17-08-2025

1803CJA101029250052 JM

PART-1 : PHYSICS

SECTION-I

1) A resistance of 40 Ω is connected to a source of alternating current rated 220 V, 50 Hz. Find the
time taken by the current to change from its maximum value to rms value :

(A) 2.5 ms
(B) 1.25 ms
(C) 2.5 s
(D) 0.25 s

2) See the adjoining circuit. The current through the cell just after closing the switch S is :

(A)

(B)

(C)

(D)

3) Two alternating voltage generators produce emf of the same amplitude E0 but with a phase
difference of The resultant emf is

(A)
(B)
(C)
(D)

4) For the series L-C-R circuit, the voltmeter connected across resistor and shown ammeter have
readings as
(A) V = 100 V, l = 2A
(B) V = 100V, l = 5A
(C) V = 1000V, l = 2A
(D) V = 300V, l = 1A

5) A circular loop of radius 1m is placed in a varying magnetic field given as B = 6t Tesla, where t is
time in sec. Find the current in the loop if its resistance is1Ω/m.

(A) 3A
(B) 1.5A
(C) 4.5A
(D) 6A

6) A rod PQ is connected to the capacitor plates. The rod is placed in a uniform magnetic field (B)
directed into the plane of the paper. If the rod is pulled out of magnetic field with velocity as
shown in figure,

(A) Plate M will be positively charged

(B) Plate N will be positively charged
(C) Both plates will be similarly charged
(D) No charge will be collected on plates.

7) An series LCR circuit is resonating with a source whose emf varies with time as described in
diagram-1. If we replace source by another source whose emf varies with time according to
diagram-2, then :

(A) for getting resonance again, decrease R

(B) current will remain in phase with source voltage
(C) for getting resonance again, decrease C
(D) current will lead source voltage after replacing the source

8) The ratio of the secondary to the primary turns in a transfomer is 3 : 2 and the output power is P.
Neglecting all power losses, the input power must be

(A)

(B)

(C)

(D) P

9) In a series LR circuit, the voltage drop across inductor is 8 volt and across resistor is 6 volt. Then
voltage applied and power factor of circuit respectively are:

(A) 14 V, 0.8
(B) 10 V, 0.8
(C) 10 V, 0.6
(D) 14 V, 0.6

10) A ideal transformer is used to step up an alternating emf of 220 volt to 11 kilo volt to transmit
4.4 kw of power. If the primary coil has 1000 turns, what is the current in the secondary?

(A) 4 A
(B) 0.4 A
(C) 0.04 A
(D) 0.2 A

11) The voltage of an AC source varies with time according to the equation,

Where t is in second and V is in volt. Then

(A) The peak voltage of the source is 100 volt

(B)
The peak voltage of the source is volt
(C) The peak voltage of the source is 50 volt
(D) The frequency of the source is 50 Hz
12) An AC circuit has and L = 80 mH connected in series. The quality factor of
the circuit is

(A) 2
(B) 0.5
(C) 20
(D) 400

13) By what percentage the reactance in an AC circuit should be increased so that the power factor
changes from (1/2) to (1/4) ?

(A) 200%
(B) 100%
(C) 50%
(D) 400%

14) A coil of inductance 5H is joined to a cell of emf 6V through a resistance 10Ω at time t = 0. The
emf across the coil at time t = ln s is :

(A) 3V
(B) 1.5 V
(C) 0.75 V
(D) 4.5 V

15) Find the ratio of time constant in build up and decay in the circuit as shown in figure :-

(A) 1 : 1
(B) 3 : 2
(C) 2 : 3
(D) 1 : 3

16) In a L–R decay circuit, the initial current at t = 0 is I. The total charge that has flown through the
resistor till the energy in the inductor has reduced to one–fourth its initial value, is

(A)
(B)

(C)

(D) None

17) An alternating current is given by the equation . The r.m.s. current is

given by

(A)

(B)

(C)

(D)

18) In the circuit, as shown in the figure, if the value of R.M.S current is 2.2 ampere, the power

factor of the box is

(A)

(B) 1

(C)

(D)

19) A uniform metal rod is moving with a uniform velocity v parallel to a long straight wire carrying
a current I. The rod is perpendicular to the wire with its ends at distances r1 and r2 (with r2 > r1)
from it. The emf induced in the rod is :-

(A) 0

(B)

(C)

(D)

20) The effective value of current i = 2 sin 100 π t + 2 sin(100 π t + 30°) is :

(A) Amp

(B)
Amp
(C) 4 Amp
(D) None
 SECTION-II

1) An ac circuit is shown in figure. then what will be average power

dissipated, in Joule in the circuit.

