27-04-2025

1803CJA101029250020 JM

PART-1 : PHYSICS

SECTION-I

1) A conductor having uniform linear charge density λ is placed in circular form in 3 quadrants with
different polarities as shown in the figure. Let be the electric field at O. Then the angle made by

with the line along negative y-axis is -

(A)

(B)

(C)

(D) None

2) An electron is projected as in figure with kinetic energy K, at an angle θ = 45° between two
charged plates. The magnitude of the electric field so that the electron just fails to strike the upper

plate, should be greater than:

(A)

(B)

(C)

(D) Infinite

3) An insulating sphere of radius 'R' having a cavity of radius R/4 at the periphery is charged
uniformly with charge Q. The magnitude of electric field at point 'P' due to the above charge
distribution is :
[Take ]

(A)

(B)

(C)

(D)

4) A cube of side 'a' has point charges +Q located at each of its vertices except at the origin where
the charge is . The electric field at the centre of cube is:

unit vector along x - axis

unit vector along y - axis
unit vector along z - axis

(A)

(B)

(C)

(D)

5) Two semicircular rings lying in the same plane of uniform linear charge density λ have radii r and
2r. They are joined using two straight uniformly charged wires of linear charge density λ and length
r as shown in the figure. The magnitude of electric field at common centre of semi circular rings is
(A)

(B)

(C)

(D)

6) The figure shows the electric field lines in the vicinity of two point charges. Which one of the
following statements concerning this situation is true?

(A) q1 is negative and q2 is positive

(B) The magnitude of the ratio (q2/q1) is less than one
(C) Both q1 and q2 have the same sign of charge
(D) The electric field is strongest midway between the charges.

7) A thread carrying a uniform charge per unit length has the configuration shown in figure.
Assuming a curvature radius R to be considerably less than the length of the thread, the magnitude
of the electric field strength at the point O is , then n is:

(A) 2
(B) 4
(C) 8
(D) 1

8) Two concentric rings one of radius a and the other of radius b = 2a have charges qa and qb
respectively as shown in figure. A charged particle placed on the axis at z = a is in equilibrium, if the

ratio is equal to _______

(A)

(B)

(C)

(D)

9) Two charges + q1 and -q2 are placed at A and B, respectively. A line of force emanates from q1 at
an angle α with the line AB. At what angle β will it terminate at

(A) β = α

(B)

(C)

(D)
10) A point is considered at a distance near the bottom most point of a hemispherical surface
having a uniform charge density σ as shown in figure. The electric field near the curved surface of

the hemisphere is nearly.

(A)

(B)

(C)

(D)

11) A point charge Q is located on the axis of a disc of radius R at a distance 'a' from the plane of the
disc. If one fourth (1/4th) of the flux from the charge passes through the disc, then value of a is :-

(A)

(B)

(C)

(D)

12) Four charges equal to -Q are placed at the four corner of a square and a charge q is at its
centre. If the system is in equilibrium, the value of q is

(A)

(B)

(C)

(D)
13) An infinitely long thin non-conducting wire is parallel to the z-axis and carries a uniform line
charge density λ. It pierces a thin non-conducting spherical shell of radius R in such a way that the
arc PQ subtends an angle 120° at the centre O of the spherical shell, as shown in the figure. The

permittivity of free space is ∈ . Which of the following statements is (are) true?

(A) The electric flux through the shell is

(B) The z-component of the electric field is non-zero at two points on the surface of the shell
(C) The electric flux through the shell is
(D) The electric field is normal to the surface of the shell at all points

14)

Consider an electric field where E0 is a constant. The flux through the shaded area (as
shown in the figure) due to this field is:-

2
(A) 2E0a
(B)
2
(C) E0a

(D)

15) A charge 'q' is placed on the diagonal AP of a cube at a distance from the point A. Choose the

correct options.
 The sum of electric flux passing through the surface ABCD and PQRS is
(A)

The sum of electric flux passing through the surface ABCD and PQRS is
(B)

(C) The flux through both the surfaces ABCD and PQRS are same
The sum of electric flux passing through the surface ABCD and PQRS is
(D)

16) The total charge contained within the cube (see figure), in which the electric field is given by

