (Aℓ) in the molecule is .

4) How many compounds are more reactive towards SN1 as well as SN2 than CH3–CH2–CH2–Cl ?

(i) (ii) CH3–O–CH2–Cl (iii)

(iv) (v) (vi) CH2=CH–CH2–Cl

(vii)
5) How many reactions give correct major product?

(i) (ii)

(iii) (iv)

(v)

PART-3 : MATHEMATICS

SECTION-I (i)

1) Which of the following options is/are correct involving the following four statements ? (S-1) If |A|
= 27, |A ∩ B| = 11, then .
(S-2) If , |B| = 25, then .
(S-3) If , , |A Δ B| = 8, then .
(S-4) If , then |A| = δ.
(Where |A| denotes number of elements in A)

(A) α + δ = 50
(B) β + γ = 70
(C) α + γ = 28
(D) β + δ = 80

2) Let f : R → [0, 1] be defined as f(x) = then which of the following


is/are correct?

(A) Range of f is (0, 1)


(B) f is even
(C) f is many one
(D) f is into

3) Let f : R → [–1, 1] be defined as f(x) = cos(sin x) then which of the following is/are correct?

(A) f is periodic with fundamental period 2π


(B) range of f is [cos 1, 1]

(C)

(D) f is neither even nor odd function

4) Let 'n' be a +ve integer with f(n) = 1! + 2! + 3!+...+n! and p(x), q(x) be polynomials in 'x' such
that f(n + 2) = p(n). f(n + 1) + q(n). f(n) for all n > 1 then

(A) p(x) = x + 3
(B) q(x) = – x – 2
(C) p(x) = – x – 2
(D) q(x) = – x + 3

5) Let a1, a2, ..... an, be real numbers such that

, then

(A)

(B)

(C)

(D)

SECTION-I (ii)

Common Content for Question No. 1 to 2

Let
f(x) = 4x + 8x + 9x – 2x – 6x – 12x ; x ∈ R

Based on above information, answer the following questions :

1) The value of λ + max(f(x)) is greater than or equal to

(A) 2
(B) 1
(C) 5
(D) 4

2) The smallest value of x + y is less than or equal to, if (x, y) ∈ A

(A) 27
(B) 28
(C) 60
(D) 35

Common Content for Question No. 3 to 4

Given that x, y, z are real numbers satisfying x ≥ y ≥ z ≥ tan–1(2 – ) and x + y + z =

Consider a function ; t ≠ ±1
Based on above information, answer the following questions

3) If S = cosx siny cosz, then integer closest to 20(Smin + Smax) equals

(A) 10
(B) 9
(C) 12
(D) 13

4) The value of is less than or equal to

(A) 11
(B) 9
(C) 8
(D) 10

SECTION-I (iii)

1)

List – I List – II

The number of solution(s) of the equation


(P) (1) 0
2
(x + 1), is (are)

(Q) (2) 1
If the range of the function f(x) = is
(a, b], then [a + b] is equal to
If α and β are the roots of the 2x2 – 3x – 2 = 0, then

(R) (3) 2

is

If f(x) = sin(cos–1 (sin(cos–1x)) + sin–1 (cos(sin–1x))), then


(S) (4) 3
the value of is equal to

(5) 4
[Note : sgn z and [z] denotes signum function and greatest integer less than or equal to z
respectively.]
(A) P → 1;Q → 1;R → 5;S → 5
(B) P → 1;Q → 2;R → 5;S → 4
(C) P → 3;Q → 1;R → 4;S → 4
(D) P → 3;Q → 2;R → 4;S → 5

2) If x, y, z, u > 0 are distinct real numbers in G.P. and a, b, c, d are real & distinct, non-zero
numbers in A.P., then match the correct answers.

List-I List-II

(P) (1) only in A.P.


a – log will be

(Q) (b – a)xy, (c – b)yz, (d – c)zu will be (2) only in G.P.