2) In an alternating source of frequency of 50 Hz we connected a resistor of 500 ohms and an

inductor. If the phase difference between the current and the applied voltage is π/4, what is the
power dissipated in the circuit (in W)? The applied voltage is 200 V.

3) Find potential difference (in volt) across inductor at t = 1 sec. All data are given in the figure.

4) When magnetic flux through a coil is changed, the variation of induced current in the coil with
time is as shown in figure with current falling from 4A to zero ampere in 01. sec. If resistance of the
coil is 10 Ω, then find the magnitude of change in the magnetic flux linked with the coil.

5) A series LCR circuit consists of R=80Ω. XL=100Ω, and XC=40Ω. The input voltage is 2500 cos(100
πt) V. The amplitude of current, in the circuit, is__________A.

PART-2 : CHEMISTRY

SECTION-I
1)

(A)

(B)

(C)

(D)

2) In the given reaction :

[X] + Acetic anhydride → Aspirin
[X] will be :

(A)

(B)

(C)

(D)
3) The
compound (X) is

(A) (CH3CO)2O
(B) Br CH2–COOH
(C) CH3COOH
(D) CHO–COOH

4) N‑Ethyl pthalimide on hydrolysis gives:

(A) Ethyl amide

(B) Ethyl amine
(C) N, N–diethyl amine
(D) N, N–dimethyl amine

5)

(A)

(B)

(C)

(D)

6) ?
Consider the above reaction and predict the major product.

(A)

(B)
(C)

(D)

7) The major product of the following reaction is

(A)

(B)

(C)

(D)

8) By which of the following sequence of steps can the alcohol RCH2CH2OH(X) be converted into
RCH2CH2COOH(Y)?

(A)
(B)
(C)

(D)
9)
Major product of the reaction is :-

(A)

(B)

(C)

(D)

10) Which is incorrect reaction:

(A)

(B)

(C)

(D)

11) An organic compound [A] (C4H11N), shows optical activity. The compound [A] reacts
with PhSO2Cl producing a compound which is soluble in KOH. The structure of A is:-

(A)
(B)

(C)

(D)

12) The solubility in water of a sparingly soluble salt AB2 is 1.0 × 10–5 mol L–1. Its solubility product
will be

(A) 1 × 10–15
(B) 1 × 10–10
(C) 4 × 10–15
(D) 4 × 10–10

13) A student needs to prepare a buffer solution of propanoic acid and its sodium salt with pH 4. The

ratio of required to make buffer is ……….

Given : Ka(CH3CH2COOH) = 1.3 × 10–5

(A) 0.03
(B) 0.13
(C) 0.23
(D) 0.33

14) The titration curve of weak acid vs. strong base with phenolphthalein as indictor) is shown
below. The Kphenolphthalein = 4 × 10–10.

Given: log2 = 0.3 The number of following statements which

is/are correct about phenolphthalein is _________.
(A) It can be used as an indicator for the titration of weak acid with weak base.
(B) It begins to change colour at pH = 8.4
(C) It is a weak organic base
(D) It is colourless in acidic medium

15) If 40 ml of 0.2 M KOH is added to 160 ml of 0.1 M HCOOH [Ka = 2×10–4], the pOH of the
resulting solution is

(A) 3.4
(B) 3.7
(C) 7
(D) 10.3

16) When a salt is warm with dilute H2SO4 it gives a gas which smells like rotten eggs, the salt is–

(A) Sulphate Salt

(B) Carbonate Salt
(C) Sulphide Salt
(D) Chloride Salt

17) “Cacodyl oxide” is formed in the specific test of -

(A) Formate
(B) Formate
(C) Acetate
(D) Nitrate

18) Which of the following ion gives brown gas test with dil. H2SO4.

