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Solution

The document contains a series of physics and chemistry problems, including questions about electric charges, lenses, and molecular structures. It also features mathematical problems involving functions, expansions, and geometric properties. The content is structured into sections with multiple-choice questions and calculations across different scientific disciplines.
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0% found this document useful (0 votes)
10 views26 pages

Solution

The document contains a series of physics and chemistry problems, including questions about electric charges, lenses, and molecular structures. It also features mathematical problems involving functions, expansions, and geometric properties. The content is structured into sections with multiple-choice questions and calculations across different scientific disciplines.
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

25-01-2026

1001CJA106216260034 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Two point charges Q1 and Q2 of equal magnitude are placed at a certain distance from each other.
Assuming the field strength to be positive in the positive direction of x–axis

The signs of the charges Q1 and Q2 for given graphs are

(A) +,+ ; +,– ; –,+ ; –,–


(B) +,– ; +,+ ; –,+ ; –,–
(C) –,+ ; +,– ; +,+ ; –,–
(D) +,+ ; +,– ; –,– ; –,+

2) A thin convex lens made from crown glass has focal length f. When it is measured in two

different liquids having refractive indices It has the focal lengths f1 and f2, respectively.
The correct relation between the focal lengths is

(A) f1 = f2 < f
(B) f1 > f and f2 becomes negative
(C) f2 > f and f1 becomes negative
(D) f1 and f2 both becomes negative

3) A block of mass m is connected to a spring (spring constant k). Initially the block is at rest and the
spring is in its natural length. Now the system is released in gravitational field and a variable force F
is applied on the upper end of the spring such that the downward acceleration of the block is given
as a = g – αt, where t is time elapses and α is positive constant the velocity of the point of application
of the force is :

(A)

(B)

(C)

(D)

4) A parallel beam of monochromatic light is incident on face AD of the box ABCD, which contains a
thin plano convex and a thin plano concave lens of refractive indices μ1 and μ2 respectively. The
lenses are coaxial and are submerged in a liquid of refractive index μ0 as shown in the figure. The
lenses have equal radius of curvature of their curved surfaces. The box is kept in air co-axially with a
thin convex lens of focal length 20 cm. The final point image of the beam after passing through the

0
box and the lens is formed 20 cm beyond the convex lens on the axis itself. If μ1 = μ + and μ2 =

μ0 + where b and c are positive constants and λ is wavelength of light in air. Find the value of λ
for which the above observation is possible.

(A)

(B)

(C)

(D)

SECTION-I (ii)
1) Two charged small balls each of charge 'q' and mass 'm' when suspended from a common point
by strings of length 'l' in air, then these strings form an angle of 120° with each other. When the
system is immersed in a liquid of dielectric constant 'k' (ratio of density of liquid and ball's material

) then the angle between the strings remain same. Mark the correct statement(s) :

(A) The dielectric constant of the liquid is 3/2.


The electrostatic force exerted by the liquid on one of the balls is
(B)

The electrostatic force exerted by the liquid on one of the balls is


(C)

The total system is placed in a gravitational free space then angle between the strings will be
(D)
180°.

2) In a certain arrangement a fine pencil of laser light is made to fall on one of the equal faces AB
(AB = BC) of an isosceles prism. The prism is resting on a horizontal surface on its triangular base.

The laser beam makes angle θ = 15° with face AC in the horizontal
plane. There are three prisms which will be kept in the above arrangement one by one. Prism-1 has a
prism angle A = 60° and the refractive index of material is . Prism-2 has A = 30° and its
material has refractive index of n2 and Prism-3 has A = 90° and is made up of material of refractive
index n3. The emergent rays in the case of each prism is parallel to each other.

(A) For prism-1 the emergent ray is deviated by 30°.

(B)
For prism-2, .

(C)
For prism-3, .
(D) For all the three prisms the beam is parallel to face AC inside the prism.

3) An arrangement of the masses and pulleys is shown in the figure. Strings connecting masses A
and B with pulleys are horizontal and all pulleys and strings are light. Friction coefficient between
the surface and the block B is 0.2 and between blocks A and B is 0.7. The system is released from

rest. (use g = 10 m/s2)

The magnitude of acceleration of the system is 2 m/s2 and there is no slipping between block A
(A)
and block B.
(B) The magnitude of friction force between block A and block B is 42 N.
(C) Acceleration of block C is 1 m/s2 downwards.
(D) Tension in the string connecting block B and block D is 12 N.