(R) (3) only in H.P.


will be

(a2 – b2)(x2 – y2), (b2 – c2)(y2 – z2), (c2 – d2)(z2 – u2)


(S) (4) only in A.G.P.
will be

(5) none of above


(A) P → 2;Q → 1;R → 3;S → 4
(B) P → 1;Q → 2;R → 1;S → 4
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 2;Q → 4;R → 5;S → 1

3)

List-I List-II

(P) If , then (1)


possible subset of A is/are

Subset of interval in which 'a' lies if x2 – (α


(Q) – β)x + (1 – α – β) = 0 has distinct real (2) (1, 2)
roots for all real β, is
The interval in which 'b' lies, if the roots of
(R) x3 – 6x2 + 2ax – 4b = 0, (3)
where a ∈ (5,6), are in A.P., is

Subset of set of values of λ for which both


(S) roots of equation x2 – 6λx + 2 – 2λ + 9λ2 = (4)
0 are greater than 3, is

(5)

(A) P → 1;Q → 2,3;R → 2;S → 4


(B) P → 4;Q → 2;R → 3;S → 5
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 2;Q → 1;R → 4;S → 5

SECTION-II

1) Let f : R – {0, 1} → R, be a function satisfying . Then, the value of 20 f(5) is


equal to

2) Of the 100 members of a sport club : 48 play squash (S), 45 play badminton (B), 52 plays table
tennis (T). If each member plays at least one game, then maximum possible number of members
playing all three games is equal to

3) The number of integers satisfying the inequality

, is

4) If the number of onto functions from {1, 2, 3, 4} → {2, 3, 4} such that f(i) ≠ i for i = 1, 2, 3, 4 is

k, then is equal to_________

5) Consider, f(x) = x2 – 4(p – 1) x+ and g(x) = . If the

set of values of 'p' is [α, β] for which exists for all k ∈ R, then (α + β) is equal to
ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5
A. A,B,D B,D B,D A,D A,C

SECTION-I (ii)

Q. 6 7 8 9
A. B,C B A,C A,B

SECTION-I (iii)

Q. 10 11 12
A. A C B

SECTION-II

Q. 13 14 15 16 17
A. 2.00 5.00 0.45 to 0.48 0.72 to 0.74 2.33

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21 22
A. A,B,C A,C B,C,D A,B,D A,C

SECTION-I (ii)

Q. 23 24 25 26
A. A B D B,D

SECTION-I (iii)

Q. 27 28 29
A. A D B

SECTION-II

Q. 30 31 32 33 34
A. 14.50 to 14.75 9.00 17.00 4.00 5.00

PART-3 : MATHEMATICS
SECTION-I (i)

Q. 35 36 37 38 39
A. C,D B,C,D B,C A,B A,C

SECTION-I (ii)

Q. 40 41 42 43
A. A,B B,C,D C A,D

SECTION-I (iii)

Q. 44 45 46
A. D B A

SECTION-II

Q. 47 48 49 50 51
A. 9.25 22.00 3.00 3.00 2.00
SOLUTIONS

PART-1 : PHYSICS

1)

Correct answer is (A,B,D)

2)
Distance of image offish as seen by bird only after refraction is

Differentiate w.r.t. time

Similarly we can calculate for 2nd case.

3)

Correct answer are B,D.

4) Key ideas :
From frame of river litter remains stationary and collinear with the line of motion of boat since
river appears stationary from this frame (just like a road). Also the litter particles must be
behind the boats. Accordinaly the only possibilities of lines of motion of the boats are shown by
dotted lines. The meeting point of boats must be the intersection point of the two lines.

(Marked by point P).


5)

here,
d = 2f

(A)

& this paraller beam focused at focus of second lens so final image is at 10 cm.

(C) for first lens

v = 15 cm.
for second lens.

v = – 10 cm

6)

Correct answer are B,C.

7) Correct answer is (B)

8) Correct answer is (A,C)

9) Correct answer is (A,B)


10)

Correct Answer is (A)

11)

v = t2 – 3t + 2 = (t – 1) (t – 2)
0 < t < 1 sec, v = +ve but decreasing because at t = 1 sec, v = 0 and particle is changing its
direction.
1 < t < 2 sec, v = – ve ⇒ Particle is moving towards origin.
t > 2 particle accelerates

12) (P)
Direction changes with sign of V. Initial & final position are zero so it returns to initial
position. Graph is parabolic, hence, acceleration is constant & negative. v = 0, means particle
comes to rest. Initial slope is nonzero, so initial velocity is non zero.

(Q)
Speed does not have direction. It is possible to return back. Slope is tanθ is constant so,
acceleration is constant,
Rest means speed = 0
But initial speed is ≠ 0

(R)
Acceleration cannot give direction of velocity. It is possible to return back. Acceleration is not
constant area of a/t graph gives change in velocity only.

(S)
Distance has no direction, but it is possible to return back, slope, tan θ = speed.