–
(A) NO2
–
(B) NO3
(C) Both (A) and (B)
(D) None

19) Which of the following anions are identified by dil. HCl :

– – 2–
(A) NO2 , NO3 , CO3
– – 2–
(B) NO2 , NO3 , SO3
– 2– –
(C) S2 , SO3 , NO2
– – 2–
(D) CH3COO , I , CO3

20) can be distinguished by

(A) Phenolphthalein
(B) BaCl2 solution
(C) HgCl2 solution
(D) All of these

SECTION-II

1) Find the total number of acidic radical which produce volatile product with dil HCl :
(i) (ii) I¯ (iii) (iv) (v) (vi)

2) No. of DOU in C is.

3)

Number of sp2 hybridised orbital present in E is?

4) How many number of amines gives foul smelling isocyanide when treated with CHCl3 + KOH?

5) Calculate the concentration of CH3COO– in 0.1M CH3COOH(aq.) solution when mixed with equal
volume of 1M HCl (Ka = 10–5)
If your answer is x × 10y then fill ‘y’ in OMR. Where ‘x’ is single digit number.

PART-3 : MATHEMATICS

SECTION-I

1) If |A| ≠ 0 and A2 - 5A + 6I = 0, find A-1

(A)

(B)

(C)
(D)

2) If A is a skew symmetric matrix such that ATA = I (where I is an identity matrix of same order as
A), then A4n–1 is equal to (where n ∈ N)-

(A) –AT
(B) I
(C) –I
(D) AT

3) Let the matrix A and B be defined as A = and B = then the value of Det(2A9B–1) is

(A) 2
(B) 1
(C) –1
(D) –2

4) Number of skew-symmetric matrices of order 3 whose elements are 0, 0, 0, 1, –1, 2, –2, 3, –3 is

(A) 8
(B) 12
(C) 24
(D) 48

–1
5) If where , then A is equal to -

(A)

(B)

(C)

(D)

6) If , then number of values of satisfying A + AT = I is-

(Here I is 2 × 2 matrix and AT is transpose at matrix A)

(A) 4
(B) 2
(C) 8
(D) 6

7) If A is square matrix of order 3 such that |A| = 3, then |adj (adj (adj A))| is-

(A) 38
(B) 39
(C) 310
(D) 311

8) If an idempotent matrix is also skew symmetric then it must be-

(A) an involutary matrix

(B) an identity matrix
(C) an orthogonal matrix
(D) a null matrix

9) Let P and Q are two square and invertible matrices such that Q = –P–1QP then (P + Q)2 is equal to
-

(A) Null matrix

(B) P2 + 2PQ + Q2
(C) (P – Q)2
(D) Identity matrix

10) If A and B are two square matrices of order 3 such that AB = BA and A2 + AB = 2B2. If det(A – B)
≠ 0 and det(B) ≠ 0, then det(AB–1) is

(A) –2
(B) 0
(C) 8
(D) –8

11) For let be a square matrix of 2nd order such that

, then trace of matrix B5 is equal to-

(A) –2
(B) –1
(C) 1
(D) 2

12) Let A be real matrix such that

Then, the system

has

(A) unique solution

(B) exactly two solutions
(C) no solution
(D) infinitely many solutions

13) If P is a 3 × 3 matrix such that PT = 2P + I, where PT is the transpose of P and I is the 3 × 3

identity matrix, then there exists a column matrix such that

(A)

(B) PX = X
(C) PX = 2X
(D) PX = –X

14) Let a unit vector make angles and with the vectors

and respectively. If then is equal to

(A)

(B)

(C) 9
(D) 7

15) If and then the unit vector parallel to is

(A)

(B)

(C)

(D)

16) The vectors from origin to the points A and B are and respectively,
then the area of is equal to

(A) 340
(B)
(C)

(D)

17) Consider three vectors . Let and . If is the angle

between the vectors and , then the minimum value of is equal to :

(A) 110
(B) 105
(C) 124
(D) 121

18) If and are two non-zero vectors such that , then angle between and is
:-

(A) 120°
(B) 60°
(C) 90°
(D) 30°

19) If the vectors and are the sides of a triangle ABC, then the length
of the median through A is :

(A)
(B)
(C)
(D)

20) A, B, C, D, E are five coplanar points then is equal to :

(A)
(B)
(C)
(D)

SECTION-II

1) Let and be two vectors such that and . Then is

equal to____.

