04-01-2026

1001CJA106216260021 JA

PART-1 : PHYSICS

SECTION-I

1) Figure shows three systems in which a block of mass m can execute S.H.M. What is ratio of

frequency of oscillation?

(A) 2 : 1 : 4
(B) 1 : 2 : 4
(C) 4 : 2 : 1
(D) 3 : 2 : 1

2) A toy car of mass m is having two similar rubber ribbons attached to it as shown in the figure. The
force constant of each rubber ribbon is k and surface is frictionless. The car is displaced from mean
position by x cm and released. At the mean position the ribbons are undeformed. Vibration period is

(A)

(B)

(C)

(D)

3) A uniform rod of length ℓ swings from a pivot as a physical pendulum. The position of the pivot
can be varied along the length of the rod. The minimum time period with which the rod can oscillate

with an appropriate position of the pivot is T = where L is equal to :-

(A)

(B)

(C)

(D)

4) A body of mass m is moving in one dimension under the influence of a potential energy U(x) given

by , where a and c are positive constant. Find angular frequency of small oscillations
about its equilibrium position.

(A)

(B)

(C)

(D)

5) A block of mass m lies on a horizontal frictionless surface and is attached to one end of a
horizontal spring (with spring constant k) whose other end is fixed. The block is initially at rest at
the position where the spring is unstretched (x = 0) when a constant horizontal force in the
positive direction of the x-axis is applied to it. A plot of the resulting kinetic energy of the block

versus its position x is shown in figure. What is the magnitude of .

(A) 2 N
(B) 4 N
(C) 8 N
(D) 16 N

6) Consider a spring-mass system of mass m and spring constant k on a frictionless, horizontal table.
If the initial Amplitude is A and another mass m is dropped vertically onto the oscillating mass and

sticks with it when its displacement is , then which is incorrect statement

(A)
Amplitude after collision is A

(B)
Total mechanical energy after collision is
(C) Time period after collision is times of initial time period
(D) equilibrium position of S.H.M will change

7) The maximum range of a shell fired from a gun is R = 22.5 m. This gun is mounted on a platform
that moves horizontally with a constant speed υ 15.0 m/s. At what angle above the horizontal, must
the gun be aimed to achieve maximum horizontal range ? Neglect air resistance as well as height of
the gun. Acceleration of free fall g = 10.0 m/s2.

(A) 90°
(B) 45°
(C) 60°
(D) 30°

8) A projectile is fired at an angle θ with the horizontal. Find the condition under which it lands

perpendicular on an inclined plane of inclination α as shown in figure.

(A) sin α = cos (θ – α)

(B) cos α = sin (θ – α)
(C) tan θ = cot (θ – α)
(D) cot(θ – α) = 2tanα

9) A man moving on track ABC, getting rain drops vertical for the path AB, and along same line of its

motion for path BC then actual speed of rain drop is :-

(A)

(B)

(C)
(D) Can’t find

10) Two particles moving with constant velocities V and 2V along X and Y direction respectively are
at the positions shown in the figure at some instant. Distance between them at that moment is 1 km.
What will be the minimum distance between them?

(A)

(B)

(C)

(D)

11) A parallel beam of light is incident from air at an angle α on the side PQ of a right angled
triangular prism of refractive index . Light undergoes total internal reflection in the prism at

the face PR when α has a minimum value of 45°. The angle θ of the prism is :

(A) 15°
(B) 22.5°
(C) 30°
(D) 45°

12) For a prism of apex angle 45°, it is found that the angle of emergence is 45° for grazing
incidence. Calculate the refractive index of the prism.

(A) (2)1/2
(B) (3)1/2
(C) 2
(D) (5)1/2

13) A linear object AB is placed along the axis of a concave mirror. The object is moving towards the
mirror with speed V. The speed of the image of the point A is 4 V and the speed of the image of B is
also 4V. If centre of the line AB is at a distance L from the mirror then length of the object AB will be
(A)

(B)

(C) L

(D)

14) A prism of angle A and refractive index 2 is surrounded by medium of refractive index . A ray
is incident on side PQ at an angle of incidence i (0 ≤ i ≤ 90°) as shown in the figure. The refracted
ray is then incident on side PR of prism. The minimum angle A of prism for which ray incident on
side PQ does not emerge out of prism from side PR (for any value of i) is :-

(A) 30°
(B) 45°
(C) 60°
(D) 120°

15) A bird is flying up at angle sin–1 (3/5) with the horizontal. A fish in a pond looks at that bird.
When it is vertically above the fish. The angle at which the bird appears to fly (to the fish) is: [nwater =
4/3]

(A) sin–1 (3/5)

(B) sin–1 (4/5)
(C) 45°
(D) sin–1 (9/16)

16) A point source has been placed as shown in the figure. What is the length on the screen that will
receive reflected light from the mirror ?

