ANSWER KEYS
PART-1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4 5 6 7 8
A. A,B,C A,C,D B,C A,B,D A,C A,B,C B,D A,B,C
SECTION-I (ii)
Q. 9 10 11 12
A. C B D C
SECTION-II
Q. 13 14 15 16 17 18
A. 0.00 2.00 1.00 or 1.02 0.25 1.50 2.00
PART-2 : CHEMISTRY
SECTION-I (i)
Q. 19 20 21 22 23 24 25 26
A. A,C,D A,C A,B,C,D A,B C,D A,B,D B,C B,D
SECTION-I (ii)
Q. 27 28 29 30
A. A B D A
SECTION-II
Q. 31 32 33 34 35 36
A. 3.00 18.00 6.00 2.11 5.00 8.00
PART-3 : MATHEMATICS
SECTION-I (i)
Q. 37 38 39 40 41 42 43 44
A. B,C A,B,C A,C A,B,C A,D A,C C A,B,C
SECTION-I (ii)
Q. 45 46 47 48
A. C B D B
SECTION-II
Q. 49 50 51 52 53 54
A. 8.00 6.00 5.00 0.00 8.00 1.00
SOLUTIONS
PART-1 : PHYSICS
1)
Applying WET from (1) to (2)
wg + wT = KF – KI
mgℓsinθ =
v=
vertical component of velocity = v cos θ
vy =
for vy to be max ⇒ tanθ =
⇒v= =
(B) Tension in thread
T – mgsinθ =
T = mgsinθ +
T = mg +
T=
(C) Acceleration of object
aNet = =
aNet =
2) (A) Friction force acts between block and plank which will be kinetic in Nature and hence it
performs work due to which energy of system will be lost in the form of heat, hence kinetic
energy of system will not be cons. (C)
For system (τNet)origin ≠ 0. Hence angular momentum is not conserved.
(D) ∵ (Fext)x = 0 ⇒ (pI)x = (pf)x.
⇒ mv0 + 0 = 2m(v) ⇒ v =
(KE)initial = , (KE)final =
(KE)final =
∵ there is a net loss of kinetic energy due to friction between and plank, there fore wfriction ≠ 0
3)
Let a = 5ℓ; b = ; c = 7ℓ
Area of triangle
Now Leff =
Toscillation =
and this result is also independent from "M".
4) Charge particle will move in helical path with increasing pitch
along z axis where radius is given by R = at t = the particle moves in half revolution so
y co-ordinate will be .
(B) ∵ Vinitial along z axis is 0 and it accelerates along z-axis with acceleration .
Sn = u +
th =0+
Therefore the distance between two consecutive point on the z-axis where the particle touches
the z-axis is an odd multiple of constant distance.
(D) will meet z-axis after 1 revolution i.e. τ =
5) Before collision
After collision
loss in KE due to collision =
(KEloss)max =
This loss of energy is uitilised for excitation (ΔE)min req. for excitation = 10.2 eV.
⇒ (KE)incident = 20.4 eV
If incident neutron has KE less than 20.4 eV than collision will be elastic in nature, and
neutron will give its whole kinetic energy to hydrogen atom.
6)
(A) ΔABC and ΔCDE are similar so
;
wf = 6.0 mm
(B) Energy of incident beam = Energy of outgoing beam
(Intensity × Area × time)incoming = (Intensity × Area x time)outgoing
⇒ If = 1.5625 kW/m2
(C)
d = f2 – f1
d = (30 – 26)on
d = 4cm
7)
Four forces will act on ball
(1) gravitational (2) Normal (3) Static friction (4) Lorentz force
None of these forces perform mechanical work on the ball, so kinetic energy of ball remains
conserved. Hence speed of com will be v0.
QvB – F = mΩ2r .....(1)
v0 = Ωr = ωR .....(2)
Torque exerted due to magnetic field
+ F.R = .....(3)
from (1), (2) and (3)
r=
8)
L. + iR = ε =
Let C = ⇒
⇒I =
Case-I :
If C < 0, I↓
⇒ A is true so C is also true
Case-2 :
C > 0, I
⇒ B is true
9)
Mg – NA – f = may ; NB = Max
ax = ; ay = initially
(2) Mg – NA – =
(3) NB =
NA – NB – µNB =
NA =
mg = (µ + 1) + (µ + 1) +
g=
α= ;α=
aA = ax + =
NA = =3× × =6
aCOM = ; aCOM =
10)
M = 1kg ; L = 2M, g = 10 m/s2
mg – NA = may
mg –
aA = ; mg =
ay = ;g=
g= ;α=
aA = = 6 m/s2 Ans
α= rad/s2 Ans
NA = = 4N ans
aCOM = Ans.