2) The least positive integral value of x for which the angle between vectors and
is acute is

3) The vector along bisector of angle between and , where

is given by , (a > 0) then a + b + c is :

4) If and A2 – kA – I2 = 0, then value of k is -

5) Let A and B be two square matrices of order 3 such that AB = A and BA = B. If (A + B)10 = k(A +
B), then find the value of k.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A D C A A A D D C B C A B A B B C A B D

SECTION-II

Q. 21 22 23 24 25
A. 120 40 360 2 25

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A C A B C D A A A B D C B B D C C A C D

SECTION-II

Q. 46 47 48 49 50
A. 3 1 18 3 6

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D D D D A B A D C D A A D B D D C C C B

SECTION-II

Q. 71 72 73 74 75
A. 14 2 6 4 512
 SOLUTIONS

PART-1 : PHYSICS

1)

Considering sinusoidal AC.

Phase at maximum value

Phase at rms value =

Thus phase change

Now ω = 2πf
= 2π × 50
= 100 π

Time taken t =
t = 2.5 × 10–3 = 2.5 ms

2)

3)

According to superposition principle, we get

4) In L-C-R series circuit,

and

So, voltage across resistance,

VR = 100 V
As we know that rms value of a current,

At resonating condition,
5) the current in the loop if its resistance is1 Ω/m.

i= = = = = 3 amp.

6) Consider the force on an electron in PQ. This electron experiences a force towards Q. Free
electrons in PQ tend to move towards N. So M will be positively charged.

7)

;
ω2 < ωR from diagram
Circuit with behave as capacitance circuit
∴current leads voltage

8) For ideal transformer, input power = output power.

9) VL = 8V, VR = 6V, V = = 10 V

power factor = cos ϕ = = = 0.6

10) Is = PS/VS

⇒ IS = = 0.4A

11)
Hence, peak voltage of source is 50 volt, and frequency

of source

12) Given that,

For a series L-C-R AC circuit,

Quality factor,
13) , ,
∴ %change in X = 100 %

14) Time constant =

so EMF will be half at t =

E⇒ = 3V

15) Build up circuit

Decay

Ratio = 3 : 2

16) Energy of inductor (i) ⇒ Current i =

17)

< sin θ > = 0

18) z = 100 cos ϕ = =

z = R ( ⇒ xL = xC) =

19)

ε=

20) i = 2 sin 100 πt + 2 sin (100 πt + 30°)

=

=
Effective value of current Or rms value.

21)

As

Given V0 =

Z = 50

Also,

22)
ωL = R
 23) VL = 360 sin

VL = 360 sin
= 360 volt

24) Rq = Δϕ

Δϕ =2

25)

PART-2 : CHEMISTRY

26)

27)

28)
29)

30)

31)

32)

33) R–CH2–CH2–OH R–CH2–CH2–Br R – CH2 – CH2 – CN R – CH2–CH2–COOH

34) Hoffmann Bromamide reaction has total retention of configuration.

35) 1° unhindard Alkyl halide + NH3 SN2

2° Alkyl halide + NH3

3° Alkyhltialite + NH3 E2 (Major Products)

(A)

(B)
[3° + NH3 (room temp.) → E2]

(C)

(D)

36) C4H11N releases N2 with HNO2 i.e. it is primary amine. After reacting with Hinsberg
reagent it forms a compound which is soluble in KOH, Hence, the amine is primary.

37)

Ksp = 4s3
= 4(10–5)3 = 4 × 10–15

38)

39)

(B) pkIn = –log (4 × 10–10) = 9.4

Indicator range
⇒ pkIn ± 1
i.e. 8.4 to 10.4
(D) In acidic medium, phenolphthalein is in unionized form and is colourless.

