ANSWER KEYS
PART-1 : PHYSICS
SECTION-I
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B D A B B A B B B D D C C B A D C D B A
SECTION-II
Q. 21 22 23 24 25
A. 10 24 12 23 4
PART-2 : CHEMISTRY
SECTION-I
Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A D B D B B A B D B C C D C A B B D C A
SECTION-II
Q. 46 47 48 49 50
A. 5 48 7 5 50
PART-3 : MATHEMATICS
SECTION-I
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D B A B C C D C C A B B B D C C A A D A
SECTION-II
Q. 71 72 73 74 75
A. 10 4 9 14 0
SOLUTIONS
PART-1 : PHYSICS
1) For same deviation i & e are interchanged. δ = (i + e) – A
A = (i + e) – δ
A = (17 + 39) – 27
A = 56 – 27 = 29º
2) In Forward bias, ideal diode behaves as a short circuit
14 kΩ & 12 kΩ are shorted
so
3)
Since, L = constant
mvr = constant
as r decreases from aphelion to perihelion, v increases.
4)
5)
∴ [At] = [F]
⇒ [AT] = [M L T–2]
⇒ [A] = [M L T–3]
[x] = [Bm]
⇒ [L] = [BM]
⇒ [B] = [LM–1]
[M2 T–3]
6)
C
=A+B
7) Correct answer is (B)
8) Taking out of page as +ve direction.
for ring Icm = mR2
L = – mvR
L<0
as L is into the page, the ring will move towards right
For Solid sphere Icm =
L
out of page
as L is out of the page, the sphere will move towards left.
9)
Correct answer is (B)
10) as
3m(Δx2) + m(–Δx1) = 0
3Δx2 = Δx1
Δx1 + Δx2 = ℓ
11)
12) V1 =
and
,
On calculation
13) For first minimum a sin θ = l
So = sin 30° =
Now for first secondary maximum a sinθ =
Therefore sin θ =
⇒ θ = sin–1
14) i2rms = , i = 5t =
15)
16)
Correct answer is (D)
17)
Correct answer is (C)
18)
Correct answer is (D)
19) Direction of propagation,
20) We know for paramagnetic material
B0 = external magnetic field
21) For plastic plate charge will be distributed on a single surface
So, &
in copper plate, charge will be distributed on both the surface
so σA × 2 = Q
Electric field due to copper plate =
22) By first polaroid P1 intensity will be halved then P2 and P3 will make intensity cos2(60°) and
cos2(60°) times respectively.
Intensity out = = = 24
23) Diagram shows Δx at different point on circle From diagram
it is clear that number of maxima = 12
24)
Req. =
25) E2n – E1 = 204
....(i)
and E2n – En = 40.8
....(ii)
From (i) & (ii)
n=2
& E1 = –217.6 eV
E1 = –13.6 Z2
Z=4
PART-2 : CHEMISTRY
26) ΔTb = [Link].m
10.4 = 4 × 0.52 × m
⇒ nsolute = 5 × 0.25 = 1.25
m = 40
27) NCERT statement.
28) Nitrous acid gives ion (E⊕) which attacks phenol at less hindered p-position leading to
formation of p-nitrosophenol.
29) Due to common ion effect, dissociation of both salt is suppressed. Hence each salt
dissolves less than it would in pure water.
So simultaneous solubility < individual solubility.
30) FeSO4. (NH4)2 SO4 · 6H2O (Mw 392 gm)
1 mol of this compound contain = 64 gm of 'S' present along with 2 mol NH4+ in solution
Since the amount of solute low dsolution = 1gm/ml
Molarity of
31) First check central atom 3d < 4d < 5d Co → belongs to 3d
Rh → belongs to 4d
Ir → belongs to 5d
then check ligand strength
Cl– < CN–
strong ligand
32)
Theory Based.
33) Eº = –0.12 V
Eº = –0.15 V
Eºcell
= –0.15 V – 0.12 V
= –0.27 V
Eºcell = –ve
Non-spontaneous.