(A) 2 H
(B) 3 H
(C) H
(D) None of these

17) A transparent block A having refractive index μ = 1.25 is surrounded by another medium of
refractive index μ = 1.0 as shown in figure. A light ray is incident on the flat face of the block with
incident angle θ as shown in figure. What is the maximum value of θ for which light suffers total

internal reflection at the top surface of the block ?

(A) tan–1 (4/3)

(B) tan–1 (3/4)
(C) sin–1 (3/4)
(D) cos–1 (3/4)

18) In list-I possible instantaneous velocity vector of the object with respect to ground are shown.
The corresponding velocity vectors of images are the situations shown in list-II. Match list-I with the
list-II.

List-I List-II

(P) (1)
 (Q) (2)

(R) (3)

(S) (4)

(5)
(A) P-1, Q-2, R-3, S-4
(B) P-4, Q-1, R-3, S-2
(C) P-1, Q-3, R-2, S-4
(D) P-3, Q-1, R-2, S-4

19) This question has 2 statements: assertion and reason.

Assertion: The focal length of the mirror is f and distance of the object from the focus is u, the
magnitude of magnification of the mirror is f / u.

Reason: Magnification
Choose the appropriate statement from below:

(A) If both assertion and reason are true and the reason is the correct explanation of the assertion.
(B) If both assertion and reason are true but reason is not the correct explanation of the assertion.
(C) If assertion is true but reason is false.
(D) If the assertion and reason both are false.

20) Statement-I : The formula connecting u, v and f for a spherical mirror is valid only for mirrors
whose sizes are very small compared to their radii of curvature.
Statement-II : Laws of reflection are strictly valid for plane surfaces, but not for large spherical
surfaces.

(A) Statement-I is True, Statement-II is True; Statement-II is a correct explanation for Statement-I.
Statement-I is True, Statement-II is True; Statement-II is NOT a correct explanation for
(B)
Statement-I.
(C) Statement-I is True, Statement-II is False.
(D) Statement-I is False, Statement-II is True.

SECTION-II

1) On a frictionless horizontal plane, a bob of mass m = 0.1 kg is attached to a spring with natural
length ℓ0 = 0.1 m. The spring constant is k1 = 0.009 Nm–1 when the length of the spring ℓ > ℓ0 and is
k2 = 0.016 Nm–1 when ℓ < ℓ0. Initially the bob is released from ℓ = 0.15 m. Assume that Hooke's law
remains valid throughout the motion. If the time period of the full oscillation is T = (nπ) s, then the
integer closest to n is _________.

2) A block is placed on a horizontal platform vibrating up and down, simple harmonically. It is

observed that the block loses its contact with the platform when its angular frequency is 5 rad/s. The
amplitude of vibration can not be less than ‘A’ cm, then find the value of A. [g = 10 m/s2]

3) A ball rolls down a tube that is inclined at an angle of 53° with the horizontal. The ball leaves the
lower opening of the tube with a speed of 5 m/s. A strong horizontal wind imparts the ball uniform
horizontal acceleration everywhere during its flight as shown in the figure. As a result, the ball
strikes the ground at a point that is 12 m vertically below the lower opening of the tube. What is the

horizontal acceleration imparted by wind to the ball.

4) A girl wishes to swim across a river to a point directly opposite as shown. She can swim at 2 m/s
in still water and the river is flowing at 1 m/s. The angle θ (in radian) with respect to the line joining

the starting and finishing points at which she should swim is given by . Fill the value of N.
5) Airplanes A and B are flying with constant velocity in the same vertical plane at angles 30° and
60° with respect to the horizontal respectively as shown in figure. The speed of A is . At
time t = 0s, an observer in A finds B at a distance of 500m. This observer sees B moving with a
constant velocity perpendicular to the line of motion of A. If at t = t0, A just escapes being hit by B, t

in seconds is :-

PART-2 : CHEMISTRY

SECTION-I

1) Statement-I : Solubility of n-alcohols in water decreases with increase in molecular weight.

Statement-II : The relative proportion of the hydrocarbon part in alcohols increases with increasing
molecular weight, which permits enhanced hydrogen bond with water.