SECTION-II (i)

Common Content for Question No. 1 to 2


A plane mirror is inclined at an angle 30° with the horizontal surface. A particle is projected from
ground (at t = 0) with velocity V = 20 m/s at an angle 60° with the horizontal. The image of particle
is observed. (The particle does not collide with the mirror). Then... (Use g = 10 m/s2)

1) The time when image is at rest with respect to particle is . Find n.

2) Find the time at which particle and its image in the mirror are moving orthogonally.

Common Content for Question No. 3 to 4


Shown below a system in which one mole of helium gas is filled in a vessel with a fixed piston made
up of glass having refractive index 4/3 (constant). The gas is supplied with heat at a constant rate of

1000 J/s. The refractive index of He varies with temperature as . [Initially the gas is at
room temperature of 300 K]

3) If the gas is replaced by CO2, magnitude of velocity of black spot as observed by an observer
outside the vessel when T = 400 K is

4)

The magnitude of the velocity of the point black spot as seen by an observer outside the vessel when
T = 400K is

SECTION-II (ii)

1) A charged particle is in equilibrium at a height h = 1m from a horizontal infinite line charge with
uniform linear charge density. The charge lies in the vertical plane containing the line charge. If the
particle is displaced slightly in vertical direction, find the time period of SHM in second. (π = )

2) An infinitely long wire with linear charge density λ1 and a segment of length ℓ with charge density
λ1 lie in a plane at right angle to each other and separated by a distance r0 as shown in figure. The

0
force with which these two interact is . If = 2r , then find the value of x :

3) The electric field intensity at the centre of a uniformly charged hemispherical shell is 50 N/C.
Now two portions of the hemisphere are cut from either side and remaining portion is shown in

figure. If α = β = , then electric field intensity (in N/C) at centre due to remaining portion is :
4) A converging lens (focal length f) is broken in two equal pieces and placed at 60 cm as shown
along with the object. It is found that real images are formed at the same place and ratio of image

heights is 9:1. If the value of f is cm then value of x is

5) Find the acceleration (in m/s2) of the block of mass M = 5 kg in the situation of figure. The
coefficient of friction between the two blocks is µ = 0.5 and the ground is frictionless.(m = 2kg)

6) All the strings, springs and pulleys shown in figure are ideal. Initially the system is in equilibrium
and blocks are at rest. Now, the upper spring is cut. The acceleration of block 1 just after cutting the

upper spring is found (y) × (g) m/s2. Find y?

PART-2 : CHEMISTRY
SECTION-I (i)

1) The most stable enol form of the compound

(A)

(B)

(C)

(D)

2) Which option has both the species are paramagnetic and each has two unpaired electrons.


(A) O2 and C2
(B) NO and N2
(C) O2 and B2
(D) and

3) Which of the following is/are correct

(A) Due to back bonding in H3BO3, there is no change in any bond angle

(B) In ClO2, NO2 & CHF2, Odd e present in hybrid orbital
(C) Due to back bonding in H3SiNCS & N(GeH3)3 hybridisation of Nitrogen is not changed.
(D) THF, R2O, CO, Py, all doing homolytic cleavage of B2H6

4) In a defective crystal of Fe which shows bcc arrangements, some of the unit cells have following
arrangement. Apart from these there are no other defects. Identify the option which is correct :

(A) Effective number of atoms in the complete crystal structure will be 1 instead of 2.
(B) Density of defective crystal will lie in between half the original density to original density
(C) The crystal will now have structure similar to simple cubic
(D) Co-ordination number of all atoms will become 6.

SECTION-I (ii)

1) Which of the given option(s) is/are correct regarding

(A) I and II are conformational diastereomers


(B) I and II are configurational diastereomers
(C) I shows optical isomerism but II does not

(D)

and compound I are conformations

2) Which of the following is/are correct statement(s).

