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Electro Class Work Sheet

The document presents a series of questions and answers related to redox reactions, electrolysis, and oxidation states in chemistry. It includes multiple-choice questions about various chemical reactions, the behavior of metals in solutions, and the principles of electrochemistry. The content is structured as a quiz format, testing knowledge on fundamental concepts in chemistry.

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2 views12 pages

Electro Class Work Sheet

The document presents a series of questions and answers related to redox reactions, electrolysis, and oxidation states in chemistry. It includes multiple-choice questions about various chemical reactions, the behavior of metals in solutions, and the principles of electrochemistry. The content is structured as a quiz format, testing knowledge on fundamental concepts in chemistry.

Uploaded by

era88381
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
Eine Which of the following is a redox reaction? (a) NaCl + KNO, —> NaNO, +KCI (b) CaC,0, + 2HC1—> CaCl, + Hy (©) Mg(OH), + 2NH,CI—> MgCl, (@) Zn+2AgCN ——> 2Ag + Zn(CN), NH,OH ‘Which of the following is not a redox reaction? (a) MgCO, —> MgO + CO, (b) 0, + 2H, —> 21,0 (©) Na+ H,0 —> NaOH + % H, (@) SnCl, —> SnCl, + Cl, In the following rection 4P + 3KOH + 3H,0 —> 3KH,PO, + PH, (a) Pis only oxidized (b) Pis only reduced (©) Pis both oxidized as well as reduced (4) none of these ‘The oxidation number of V in Cs,Na(HV,,0,,) is (a) +2 (b) +5 (2 (a) +3 The most convenient method to protect the bottom of ship made of iron is (a) coating it with red lead oxide (b) white tin plating (©) connecting it with Mg block (d) connecting it with Pb block Given E° (Fe Fe) = ~ 0.44 V and £° (Fe"/ Fe™) = o77V Fe, Fe! and Fe are placed together then (a) Fe increases (b) Fe decreases (©) [Fe V{Fe"] remains unchanged (@) Fe decreases ‘Which reaction is not feasible? (a) 2KI-+ Br, —> 2KBr +1, (b) 2KBr + 1, —> 2KI+Br, (©) 2KBr + Cl, ——» 2KC1+ Br, (d) 2H,0 + 2F, —> 4HF +0, 8. In electrolyses of NaCl, when Pt electrode is taken then H, is liberated at cathode, while with Hg cathode it forms sodium amalgam because (@) Hg is more inert than Pt (b) more voltage is required to reduce H’ at Hg than at Pt {c) Na is dissolved in Hg while it does not dissolve in Pt (@) concentration of H’ ions is larger when Pt elec- ‘trode is taken, 9. In the silver plating of copper, K[Ag(CN),] is used instead of AgNO, The reason is. (a) athin layer of Ag is formed on Cu (b) more voltage is required (©) Ag’ ions are completely removed from solution (A) less availability of Ag* ions, as Cu cannot displace Ag from [Ag(CN),"] ion 10. Zn gives H, gas with H,SO, and HCI but not with HNO, because (a) Znacts as oxidizing agent when reacts with HNO, (b) HINO, is weaker acid then H,SO, and HC (©) inelectrochemical series Zn is above hydrogen (@) NO; is reduced in preference to hydronium ion 11, The oxidation state of oxygen in O,PtF, is (a) zero () -% Orth @4H 12, The oxidation number of phosphorous in ATP (adenosine triphosphate) is @)2 o4 (b)3 @s In the reaction, , + 28,0} ——> 21° + S,03, equivalent weight of iodine will be equal to (@) twice its molecular weight (®) its molecular weight (©) ‘its moleculear weight (@) “its molecular weight 4. 15. 16. 7. 19. 20. 2. Removal to basic oxide from metal before electro- plating is known as (a) poling (©) pickling (b) galvanizing (@) anodizing Among the following molecules, in which docs bromine show the highest oxidation number? (a) HgXBrO,), (b) Br-Cl (c) KBr, (d) Br, The equivalent weight of Na,S,O, in the reac- tion 2NaS,0, + 1, ——» NaSO, + 2Nal is (M=molecular weight) @M (b) Mia (© Ms (@ M2 The equivalent weights of KMnO, in an acidic, a neutral and a strong alkaline medium respectively are (M = molecular weight) (@) M/S, M/2,M_——(b) M/S, M/3, M/2 (©MS,M3,M — (d) M3, M, M/S For the redox reaction MnO, + C,O} + H’ ——» Mn™ + CO, + H,O, the correct coefficients of the reactants for the balanced reaction are MnO, C0} HI @ 2 5 16 @ i Ss 2 os 6 2 @ 2 6 5 When white phosphorus reacts with caustic soda, the products are PH, and NaH,PO,. This reaction is an example of (a) oxidation (b) reduction (©) disproportionation (@) neutralization In the following reaction Cr(OH), + OH- +10; —> CrO; + H,0 +1 (a) 10, is oxidizing agent (b) Cr(OH), is oxidized (©) Ge" are being taken per I atom (@) all are true ‘The oxidation states of the most electronegative ele- ment in the products of the reaction of BaO, with dilute H,SO, are 2, 23. 