40) KOH + HCOOH → HCOOK + H2O

 0.2 H, 40 ml 0.1 M. 160 ml
8 m mole 16 m mole 0
0 8 m mole 8 m mole
Mixture of weak acid HCOOH and salt HCOOK
⇒ Acidic buffer solution.

pH = pKa + log
pOH = 14 – 3.7 = 10.3

41)

H2S – Rotten egg smell

42)

Cacodyl test :– when As2O3 is heated with CH3COONa then it gives nausting smell.

43) gives brown fumes with dil H2SO4 but gives brown fumes with conc. H2SO4

44) Fact

45)

HgCl2 No reaction Red brown ppt

Ba(HCO3)2 BaCO3↓
BaCl2
Clear solution White ppt

Phenolphthalein Colourless solution Pink solution

46) (iii, v, vi)

, ,
 47)

48)
Number of sp2 hybridised orbital present in E is?

49) Only primary amines will give carbylamine.

50) CH3COOH CH3COO– + H+

= x

Ka = 10–5 =
x = 10–6

PART-3 : MATHEMATICS

51)

A2 - 5A + 6I = 0
multiply by A-1
A1 - 5I + 6A-1 = 0

A-1 =

52) AT = –A & ATA = I

⇒ A2 = –I ⇒ A4n = I
A4n–1 = A–1 ⇒ A4n–1 = AT (A is orthogonal)
53) |A| = –1, |B| = 2

|2A9B–1| = 22|A|9

54) A=
Number of skew symmetric matrices = 3! × 8 = 48. Ans.
As, diagonal element must be 0 and conjugate pair elements are additive inverse of each
other in skew-symmetric matrix.
Aliter :
1 can be put by 6 ways
– 1 can be put by 1 way
2 can be put by 4 ways
– 2 can be put by 1 way
3 can be put by 2 ways
– 3 can be put by 1 way
∴ Number of skew symmetric matrices = 6 × 1 × 4 × 1 × 2 × 1 = 48. Ans.

55) By given condition

Now adj A =
|A| = – 9

OR

56)

57) |adj (adj A)| =

|adj (adj (adj(A)))| = = 38

58) A' = – A and A2 = A

So (A2)' = A' Þ (A')2 = – A
⇒ (– A)2 = – A ⇒ A = – A
⇒ A=0

59) Q = –P–1QP ∴ PQ = –QP

(P + Q)2 = (P + Q)(P + Q)
= P2 + PQ + QP + Q2 = P2 + Q2
(P – Q)2 = (P – Q)(P – Q)
= P2 – PQ – QP + Q2 = P2 + Q2

60) A2 + AB – 2B2 = 0
(A – B)(A + 2B) =0
⇒ A = –2B ⇒ AB–1 = –2I
det(AB–1) = |–2I| = –8

61) ;

∴ Tr(B5) = 2cos5θ

62) Let

Given …. (1)

…. (2)
…. (3)
…. (4)

Given
 …. (5)
…. (6)

Given

∴ from (2), (3), (4), (5), (6) and (7)

63) PT = 2P + I
⇒ P = 2PT + I
⇒P = 2(2P + I) + I
⇒ P = 4P + 3I
⇒ P = –I
⇒ PX = –X

64) Unit vector

Now angle between

….(i)

Angle between

….(ii)

Angle between

…. (iii)
from equation (i), (ii) and (iii) we get

y=0 z=

Thus

65) Unit vector

66)
67)

68) a2 + 4b2 + 2 . 2 =
⇒

69)

70)

71) ;

As

72) For the angle to be acute

⇒
73) ,

74) is the characteristic equation

∴ Characteristic equation of given matrix is

A2 – 4A – I2 = 0
so K = 4

75) A = AB = A·BA = AB·A = A·A = A2

B = BA = BAB = B2
∴ (A + B)2 = A2 + B2 + AB + BA = A + B + A + B = 2(A + B)
(A + B)3 = (A + B)(A + B)2 = 2(A + B)2 = 4(A + B)
Similarly, (A + B)n = 2n–1 (A + B)
Hence, (A + B)10 = 512 (A + B) Ans.