(A) Increasing covalent character : NaCl < MgCl2 < AlCl3


(B) Water solubility : LiOH < NaOH < KOH < RbOH < CsOH
(C) Increasing polarizability : F– < Cl– < Br– < I–
(D) Decreasing ionic nature : MCl3 > MCl2 > MCl

3) Choose incorrect statement(s) is/are :

(A) In presence of non-stoichiometric defects, ionic crystals lost their electrical neutrality.
e– holes or e– vacancy move towards positively charged plate, under influence of electric field in
(B)
p-type semiconductor.
(C) a = b ≠ c represents both tetragonal & trigonal crystal system.
(D) HCP and CCP both have 74% packing efficiency.

SECTION-II (i)

Common Content for Question No. 1 to 2


Molecular orbital theory is based on linear combination of atomic orbitals (LCAO). According to
LCAO when respective atomic orbitals of the atoms interact, they undergoes constructive and
destructive interference giving two types of molecular orbital i.e. bonding and antibonding
molecular orbitals respectively.

1)
Number of the following overlapping result ungerade molecular orbital.

(1) (2)

(3) (4)

(5) (6)

2) Find the value of the of (a + b) for the following species.


C22–, B2, F2, O2+, O22–, N2 , He2+
Where a = Number of species which are paramagnetic
b = Number of species which having B.O > 2.5

Common Content for Question No. 3 to 4


0.20 moles of CO taken in a 2.463 litre flask is maintained at 750K along with a catalyst so that the
following reaction can take place: CO(g) + 2H2(g) ⇌ CH3OH(g). Hydrogen is introduced until the
total pressure of the system is 7.5 atm at equilibrium and 0.1 mole of methanol is formed.
(R = 0.0821 L-atm/K-mol).

3) For the reaction, KP (in atm–2), is :

4) For the reaction, KC (in M–2), is [Given: (2.463)2 = 6.07]


SECTION-II (ii)

1)
What is the mass of gas (A) evolved (in gm)

2)
for the given compound, calculate the value of (x + y), where
x = total resolvable stereoisomers
y = total π electrons in resonance

3)
For the given compound, calculate the value of (x+y+z), where
x = sum of locants of substituents (According to IUPAC rule)
y = total stereoisomers
z = total stereoisomers having C2 axis of symmetry

4) Identify correct number of statements


(i) Most soluble IIA fluoride is BeF2
(ii) The Be atom in BeCl2(s) is sp3 hybridised.
(iii) Order of bond angle Cl2O > F2O
(iv) Oxidizing strength of Tℓ3+ > In3+
(v) BF3, CH4, PCl5, SF6, IF7, XeF4 all are Non–polar
(vi) p-nitrophenol has less boiling point as compared to o–nitrophenol

5) A mixture weighing 4.06 g of BaO and unknown carbonate XCO3 was heated strongly. The residue
weighed 3.62 g. This was dissolved in 100 mL of 1 M HCl. The excess acid required 16 mL of 2.5 M
NaOH solution for complete neutralization. If atomic weight of metal is 'x' then X/10 = ?
[Use : Ba = 137]

6) 24 gm pure sample of magnesium is burned in air to form magnesium oxide and magnesium
nitride. When products are treated with excess of H2O, 3.4 gm of gaseous NH3 is generated
according to give reactions.
Mg + O2 —→ MgO
Mg + N2 —→ Mg3N3
Mg3N2 + 6H2O —→ 3Mg(OH)2 + 2NH3
Calculate the mass % of Mg converted into Mg3N2.

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let f(x) = ex + e–x + a has exactly 2 distinct real roots, then

(A) a > 0
(B) a < 0
(C) a < –2
(D) a ∈ ϕ

2) The term independent of x in the expansion of is equal to -

(A) 98
(B) 99
(C) 100
(D) 101

3) If the 9th term in the expansion of is equal to 495, then the value of x may be -

(A) 1
(B) 3
(C) a proper fraction
(D) an irrational number

4) If the equation of sides of a triangle are x = 3, y = 5 and x + y = 15, then identify the Incorrect
option :
(A) orthocentre is (3, 5)

(B)
circumcentre is
centroid is
(C)

(D) incentre is (5, 6)

SECTION-I (ii)

1) Which of the following is (are) positive -

(A) log725
(B) log3(log39)

(C)

(D)

2) Let and , then which of the following


is/are true -

(A) (f + g) (1) = 9
(B) (f – g) (3.5) =1
(C) (f g) (0) = 24

(D)

3) For the circle x2 + y2 – 2x – 10y – 1 = 0 which of the following is/are true :-

(A) x intercept of the circle is

(B)
y intercept of the circle is
(C) line x + y = 6 is diameter of the circle

(D)
area of equilateral triangle inscribed in the circle is

SECTION-II (i)

Common Content for Question No. 1 to 2


Consider the name of a baby girl 'HARSHITA'. New names are formed (with or without meaning) by
using all the letters of the given word.