24, 25, 26. 21. 28, 29, (a) Oand-1 (c) -2ando (b) “Land -2 (d) -2 and +1 The brown ring complex compound is formulated as [Fe(H1,0),NOJSO,. The oxidation state of iron in the compound is @) 1 () 3 (b) 2 @o ‘A metal ion M? loses three electrons to produce another cation, The oxidation number of the metal in the cation is @ 8 @3 () +4 @ +6 ‘A, Band C have the oxidation numbers of +6, -2 and =I respectively, the possible molecular formula when these atoms combine will be (a) ABC (b) ABC, (©) ABC, (d) ABC Oxidation numbers of carbon in H,C,O,. CH, and dia- mond respectively are (a) 43,4 and +4 (b) +3,-4 and zero (©) +6,+4 and zero (@) +6, +4 and +4 ‘Which of the following does not represent redox reactions? (a) Cr,0} + 20H" —> CrO} +H,0 (b) SO} + 21+ 2H" > I, + SO} +H,0 (©) 2Ca(OH), + 2Cl, —> Ca(CI0), +CaCl, +2H,0 (@) PCI, —+ PCI, +Cl, IC Cl, is passed through hot NaOH, oxidation number of Cl changes from (a) 1100 (b) Ot0-1 (©) 01045 (@) 01041 Cr,O} + 61 + 14H" ——> 2Cr" + 7H,O + 31, Equivalent weight of Cr,O* is (@) M3 b) M6 (©) M2 (d) none of these The cell constant of a solution, whose specific conduc- tance and observed conductance are same, is equal to @)1 oo (©) 10 (@ 100 30. Electrolysis of dilute H,SO, will give (a) SO, and 0, (©) HO and (b) H, and O, (@) SO, and H, 31, In the electrolysis of a fused salt, the weight of the deposit on the electrode, will not depend on (a) current intensity (b) electrochemical equivalent of the ions (c) time for electrolysis (@) temperature of the bath 32. On electrolysis of acidified water, if volume of hydro- gen liberated is 5.6 em’, then the volume of oxygen liberated equal to (a) 14cm" (b) 2.8 em? (c) 82¢m (@) 5.6 cm? 33. By removing a salt bridge between the two half cells, the voltage (@) increase gradually (b) increase rapidly (©) does not change (@) drops to zero 34, The best conductor of electricity is a 0.1 M solution of (a) H,S0, (&) CH,COOH (©) CH,CH,COOH (@) borie acid 35. For reducing 1 mol of Cr,0} to Cr’, the charge required is (a) 3 * 96500 coulomb (b) 6 «96500 coulomb (©) 03F (@) 06F 36. Which of the following reactions is used to make a fuel cell? (a) Ca{s) + 2Ni(OH), (s) —> CdO(s) + 2Ni(OH), (s) + H,0 (1) (b) Pb(s) + PbO, (s) 2H,SO, (aq) —> 2PbSO, (s) + 2H,0 (8) (©) 2H, (g) + O, (g) —> 2H,0() (d) 2Fe (s) +O, (g) + 4H" ——> 2Fe™ (aq) +2H,0() 37. When a Zn strip is placed in CuSO, solution, Cu gets precipitated, because standard oxidation potential of Znis (@) Cu (© SO, 38. Laws of electrolysis was given by (a) Faraday (b) Ostwald (©) Arthenius (a) Lamark 39, In an aqueous solution, hydrogen will not reduce (a) Ag’ (b) Cu” (©) Zn (a) Fe 40. 4. 42, 43. 45. Aqueous copper sulphate solution is electrolyzed using, platinum electrodes. The electrode reaction occurring, at cathode is, (a) Cu* (aq) + 2e ——> Cu(s) (b) Cu (8) —> Cu (ag) +2¢ (c) 2H,0 (1) ——> 0, (g) + 4H” (aq) + 4e~ (d) O, (g) + 4H" (aq) + 4e° —> 21,0 (1) The variation of equivalent conductance of weak electrolyte with Veoncentration is correctly shown in figure @ y oY A 4 ON « ve ——> ve ——* @y @ y A N A ve——>* e—* Molten CuCl, is electrolyzed using platinum elec- trodes. The reaction occurring at anode is (a) 2C- —+ Cl, (g) +2¢ (b) Cl, (g) + 2e° —> 2¢1 (c) Cu" + 2e° > Cu(s) (8) Cuts) —> Cu" + 2¢ ‘What is the effect of dilution on the equivalent condue- tance of strong electrolyte? (a) decrease on dilution(b) remains unchanged (©) increase on dilution (d) none of these When an acid cell is charged, then (a) voltage of cell increases (b) electrolyte of cell dilutes (6) resistance of cell increases (@) none of these Which of the following is not correct? (a) aqueous solution of NaCl is an electrolyte (b) the units of electrochemical equivalent are g. coulomb (©) inthe Nernst equation, *n” represents the number of electrons transferred in the electrode reaction (@) standard reduction potemtial of hydrogen electrode is zero volts 46. 