(A) Statement-I is True, Statement-II is True

(B) Statement-I is False, Statement-II is False
(C) Statement-I is True, Statement-II is False.
(D) Statement-I is False, Statement-II is True.

2) Aziridines of structure 1 have not been isolated, yet isomeric aziridines of structure 2 are rather

common. This is because

(A) Structure 2 has less steric strain
(B) Structure 1 is too sterically crowded
(C) Structure 1 is anti-aromatic
(D) Structure 2 is aromatic.

3) Out of the given compounds, which compound has second highest pKb value

(p) (q) (r) (s)

(A) p
(B) q
(C) r
(D) s

4) In each option, a pair of compounds is given. Select the option in which both the compounds of
the pair have different number of stereoisomers :

(A)

(B)

(C)

(D)

5)
Given compound has IUPAC name

(A) 3–Chloro–4–oxopentanal
(B) 4–Formyl–3–chlorobutan–2–one
(C) 3–Chloropentane–1,4–dione
(D) 3–Chloro–5–oxopentan–2–one
6) Tautomer of which of the following compound cannot show stereoisomerism?

(A) CH3–CH2–CHO
(B) CH3–CH2–CO–CH2–CH3

(C)

(D)

7) Which of the following compounds is not soluble in aq. NaOH solution ?

(A) p-toluidine
(B) Crotonic acid
(C) o-cresol
(D) Quinol

8) Which of the following species has integral bond order, gerade type Homo and paramagnetic
nature.

(A) N2
+
(B) O2
(C) C2
2–
(D) N2

9) Consider reactions given for B2H6

Which of the following statement is incorrect?

(A) X contains two 3c–2e– bond and four 2c – 2e– bonds.

(B) Y contains maximum ten atoms in a plane.
(C) Z Contains 2pπ – 2pπ bond
(D) X, Y and Z, all have same number of 2c-2e– bonds per molecule.

10) For the following which option represent CORRECT order

(A) Atomic size : Tℓ > In > Ga > Aℓ > B
(B) Ionization Enthalpy : B > Tℓ > Ga > Aℓ > In
(C) Lewis acidic character : BF3 > BCl3 > BBr3 > BI3
(D) Acidic nature : B2O3 > Al2O3 > Ga2O3 > In2O3

(A) Only B
(B) Both B and C
(C) A,C and D
(D) Both B and D

11) Which of the following order is INCORRECT?

(A) Thermal stability : BeSO4 < MgSO4 < CaSO4 < SrSO4 < BaSO4
(B) Basic Nature : BeO < MgO < CaO < SrO < BaO
(C) Melting point : NaCl < MgCl2 < AlCl3
(D) Melting point : NaF < MgF2 < AlF3

12) Which of the following changes about B when B2H6 is reacted with excess NH3 at room
temperature.
(a) < BHB bond angle
(b) Total valence electrons around B.
(c) Lewis acidic Nature
(d) Hybridisation of B

(A) a, b only
(B) b and c only
(C) a,b,d only
(D) a,b,c only

13) Assertion : For Cl+ & Cl pair net enthalpy change remains zero, when one electron is added in
to first one and removed from other one respectively.
Reason : Magnitude of enthalpy change remains same for any reverse process.

(A) If both assertion and reason are true and the reason is a correct explanation of assertion.
(B) If both assertion and reason are true but reason is not a correct explanation of assertion.
(C) If assertion is true but the reason is false.
(D) If assertion is false but the reason is true.

14) n → orbit no; z → at no; rn,z → radius of orbit; Vn,z → speed of electron; Tn,z → Time period of
revolution of electron; Kn,z → kinetic energy of the electron

Column-I Column-II
(single electron species) (ratio)

(A) r2, 1 : r1, 2 (P) 9:1

(B) V1, 3 : V3, 1 (Q) 8 : 1

(C) T1, 2 : T2, 1 (R) 16 : 1

(D) K1, 2 : K2, 1 (S) 1 : 32

(A) A-P, B-R, C-P, D-S
(B) A-Q, B-P, C-S, D-R
(C) A-S, B-Q, C-R, D-P
(D) A-Q, B-S, C-P, D-R

15) An amount of 1 mole each of A and D is introduced in 1L container, simultaneously the following
two equilibria are established:
A ⇌ B + C; KC = 106 M
B + D ⇌ A; KC = 10–6 M–1
The equilibrium concentration of A will be :

(A) 10–6M
(B) 10–3M
(C) 10–12M
(D) 10–4M

16) 0.2 mole of each A2(g) and B2(g) are introduced into a sealed flask and heated to 2000K. When the
following equilibrium is established. A2(g) + B2(g) 2AB(g). At equilibrium moles of AB is 0.3. At this
stage 0.1 mol of 'C2(g)' is added and the following equilibrium also established. A2(g) + C2(g) 2AC(g).
At the equilibrium moles of AB becomes 0.24. The equilibrium constant for the second reaction is :

(A) 24
(B) 18
(C) 16
(D) 12

17) Select the correct statement about Li2O structure.