, where ε is the permittivity of free space, is :-

(A) 7Kε0
(B) 5Kε0
(C) 33Kε0
(D) Zero

17) Three infinitely long charge sheets are placed as shown in figure. The electric field at point P is:-

(A)

(B)
–

(C) –

(D)

18) Consider a triangular surface whose vertices are three points having co–ordinate A (2a,0,0),
B(0,a, 0), C(0,0,a). If there is a uniform electric field . then flux linked to triangular
surface ABC is –

(A)
2
(B) 3E0a

(C)

(D) Zero

19) A charged particle enters at point A and comes out from B. Its velocity makes angle α and β with
electric field at these two points. Ratio of kinetic energy of changed particle at A and B will be –

(A)

(B)

(C)

(D)

20) Consider the following conclusions regarding the components of an electric field at a certain
point in space given by
Ex = – Ky Ey = Kx Ez = 0
(I) The field is conservative.
(II) The field is non-conservative.
(III) The lines of force are straight lines
(IV) The lines of force are circles.

(A) II and IV are valid

(B) I and III are valid
(C) I and IV are valid
(D) II and III are valid

SECTION-II

1) A sphere of radius R have volume charge density given as ρ(r) = Kr for r ≤ R, 0 for r > R. If

electric field at distance from centre is , then N will be :-

2) In the figure electric field lines of three charges are shown. If q1= +8μC and q3 = –12μC what is
magnitude of charge q2 in μC ?

3) A finite wire of charge density C/m is placed in gravity free space as shown in figure. A
particle of charge 10 nC and mass 3 gm is released from point P. The magnitude of initial

acceleration of particle is a × 10b m/s2 then is ....... :-

4) Two blocks of mass 1 kg & 2 kg carry a charge of 2µC each. Initially they are at a large distance
apart on a smooth level ground. Now 1 kg block is directly projected towards 2kg block with a
velocity of 6m/s. At some point of it's motion, 1 kg block stops and turns back. Find the distance
between the two blocks at that moment (in mm). Assume that both blocks are free to move.

5) A point charge +q is placed on the axis of a closed cylinder of radius R and height as shown.

If electric flux coming out from the curved surface of cylinder is , then calculate x.

PART-2 : CHEMISTRY

SECTION-I

1) The following results were obtained during kinetic studies of the reaction :
2A + B → Products
 [A] [B] Initial Rate
(in (in of reaction
Experiment –1
mol mol (in mol L
–1 –1 –1
L ) L ) min )

(I) 0.10 0.20 6.93 × 10–3

(II) 0.10 0.25 6.93 × 10–3

(III) 0.20 0.30 1.386 × 10–2

The time (in minutes) required to consume half of A is :
(A) 10
(B) 5
(C) 100
(D) 1

2) consider the elementary reaction A(g) + B(g) → C(g) + D(g) If the volume of reaction mixture is

suddenly reduced to of its initial volume, the reaction rate will become ‘x’ times of the original
reaction rate. The value of x is :

(A)

(B) 9

(C)

(D) 3

3) For the reaction A + B —→ C; starting with different initial concentration of A and B, initial rate of
reaction were determined graphically in four experiments.

[Link] [A]0 (Initial conc.) [B]0 (Initial conc.) rate (M sec-1)

1 1.6x 10-3M 5 x 10-2M 10-3

2 3.2 x 10-3M 5 x 10-2M 4 x 10-3

3 1.6 x 10-3M 10-1M 2 x 10-3

4 3.2 x 10-3 M 10-1 M 8 x 10-3

Rate law for reaction from above data is
(A) r = k[A]2 [B]2
(B) r = k[A]2 [B]
(C) r = k[A] [B]2
(D) r = k[A] [B]

4) Which graph represents zero order reaction [A(g) → B(g)] :

(A)

(B)

(C)

(D)

5) At certain temperature, the half life period for the thermal decomposition of a gaseous substance
depends on the initial partial pressure of the substance as follows

P(mmHg) 500 250

t1/2 (in min.) 235 950

Find the order of reaction [Given log (23.5) = 1.37 ; log (95) = 1.97; log 2 = 0.30]
(A) 1
(B) 2
(C) 2.5
(D) 3
6) For a reaction A → Product What is the value of k for the given reaction -

(A) 4 × 10–5 M–1 s–1

(B)
× 10–5 M–2 s–1
(C) 2 × 10–5 M–2 s–1

(D)
× 10–5 M–2 s–1

7) Which of the following statement is not correct for pseudo first order rate constant for gaseous
bimolecular reaction?