47. 49. Si. 52. What is the electrochemical equivalent (in g cou- Jomb') of silver? (@) 108F (b) 108/F (©) Fv108 @) W108 F Which one of the following condition will increase the voltage of the cell represented by the equation Cu (s) + 2Ag" (aq) = Cu* (aq) + 2Ag (5)? (a) increase in the (b) increase in the dimension of Ag electrode (c) increase in the concentration of Cu ions (d) increase in the concentration of Ag’ ions iension of Cu electrode During an electrochemical process, (a) Gibbs free energy increases (b) Gibbs free energy remains constant (©) no prediction can be made about Gibbs free energy (d) Gibbs free energy decreases The equivalent conductance at infinite dilution of HCI and NaCl are 426.15 and 126.15 mho cm? g eq" respectively. It can be said that the mobility of (@) HV ions is much more than that of CI ions (b) Ch ions is much more than that of H’ ions (6) H’ ions is much more than that of Na ions (@) Na’ ions is much more than that of H ions Saturated solution of KNO, is used to make ‘salt bridge’ because (a) velocity of K* is greater than that of NO; (b) velocity of NO, is greater than that of K" (©) velocities of both K* and NO; are nearly the same (@) KNO, is highly soluble in water The reaction, 3C10- (aq) ——> C10; (aq) + 2CI- (aq) is an example of (a) oxidation reaction (b) reduction reaction (©) disproportionation reaction (@) decomposition reaction The correct order of equivalent conductance at infinite dilution of LiCl, NaCl and KClis (a) LiCl > NaCl > KCL (b) KCI> NaCl > LiCl () NaCl >KCI> LiCl (@) LiCl > KC1> NaCl 33. 58. ST. The standard reduction potential values of three metallic cations X, Y, and Z are 0.52, -3.03 and -1.18 respectively. The order of reducing power of the corre- sponding metal is (a) Y2>X (©) BYox (b) X>Y>Z (@) XY Among the following, identify the species with an atom in +6 oxidation state (a) MnO; (b) CHEN (©) NiF? (@ Cro,cl, Variation of resistance with increase in cell constant gives graph of the type @y » Y R 8 x x ‘A standard hydrogen electrode has zero electrode potential because (a) hydrogen is easiest to oxidize (b) its electrode potential is assumed to be zero (©) hydrogen atom has only one electron (d) hydrogen is the lightest element Inthe reaction, 3Br, + 6CO? + 3H,0 ——> SBr +BrO; + 6HCO; {a) bromine is oxidized and carbonate is reduced (b) bromine is reduced and water is oxidized (©) bromine is neither reduced nor oxidized (@) bromine is both reduced and oxidized Ofthe following metals, those that cannot be obtained by the electrolysis of the aqueous solution of their salts are (a) AgandMg ——(b) Agand Al (c) Mgand Al (@) Cuand Cr 59, 60, 61. 62. 63. When a copper wire is placed in a solution of AgNO,, the solution acquires blue colour. This is due to the formation of (a) Cu’ ions (b) Cu’ ions (©) soluble complex of copper with AgNO, (4) Cur ion by the reduction of Cu The electric charge for electrode deposition of one gram equivalent of a substance is (a) charge on one mole of electrons (b) 96500 couloumbs per second (©) one ampere per second (@) one ampere for one hour ‘The Nernst equation, E = £° - (RT / nF) In Q cates that the equilibrium constant K, will be equal to Qiwhen (a) E=ze10 (© E=EB (b) E=1 (@) RU/nF=1 In the reaction 4Fe +30, —> 4Fe" + 60%, which of the following statements is incorrect? (a) metallic iron is reducing agent (b) Fe” is an oxidizing agent (©) metallic iron is reduced to Fe” (d) redox reaction A compound contains atoms X, Y, Z the oxidation number of X is +2, Y is +5 and Z is -2 The possible form of the compound is (a) XY,Z, (b) Y(XZ,), (©) XYZ), @ XV, When Benzoic acid is titrated with NaOH, varia- tion of conductance (Y-axis) with addition of NaOH (X-axis) can be shown by ey mY _¥* x x WA Lay 6. 