11)
As we close switch initially AB forms closed circuit & capacitor behaves like plane wire.
Equivalent circuit
Req = 3Ω
(I) i = = 10 A (R)
Current in both branches will be equal (5 A each)
vCD = iCDRCD = 5 × 2 = 10V (R)
iAB = i – iCD = 10 – 5
vAB = 0 (short circuit) (Q)
12)
As we close switch AB behave as open circuit immediately after closing the switch
(I) i = A(T)
(II) VCD = iRCD = (S)
(III) iAB= 0 (open circuit) (Q)
(IV) vAB = 15 = VCD (S)
13)
Correct Answer is 0
14)
Area of BCD = = 3πa2
Area of AFE = = πa2
Area inside the loop is = 2πa2
0
thus ε = = 2πa2B ωsinωt
15)
Correct Answer is 1.00 to 1.02
16)
Correct Answer 0.25
17)
De Brogile relation
;
Given :
vp = 3ve ,
mp = 1.5 × 10–27 kg
Given :
mP = k × 10–27 kg
k = 1.5
18)
Correct Answer is 2
PART-2 : CHEMISTRY
19) Cu2SO4(aq) → Cu+1(aq) → Cu2+(aq) + Cu(s) as Cu+1(aq) disproportionates in aqueous
medium
CO3+ → CO2+ E° = +ve
Cr2+ is a good reducing agent and evolve hydrogen gas from dilute acids.
20) B(OC2H5)3 + H2
H3BO3 + Na[B(OH)4]
21) 2PbO.PbO2 + HNO3 → Pb(NO3)2 + PbO2 + H2O
PbO + HNO3 → Pb(NO3)2 + H2O
PbO2 is filtered out as such
so, Here HNO3 is behaving as acid only and not as oxidising agent
(B) POCl3 + SOCl2
(C) C + H2O
(D) XeO3 + HF
22) Feo + + inert impurity = 5g
No of equivalents of
Fe2O3 = No of equivalents of KI
No of equivalents of I2
⇒ moles of Fe2O3 =
= 2.5 × 10–3 (in 40 mL solution)
So total moles of Fe2O3 = 2.5 × 10–3 × 5
= 12.5 × 10–3
So moles of Fe2O3 = moles of FeO = 0.0125
So mass of Fe2O3 = 0.0125 × 160 = 2g ⇒ % of Fe2O3 = 40%
mass of FeO = 0.0125 × 72 = 0.9 g ⇒ % of FeO = 18%
So % of inert impurity = 100 – 40 – 18 = 42%
23)
24) For free expansion
Wsys = 0, qsys = 0
ΔSsys = 2.303 × 1 × 8.314 × log 2 = 5.8 J/k
ΔSsys > 0
25)
The correct answer option is (B), (C)
26)
The correct answer option is (B), (D)
27) The correct answer is option (A)
28) The correct answer is option (B)
29) Correct answer is option (D)
30) Correct answer is option (A)
31) [Co(H2O)3]3+, [Co(CN)6]3–, [Ni(CN)4]2–
32)
X → Na4 [Fe(CN)5(NOS)]
CN–1 → ambidentate with donor sites C and N
NOS–1 → ambidentate with donor sites N, O, S
[Fe(CN)5(NOS)]4–, [Fe(CN)4(NC)(NOS)]4–, [Fe(CN)3(NC)2(NOS)]4–, [Fe(CN)2(NC)3(NOS)]4–,
[Fe(CN)(NC)4(NOS)]4–, [Fe(NC)5(NOS)]4– → 6 isomers
Similarly 12 more
33)
⇒ Total 6 moles of gaseous products
34) Au+ + 2CN– [Au(CN)2]–
At time t a b c
Given
So
35)
The correct answer is 5.00
36)
The correct answer is 8.00
PART-3 : MATHEMATICS
37) We have
= 10 + 15 + 20 – 8 – 9 – n(C ∩ A) + n(A ∩ B ∩ C)
= 28 – {n(C ∩ A) – n(A ∩ B ∩ C)} ...(i)
Since n(C ∩ A) ≥ n(A ∩ B ∩ C)
We have n(C ∩ A) – n(A ∩ B ∩ C) ≥ 0 ...(ii)
From (i) and (ii)
n(A ∪ B ∪ C) ≤ 28 ...(iii)
Now,
= 10 + 15 – 8 = 17
and
= 15 + 20 – 9 = 26
Since, and
