16-02-2026

4602CJA101801250012 JM

PART-1 : PHYSICS

SECTION-I

1) The given diagram shows a spring-operated latch fitted in a door. The mechanism is well-
lubricated so friction may be taken as negligible. The latch is pushed in and then released suddenly.
The spring remains within its elastic limit through the motion. Which of the following graphs best
shows the variation of the acceleration a of the latch with the distance x it moves before it is stopped

(A)

(B)

(C)
(D)

2) A uniformly dense rod with non uniform young's modulus is hanging from ceiling under gravity. If
elastic energy density at every point is same then young's modulus with x will change as which of

the shown graph :-

(A)

(B)

(C)

(D)

3) Consider a case in which, the driver of a car travelling at a high speed suddenly sees a wall at a
distance r directly in front of him. To avoid collision,

(A) he should apply brakes sharply

(B) he should turn the car sharply
(C) he should apply brakes and then sharply turn
(D) None of these

4) As shown in figure a particle of mass ‘m’ is moving on the circular path under the influence of a
force whose magnitude always remains ‘F’ & direction towards a fixed point ‘p’ on circumference.

Find the ratio of &

(A) 2 tan θ
(B) tan θ

(C)

(D)

5) A thin vertical uniform wooden rod is pivoted at the top and immersed in water as shown. The
container is slowly raised. At a certain moment, the equilibrium becomes unstable. If density of
water is 9/5 times the density of wood, then ratio of total length of rod to the submerged length of

rod, at that moment is :-

(A) 2
(B) 3
(C) 4
(D) 6

6) Consider a solid sphere of radius R and mass density , . The minimum

density of a liquid in which it will float is :

(A)
(B)

(C)

(D)

7) A block of mass m is kept on smooth horizontal surface and connected with two springs as shown
in figure. Initially springs are in their natural length. Time period of small horizontal oscillation of

the block is :

(A)

(B)

(C)

(D)

8) If the mass of the pulleys shown in figure are small and the cord is inextensible, the angular

frequency of oscillation of the system is :-

(A)

(B)

(C)

(D)
9) Two identical discs of mass m and radius r are arranged as shown in the figure. If is the angular
acceleration of the lower disc and is acceleration of centre of mass of the lower disc, then
relation between , is:

(A)

(B)
(C)
(D) None of these

10)

Sixteen beads of equal mass in a light string are placed on a smooth inclined plane of inclination
sin–1(1/3) such that some of them lie along the incline whereas the rest hang over the top of the
plane. If acceleration of each bead is g/2, the arrangement of beads is that-

(A) 12 hang vertically

(B) 10 lie along inclined plane
(C) 8 lie along inclined plane
(D) 10 hang vertically

11) A particle is projected with speed u from ground at an angle θ with the horizontal such that the

area under the trajectory is maximum. The value of θ is :

(A) 30°
(B) 45°
(C) 60°
(D) None of these

12) Two blocks A & B of mass ‘m’ & 2m respectively are joined to the ends of an undefomed
massless spring of spring constant ‘k’. They can move on a horizontal smooth surface. Initially A & B
has velocities ‘u’ towards left and ‘2u’ towards right respectively. Constant forces of magnitudes F
and 2 F are always acting on A and B respectively in the directions shown. The maximum extension

in the spring during the motion is

(A)

(B)

(C)

(D)

13) A small particle A is released from rest inside a fixed hemispherical bowl from the horizontal
position. Another identical particle B is resting at the lowest position. The right half of the bowl is
smooth and left half is rough with coefficient of friction µ ≥ 0. The mass of each particle is m and
radius of bowl is R. Then which of the following options is incorrect

If collision between the particles is perfectly inelastic and particles rise to a maximum height
(A)
of R/8 above the lowest point. Then work done against friction in this period is
If collision is perfectly elastic and particle B is just unable to collide with particle A for
(B)
the second time then total work done against friction in this period is mgR

If coefficient of restitution is and µ = 0 for left half of the hemisphere also, then
(C)
maximum potential energy achieved by B above the lowest point is mgR
If collision is perfectly elastic and particle B is just unable to collide with particle A, then
(D)
total work done against friction in this period is