66. 1. 68. 69. Which one of the following graphs correctly represents the change in electrical conductivity as copper (II) carbonate is gradually added to dilute sulphuric acid Ot» (b) te Bef Bg Go Mass of —e BS “Mass of —> CuCO3 added CuCO3 added @ i, ‘Mass of — CaCO} added Mass of —* CuCO3 added Consider the following four electrodes (1) Cu?(0.0001 M) | Cu(s) (2) Cu(O.1M)Cu(s) (3) Cu"(0.01M)ICuls) (4) Cu(0.001 M)ICu(s) Ifthe standard reduction potential of Cu | Cu is +0.34 Y, the reduction potentials (in volts) of the above elec- trodes following the order (a) 1>4>3>2 (b) L>2>3>4 ()3>4>2>1 d) 2>3>4>1 Inthe redox reaction xMnO + yPbO, + 7HNO, ——> HMn0, + PO(NO,), + HO Ifa current of 80.0 microampere is drawn from a cell for 100 days, then the number of farads involved are (a) 7.16 x104 (b) 7.16 x 10° (©) 1432102 @) 3.46 * 10° The same amount of electricity was passed through two separate electrolytic cells containing solutions of nickel nitrate and chromium nitrate respectively. 1£ 0,3 g of nickel was deposited in the first cell, the amount of chromium deposited is (atomic weight of Ni cr=52) (a) 0.1308 (©) 0.176 g (b) 0.236 g (@) 176g 70. The charge required to deposit 40.5 g of Al (atomic mass = 27.0 g) from the fused AL,(SO,), is (a) 0.434 x 10°C (b) 434 «10°C (0) 3.34 x 10°C (d) 43.4 « 10°C 71. A certain current liberates 0.504 g of hydrogen in 2 hour. The amount (or mass) of copper deposited at the cathode during the electrolysis of CuSO, (ag) solu- tion by the same current flowing for the same time is (atomic masses H = 1.0, Cu = 63.5) (a) 16.08 (b) 320g (©) 86g (@) 160g 72. Which of the following statements are incorrect? (1) specific conductance increases with (2) equivalent conductance decreases with dilution (3) the conductance of all electrolytes increase with temperature Select the correct answer using the codes given below (a) Land 2 (b) Land3 (c) 2and 3 (@) 1,2and3 73. Specific conductance of 0.01 N solution of an electro- Iyte is 0.00419 mho em. The equivalent conductance of this solution will be (a) 4.19 mhoo (b) 419 mho cm? (©) 0.0419 mho cm? (@) 0.209 mho cm* Assolution of CuSO, is electrolyzed for 7 minutes with a current of 0.6 A. The amount of electricity passed equal to (a) 26 (©) 2.6% 104F 74. (b) 4.2C (d) 2.6 10°F 75. The specific conductance of 0.1 N KCI solution at 23°C is 0.012 ohm cm". The resistance of cell con- taining the solution at the same temperature was found to be $5 ohm. The cell constant will be (a) 0.142 cm* (b) 0.616 cm (©) 6.16 em" (@) 616 cm" 76. The equivalent conductance of Ba” and Cl are respectively 127 and 76 ohm cm* equiv" at infinite dilution, The equivalent conductance (in ohm-! cm? equiv") of BaCl, at infinite dilution will be (a) 139.5 (b) 203, (©) 279 (@) 101.5 7 78. 19. 80, BI. 82. Cu'(aq) is unstable in solution and undergoes simul- taneous oxidation and reduction according to the reaction, 2Cu‘ (aq) = Cu (aq) + Cu (s) choose correct £° for above reaction if E° (Cu"/ Cu) = 0.34 V and E° (Cu Cu’) = 0.15 V (@) -038V (b) +0.49V (©) +0.38V (@) -0.19V The standard reduction potentials of Ag, Cu, Co and Zn are 0.799, 0.337, -0.277 and -0.762 V respectively. Which of the following cells will have maximum cell emf? (a) Zn | Zn* (IM) || Cu** (1M) | Cu (b) ZniZn*(IM)|| Ag’(IM)}Ag (c) CulCu*(IM)|| Ag"(IM)/Ag. (d) Zn | Zn®* (IM) |] Co™ (IM) | Co On the basis of the information available from the reaction, } Al +O,» AG =-827 ks mol" of O,. The minimum emf, required to carry out an electroly- sis of Al,O, is (F = 96500 C mot) (@) 642 (b) 8.56V @214V (a) 4.28 One ampere of current is passed for 9650 seconds through molten AICI,. What is the weight in grams of Al deposited at cathode? (Atomic weight of =27) (a) 0.9 (b) 9.0 (©) 0.18 (d) 18.0 ‘The emf of a Daniell cell at 298 K is E, Zn| ZnSO, || CuSO, | Cu (001M) (10M) when the concentration of ZnSO, is 1.0 M and that of CuSO, is 0.01M, the emf changed to £,, What is the relationship between £, and £,? (a) E,-E, (b) E,#E, © E> @) E<é, In the ionic equation xBrO, + yCr* +2H,0 —> Br, + HCrO, +H" 83. 