Eºcell = 0.15V
4+ –
A→A + 4e Eºcell = 0.03V
34)
The correct answer is option (D)
35)
pKa = 4.95
pKa = 2.17
pKa = 3.19
36) Last line of lyman series ∞ → 1
ΔEn = Eº
ΔEn for =
n = 10
no. of Paschen line = 8 to 3
⇒8–3=5
37) Fe+2 —→ Turnbull's Blue ppt.
38)
39) (i)
(ii) 2CO + O2 → 2CO2
i 1 1 –
r 1 0.5 1
f 0 0.5 1
40)
41)
42)
43) No. of unpaired e– = 3
44)
The correct answer is option (C)
45)
The correct answer is option (A)
46) Compound :- 1,2,3,5,9 are aromatic.
47) 2A(g) + B(ℓ) → 2C(g) + D(g)
Δng = 1
ΔrH = ΔrE + ΔngRT
ΔrH = –20 + 2.4
= – 17.6 kJ/mol
ΔrH = Eaf – Eab
Eab = 30 – (–17.6)
= 47.6 kJ
48) Pb(NO3)2 + 2KI → PbI2(s) + 2KNO3(aq)
50 milli 200 milli
100 milli
(Pb+2) = = 2 × 10–7 M
49) NCERT Based
50) gm equivalent of KClO3 =
3 × 10–4 = 10 × 10–3 ×
x = 50%
PART-3 : MATHEMATICS
51) Apply LMVT in f '(x), x ∈ [–4,0]
f '(0) ≥ –2 ....(i)
Apply LMVT in f '(x), x ∈ [0,4]
Also
f '(0) ≤ –2 ....(ii)
from (i) & (ii) we get f '(0) = –2
Now again apply LMVT in f '(x), x ∈ [0,x]
Also by LMVT in f '(x), when x ∈ [x,4]
⇒ f '(x) ≤ –14 + 3 (4 – x), ∀ x ∈ (0,4)
⇒ f '(x) < 0 ⇒ f(x) is decreasing for ∀ x∈(0, 4)
⇒ f(x) < 0; ∀ x ∈ (0, 4) ; f(0) = 0 g'(x) = f(x) < 0 ; ∀ x ∈ (0, 4)
g(x) decreases in (0, 4)
Also g"(x) = f '(x) < 0
g(x) is concave down is (0, 4)
52) Let 3K = α, 2K = β
Now,
=
=2
53)
Equation of normal at point P (10cosθ, 5sinθ) is
10x sec(θ) – 5y cosec(θ) = 75
2xsec(θ) – ycosec(θ) = 15
Perpendicular distance from origin on normal is equal to radius of circle
⇒ r is maximum when
⇒ rmax = 5
54)
A=
12A = 41 × 4 = 164
55) Mean of A = μA
Mean of B = μB = 2μA
Variance of A =
Variance of B =
Mean of combined data =
56) E:
P(1 + r1cosθ, 2 + r1sinθ)
Q(1+r2cos(90 + θ), 2 + r2sin(90+θ))
P & Q lies on the ellipse, then
Similarly, we get
57) Tangent at (x1, y1) on the parabola y2 = 4ax
∴ yy1 = 2a(x + x1)
any point on this tangent will be with respect to circle
is xx' + y.
⇒ xx'y1 + 2ayx' + 2ayx1 = a2y1
⇒ (2ayx1 – a2y1) + x'(xy1 + 2ay) = 0
Which is family of straight lines passing through point of intersection of 2ayx1 – a2y1 = 0
and xy1 + 2ay = 0
⇒
The fixed point is (x2, y2)
then
58) ⇒
59)
(A)
(3 vertices in single phase) + (selecting adjacent faces 1 – 2 or 2 – 3 or 3 – 4 or 4 – 5 and on
side 5 or 6 is selected automatically)
1→OAED, 2→AEFB, 3→BFGC,
4→GCOD, 5→DEFG, 6→OABC
(B)
(C)
(D)
60)
= 61012 = (7 – 1)1012 = 49r + 22
61) When
⇒ cot (x) < cot2(x) < cot3(x)
and x2 < x ; –x2 > –x
⇒ I4 > I3 > I2 > I1
62)
⇒ x = 0 is not the solution
⇒∀x∈ ; f(x)
f(x) = sin–1 (x – 1)2 +
& g(x) = tan–1(x) are strictly increasing functions,
where
so 1 solution.