14) A thin uniform annular disc (see figure) of mass M has outer radius 4R and inner radius 3R. The
work required to take a unit mass from point P on its axis to infinity is :
(A)

(B)

(C)

(D)

15) Two small balls of mass m each are suspended side by side by two equal threads of length L as
shown in the figure. If the distance between the upper ends of the threads be a, the angle θ that the
threads will make with the vertical due to attraction between the balls is :

(A)

(B)

(C)

(D)

16) Three rods A, B and C of thermal conductivities K, 2K and 4K, cross-sectional areas A, 2A and 2A
and lengths 2l, l and l respectively are connected as shown in the figure. If the ends of the rods are
maintained at temperatures 100°C, 50°C, and 0°C respectively, then the temperature θ of the
junction is:-

(A)

(B) 20°C

(C)

(D)

17) Figure shows a triangular plate ABC which is anisotropic. αx and αy are coefficients of thermal
expansion along BC and AB. The coefficient of thermal expansion along AC is :-

(A)

(B)

(C)

(D)

18) A lead pellet flying with a velocity of 100 m/s pierces a fixed board after which it's velocity
becomes 60 m/s. If 40% of energy lost increases the temperature of pellet, find change in it's
temperature. Specific heat capacity of lead = 125 J/kg K :

(A) 10.2°C
(B) 6.3°C
(C) 12.1°C
(D) 0.2°C

19) Steam at 100°C is passed into 1.1 kg of water contained in calorimeter of water equivalent 0.02
kg at 15°C till the temperature of the calorimeter rises to 80°C. The mass of steam condensed in
kilogram is :-
(A) 0.13
(B) 0.065
(C) 0.260
(D) 0.135

20) A transverse sinusoidal wave moves along a string in the positive x-direction at a speed of 10
cm/s. The wavelength of the wave is 0.5m and its amplitude is 10 cm. At a particular time t,
the snap-shot of the wave is shown in fig. The velocity of P when its displacement is 5 cm is :-

(A)

(B)

(C)

(D)

SECTION-II

1) A glass flask contains some mercury at room temperature. It is found that at different
temperatures the volume of air inside the flask remains the same. If the volume of mercury in the

flask is 300cm3, then find the volume of the flask. If your answer is N (in cm3), fill value of .
[Given that coefficient of volume expansion of mercury and coefficient of linear expansion of glass
are 1.8 × 10–4 (°C)–1 and 9 × 10–6 (°C)–1 respectively]

2) Two different rods A and B are kept as shown in figure. The variation of temperature of different
cross sections is plotted in a graph as shown in figure find ratio of thermal conductivities of B to A.
3) Suppose 0.5 mole of an ideal gas undergoes an isothermal expansion as energy is added to it as
heat Q. Graph shows the final volume Vf versus Q. The temperature of the gas is found to be x times

90 K. Find the value of x.

4) Three rods of equal length / are joined to form an equilateral triangle PQR. O is the mid point of
PQ. Distance OR remain the same for small change in temperature. Coefficient of linear expansion
for PR and RQ is the same, i.e., but that for PQ is . Then find the ratio .

5) Block on the sphere shown in figure is in equilibrium (it implies that net force is zero). If sphere
applies a force (N) of 3N on the block in the direction perpendicular to the surface of the sphere and
weight of the block (mg) is 5 N vertically downward. Find the force (in N) applied by the string on

the block (T), if it acts tangentially.

PART-2 : CHEMISTRY

SECTION-I
1)
The gas A2 in the left flask allowed to react with gas B2 present in right flask as
A2(g) + B2(g) 2AB(g);
Kc = 4 at 27°C. What is the concentration of AB when equilibrium is established ?