84. 85. 86. 87. 89. ‘The standard electrode potential for electrodes A and B are A (aq)/A (s) E° = 0.30 V, B™ (agB (s) E°= 0.40 V ‘They are combined in a cell as shown below: A ag (1M) Brag (1M) Which of the following is the description of such a cell electrode where positive ions emfV enter the solution ? (a) AOL (&) A027 (© BOI (d) BOT ‘The standard emf of a galvanic cell involving cell reaction with n = 2 is found to be 0.295 V at 25°C. The equilibrium constant of the reaction would be (Given F= 96500 C mol"; R=8.314 JK! mol!) (a) 2.0 10" (b) 4.0 x 10" (c) 1.0 * 10° (d) 1.0 « 10° A hypothetical electrochemical cell is shown below: A| A" (XM) [| BY (yM) |B ‘The emf measured is +0.20 V. The cell reaction is (a) the cell reaction cannot be predicted (b) A+ B'——+ A+B (c) A" +B——+ A+B (d) A’ +e —+ A; B' +e —+B If E? (Fe""/Fe) =-0.441 V and E°(Fe"/Fe") = 0.771 V, the standard emf of the reaction Fe + 2Fe ——» 3Fe™ will be (a) 1.212 (b) OV (© 0.330¥ @) 1.653 V By passing 0.50 ampere current in an aqueous solution 0.5 g of an element (Eq. wt = 96.5) is liberated. The time of passing current in seconds is (a) 1008 (b) 500s (©) 1000s (@) 2000s In the redox reaction xKMnO, + yNH, ——» KNO, + MnO, + KOH (b) x=6,y=3 (d) x=8, 3 (a) x=3,y=8 (©) x=5,y=10 The values of standard oxidation potemtials of follow- ing reactions are given below: 2n—>» Zn + 203 EP =0.762V Fe > Fe +26; = 0.440V 90. 1. Cu——> Cu +2e5 £7=-0.345V Ag——> Ag’ + 2c; £°=-0.800V Which of the following is most easily reduced? (a) Fe (©) Zn How much chlorine will be liberated on passing one ampere current for 30 min through NaCl solution? (a) 0.66 mol (b) 0.33 mol (©) 0.66 g (@) 033g Time required to deposit 1 millimol of alumin- ium metal by the passage of 9.65 ampere of current through aqueous solution of aluminium ion, is (a) 30s (b) 10s (c) 30,000 s (a) 10,000 s 92, The chemical reaction, 93, 94, 95, 96. 2AgCl (s) + H,(g) —> 2HCI (aq) + 2Ag (8) taking place in a galvanic cell is represented by the notation (a) Pt(s)| H, (g), | bar | 1 M KCI (aq) [AgCl (s) | Ag (s) (b) Pt (s)| H, (g), | bar| 1 M KCI (aq) [1 M Ag® (aq) | Ags) (©) Pt(s)| H, (g), | bar | 1 M KCI (aq) | AgCl (5) | Ag (s) (A) Pt(s)| H, (e), | bar | 1 M KCI (aq) | Ag (s) | AgCl ‘The emf of the cell ‘Ag/Ag’ =-0.80V (a) +0.46V (b) -0.46V (© +114v (@) -1.14v One faraday of electricity is passed separately through one litre of one molar aqueous solutions of (i) AgNO, (ii) SnCl, and (iii) CuSO,. The number of moles of Ag, Sn, and Cu deposited at cathode are respectively (a) 1.0, 0.25,0.5 (b) 1.0, 0.5, 0.25 (ec) 0.5, 1.0,0.5 (a) 0.25, 0.25, 0.5 2MnO; + aki" + bH,O, ——> 2Mn?+H,0 + 40, ‘What are the values of a, b, ¢ and d? . (a) 4,5,4,5 (b) 6,5, 8,5 (c) 3,2,4,8 (@) 2,5,4,6 When X amperes of current is passed through molten AICI, for 96.5 seconds, 0.09 grams of aluminium is deposited. What is the value of X? (a) 10 (b) 20 (c) 30 (a) 40 97, The electrochemical equivalent ofa metal is “x” g. cou- lomb-!. The equivalent weight of metal is f@) x (b) x. 96500 (6) ¥/96500 (d) 1.6« 10" 98. In electrolysis of dilute H,SO,, what is liberated at anode? (b) SOP (a) 0, 99, The hydrogen electrode is dipped in a solution of pH 3 at 25°C. The potential would be (the value of 2.303 RTVF is 0.059 V) (@) 0.177 (©) 0.059 (b) 0.087 V (d) -0.177V. [Link] of iron is essentially an electrochemical phenomenon where the cell reactions are (a) Fe is oxidized to Fe and dissolved oxygen in water is reduced to OH (b) Fes oxidized to Fe” and H,0 is reduced to O} (©) Fe is oxidized to Fe and 11,0 is reduced to 0, (q) Feis oxidized to Fe and H,0 is reduced to 101. What is the quantity of electricity (in coulombs) required to deposit all