(A) Its value is independent of the reactant present in small amount.

(B) Its value is dependent on the temperature
(C) Its value will not change if volume of container is changed.
(D) It is dependent on the concentration of the reactant.

8) Which of the following reaction may be elementary reaction ?

(A) Zero order reaction

(B) 2A + 3B —→ Products
(C) A + 2B —→ products, r = K[A] [B]2

(D)
—→ products, r = K[A]1/2 [B]3/2

9) For the reaction 2A → B + 3C; if ; the correct

relation between k1, k2 and k3 is

(A) k1 = k2 = k3
(B) 3k1 = 6k2 = 2k3
(C) 4k1 = k2 = 3k2

(D)

10) Choose the correct statement regarding the formation of carbocations A and B given :-
(A) Carbocation B is more stable and formed relatively at faster rate
(B) Carbocation A is more stable and formed relatively at slow rate
(C) Carbocation B is more stable and formed relatively at slow rate
(D) Carbocation A is more stable and formed relatively at faster rate

11)

(A)

(B)

(C)

(D)

12) Which one of the following has maximum nucleophilicity in polar protic solvent?

(A)

(B)

(C) Et3N
(D)

13)
Major product (X) is

(A)
(B)

(C)

(D)

14) Select correct order of leaving groups

(A)

(B)

(C)

(D)

15)

In the given reaction : [X] as major product [X] will be :

(A)

(B)

(C)

(D)
16) Which carbocation is least likely to be formed as an intermediate ?

(A)

(B)

(C)

(D)

17) Identify set of electrophiles :

(A) CO , , ∶CH2, Br2

2

(B)

(C)

(D)

18) In the following carbocation; H/CH3 that is most likely to migrate to the positiviely charged

carbon is

(A) CH3 at C-4

(B) H at C-4
(C) CH3 at C-2
(D) H at C-2

19) Which of the following carbocation is most stable ?

(A)

(B)

(C)
(D)

20)
Product A is :

(A)

(B)

(C)

(D)

SECTION-II

1)

For a first order reaction, time required for 99.0% completion is 'x' times for the time required for
the completion of 90% of the reaction then value of x is ?

2) For an elementry reaction :

where
Initially only 2 moles of A are present. The total number of moles of A, B and C at the end of 75%
completion of reaction are 'x', then value of 2x is ?

3) A and B decompose via first order kinetics with half-lives 54.0 min and 18.0 min respectively.
Starting from an equimolar non reactive mixture of A and B, the time taken for the concentration of
A to become 16 times that of B is ______ min. (Round off to the Nearest Integer).

4) In the given compounds, how many of the following compound is an electrophile.

H⊕, SbCl5, Ag+, BH3, BF3, , CO2, , CH3–C≡N, CH2=CH2 ,

5) Number of carbocation would you be expect to rearranged :

(i) (ii) (iii)

(iv) (v)

(vi) (vii)

PART-3 : MATHEMATICS

SECTION-I

1) is equal to

(A) 1
(B) 0
(C) does not exist
(D) none of these

2)

The value of is :

(A)

(B)

(C)

(D)

3)
Let f(x) = then (1 + f(x))2 has the value equal to

(A) 10
(B) 100
(C) 1000
(D) none

4) Let . Then

(A) f is continuous at x = 1
(B)

(C)

(D) does not exist

5) Let f(x) = |2x2+5|x|–3|, x∈R. If m and n denote the number of points where f is not continuous and
not differentiable respectively, then m + n is equal to :

(A) 5
(B) 2
(C) 0
(D) 3

6) If then

(A) f(x) is not continuous at x = 0

(B) f(x) is not differentiable at x = 0
(C) f(x) is differentiable at x = 0
(D) f '(x) is continuous at x = 0

7) Let ƒ(x) in R → R is an odd and continuous function such that ƒ(2) = 3; ƒ(4) = –4; ƒ(5) = 9 and ƒ(7) =
–4, then minimum number of zeroes of the equation is