(A) 1.33 M
(B) 2.66 M
(C) 0.66 M
(D) 0.33 M

2) At what ratio of total pressure of reaction X 2Y and Z P + Q have same value of Kp if degree
of dissociation of X and Z are same :-

(A) 1 : 36
(B) 1 : 4
(C) 1 : 9
(D) 1 : 3

3) Two systems PCl5(g) PCl3(g) + Cl2(g)

and COCl2(g) CO(g) + Cl2(g) are simultaneously in equilibrium in a vessel at constant volume. If
some CO(g) is introduced in the vessel at constant volume, then at new equilibrium the
concentration of :-

(A) PCl5 increases

(B) PCl3 remains unchanged
(C) PCl5 decreases
(D) Cl2 increases

4) The solubility of Ba3(AsO4)2 (molar mass = 690) is 6.9 × 10–2 g/100 mL. What is the value of its Ksp?

(A) 1.08 × 10–11

(B) 1.08 × 10–13
(C) 1.0 × 10–15
(D) 6.0 × 10–13

5) Ksp of Ca(OH)2 is 4.0 × 10–6. At what minimum pH, Ca2+ ions start precipitating in 0.01 M CaCl2?

(A) 12 – log 2
(B) 12 + log 2
(C) 2 – log 2
(D) 2 + log 2

6) The solubility of solid silver chromate Ag2CrO4, is determined in three solvents

(Ksp of Ag2CrO4 = 9 × 10–12) :-
(I) Pure water
(II) 0.1 M K2CrO4
(III) 0.1 M Na2CrO4
Predict the relative solubility of Ag2CrO4 in the three solvent-

(A) I = II = III
(B) I < II < III
(C) II = III < I
(D) II < III < I

7) Acetic acid was titrated with NaOH. When 25%, 50% and 75% of titration is over then the

pH of the solution will be respectively: :-

(A)
5 + log , 5, 5 + log 3

(B)
5 + log 3, 4, 5 + log

(C)
5 + log , 5, 5 – log 3

(D)
5 – log , 4, 5 + log

8) Which of the following statement is wrong ?

(A) d-orbital taking part in dsp2 is

3
(B) d-orbital taking part in sp d is dxy.
(C) d-orbitals taking part in sp3d2 are and
(D) d-orbitals taking part in sp3d3 are , dxy and

9) Which of the following option is correct :

Time period of electron in the nth orbit for 'H' atom is proportional to n2 (n-principal quantum
(A)
number)
The maximum possible number of spectral lines in visible region when electron jumps from 7th
(B)
excited state to ground state in a 'H' atom are five.
The maximum number of electrons in Cr atom which have set (m = – 1 and s = – 1/2, n ≠ 2) are
(C)
'3'
When 28.6 eV of energy is given to 'H' atom in ground state the debroglie wave length of
(D)
ejected electron is Å

10) A2Ox is oxidised to AO3¯ by MnO4¯ in acidic medium. If 1.5 × 10–3 mole of A2Ox requires 40 ml of
0.03M KMnO4 solution in acidic medium. Which of the following statement(s) is/are correct?

(A) The value of "x" = 1

(B) The value of "x" = 3
(C) Empirical formula of oxide is AO3.
(D) Empirical formula of oxide is A2O.

11)

How many grams of KMnO4 will be present in 4 liters of 0.05 N KMnO4 solution ? KMnO4 is used as
oxidation agent in acidic medium.
(Atomic weight of KMnO4 = 158 g/mol)

(A) 58 gm
(B) 15.8 gm
(C) 6.32 gm
(D) 31.6 gm

12) 50 ml of hydrogen diffuse through a small hole from a vessel in 20 minutes. Time taken for 40 ml
of oxygen to diffuse under similar conditions through a same hole will be

(A) 12 minutes
(B) 64 minutes
(C) 8 minutes
(D) 32 minutes

13) Which gas show real behaviour ?

(A) 8g O2 at STP occupies 5.6 L

(B) 1 g H2 in 0.5 L flusk exerts a pressure of 24.63 atm at 300 K
(C) 1 mol NH3 at 300 K and 1 atm occupies volume 22.4 L
(D) 5.6 L of CO2 at STP is equal to 11 g

14)

If Z is a compressibility factor, van der Waals equation at low pressure can be written as:

(A)

(B)

(C)

(D)

15)
Select the correct order for dipole moment?