1) Number of words in which vowels occupy even places -


2) Number of words which contains the word 'AAI' is-

Common Content for Question No. 3 to 4


Let (1 – x + x2)30 = a0 + a1x + a2x2 + a3x3 + ......... + a60x60.

3)

4)

SECTION-II (ii)

1) Let f be a function satisfying the functional equation , then the

value of is [Note : [.] denotes greatest integer function]

2) The number of integral values of k for which the domain of f(x) = is all real
number

3) Let ƒ : → , be a function such that x = m is the solution of ƒ(x) +


–1
2ƒ (x) + 2 = ƒ(ƒ(x)), then 'm' is equal to

4) Let ƒ(x) be an even function satisfying ƒ(x) + ƒ(x + 2) = ƒ(x + 1) ∀ x ∈ R, where ƒ(–13) = 4, then
ƒ(–5) + ƒ(1) is equal to

5) Let two circles are passing through a fixed point (x1, y1) where x1 > 0, y1 > 0 and both circle touch

coordinate axes. If sum of their radii is equal to product of their radii, then is
equal to

6) The vertex A of ΔABC is (3, –2) and the equations to two of its medians are 5x + 3y = 11 and 4x +
3y = 8. If the equation of side BC is ax + by = 7, then (a + b) is equal to
ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B B A B

SECTION-I (ii)

Q. 5 6 7
A. A,B,D A,B,C,D A,D

SECTION-II (i)

Q. 8 9 10 11
A. 1.50 2.00 0.72 1.20

SECTION-II (ii)

Q. 12 13 14 15 16 17
A. 2 9 25 2 2 2

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. D C D B

SECTION-I (ii)

Q. 22 23 24
A. B,D A,B,C A,B,C

SECTION-II (i)

Q. 25 26 27 28
A. 3.00 5.00 0.16 or 0.17 607.00

SECTION-II (ii)

Q. 29 30 31 32 33 34
A. 92 24 14 5 4 30

PART-3 : MATHEMATICS
SECTION-I (i)

Q. 35 36 37 38
A. C D C D

SECTION-I (ii)

Q. 39 40 41
A. A,B,C,D A,B,C A,B,C,D

SECTION-II (i)

Q. 42 43 44 45
A. 720.00 360.00 1.00 2.00

SECTION-II (ii)

Q. 46 47 48 49 50 51
A. 5 4 2 8 2 5
SOLUTIONS

PART-1 : PHYSICS

1)

Correct answer is (B)

2)

Correct answer is (B)

3)
Let the elongation of the spring be x.
From the N.L.M. of the block
mg – kx = m(g – t)
kx = mt
or k(I – l0) = mt
Differentiating w.r.t. time

k(V + V') = m

v=

4) The rays are getting focused at 20 cm right of the lens. Hence rays incident on the lens are
parallel to its principal axis. If the rays are getting focussed 20 cm from the lens,

∴ the rays are not deviated by


combination of lenses in the box or the equivalent focal length of the combination of lenses
inside the box is ∞.

Now,

5)

Correct answer is (A,B,D)

6)

From geometry
For prism-1
i = 15° + 30° = 45°
By snell's Law at 1st surface
Sin45° = sin r1,
r1 = 30° → r2 = 30°
So, e = 45°
δ = i + e – A = 30°
As incident ray is same and emergent rays are parallel this suggests that for each prism
condition for minimum deviation is satisfied.
for prism-2

i = 15° + 15° = 30° and r = = 15°

So
for prism-3

i = 15° + 45° = 60° and

So

7) Suppose blocks A and B move together. Applying NLM on C, A + B, and D


60 – T = 6a
T – 18 – T' = 9a
T' – 10 = 1a
Solving a = 2 m/s2
To check slipping between A and B, we have to find friction force in this case. If it is less than
limiting static friction, then there will be no slipping between A and B.
Applying NLM on A.
T – f = 6.2
as T = 48 N
f = 36 N
and fs = 42 N hence A and B move together.
and T' = 12 N.