63) Let P(t, t2) be the parametric co-ordinates of any point on the parabola y = x2
Hence normal at P is
If this line meets the curve again at Q(t1, t12), then
If ℓ is length of the normal chord then z = (ℓ)2 = PQ2
Let put 4t2 = p ; where p > 0
and
Hence z is minimum when p = 2 = 4t2
64) Clearly domain is [–1, 1]
sin–1x + tan–1x is increasing in [–1, 1]
and cos–1x + cot–1x is decreasing in [–1, 1]
So, maximum value of the function occurs at
Clearly maximum value is 3.
65)
Let the angle be θ between and
2 + 2 cosθ + 4 sin2θ = 4
2 + 2 cosθ – 4cos2θ = 0
Let cosθ = t then
2t2 – t – 1 = 0
2t2 – 2t + t – 1 = 0
2t (t – 1) + (t – 1) = 0
(2t + 1) (t – 1) = 0
t= or t=1
not possible as θ ∈ (0, π)
Now,
S1 is correct
S2 projection of on
C option is true.
66) Let, centre
Solving (i) & (ii)
67)
68) Let log30(log1530) = t
& (log30(log3015) = (log30(log1530)–1 = –t
ƒ(t) + ƒ(–t) = 12
ƒ(–t) = 5
69)
= [Link]
70) Reflexive and symmetric are obvious.
for transitive consider
71) z = x + iy
x – 2 = |(x – 7) + i(y + 2)|
x2 + 4 – 4x = x2 + 49 – 14x + y2 + 4 + 4y
10x – 45 = (y + 2)2
(y + 2)2 = 10(x – 9/2)
y2 = 4ax
Focus ≡ (7, –2)
equation of directrix ⇒ x = 2
Let z0 = 2 + αi
PQ is focal chord
minimum value of PQ = 10
72) 3xy dy – 2x4dy – 4x3ydx + y2dx = 0
Multiply with y
(3xy2dy + y3dx) – (2x4y dy + 4x3y2 dx) = 0
d(xy3) = d(x4y2)
xy3 = x4y2 + c
xy3 = x4y2
y = x3
73) Symmetric matrix
⇒
Skew symmetric
⇒ type
for Symmetric (b = c)
|A| = a2 – b2 = (a – b) (a + b) = 5λ
Solve in the set {0,1,2,3,4};
* a = b ; 5 solutions (one for each a).
* a + b ≡ 5λ ; 5 solutions (0,0), (1,4), (2,3), (3,2), (4,1)
So total solution 5 + 5 – 1 = 9.
For Skew symmetric (a = 0, c = – b)
|A| = b2 = 5λ so b = 0
only zero matrix is a solution
so total number of solution are 9.
74)
75) Required plane will contain the points (1,2,3) and (-1,-3,1) and parallel to line having
direction ratios (2,3,4).
let equation of plane be a(x - 1) + b(y - 2) + c(z - 3) = 0
Now (-1, -3, 1) also satisfy above equation
a(-1-1) + b(-3-2) + c(1-3) = 0
-2a - 5b - 2c = 0 ......(1)
and 2a + 3b + 4c = 0 .......(2)
solving (1) and (2)
so, a = -7k, b = 2k, c = 2k
therefore equation of plane is
-7k (x - 1) + 2k(y - 2) + 2k (z - 3) = 0
7(x - 1) - 2 (y - 2) - 2 (z - 3) = 0
7x - 2y - 2z + 3 = 0