13) = 10 rad/s

3 = 100 (A2 –0.12) ⇒ A2 = 0.03 + 0.01 = 0.04


A = 0.2 meter
reading = (mP + mQ)g + mPw2A & (mP + mQ)g – mPw2A

14)

For the right angle prism, n = 1.5, the critical angle which is smaller
than the angle of incidence 45°, at the hypotenuse of the prism.
Therefore total internal reflection occurs, which forms a virtual image.
The prism, equivalent to a glass plate of thickness 6 cm, would cause a image shift of

.
Thus the effective object distance for the first lens is .
As , we have . Then for the second lens, .
With , we get .
Hence the final image is inverted and virtual, 10 cm to the left of the second lens.

The size of the image is .

15)

Correct answer is (0.45 to 0.48)

16)

y cot 30° + x + y cot 45° = L


y( + 1) + x = L

– ay + a0 = 0

ax = ay cot 30° ⇒ ax =
so a =

17) The ray diagram is drawn for the sake of convenience.

r1 = r3 = r
i1 = i2 = i
r2 ≈ C
Since, r1 + r2 = r2 + r3 = 60°
⇒ r1 = r3 = r (say)
Similarly by symmetry, we have i1 = i2 = i (say)
Also, r2 ≈ C
⇒ r = 60° – C
Given, δtotal = 120°



⇒ 2i = 60°
⇒ i = 30°
Now, according to Snell’s Law, we have

But r1 + r2 = 60°
⇒ r + C = 60° ⇒ r = 60° – C

⇒ ⇒

But sin C =

⇒ ⇒

⇒ ⇒
⇒ ⇒ ⇒ μ = 1.52

PART-2 : CHEMISTRY

18) Molecule : C2
C2 has electrons in B.M.O which are difficult to remove compared to C.

19) The distance between nearest neighbours is same in both forms means '2r' is same in both
and hence the unit cell edge length, i.e., cell constant, a, is different in both.

aα = and aβ =
The distance between next nearest neighbours in both form is 'a', which is different.
Void space in BCC = 32%, FCC = 26%
In both forms, the required diameter of largest spheres = (a – 2r) and 'a' is different

2rc =

20) Al2Cl6 → 3c → 4e¯ Bond.


C(CN)3– is planar due to resonance.

21) (A) (Syn-addition)

(B) (Anti-addition)

(D)
22) The correct answer is option (A,C)

23)

Correct answer is option (A)


24)

Correct answer is option (B)

25)

Theory Based

26)

SF4, IF7, SO2F2, BrF5 have unequal Bond lengths.

27)

Correct answer is option (A)

28)

Theory Based

29) The correct answer is option (B)

30)

735 – 522x = 696.78


x = 0.0732

%K2Cr2O7 = = 14.64%

31) If all atoms along one body diagonal is removed.

A=
B=3

A:B= : 3 ⇒ 15 : 12
⇒ 5 : 4 ⇒ A5B4
So, x = 5, y = 4
x+y=9

32) x = 6
y=6
z = (3 + 2) = 5
x + y + z = 17
33)

The correct answer is 4.00

34)

All five are give correct major products.

PART-3 : MATHEMATICS

35) (A) a + b = 27
b = 11
∴ α = 16
(B) c + d = 35
c + b = 25
d = 20
c = 15
b = 10
(C) a + b + d = 14
b + c + d = 18
a+c=8

∴b+d=
(D) A ∪ B = a + b + c

α = 16, β = 45, γ = 12, δ = 35

36) Domain is x ∈ R

Also f(x) =
where cot θ = x

sinθ =
=

= (cosϕ)2 =

f(x) = =1– Range is ; f'(x) =


Hence f' (0) = 0
Also f(x) = 1
Hence (B), (C), (D)

37)

(A) f(x) = cos(sinx)


As f(x + π) = cos(sin(π + x)) = cos (–sin x) = cos(sin x) = f(x)
(B) As –1 ≤ sinx ≤ 1
cos1 ≤ cos(sinx) ≤ 1

(C)

=
(D) Clearly, f(x) is even function

38) f(n + 2) – f(n + 1) = (n + 2)!


= (n + 2) (n + 1)!
= (n + 2) [f(n + 1) – f(n)]
⇒ f(n + 2) = (n + 3) f(n + 1) – (n + 2) f(n)
∴ p(x) = x + 3; q(x) = –x – 2