(A) Lithium ion is surrounded by 8 fluoride ions.

(B) Closest distance between Li+ – Li+ ion is 0.5a. (where a = edge length)
(C) Li+ ions forming cubic closed packing.
(D) Li+ ions occupy all octahedral voids.

18) Metal X crystallizes in primitive (simple) cubice lattice. The radius of largest atom that can fit
into the voids of metal X lattice without disturbing it is 146.4 pm. The edge length of unit cell is :

(A) 200 pm
(B) 400 pm
(C) 707.2 pm
(D) 292.8 pm

19) A crystalline solid is made of X, Y and Z elements. Atoms of element X form FCC packing; atoms
of element Y occupy octahedral voids while atoms of element Z occupy tetrahedral voids. What will
be the simplest formula of solid if atoms along one axis along the body diagonal are removed

(A)
(B)
(C)
(D)
20) A compound AB2 crystallizes in CaF2 lattice = 'x' pm, = 'y' pm, where and
–
respectively are ionic radii. Maximum & minimum distances between two B ions in an unit cell are

(A)

(B)

(C)

(D)

SECTION-II

1) How many compounds are chiral ?

(a) (b)

(c) (d)

(e) (f)

(g) (h) (i)

2) Consider the following given species :

CO2 , NO2 , CH4 , , , ClO3 , NO

Number of planar species among given = x
Number of species which can dimerize easily = y
The value of (x × y) is....

3) How many of the following species is/are paramagnetic

O22– O2+ O2 N2 B2
CO NO monomer of N2O4,
CuSO4.5H2O monomer of Al2Cl6,

4) A gas of identical H-like atom has some atoms in the lowest (ground) energy level A and few
atoms in a particular upper (excited) energy level B and there are no atoms in any other energy
level. The atoms of the gas make transition to a higher energy level by absorbing monochromatic
light of photon energy 2.55 eV. Subsequently, the atoms emit radiation of only six different photons
energies. Some of the emitted photons have energy 2.55 eV. Some have more and some have less
than 2.55 eV. How many statements is/are correct ?
(i) The principal quantum number of initially excited level B = 2.
(ii) The ionisation energy for the gas atoms is 13.6 eV.
(iii) The maximum and the minimum energies of the emitted photons will be 12.75 eV and 0.66 eV
respectively.
(iv) If all emitted photons have energy ≥ 2.55 eV, then in this case principal quantum number of
initially excited level B = 3.

5) 2.00 g of a cube shaped ideal crystal of solid AB (M = 60) which has NaCl type lattice contain x ×
1021 unit cells. Find value of x. (Given : Molar mass of AB = 60 g mol–1, NA = 6 × 1023)

PART-3 : MATHEMATICS

SECTION-I

1) Find number of shortest path from A to B on given grid.

(A) 924
(B) 462
(C) 154
(D) 132

2) Number of ways to distribute 2 Identical Red ball, 2 Identical blue ball and 1 green to 5 boys
seating around a table if no two consecutive boys get same colour ball

(A) 10
(B) 20
(C) 30
(D) 15

3)

Let L1 : a1x + b1y + c1 = 0, L2 : a2x + b2y + c2 = 0 and L3 : a3x + b3y + c3 = 0.

Assertion (A) : If L1, L2 and L3 are three concurrent lines, then

Reason (R) : If , then the lines L1, L2 and L3 must be concurrent.