(A) NH3 > NCl3

(B) XeF2 = XeF4 < SO2
(C) P(CH3)2 (CF3)3 < P (CF3)2(CH3)3
(D) 1 & 2 both are correct

16) The xenon compound(s) that are iso-structural with and respectively are :

(A) Linear XeF2 and pyramidal XeO3

(B) Bent XeF2 and pyramidal XeO3
(C) Bent XeF2 and planar XeO3
(D) Linear XeF2 and tetrahedral XeO3

17) Wrong match is :-

(A) B < C < N < O (Ist IP)

(B) Al+3 < Mg+2 < Na+ < F– (Ionic radius)
(C) Li < Na < K (Metallic radius)
(D) I < Br < F < Cl (EA)

18) In which of following first is more stable than second :-

(A) a,c,d
(B) a,c,d,f
(C) b,c,e
(D) b,c,f

19) Product is :-

(A)

(B)

(C)

(D)

20) 1-Methylcyclohexane is allowed to react with B2H6. The product is then treated with H2O2 and

NaOH. The reaction is : ?

The product formed is :-

(A) 1-methyl cyclohexanol

(B) 2-methyl cyclohexanol
(C) (±) trans-2-methyl cyclohexanol
(D) (±) Cis-2-methyl cyclohexanol

SECTION-II

1) From the list below how many of them are stronger acid than benzoic acid

I. II.

III. IV.
V. VI.

VII. VIII.

IX. X.

2) How many of the following compounds will show geometrical isomerism?

3) For the given reaction how many mono bromo products are optically active (all isomers) :

4)

1 M benzoic acid (pKa = 4.2) and 1M C6H5 COONa solutions are given separately. What is the volume
of benzoic acid required to prepare a 93 mL buffer solution of pH = 4.5 ?

5) Total number of species which used all three p-orbital in hybridisation of central atoms and should
be non-polar also.

PART-3 : MATHEMATICS
 SECTION-I

1) The reflection of A(3, 4) in the line x + 2y = 5 is the point B. The reflection of B in line 3x – y = 8
is the point C, then the circumcenter of the triangle ABC is-

(A) (5, 6)
(B) (8, 9)
(C) (3, 1)
(D) (4, 5)

2) If 0 x 3π, 0 y 3π and cos x ⋅ sin y = 1, then the possible number of values of the ordered
pair (x, y) is :-

(A) 6
(B) 12
(C) 8
(D) 15

3) If (1 + x)n = , then

..... =

(A)

(B)

(C)

(D)

4) If x = then value of (1 + x)48 is :-

(A) 5
(B) 25
(C) 125
(D) 625

5) The sum of 'n' terms of series

1·4·7 + 4·7·10 + 7·10·13 + ....... ,

then a + b + c + d equals
(A) 100
(B) 212
(C) 112
(D) –112

6)

Let θ ∈ [0, 4π] satisfy the equation (sin θ + 2) (sin θ+ 3) (sinθ + 4) = 6. If the sum of all the values of
θ is of the form kπ, then the value of k is:-

(A) 6
(B) 5
(C) 4
(D) 2

7)

Root of the equaiton 4x + 6x = 9x is/are :-

(A) 0, 1

(B)

(C)

(D) None of these

8) equals :-

(A) cos y
(B) 1
(C) 0
(D) sin y

9) If G be the GM between x and y, then the value of is equal to :-

(A) G2

(B)

(C)

(D) 3G2

10) Coefficient of x2009 in (1 + x + x2 + x3 + x4)1001 (1–x)1002 is :-

(A) 0
1001
(B) 4 · C201
(C) –2009
(D) None of these

11) Match the following trigonometric ratios with the equation whose one of the root is given

List-I List-II

(A) cos20° (I) x3 – 3x2 – 3x + 1 = 0

(B) sin10° (II) 32x5 – 40x3 + 10x – 1 = 0

(C) tan15° (III) 8x3 – 6x – 1 = 0

(D) sin6° (IV) 8x3 – 6x + 1 = 0

(A) (A)→IV, (B)→III, (C)→I, (D)→II
(B) (A)→III, (B)→IV, (C)→I, (D)→II
(C) (A)→III, (B)→I, (C)→IV, (D)→II
(D) (A)→IV, (B)→II, (C)→III, (D)→I