(A) 3
(B) 4
(C) 7
(D) 8

8) Let where [•] denotes greatest integer, then

(A) ℓ exists but m does not
(B) m exists but ℓ does not
(C) Both ℓ and m exists
(D) neither ℓ nor m exists

9) (where [•] denotes the greatest integer function) is

(A) 5
(B) 6
(C) 7
(D) Does not exist

10) If then

(A)

(B)

(C)

(D)

11) If y = sec(tan–1x) then at x = 1 is equal to

(A)

(B)

(C) 1
(D) None of these

12) If f and g both are differentiable functions of x such that f(2) = 4, g(2) = 1, f '(2) = 2, g'(2) = 4

and , then find h'(2).

(A) 8
(B) –10
(C) –14
(D) 12
13) Let . If f(x) is continuous and differentiable at any point, then

(A)
(B)
(C)
(D)

14) Consider the function f(x) = min {|x2 – 9|, |x2 – 1|}, then the number of points where f(x) is non-
differentiable is/are

(A) 0
(B) 7
(C) 6
(D) 4

15) Derivative of cos–1(2x2 – 1) with respect to when is:

(A) 4
(B) –4
(C) 6
(D) –6

16) If
is differentiable at x = 1, then the value of b – a is equal to

(A) 0
(B) 1
(C) –1

(D)

17)
then find the values of b and c if f(x) is differentiable at x = 1.

(A) b = 1, c = 1
(B) b = 1, c = –1
(C) b = –1, c = 1
(D) None of these

18) Let f(x) = (lnx)x + ln(xx) + (x)lnx then fʹ(e) equal to:
(A) 5
(B) e–1
(C) 1
(D) 0

19) Let f (x) = min {1, 1 + x sin x}, 0 ≤ x ≤ 2π. If m is the number of points, where f is not
differentiable and n is the number of points, where f is not continuous, then the ordered pair (m, n)
is equal to

(A) (2, 0)
(B) (1, 0)
(C) (1, 1)
(D) (2, 1)

20) The number of points, where the function f : R → R, f (x) = |x – 1| cos |x – 2| sin |x – 1| + (x – 3)
|x2 – 5x + 4|, is NOT differentiable, is :

(A) 1
(B) 2
(C) 3
(D) 4

SECTION-II

1) equals. (n ∈ Z+)

2) If the function is differentiable on R, then 48 (a + b) is equal to

3) Number of points where f(x) = [x] + [x + 1/3] + [x + 2/3], then ([•] denotes the greatest integer
function) is discontinuous for x ∈ (0, 3)

4) A differentiable function f satisfying a relation f(x + y) = f(x) + f(y) + 2xy(x + y) –

and . Then the value of [f(2)] is (where [x] represents greatest integer function)

5) If ; then
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C A B D B A A C C B B A C A A A C B A

SECTION-II

Q. 21 22 23 24 25
A. 16 6 2 4 7

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B B D D C C C B A D A A A B C A D C D

SECTION-II

Q. 46 47 48 49 50
A. 2 7 108 9 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A C B C D C C B B C A C B C C D C A B B

SECTION-II

Q. 71 72 73 74 75
A. 27 15 8 8 1275
 SOLUTIONS

PART-1 : PHYSICS

1)

Electric field due to ring at centre =

4) E will be towards origin and it will be equivalent to charge at origin and diagonally opposite

7)

9)

11)
An element is taken in the form of a ring of radius "r" and thickness "dr"
electric field at ring = E
E=
area of element (dA) = 2πrdr
flux through ring (dϕ) = EdA cosθ

dϕ =

tanθ = ⇒ r = a tan θ
dr = a sec2 θ .dθ

dϕ = =

dϕ =

ϕ= =

θ=

0
cos θ =

ϕ= =

2a = , 4a2 = a2 + R2, 3a2 = R2, a =

14)
AB = a
BC =
area ABCD (A) = (AB) (BC)
A = (a) ( )
A=
line AD makes θ = 45° with z-axis hence plane ABCD lies at 45° on y-z plane. Projection of
area over
y-z plane (A') = A cos 45°

A' =
required flux (ϕ) = E0 · A'
ϕ = E.a2

16) (i) x = 1, ,

So,
(ii) x = 0, ,

So,
(iii) y = 1, ,

So,
(iv) y = 0, ,

So,
(v) z = 1, ,

So,
(vi) z = 0, ,

So,

Thus

20)

So the field is nonconservative.