(A) Both A and R are correct and R is the correct explanation of A

(B) Both A and R are correct but R is NOT the correct explanation of A
(C) A is correct but R is not correct
(D) A is not correct but R is correct

4) Let S = {1,2,3,....,6}. Let |A| = 3 and |B| = 2. Then number of ordered

pair (A,B) = ? [|X| = Represent number of element in set X]

(A) 90
(B) 180
(C) 100
(D) 140

5) If β is one of the angles between the normals to the ellipse, x2+3y2 = 9 at the points (3

cosθ, sinθ) and ; then is equal to

(A)

(B)

(C)

(D)

6) If the tangents drawn to the hyperbola 4y2=x2+1 intersect the co-ordinate axes at the distinct
points A and B, then the locus of the mid point of AB is :

(A) 4x2 – y2 – 16x2y2 = 0

(B) 4x2 – y2 + 16x2y2 = 0
(C) x2– 4y2 + 16x2y2 = 0
(D) x2– 4y2– 16x2y2 = 0
7) If λ ∈ R is such that the sum of the cubes of the roots of the equation, x2+(2–λ)x+(10–λ) = 0 is
minimum, then the magnitude of the difference of the roots of this equation is :

(A)
(B) 20
(C)
(D)

8) If n is the degree of the polynomial, and m is

the coefficient of xn in it, then the ordered pair (n,m) is equal to:

(A) (24, (10)8)

(B) (12, (20)4)
(C) (12, 8(10)4)
(D) (8, 5(10)4)

9) Consider a three-digit number p = x1x2x3 such that x1, x2, x3 are single digits (x1, x2, x3 ∈ N). Match
the following :

List-I List-II

(A) Numbers of possible value of p, if x1 < x2 < x3 (I) 36

(B) Numbers of possible value of p, if x1 = x2 > x3 (II) 189

(C) Numbers of possible value of p, if x1 . x2 . x3 = 480 (III) 45

(D) Number of positive integral solution of x1 + x2 + x3 = 10 (IV) 120

(A) (A) – IV, (B) – III, (C) – II, (D) – I
(B) (A) – III, (B) – IV, (C) – I, (D) – II
(C) (A) – II, (B) – I, (C) – III, (D) – IV
(D) (A) – I, (B) – II, (C) – IV, (D) – III

10) Let,

and Bn = 1–An. Then, the least odd natural number p, so that Bn > An, for all n ≥ p, is :

(A) 11
(B) 9
(C) 5
(D) 7

11) If the system of linear equations :

x + ay + z = 3
x + 2y + 2z = 6
x + 5y + 3z = b
has no solution, then :-

(A) a = –1, b = 9
(B) a ≠ –1, b = 9
(C) a = 1, b ≠ 9
(D) a = –1, b ≠ 9

12) The number of four letter words that can be formed using the letters of the word BARRACK is :-

(A) 270
(B) 120
(C) 264
(D) 144

13) If a circle C, whose radius is 3, touches externally the circle, x2 + y2 + 2x – 4y – 4 = 0 at the

point (2,2), then the length of the intercept cut by this circle C, on the x-axis is equal to :

(A)
(B)
(C)
(D)

14) Let p, q and r be real numbers (p ≠ q, r ≠ 0), such that the roots of the equation

are equal in magnitude but opposite in sign, then the sum of squares of these roots
is equal to :

(A) p2 + q2
(B) 2(p2+q2)
(C) p2 + q2 + r2

(D)

15) Consider the following two statements :-

Statement I : The value of sin120° can be derived by taking
θ = 240° in the equation

Statement II : The angles A, B, C and D of any quadrilateral ABCD satisfy the equation

(A) Both Statement-I and Statement-II are true

(B) Both Statement-I and Statement-II are false
(C) Statement-I is false but Statement-II is true
(D) Statement-I is true but Statement-II is false
16) The number of numbers between 2,000 and 5,000 that can be formed with the digits 0,1,2,3,4
(repetition of digits is not allowed) and are multiple of 3 is :-

(A) 36
(B) 48
(C) 24
(D) 30

17) The number of ordered pairs (r, k) for which 6·35Cr = (k2 – 3)·36Cr + 1, where k is an integer, is :

(A) 3
(B) 2
(C) 4
(D) 6

18) Total number of 6-digit numbers in which only and all the five digits 1, 3, 5, 7 and 9 appear, is:

(A)

(B) 56

(C)

(D) 6!

19) The sum of the series 2.20C0 + 5.20C1 + 8.20C2 + 11.20C3 + ... +62.20C20 is equal to :

(A) 224
(B) 225
(C) 226
(D) 223

20) All possible numbers are formed using the digits 1, 1, 2, 2, 2, 2, 3, 4, 4 taken all at a time. The
number of such numbers in which the odd digits occupy even places is :

(A) 175
(B) 162
(C) 160
(D) 180

SECTION-II

1) For a positive integer n, is expanded in increasing powers of x. If three consecutive

coefficients in this expansion are in the ratio, 2 : 5 : 12, then n is equal to________.
2) The number of integral values of k for which the line, 3x + 4y = k intersects the circle, x2 + y2 – 2x
– 4y + 4 = 0 at two distinct points is ______.