12) If , then the value of

cosθ · cos2θ · cos22θ .... cos2n–1 θ is

(A)

(B)

(C)

(D)

13) The value of is equal

(A)

(B)

(C)

(D)

14) The equations of the sides AB and AC of a triangle ABC are (λ + 1)x + λy = 4 and λx + (1 – λ)y +
λ = 0 respectively. Its vertex A is on the y-axis and its orthocentre is (1, 2). The length of the tangent
from the point C to the part of the parabola y2 = 6x in the first quadrant is :

(A) 2
(B) 4
(C)
(D)

15) If , then p and q are roots of the equation:

(A)

(B)

(C)

(D)

16) In the right angle triangle as shown, an altitude is drawn from the right angle to the hypotenuse.
Circles are inscribed within each of the smaller triangles. What is the distance between the centres

of these circles?

(A) 6
(B) 7
(C) 8
(D) None of these

17) The natural numbers are grouped as follows {1}, {2, 3, 4}, {5, 6, 7, 8, 9}, .... , then the first
element of the nth group is-

(A) n2 – 1
(B) n2 + 1
(C) (n – 1)2 – 1
(D) (n – 1)2 + 1

18) Let A be a point on ellipse . Let the line passing through A and parallel to y-axis meet
the circle x2 + y2 = 9 at B such that A and B are on the same side of the x-axis. Then the eccentricity
of the of the locus of the point C on AB such that AC : CB = 4 : 3 as A moves on the ellipse

(A)

(B)
(C)

(D)

19)

The focal chord of y2 = 16x is tangent to (x - 6)2 + y2 = 2. Then the possible values of the slope of this
chord are

(A) {1, -1}

(B)

(C)

(D)

20) Let Q, R and S be four points on the ellipse 9x2 + 4y2 = 36. Let PQ and RS be

mutually perpendicular and pass through the origin. If where p and q are
coprime, then p + q is equal to :

(A) 143
(B) 147
(C) 137
(D) 157

SECTION-II

1) If |z1| = 1, |z2| = 2, |z3| = 3

and |9z1z2 + 4z1z3 + z2z3| = 12
then the value of |z1 + z2 + z3| is equal to :-

2) Let there be 15 letters . If the number of different arrangement of

these letters in a line so that there is atleast two alike letters (Q) between two distinct letters is ,
then 'k' is equal to

3) Tangents are drawn from (a, b) to the hyperbola 3x2 – 2y2 = 6 making angles θ1 and θ2 with
transvere axis. If tanθ1 tanθ2 = 2 then 2α2–β2=
4) If solution of the equation

3cos2θ – sinθ cosθ – 3sin2θ = 0 are and , then |r – s| =

5) If x = – , then the value of x3 + 3x – 4 is equal to ______.

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C A A B D C C B D C B D A B B C A A C

SECTION-II

Q. 21 22 23 24 25
A. 8.00 2.72 4.00 4.00 4.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B C B B C A B D B C B C B D A A A C C

SECTION-II

Q. 46 47 48 49 50
A. 6.00 6.00 4.00 31.00 2.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A D C C B B A C A B A C C A D D B A D

SECTION-II

Q. 71 72 73 74 75
A. 2.00 7.00 7.00 9.00 10.00
 SOLUTIONS

PART-1 : PHYSICS

1)

Explanation Question: The problem asks to identify the graph that best represents the
variation of the acceleration 'a' of a spring operated latch with the distance x it moves before
being stopped, assuming negligible friction and elastic behaviour of the spring.
Concept: Hooke's Law and newton's second law
Solution:
Spring force on the latch, Fs = k ( – x)

thus,
where is the natural length of spring.

Final Answer
The correct option is (1)

2)
Elastic energy density at

= constant

= constant

Y ∝ x2

3) Stopping distance for brake

Turning distance for 90o turn = R

∴ (S < R) so he should apply brake.