the silver from 250 mL. of 1 M AgNO, solution? (Ag = 108) (a) 2412.5 (b) 24125 (©) 4825.0 (a) 48250 102. The standard reduction potentials of Zn | Zn and Cu** | Cu are -0.76 V and +0.34V respectively. What is the cell emf (in V) of the following cell? (RT/F= 0.059) Zn_| Zn** (0.05 M) || Cu® (0.005 M) | Cu (a) 1.1295 (b) 1.0705 © Ll (d) 1.041 103.K,, of BaSO, is 1 x 10° If the ionic conductances of Ba’ and SO; ions are 64 and 80 ohm cm? mol respectively, then its specific conductance is (a) 1.44 10% ohm* env (b) 144 = 10 ohm em (©) 1.44 * 10° ohm? cnr (@) 144 * 10° ohm env 104. Two electrochemical cells Zn | Zn" || Cu” | Cu and Fe | Fe” || Cu | Cu are con- nected in series. What will be the net emf of the cell at 25°C? Given: Zn™ | Zn =-0.73 V, Cu" | Cu=40.34V Fe"|Fe=-O41V (a) +1.85 (c) 40.83 V (b) -1.85V (d) -0.83V mn potential values of M, N and © are -13 and -3.13 V respectively. Which of the following order is correct, regarding their reducing Property? (a) O>N>M (bt) O>M>N (©) M>N>O @ M>O>N 106,aHNO, + bH,S ——» cNO + d H,O + 3S. What are the values of a, b, ¢, ? - (a) 2,3,2,2 (b) 2,3,2,4 © [Link] (@) 4.3.12 107.1f the aqucous solutions of the following salts are electrolysed for | hour with 10 ampere current, which solution will deposit the maximum mass of the metal at the cathode? The atomic weights are Fe = 56, Zn = 65, Ag = 108, Hf = 178 and W = 184 (a) ZnSO, (b) Feel, (©) HICL, (@) AgNO, [Link] the standard reduction potentials Zn™/Zn = 0.74 V, CL/CI = 1.36 V, H'/% H, = 0 V and Fe"'/Fe* 0.77 V. The order of increasing strength as reducing agent is (a) Zn, H,, (b) Hi, Zn, Fe, Cl- (©) Cl, Fe*, Zn, H (@) CL, Fe, H, Zn 109. In the electrolytic cell, low of electrons is from (a) cathode to anode in solution (b) cathode to anode through external supply (©) cathode to anode through internal supply (@) anode to cathode through internal supply [Link] the standardization of Na,S,O, using K,Cr,0, by iodometry, the equivalent weight of K,Cr,0, is (a) (molecular weighty2 (b) (molecular weighty/6 (©) (molecular weighty’3 (d) same as molecular weight 111.A gas at 1 atm is bubbled through a solution contain- ing a mixture of 1 MY- and | MZ: at 25°C. If the reduction potential of Z > Y > X, then (a) ¥ will oxidize X and not Z (b) ¥ will oxidize Z and not X (©) ¥ will oxidize both X and Z (4) Y will reduce both X and Z 112. The oxidation number of sulphur in S,, S,F,, H,S respectively, are (a) 0,+1 and-2 (b) +2, +1 and -2 (c) 0, +1 and +2 (@) -2,+1 and—2. 113.A dilute aqueous solution of Na,SO, is electrolyzed using platinum electrodes. The product at the anode and cathode are (a) 0H, (©) 0,.Na 114. The standard reduction potential for Fe*"/Fe and Sn**/ Sn electrodes are -0.44 and -0.14 volts respectively. For the cell reaction Fe + Sn——> Fe + Sn* ‘The standard emf is, (a) +0.30V (b) -0.58V (© +0.58V (@) -0.300V 115. The standard oxidation potential E* for the half reac- tions are as Zn ——> Zn" + 207; E° = + 0.76V Fe > Fe" +2e; = +041V The emf for the cell reaction Fe + Zn ——» Zn** + Feis (@) H.17V (b) -035V (c) +0.35V (d) O.1I7V 116. When a lead storage battery is discharged (a) lead is formed (b) lead sulphate is consumed (d) sulphuric acid is consumed 117. A solution of sodium sulphate in water is electrolyzed using inert electrodes. The products at the cathode and anode are respectively (@) 0,4, (b) 0,,Na (© 0,80, (d) H,,0, 118. The reaction % Hg (g) + AgCl(s) = H'(aq) +CI-(aq)+ Ag(s) occurs, in the galvanic cell (a) Pt] H, (g) | KCI (solution) | AgCl (s) | Ag. (b) Pt| H, (g) | HCI (solution) | AgCI (s) | Ag (©) Pt|H, (g) | HCI (olution) | AgNO, (solution }| Ag, (@) Ag| AgCl(s) | KCI (solution) | AgNO, (solution) | Ag 119.A. solution containing one mole per litre of cach Cu(NO,),; AgNO,; Hg,(NO,),; is being electrolyzed by using inert electrodes. The values of standard electrode potentials in volts (reduction potentials) are Ag/Ag' = +0.80, 2Hg/ He," = 40.79 CwCu"* = 40.34, Mg / Mg" =-2.37 With increasing voltage, the sequence of