3) A circle passes through the points (2,3) and (4,5). If its centre lies on the line, y–4x+3 = 0, then its
radius is equal to

4) A line parallel to the straight line 2x – y = 0 is tangent to the hyperbola at the point
(x1, y1). Then is equal to :

5) If the letters of the word 'Mother' be permuted and all the words so formed (with or without
meaning) be listed as in a dictionary, then the position of the word 'MOTHER' is ______.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C D A C D C D B A A D C D C A C D A C

SECTION-II

Q. 21 22 23 24 25
A. 6 40 5 6 5

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C C A D A C A D D D C D A B A B B B A D

SECTION-II

Q. 46 47 48 49 50
A. 7 16 6 4 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D A C B B D D B A D D A D A C D C A B D

SECTION-II

Q. 71 72 73 74 75
A. 118 9 2 6 309
 SOLUTIONS

PART-1 : PHYSICS

1)

(i)

(ii)

T = ma = –

ω2 =

(iii)
–4kx = ma

a=– ,

2)
Rubber ribbon can exert only tension not compression so at a time only one is effective.

T = 2π

3)

Correct Answer is (D).

4)
–cx2 – ca2 + 2cx2 = 0
cx2 = ca2
x = ±a
x = +a is stable equilibrium position

at displacement & from equilibrium

5)

Correct answer is (C).

6) Total energy (initially) = kA2, Time period

when mass is at A/2

U = P.E. = KA2 & KA2

&
Final speed of two masses after the collision is given by the conservation of momentum to be

Thus the final K.v is

The total machenical energy afterwords is

E' = U + k'

Now the amplitude be A'

after collision

= T
7)

Correct Answer is (C).

8)

Correct answer is (D).

9)

For path AB Vx = 5 ms–1

For path BC velocity of rain ⊥r to BC should be zero hence

Vx sin30° = Vy cos30°

10)

tan θ = ⇒ sinθ =

d = (1 km) sin θ = km
11)
1 sin 45° = sin r1
r2 – r1 = θ
θ = 45° – 30°
⇒ θ = 15°

12) i = , e= ,A=

= =μ

⇒ sinr1 = and sinr2 =

Since r1 + r2 = A =

⇒ r1 = – r2

⇒ sinr1 = cosr2 – sinr2

= sinr1 + sinr2 = cosr2

= =

= =

= =1
2
μ =5
⇒ μ=

13) Let the length of rod be ‘a’. The magnitude of transverse magnification of ends A and B is 2
each. The image of B is virtual and that of A is real. Applying mirror formula to B and A
 .... (1)

.... (2)
Solving we get a = L.

14) For no ray to emerge out of side PR, we use

A>2θC

⇒ sin

⇒ sin
⇒ sin A > 120°

15) Let y-axis be vertically upwards and x-axis be horizontal.

Vy (app.) =

Vx (app.) = Vx (real)

tan f = =
16)
Here, PQ is the length of reflected light from the mirror. From the similar triangles, PMA and
MXS'

⇒ =
Then , PA = 3 (XS') = 3H
From the similar triangles QNA and XNS'

⇒ QA = H
⇒ PQ = PA – QA = 3H – H = 2H

17)
r + θC = 90°
μ1sinθ = μ2sinr
18) For (I) :

For (II) :

For (III) :

For (IV) :

19) Magnification produced by mirror where x is distance from focus.

20) Laws of reflection are valid for all surfaces.

So statement (II) is false.

21)
if ℓ > ℓ0
K1 = 0.009 N/m

T1 =
if ℓ < ℓ0

k2 = 0.016 N/m `T2 = π

Total time period T = T1 + T2

T=

T=
n=

22) Maximum acceleration =

23)
12 = 4t + 5t2 (in vertical direction)
t = 1.2 s

a = 5 m/s2

24) To reach opposite bank with zero drift.

vBrsinθ = vR
2sinθ = 1

sinθ =

θ=

25) A projectile moves along a straight line when seen from another projectile. so
500 = ___(i)
A just escapes from being hit by B so at any time to they are at same height.
(sy)A = (sy)B
100 t0

VB = 100 m/s
 =
=
from eqn (i)

500 =

0
t =
t0 = 5 sec

PART-2 : CHEMISTRY

26) With the increase in molecular weight, the hydrophobic part of alcohol increases.