39)

a1 = 1, a2 = 2, .... an = n

40) Let N =
f(x) = 4x – 2x + 8x – 6x + 9x – 12x
= a2 – a + a3 – ab + b2 – a2b
= (a2 – b)a + (a2 – b) + b + b(b – a2) + a
= (a2 – b)(a – b + 1) + b – a – 1 + 1
= (a2 – b – 1)(a – b + 1) + 1
= 1 – (1 + b – a2)(1 + a – b)
= 1 – (1 + 3x – 4x)(1 + 2x – 3x)
f(x)max = 1, when x = 1
11 |x + 13y and 13| x + 11y
⇒ 11 |x + 2y and 13| x – 2y
⇒ 11 |6x + 12y and 13| 6x – 12y
⇒ 11 |6x + y and 13| 6x + y
⇒ 6x + y = 143k ⇒ 6(x + y) = 143k + 5y

x+y=

41) Let N =

f(x) = 4x – 2x + 8x – 6x + 9x – 12x
= a2 – a + a3 – ab + b2 – a2b
= (a2 – b)a + (a2 – b) + b + b(b – a2) + a
= (a2 – b)(a – b + 1) + b – a – 1 + 1
= (a2 – b – 1)(a – b + 1) + 1
= 1 – (1 + b – a2)(1 + a – b)
= 1 – (1 + 3x – 4x)(1 + 2x – 3x)
f(x)max = 1, when x = 1
11 |x + 13y and 13| x + 11y
⇒ 11 |x + 2y and 13| x – 2y
⇒ 11 |6x + 12y and 13| 6x – 12y
⇒ 11 |6x + y and 13| 6x + y
⇒ 6x + y = 143k ⇒ 6(x + y) = 143k + 5y

x+y=


42) x ≥ y ≥ z ≥ 15° cosx siny cosz = cosz[sin(x + y) – sin(x – y)]

=
↓ ↓

Also cosx siny cosz =


↓ ↓

∴ Smin =

43) x ≥ y ≥ z ≥ 15°

cosx siny cosz = cosz[sin(x + y) – sin(x – y)]

=
↓ ↓

Also cosx siny cosz =


↓ ↓

∴ Smin =

44) (P) ,

2 solution

(Q)
(R)

(S)

=1+1+1+1=

45) (P) a, b, c in A.P. ..... (1)


x, y, z in G.P. ..... (2)
logx, logy, logz in A.P. ..... (3)
y, z, u in G.P. ..... (4)
3logy, 3logz, 3logu in A.P. ..... (5)
logy3, logz3, logu3 in A.P. ..... (6)
Now from (1) – (3) + (6)

a – log , b – log , c – log in A.P.


(Q) x, y , z, u in G.P.
⇒ xy, yz, zu in G.P.
⇒ kxy, kyz, kzu in G.P.
where k = b – a = c – b = d – c = common difference of A.P.

(R) If , , in A.P.

⇒ + 1, + 1, in A.P.
(ab + bc + ca) and multiply by abc
⇒ a, b, c in A.P. (which is given)
(S) (a2 – b2), (b2 – c2), (c2 – d2) in A.P. ..... (1)
(x2 – y2), (y2 – z2), (z2 – u2) in G.P. ..... (2)
from (1) and (2) result will be an A.G.P.

46) (P) if 2 & lies on same


side of unity

⇒ ⇒ or

(Q) D > 0

or
This is true for all real β
⇒ 4(2 – α)2 – 4(α2 – 4 + 4α) < 0
or – 8α + 8 < 0 or α > 1.
(R) Let the roots of x3 – 6x2 + 2ax – 4b = 0 be
α – d, α, α + d
⇒ (α – d) + α + (α + d) = 6,
α(α – d) + α(α + d) + (α – d)(α – d) = 2a
& α(α – d)(α + d) = 4b

hence 2a = 12 – d2 & 2b = 4 – d2
But a ∈ (5,6)
⇒ 0 < d2 < 2
∴ 1<b<2
(S) D > 0
36λ2 – 4(2 – 2λ + 9λ2) > 0
2 – 2λ < 0
λ>1
af(3) > 0

9 – 18λ + 2 – 2λ + 9λ2 > 0


3λ > 3 9λ2 – 20λ + 11 > 0
λ>1 (λ – 1) (9λ – 11) > 0

Intersection

47)

___________________
= 9.25

48) |A| = 48, |B| = 45, |C| = 52, |A ∪ B ∪ C| = 100


2p + (x + y + z) = 48 + 45 + 52 – 100 = 45

∴ ⇒ pmax = 22

49)

∴ given equation becomes

⇒ x2 ≤ 2 ⇒
No of integers = 3

50) 3C1 × D(3) + 3C1 × D(2) × 2C1

51) g(x) =
g(x) = x2 – 5(p – 1)x + 4
For the existence of limit for all k ∈ R as
x→k
D≤0
25(p – 1)2 – 16 ≤ 0
⇒ ≤0

⇒ p∈

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