4)
 5)

Explanation Question: Ratational equilibrium at a rod dipped in liquid is to be analysed

Concept: This question is based on rotational equilibrium in fluids
Solution:

where
Balancing torque about hinge

[where θ is very small]

Final Answer
The correct option is (2)

6) In case of minimum density of liquid, sphere will be floating while completely submerged
So mg = B

=
On Solving

7) When block is displaced slightly by x

8)
9)

...(1)

...(2)
...(3)
From (1) & (2)
of point b = of point a
...(4)
Hence

10) Question explanation: The problem describes a system of sixteen beads of equal mass on
a smooth incline plane with an inclination angle θ = sin–1(1/3). Some beads are on the incline
while the rest hang over the top. The acceleration of each beed is given g/2. we need to
determine the arrangement of the beads.
Concept :- Newton's second law of motion.
Solution :-

Let n beads each of mass m are hanging vertically, then

n mg – T = nm . g/2

_______(1)
also,

Final Answer: The correct option is (4)

 11)

Area (A) =

y = x tan θ –

θ = 60°

12)

In frame of centre of mass

Work energy theorem in centre of mass frame →

(x1 + x2)2

13)
(Work done against friction) Wf = loss in M.E

= =

(Work done against friction) Wf = loss in M.E.

= = mgR

V1-V2 = ... (1)

V1-V2 = ... (2)
From (1) and (2),

P.E. =

14)

We know that the work required to take a unit mass from P to infinity = −Vp, where −Vp is the
gravitational potential at P due to the disc. To find Vp, we divide the disc into small elements,
each of thickness r. Consider one such element at a distance r from the center of the disc as
shown.

Mass of the element dm

Thus,

Putting r2+16R2 - x2, we get 2rdr = 2xdx or rdr = xdx

When r = 3R,
When r = 4R,

or

15)

dividing we get
16) Let RA, RB and RC be the thermal resistance of rods A, B and C respectively. Then

RA =

and RC =
Since thermal current

H=
or RH = θ1 – θ2
∴ 100 – θ = RAHA ...(i)
θ – 50 = RBHB ...(ii)
θ – 0 = RCHC = RC(HA – HB) ...(iii)
On substituting values of RA, RB and RC, we get

100 – θ =

=
θ = 20°C

17)
Δℓ = ℓαΔT

18) Question Explanation:

A lead pellet flying with a velocity of 100 m/s pierces a fixed board, reducing its velocity to 60
m/s. 40% of the kinetic energy lost is converted into thermal energy, increasing the pellet's
temperature. The change in temperature of the pellet is to be determined.

Concept:
Kinetic energy converted into thermal energy.

Solution:

.4 × (1002 – 602) = mcΔT

 ΔT ≈ 10.2°C

Final Answer:
The correct option is (1).

19) If the mass of steam condensed in the calorimeter is m, the heat lost by the steam in the
calorimeter is used up in
(i) Condensation = 536 m kcal and (ii) Keeping the temperature of steam down from 100°C to
80°C = m × 1 × (100 – 80) = 20 m kcal
Total heat lost by the steam
= 536 m+20 m = 556m
Also heat gained by (water + calorimeter) in raising the temperature from 15°C to
80°C = (1.1 + 0.02) × 1 × (80 – 15) = 72.8 kcal
Since, Heat lost = Heat gained

556 m = 72.8 m = = 0.13 kg

21) We have
Vflask = VHg + Vair
As (ΔV)air = 0
∴ (ΔV)flask = (ΔV)Hg
∵ Cavity having same expansion co-efficient for material
∴ Vf γf ΔT = VHg γHg ΔT

∴ = = =
3
∴ Volume of flask = 2000 cm

22)

23)

24)

⇒ (OR)2 = (PR)2 - (PO)2 = l2 -(l/2)2

⇒ (OR)2 =[l(1 + α2t)]2 -

⇒
Neglecting and , we get

25) Question Explain: The problem describes a block that is placed on a spherical surface
and is held by a string. The block is in equilibrium under three concurrent force. The objective
is to find the magnitude of the tension force.