27)

Structure 1 is anti-aromatic

28) Correct basic strength order is s > r > p > q

29)

(A) 2, 2 (B) 2, 2 (C) 2, 2 (D) 4, 2

30)

3–Chloro–4–oxopentanal

31) In (C), trans form does not exist.

32) Compounds more acidic than H2O are soluble in aq. NaOH solution.

33)

The correct answer is option (D)

34)
Maximum number of atoms in one plane = 6
maximum ten atoms in a plane

All 12 atoms are present in same plane

35)

The correct answer is option (D)

36)

Melting point : NaCl > MgCl2 > AlCl3

37) The correct answer is option (D)

38) The correct answer is option (A)

39) Correct answer is option (B)

40) A ⇌ B + C KC = 106
1–x x x
0 1M 1M

B + D ⇌ A KC = 10–6
1–x 1–x x

1 1 ⇒ x = 10–6

41) A2 + B2 2AB
0.2 0.2 0
0.2–x 0.2–x 2x
2x = 0.3 → x = 0.15

A2 + B2 2AB
0.05 0.05 0.3
0.05–x+y 0.05+y 0.3–2y
Given 0.3 – 2y = 0.24
kC = 36 So, x = 0.02
A2 + C2 2AC
0.05 0.1 0
0.05–x+y 0.1–x 2x

42) Co. No. of Li+ = 4

O2– form CCP
Li+ occupy all tetrahedral void.

43) For cubic void = 0.732 ; R =

r = 0.732 , 146.4 = 0.732 × , a = 400 pm

44) Number of atoms of X (at packing site, i.e., at corners and face-centres)

Number of atoms of
Number of atoms of
Along one body diagonal there will be two X atoms, one Y atom and two Z atoms are found and
are removed.

Number of atoms of X will be

Number of atoms of Y will be
Number of atoms of Z will be

∴ Simplest formula will be

45)
∵ A+2 occupy corners and face centres;
B– All tetrahedral voids
Max. distance between TVs
(two B– )=

=
= 2(X+Y)
Min distance (two B–)

= =

46)

(c), (d), (e), (f), (g), (h) (i)

47)

x = 4 (CO2 , NO2 , , NO)

y = 4 (NO2 , CH3 , CF3 , ClO3)

48)

The correct answer is 6

49) Since we obtain 6 emission lines, it means electron comes from 4th orbit energy emitted is
equal to, less than and more than 2.55 eV. So it can be like this :
E4 – E2 = 2.55 eV, E4 – E3 < 2.55 eV,
E4 – E1 > 2.55 eV
(i) n = 2,
(E4 – E2)atom = (E4 – E2)H × Z2
2.55 = 2.55 × Z2
Z=1
(ii) IP = 13.6 Z2=13.6 × (1)2 = 13.6 eV
(iii) Maximum energy emitted = E4 – E1
= (E4 – E1)H × Z2
= 12.75 × (1)2
= 12.75 eV
Minimum energy emitted = E4 – E3
=(E4 – E3)H × Z2
= 0.66 × (1)2 = 0.66 eV

50) AB = mole = × 6 × 1023 molecules = × 1023 molecules.

Number of unit cell =

× 1021 = 5 × 1021
 x=5

PART-3 : MATHEMATICS

51)
where n = 6

52) 5C1 × 2 = 10

53)

Assertion is a standard result

while Reason is not always true it is also true when they are parallel or coincide.

54) 6C1. 5C3. 3C2 = 180

for common element

55) ⇒ Slope of normal =

Slope of normal at

Slope of normal at

taking '–' sign

56)

Let midpoint is (h,k) then

A(2h,0) and B(0, 2k) so
equation of tangent is

Now condition of Tangency

c2 = – a2m2 + b2

(2K)2 = –

4k2h2 = – k2 +

which is required locus

57)

x2 + (2 – λ)x + (10 – λ) = 0
α3 + β3 = (λ – 2)3 – 3(10 – λ)(λ – 2)
= (λ – 2) [λ2 – λ – 26]
= λ3 – λ2 – 26λ – 2λ2 + 2λ + 52
= λ3 – 3λ2 – 24λ + 52
3λ2 – 6λ – 24
3(λ2 – 2λ – 8) = 0

λ=4
x2 + 2x + 6 = 0

|x1 – x2| =

58)

After rationalising and expansion, we have

2[8C0 (5x3 + 1)4 + 8C2(5x3 + 1)3 (+5x3 – 1) + ....+ 8C8(5x3 – 1)4]
No doubt, that the maximum power available is 12 and the coefficient of x12 is
2[8C054 + 8C254 +... + 8C854]
= 2 × 54 × 7 = 44 × 54 = (20)4