and
Hence ...(iv)
From (iii) and (iv) we obtain
26 ≤ n
Also is a positive integer
38) |z1| = |z2| = 1 ⇒ a2 + b2 = c2 + d2 = 1 ...(1)
and Re
⇒ ac + bd = 0 ...(2)
Now from (1) and (2), a2 + b2 = 1
...(3)
Also
⇒ b2= c2 ...(4)
[From (1) and (4)]
and [from(1) and (4)]
Further
[From(2)]
39)
Let where I ∈ N and 0 < F < 1
Let
...(i)
⇒ I + F + G = an even integer
⇒ F + G = an even integer – I
⇒ F + G = an integer
⇒ F + G = 1 [since 0 < F < 1, 0 < G < 1]
Putting F + G = 1 in Eq. (i), we get
I + 1 = 2m+1 × an integer
⇒ 2m+1 is a factor of the integer just greater than
40)
Verticles of the given triangle are (0, 0) and so that the area of the triangle
is equal to
Since m1, m2 are the roots of x2 – ax – a – 1 = 0
so m1 + m2 = a, m1m2 = – (a + 1)
⇒ (m1 – m2)2 = a2 + 4(a + 1) = (a + 2)2
⇒ m1 – m2 = ± (a + 2)
So the required area is
Since the area Δ is a positive quantity
if a > –1.
or a < – 2 and if –2 < a < – 1
41)
Equation of tangent at (x, y),
∴ Coordinate of A is
Radius vector
Area ΔOAP = ΔAPM
This is a linear equation and
∴ Solution is
where c is an arbitrary constant.
42)
Leads to 2α3 + 10α + 12 = 0, α2 + 6α = 0,
6α2 – 6α – 6 = 0 which do not have a common solution
If
α=0
then
∴ The vector product is
43) The rod sweeps out the figure which is a cone.
The distance of point A(1, 0, –1) from the plane is
The slant height of the cone is 2 units.
Then the radius of the base of the cone is
Hence, the volume of the cone is cubic units.
Area of the circle on the plane which the rod traces is 3π.
Also, the centre of the circle is Q(x, y, z).
Then or
44)
45)
(I)
For limit to exist and non zero ⇒ b = 1
(II)
⇒ a1/3 = 2
⇒a=8
(III)
46)
(I)
For limit to exist and non zero ⇒ b = 1
(II)
⇒ a1/3 = 2
⇒a=8
(III)
47) (I)
(II)
⇒ f2(1) – f2(0) = 0 and f3(1) – f3(0) = 54
Solving, –2f3(0) = 54
f3(0) = – 27
f(0) = –3
(III)
= 243 + 243
= 486
48) (I)
(II)
⇒ f2(1) – f2(0) = 0 and f3(1) – f3(0) = 54
Solving, –2f3(0) = 54
f3(0) = – 27
f(0) = –3
(III)
= 243 + 243
= 486
49) Given 2f(xy) = (f(x))y + (f(y))x ...(1)
Putting y = 1, we get 2f(x) = f(x) + (f(1))x
⇒ f(3) = 23 = 8
50)
Given that a10 = 3 ⇒ a1 + 9d = 3
⇒ 2 + 9d = 3[a1 = 2]
h10 = 3
∴ Common difference of corresponding AP is
so,
51)
The tangent at any point A(2secθ, tanθ) is given by
It meets the line x – 2y = 0
...(1)
Also, the tangent meets the line x + 2y = 0 at R, so
...(2)
Now,
= 22 + 12
⇒ [Link] = 5
52)
=0
And
53)
Let A denote the event that he candidate A is selected and B the event that B is selected. It is
given that
P(A) = .5
Now P(A) + P(B) – P(A∩B) = (A∪B) ≤ 1
or
or
by (2) or P(B) ≤ .8
So maximum possible value of 10P is 8.
54) Consider
So and so on
tr(A) + tr(A )tr(A ) + ...+ tr(A100)
2 3
= (–1) + (3) + (–1) + (3) +...+(–1) + (3) = 100