Concept: This question is based on Equilibrium, Newton's Laws of Motion

Solution:

The value of tension force is 4N.

Final Answer: 4.0

PART-2 : CHEMISTRY

26)

⇒ mole

[AB(g)] =

27) X 2Y Z P +Q
1 – α1 2α1 1 – α2 α2 α2
 (α1 = α2) Given

28)

Cl2 will reduce. So to counteract PCl5 decreases

29) s = 6.9 × 10–2 gm/100 ml

= 10–4 mol/100 ml
= 10–3 mol/lit
Ksp = 108 s5
= 108 × 10–15 = 1.08 × 10–13

30) CaCl2 → Ca+2 + 2Cl

0.01 0.01 2 × 0.0
Ca(OH)2 Ca+2 + 2OHΘ
S 2S
(S' + 0.01) 2S' (in CaCl2)
ksp = [Ca+2] [OH–]2 = (S' + 0.01) (2s')2
= (S' + 0.01) × 4s'2

ksp = 0.01 × 4.S'2 S' =

S' = = 10–2
[OH–] = 2 × 10–2 pOH = 2 – log 2
p17 = 14 – (2 – log2) = 12 + log 2

31) Solubility order – other solvent > H2O > Common ion effect.

32)

When 25 % litration is complete

[salt] = 25 [acid] = 75 Ka = 10–5 pKa = 5

pH = pKa + log = 5 + log

when 50 % litration is complete
[salt] = 50 [acid] = 50
pH = pKa + log =5
when 75% titration is complete
[salt] = 75 [acid] = 25

pH = pKa + log = 5 + log3

33) In sp3d hybridisation, participates.

34) (1)

(1) → Incorrect
(2) Incorrect because number of spectral lines will be 6.

The maximum number of electrons in Cr atom which have m = – 1 and s = – 1/2

where n ≠ 2 are '2' i.e., one electrons from 3p (m = – 1, s = – ) and one electron from

3d (m = – 1, s = – )
(4)

35) 1.5 × 10–3 × (5 – x) × 2 = 0.03 × 5 ×

x=3

36)

37)
38) For real gas Z = ≠1

39)

Compressibility factor
(for one mole of real gas)
van der Waals equation

(V - b) = RT
At low pressure, volume is very lager and hence correction term b can be neglected in
comparison to very large volume of V.
i.e. V - b ≈ V

V = RT

PV + = RT

PV = RT -

Hence,

40)

41)

42)

I.P. B < C < O < N

 43)

44)

Question Explanation:
The question involves the alkoxymercuration–demercuration reaction of an alkene using
methanol.

Concept:
This reaction is based on alkoxymercuration–demercuration, a variant of oxymercuration in which an
alcohol acts as the solvent and nucleophile.

Solution:
Alkoxymercuration–demercuration proceeds via Markovnikov addition without carbocation
rearrangement. When CH3OH is used instead of water, the alkoxy group (–OCH3) adds to the
more substituted carbon of the alkene, while hydrogen adds to the less substituted carbon.

Based on this regioselectivity, the correct product corresponds to Option (3).

Final Answer: Option (3)

45)
(±)Trans 2-methylcyclohexan-2-ol

46) Acids, I, III, IV, VII, VIII and IX are all stronger than benzoic acid. I is stronger because of
stabilisation of conjugate base by intramolecular H-bonding.

III is stronger because from meta position, —OH exert

only – I-effect, its electron donating resonance effect has no role on acidic strength.
 IV is stronger acid due to loss of planarity of —COOH with phenyl ring, hence absence of
electron donating resonance effect as phenyl rings on —COOH increases acidic strength.
VII is stronger because a sulphonic acid is stronger than a carboxylic acid.
VIII is stronger because electron withdrawing inductive effect of one —COOH over other
increases acidic strength.
IX is stronger due to only – I-effect of methoxy group operate from meta position but not its
electron donating resonance effect.