59) (A) x1 < x2 = x3 ⇒ 9C2

x1 < x2 < x3 ⇒ 9C3
⇒ 9C2 + 9C3 = 84 + 36 = 120
(B) x1= x2 = x3 ⇒ 9C1
⇒ x1 = x2 = x3 ⇒ 9C2
⇒ 9C2 + 9C1 = 45
(C) Given, x1 . x2.x3 = 25.3.5
Distribution of 25 in x1,x2,x3 is done by 3 ways.
Distribution of 23.2.2 in x1,x2,x3 is done by 3 ways.
Distribution of 22.22.2 in x1,x2,x3 is done by 3 ways.
 Distribution of 24.2 in x1,x2,x3 is done by 6 ways.
Distribution of 23.22 in x1,x2,x3 is done by 6 ways.
Therefore, total number of ways of distribution of 2 is 21.
Distribution of 3 in x1,x2,x3 is done by 3 ways.
Distribution of 5 in x1,x2,x3 is done by 3 ways.
Hence, total possible number = 21.3.3 = 189
(D) x1 + x2 + x3 = 10, 1 ≤ xi ≤ 9
= 9C2 = 36

60)

61) D = 0 and D2 ≠ 0

a = –1, b ≠ 9

62)

BARRACK
B, AA, RR, C, K
C-1, xyzw : 5C4.4! = 20

C-2, xxyy : 2C2. =6

C-3 xxyz : = 144

63)

let the centre of the circle C be point R

L = 0 is the indirect common tangent
x2 + y2 + 2x – 4y – 4 = 0
P(–1, 2) and

Q is the midpoint of PR
R ≡ (5,2)
Equation of circle C : (x – 5)2 + (y – 2)2 = 32
x2 + y2 – 10 – 4y + 20 = 0
Intercept on x-axis.

64)

x2 + (p + q)x + pq = 2rx + (p + q)r

x2 + (p + q – 2r)x + pq – (p + q)r = 0

Sum = 0 = p + q – 2r ⇒

p = –α2 = pq – (p + q)r = pq –

Sum of the square of the root

= 2α2 = (p2 + q2)

65)

Statement P :

at θ = 240º :
which makes RHS negative
∴ Statement p is false.
Statement q : A + B + C + D = 360º
Also

∴ Statement q is true.

66)

Four digits that can be used

(i) 4,3,2,0 (ii) 1,2,3,0
Case I {4,3,2,0}

3 × 3! = 18 = No. of ways
Case II {1,2,3,0}

2 × 3! = 12 = No. of ways
Total = 30

67)
k2 – 3 > 0 ⇒ k2 > 3

k2 – 3 =
Possible values of r for integral values of k, are
r = 5, 35
number of ordered pairs are 4
(5, 2), (5, –2), (35, 3), (35, –3)

68) Total number of 6-digit numbers in which only and all the five digits 1, 3, 5, 7 and 9 is

69) 2.20C0 + 5.20C1 + 8.20C2 + 11.20C3 + ... +62.20C20

= 60.219 + 2.220 = 225

70)

Number of such numbers =

71) nCr–1 : nCr : nCr+1 = 2:5:12

Now
⇒ 7r = 2n + 2 …(1)

⇒ 17r = 5n – 12 …(2)
On solving (1) & (2)
⇒ n = 118

72) Circle x2 + y2 – 2x – 4y + 4 = 0
⇒ (x – 1)2 + (y – 2)2 = 1
Centre : (1, 2) radius = 1
line 3x + 4y – k = 0 intersects the circle at two distinct points.
⇒ distance of centre from the line < radius

⇒
⇒ |11 – k| < 5
⇒ 6 < k < 16
⇒ k ∈ {7, 8, 9, ...... 15} since k ∈ I
Number of K is

73)

y – 4x + 3 = 0
let centre be (4α – 3, α)

r=
⇒α=2
⇒r=2

74) Slope of tangent is 2, Tangent of hyperbola at the point (x1, y1) is

(T = 0)

Slope : …(1)
(x1, y1) lies on hyperbola

⇒ …(2)
From (1) & (2)

⇒
Now x12 + 5y12 = (4y1)2 + 5y12

= (21)y12 = 21 ×

75) MOTHER
1→E
2→H
3→M
4→O
5→R
6→T
So position of word MOTHER in dictionary
2 × 5! + 2 × 4! + 3 × 3! + 2! + 1
= 240 + 48 + 18 + 2 + 1
= 309