21) Charge enclosed

 Using gauss law ; E4π(R/2)2 =

22) Number of electric field lines are drawn in proportion to charge magnitudes.

23)

24) 1 × 6 = 2 × v ⇒ v = 3m/s

x = 4 mm

25)

PART-2 : CHEMISTRY

26) 6.93 × 10–3 = K × (0.1)x (0.2)y

6.93 × 10–3 = K × (0.1)x (0.25)y
So y = 0
and 1.386 × 10–2 = K × (0.2)x (0.30)y
 0
So r = K × (0.1) × (0.2)
6.93 × 10–3 = K × 0.1 × (0.2)0

= =

27)

R1 = K[A]1 [B]1

R1 = K

R2 =

31)
for n = 3

slope = tanθ = 2k

k = 2 × 10–5 M–2s–1

32) Suppose a reaction

A(g) + B(g) → C(g)
(excess)
rate = k [B]b [A]a = k' [A]a
k' = k [B]b
Now value of k' depends upon concentration of excess reactant and temperature.

35)
B is more stable & it will be formed at faster rate
36)

39)

Leaving ability of any leaving

group

Note : good leaving groups are weak bases

(A) (size)

(B) >
Correct order :

>
(Resonance stablize)
(C)
Correct order : NH3 > NMe3 >
(Strong base)

(D)
Correct order :
40)

41) the above carbocation cannot be formed as it violates BREDT’S RULE

[planarity is not possible at bridge head 'C'-atom]

42)
→ vacant p-orbital
:CH2 → Octet incomplete
Br2 → instantaneous dipole formation
So, option (A) contain all electrophile

44)
This is the most stable carbocation due to resonance i.e. Back Bonding

45)

46)
 Apply : kt = ln

47)

x + y = 0.75 × 2 = 1.5
nT = nA + nB + nC = a – x – y + 2x + 2y
=a+x+y
= 2 + 1.5 = 3.5 = x
then 2x = 3.5 × 2 = 7.0

48)

108

49) H⊕, SbCl5, Ag+, BH3, BF3, , CO2,

, CH3–C≡N
These all are electrophile.

50) (ii), (iii), (iv) (v), (vi)

PART-3 : MATHEMATICS

51)

(since tan–1(tanx) = x – π when )

∴ RHL
similarly LHL = 1 so

52)

54) and for

as So

Thus,

and

55) f(x) = |2x2+5|x|–3|

Graph of y = |2x2 + 5x – 3|

Graph of f(x)

Number of points of discontinuity = 0 = m

Number of points of non-differentiability = 3 = n

57) ƒ(0) = 0; one root between (2,4) and (5,7) (–4,–2) and (–7,–5)

58)
59)

= [a value slightly lesser than 7]

(|sin x| < |x|, when x → 0)

60)

61)

Differentiating w.r.t. x, we get

62)

63) For (x) to be continuous at x = 1, we must have

.....(1)
Now, for f(x) to be differentiable at x = 1, we must have
 Putting a = –1 in (1), we get b = 2

64)

66) Since, f(x) is differentiable, it must be continuous at x = 1

67)

f(x) is differentiable at x = 1
Then, it must be continuous at x = 1

for which
Also

69)
No. of non-differentiable points = 1 (m)
No. of not continuous points = 0 (n)
(m, n) = (1, 0)

70) f(x) = |x – 1| cos |x – 2| sin |x – 1| + (x – 3)| x2 – 5x + 4|

= |x – 1| cos |x – 2| sin |x – 1| + (x – 3)| x – 1||x – 4|
= |x – 1| [cos |x – 2| sin |x – 1| + (x – 3) |x – 4|]
Non differentiable at x = 1 and x = 4.
71)

73) We have f(x) = [x] + [x + 1/3] + [x + 2/3] = [3x]

Which is discontinuous when 3x = k or
x = k/3, k ∈ I
Hence points of discontinuity are 1/3, 2/3, 3/3, 4/3, 5/3, 6/3, 7/3, 8/3.

74)

75)

Differentiation both side w.r.t. x