deposition of metals on the cathode will be (a) Cu, Hg, Ag, (b) Ag, Hg, Cu, Mg (©) Mg, Cu, He, Ag (@) Ag, He, Cu 120. Electrolysis of dilute aqueous NaCl solution was car- ried out by passing 10 mili ampere current. The time required to librate 0,01 mole of H, gas at the cathode? (a) 9.65 x 10'See — (b) 19.3 * 10° See (c) 28.95 « 10*See (d) 38.6 « 10° See 121. The standard reduction potentials at 298 K for the following half-reactions are given against each Zn®* (aq) +2e ——=Zn(s) -0.762 Cr (ag) +2e—=Cr(s) -0.740 2H" (aq) + 2e == H, (g) 0.000 Fe (ag) + 2e = Fe" (aq) 0.770 Which is the strongest reducing agent? (a) Hg) (b) Cr(s) (c) Zn(s) (@) Fe" (aq) 122. For the equation NO, + 4H" + &° ——» 2H,0 + NO. The number of electrons in its balanced form would be (@) 6 (4 (c) 3 (9 123. Ag | Ag” (IM) || Ag(2M) | Ag, 1Lsolution 1 Lsolution 0.5 F of electricity in the LHS (anode) the 1F electric~ ity in the RHS (cathode) is first passed making them independent electro cells at 298 K. The emf of the cell afier electrolysis will (b) decrease (d) time is also required (a) increase (©) not change 124, One litre of 1 M CuSO, solution is electrolysed. After passing 2F of electricity, molarity of CuSO, solution will be (a) M2 (b) M4 (OM @o 125.1n acidic medium MaO,; is an ing agent MnO, + 8H + Sc* ——> Mn* + 41,0. If H ion concentration is doubled, electrode potential of the half cell MnO, Mu® / Pt will (a) increase by 28.46 mV (b) decrease by 28.46 mV (6) increase by 14.23 mV (d) decrease by 142.30 mV. [Link] the weight of copper that will be deposited at the cathode in the electrolysis of a 0.2 M solu- tion of copper sulphate, when quantity of electricity, equal to the required to liberate 2.24 L of hydrogen at STP from a 0.1 M aqueous sulphuric acid, is passed (Atomic mass of Cu = 63.5) (a) 635g (b) 3.172 (©) 1271g (@) 8.58 [Link] that? (Zn*/Zn) = -0.763 Vand E® (Cd*"/Cd) = -0.403 V, the emf of the following cell Zn | Zn* (a = 0.04) || Cd" (a= 0.2)| Cd is given by (a) E = +0.36 + [0.059 / 2] [log (0.2/0,004)] (b) E =~ 0.36 + [0.059 / 2] og (0.2/0,004)] (c) E=+0.36 + [0.059 / 2] [log (0.004/0.2)] (d) E= 0.36 + [0.059 / 2] [log (0.004/0.2)] 128. Ifthe pressure of hydrogen gas is increased from | arm to 100 atm, keeping the hydrogen ion concentration constant at 1 M, the voltage of the hydrogen half cell at 25°C will be (a) -0.059.V (©) 509 (b) +0.059V (d) 0.259V 129. The conductivity of 0.01 mol/dm’ aqueous acetic acid at 300 K is 19.5 x 10 ohm! cm’ and limiting molar conductivity of acetic acid at the same temperature is 390 chm’! em? mol, The degrce of dissociation of acetic acid is (a) 0.05 (b) 0.5 * 10 (c) 5* 107 (d) 5* 107 130. The hydrogen electrode is dipped in a solution of pHi = [Link] 25°C. The potential of hydrogen electrode would be (a) -0.177V (©) LI7V (b) 0.177 (@ 0277V 131. Three faraday of electricity is passed through aque- ‘ous solutions of AgNO,, NiSO, and CrCl, kept in three vessels using inert electrodes. The ratio in moles in which the metals Ag, Ni and Cr will be deposited is (a) 1:2:3 (c) 6:3:2 (b) 2:3:6 (@) 32:6 132. When an electric current is passed through acidulated water, 112 mL of hydrogen gas at NTP collects at the cathode in 965 seconds, The current passed, in ampere is (a) 01 (b) 05 © 10 @ 20 133. For the electrochemical cell, M | M° || X-| X, E°M'/M = 0.44 V and E? X/X = 0.33 ¥. From these data, one can deduce that (a) M+X——» M"+X-is the spontaneous rea (b) M' +X ——» M + X is spontaneous reaction (©) Egy = 0.77V @) Ey =-0.77V n 134. The emf of the following three galvanic cells (1) ZnlZn"(M) || Cu" M) | Cu Q) Zn | Zn* (0.1 M) || Cur (1M) | Cu @) Zn | Zn (1 M)|| Cu” (0.1 M)| Cu are represented by E,, £, and E,, Which of the follow- ing statement is true? (@) EPE>E, (b) EPE>E, ©) E>EPE, (@) E>E> 135. When a quantity of electricity is passed through CuSO, solution, 0.16 g of copper gets deposited. If the same quantity of electricity is passed through acidulated water, then the volume of H, liberated at STP will be (At. wt of Cu= 64) (a) 4.0 em* (©) 604 em’ (b) 56 em* (@) 8.0 em* 136.4.5 g of aluminium (at. mass 27 amu) is deposited at cathode from Al solution by a certain quantity of electric charge. The volume of hydrogen produced at STP from HI" ions is solution by the same quantity of electric charge will be (@) 44.8L (©) U2L (b) 2.4L. (d) 5.6L 137. The half cell reaction for the corrosion 2H +% 0, + 2¢ ——+ H,0, B= 1.23, Fe" + 2¢ ——+ Fe (3); E°=-0.44V Find the AG° (in kJ) for the overall reaction. (a) -76 (b) -322 (©) -161 (a) -152 138. The emf of the cell Zn | Zn** (0.01 M) || Fe** (0.001 M) | Fe at 298 K is (0.2905 volt. Then the value of equilibrium constant for the cell reaction is fa) roms (by 1920025 (©) 1005 (a) 1032205 139. For the electrolytic production of NaCIO, from NaCIO, as per the equation, NaC IO, + H,0 —+ NaClO, + H,, How many fara- days of electricity will be required to produce 0.5 mole of NaCIO,, assuming 60% efficiency? (a) 1.67F (b) 3.64 F () 2.67F (d) 4.67 F 140, The standard reduction potentials of Cu*/Cu and Cu*/ Cu’ are 0.337 V and 0.153 V respectively. The stan- dard electrode potential of Cu'/Cu half cell is (a) 0.184V (b) 0.827 (©) 0.521V (@) 0490 141, Equal quantities of electricity are passed through three voltameters containing FeSO, Fe (SO,),,and Fe(NO,), Consider the following statements in this regard (1) the amount of iron deposited in FeSO, and Fe,SO,), is equal (2) the amount of iron deposited in Fe(NO,), is two thirds of the amount of iron deposited in FeSO, G) theamount of iron deposited in Fe,(SO,), Fe(NO,), is equal . Of these statements (a) 1 and 2 are correct (b) 2and 3 are correct (©) Land 3 are correct (A) 1,2 and 3 are correct 142. The reversible reduction potential of pure water is -0.413 V under 1.00 atm H, pressure. Ifthe reduction is considered to be 2H’ + 2¢° ——» H, calculate pH of pure water, (a) 6 7 ©3 @s 143. For a Ag - Zn button cell, net reaction is Zn(s) + Ag,O (8) ——» ZnO (s) + 2Ag (8) AG?(Ag,0)= -11.21 kJ mol! AG? (ZnO) =-318.3 kJ mol! Hence £=,, of the button cell is (a) 3.591V (b) 2591 (©) -1.591V @ 1s91V 144. current of 15 amp is employed to plate Nickel in a NiSO, bath. Both Ni and H, are formed at the cathode. 1f 9.9 g of Ni are deposited with the simultaneous lib- cration of 2.51 litres of H, measured at STP, what is the current efficiency for the deposition of Ni? (Atomic weight of Ni = 58.7) (a) 60% (b) 70% (c) 80% (d) 56% [Link] elements A, B, C and D can form diatomic molecules and monoatomic anions with ~1 charge. Consider the following reactions about these. 2B +C,——> 2 +B, B, + 2D’: ——» 2B-+D, 2A +C, no reaction Select correct statement about these. (1) A, is strongest oxidizing agent while D is strong- est reducing agent (2) D, is strongest oxidizing agent while A is strong- est reducing agent (3) C, will oxidize B- and also D-to form B, and D, (4) BPAJA- is the lowest (a) 2and3 (b) 1 and3 (©) 2and4 (@) 1,2and3 Single Option Correct Type 1@ 2@ 30 4) 5) 6) 7b) BCD) 9.) 10.) 1L@) 12@)— 13.) 1) SL) 16.) 17) Ba) 19.0) 20.0) 21(b) —-22.(a)—-23.(4)_—24.(b) —25.(b)—26.(e)—27.(c)—-2BL(b) 29a) 30. (b) 31(d)— 32.(b) 33.) 34.(a)—35.(b)—36(c)—376(b) 3B) 3%.) 40 (a) AL(b) — 42.(a)—43.(0)44.(a)—45.(b)—46(b)47(d) 4B) 49.0) 50.0) S1.(c) 52.(b) 53.(a)S4.(d)—55.(a)—S6.(b)—S7.(d) SBC) 59.(b)—60.(a) Gl.(a) —62.(c)—63.(C)_—G4.(6)—65.(a)—66.(d) 6 T.(a)—GB.() «69. (c)_—70.(b) Ta) 72a) 73.(b) 74d) 75.(B)—76.(a) TT (C)—78(b) 79. (C) 80. (a) B1.(c) — 82.(d) —-83.(d) BA) 85.(b) BG. (a)—87.(c) 8B.) —89.()—90.(c) 91(a) — 92.(b) —93.(a) 94a) MSC) 9G (a) 97 (b)— 9B). «99. A)——100. (a) 101.(b) 102.(b)103.(6) 104. (a) 105. (a) 106.(b)_-107.(d)108.(d)_—109.(c)__110.(b) HL (a) 112 (a) 1B.) NA ()—ANS.(e)—116.()—117,(4)— 18. () 119.4) 120.6) A21.(c) 122.(c) —123,(¢) 124. (4) 125. (@)_—— 126. (@)_—127.(c)128.(a)_—129.(a)—130.(a) 1B1.(c) 132.(c) —133.(b)134.(a)—138.(b)—136.(d)—137.(b)138.(6)—139.(a)140.(c) T4L.(b) 142.(b) 143.) 144 (a)— 145. (6)

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