47) 1, 2, 4, 6, 7, 8

48) +

+ +

49)

V = 31 ml

50)

PART-3 : MATHEMATICS
51)

52) max cosθ = 1. So, cosx ⋅ siny = 1

⇒ cos x = 1, sin y = 1 or cos x = –1, sin y = –1
cos x = 1, sin y = 1 ⇒ x = 0, 2π

and y = (from the equation)

cos x = 1, sin y = –1

⇒ x = π, 3π and y = (from the equation)

∴ the required number of ordered pair
=2×2+2×1=6

53)

54) x =

x=

x=
x + 1 = 51/16
(x+1)48 = 53 = 125

55)
 Tn = (3n – 2)·(3n + 1)·(3n + 4)
using vn method sum.

= [(3n – 2) (3n + 1) (3n + 4) (3n + 7) + 56]

= [(9n2 – 3n – 2) (9n2 + 33n + 28) + 56]

= [81n4 + 270n3 + 135n2 – 150n]

= [27n4 + 90n3 + 45n2 – 50n]

56)

(sinθ + 2) (sinθ + 3) (sinθ + 4) = 6

L.H.S. ≤ 6 and R.H.S. = 6
Therefore, equality only holds if
sinθ = –1 or θ = 3π/2, 7π/2
∴ Sum = 5π ⇒ k = 5

57) 4x + 6x = 9x

58)

59)

x, G, y
G2 = xy
60) The given expression can be written as

(1 – x)1002 = (1–x) (1–x5)1001

So all power of x will be 5 m or 5m +1 (m∈I)
so coefficient of x2009 will be zero
Final Answer: Option (1)

61) (A) A = 20° ⇒ 3A = 60° ⇒ cos3A = 1/2

⇒ 8cos320° – 6cos20° – 1 = 0
(B) A = 10° ⇒ 3A = 30° ⇒ sin3A = 1/2
⇒ 8sin310° – 6sin10° + 1 = 0
(C) A = 15° ⇒ 3A = 45° ⇒ tan3A = 1
⇒ tan315° – 3tan215° – 3tan15° + 1 = 0
(D) A = 6° ⇒ 5A = 30° ⇒ sin5A = 1/2
⇒ 32sin56° – 40sin36° + 10sin6 – 1 = 0​​

62) Given series = =

63)
64)

65)

p and q roots of the equation

66) Let the Δ be

BD = 12

AD = 9
CD = 16
distance C1C2

67) Let Ist element of nth group is = Tn

1, 2, 5, 10, ....., Tn
= (02 + 1), (12 + 1), (22 + 1), ....., [(n – 1)2 + 1]
∴ Tn = (n – 12) + 1

68) A(3cosθ,2sinθ) B(3cosθ, 3sinθ)

C(h, k) divide line A and B in the ratio of 4 : 3

69)

Focal chord is y = m (x - 40
70)

71)

⇒ |z1 z2 z3 ( + + )| = 12
72) _ L _ M _ N _ O _ P _

x1 x2 x3 x4 x5 x6
where x2, x3, x4, x5 > 2 and x1, x6 > 0
Required number of arrangements

= 7C2 × 5! =
Hence, k = 7

73) Hyperbola …(1)

let slope of tangent = m
∴ eqn of tangent from point (α,β) –
y – β = m(x –α)
⇒ y = mx + β – mα …(2)
line (2) touches hyperbola (1)
∴ c2 = a2m2 – b2
(b – mα)2 = 2m2 –3
⇒ m2(α2–2) – 2mβa + β2 + 3 = 0 …(3)
eqn (3) is quadratic in 'm'

∴ &
tanθ1 tanθ2 = 2 ⇒ m1.m2 = 2
β2 + 3 = 2α2 – 4
⇒ 2α2 – β2 = 7

74) 3cos2θ – sin θ cos θ – 3sin2θ = 0

3– tan θ – 3tan2θ = 0
3tan2θ + tan θ – 3 = 0

tan θ =

tan θ = tan θ =

tan θ =

θ = nπ +

⇒ r=6
s = –3
⇒ |r – s| = 9

75)