8)
Particle's velocity is parallel to mirror
vx = 20 cos 60° = 10

tan 30° = =

⇒ vy = = (20 sin 60) – 10t

⇒ = –10t

∴t= =

9)
From the moment calculated in Q-13, particle's velocity vector should rotate clockwise by 45°.
⇒ δ = 30° + 45°
= 75° from t = 0

tan 15° = =
vy = 10(2 – )
Now,
–10(2 – ) = 10 – 10t
⇒t= +2– =2
10) nCVdT =dQ; Happ = ; H = 1m;

11)

Correct answer is (1.20)

12)

dF =

T=

13)

Correct answer is (9)

14)

Correct answer is (25)

15)

y = 3x ......(i)
y – x = 60 ........(ii)

f= .....(iii)
Solving (i), (ii), (iii)
f = 22.5 cm
Ans. 2

16)
17) (when system is in equilibrium)
when spring is cut tension in spring is same eixsting will change.
Let new tension in string is T"

2mg + mg – T" = ma
mg + T" = ma
4mg = 2 ma
a = 2g

PART-2 : CHEMISTRY

18)

1,2-Dicarbonyl exists in enol form to minimize π-π repulsion.

19)

O2 and B2 both have two unpaired electrons.

20) The correct answer is option (D)

21) Density of ideal crystal =

Density of defective crystal =


So density of overall crystal will be in between half of original density and original density.

22)

Both show OI. Compound I has absolute configuration (S,S) and compound II has (R, S)
23)

Class notes.

24)

Correct answer is option (A,B,C)

25) 1,3 & 5 formed ungerade number

26) a = 3 , b = 2

27)

CO(g) + 2H2(g) ⇌ CH3OH(g)


t=0 5 atm – 0
eq. 2.5 atm 2.5 atm 2.5 atm

KP =
KP = 0.16

28)

CO(g) + 2H2(g) ⇌ CH3OH(g)


t=0 5 atm – 0
eq. 2.5 atm 2.5 atm 2.5 atm

KP =
KP = 0.16

KC = = 607

29)

2 mole C14O2

30)

x=8
y = 16
31)
x=9
y=3
z=2

32) Intermolecular hydrogen bonding causes increase in boiling point.


so that correct statements are (i) , (ii), (iii), (iv) and (v)

33)

XCO3 → XO + CO2
2HCl + XO → XCl2 + H2O
2HCl + BaO → BaCl2 + H2O
Let's say
p mol BaO and q mol 'XCO3'

∴ (p + q) × 2 =
p + q = 3 × 10–2 ......(1)
153p + (60 + x)q = 4.06 . .....(2)
153p + 16 + x)q = 3.62 ......(3)
44q = 0.44
q = 10–2
p = 2 × 10–2
⇒ x = 40

34) Mg3N2 + 6H2O —→ 3Mg(OH)2 + 2NH3


0.2 mole

% Mg = × 100 = 30%

PART-3 : MATHEMATICS

35)
f(x) = ex + e–x + a
f′(x) = ex – e–x = 0
⇒ x = 0 is a point of minima
∴ f(0) < 0
⇒a+2<0
⇒ a < –2

0
36) Coeff of x in

∴ Coeff of x5 in (x2 + 1)5 (x + 1)5


= Coeff of x5 in (1 + 5x2 + 10x4) (1 + 5x + 10x2 + 10x3 + 5x4 + x5) = 1 + 50 + 50 = 101

37) T9 = 12C4

⇒ = 495
⇒ log2x = ±2

38)

39) If base and number both are greater than one, then value of log is always positive.

40) (A)
⇒ (f + g)(1) = 9

(B)
⇒ (f – g)(3.5) = 1

(C)
⇒ (f – g)(0) = 24

(D)

41) (A)
(B)
(C) Centre (1, 5) lies on the circle

(D)

42) Given word 'HARSHITA'


consonants (H,H), R,S,T vowels → (A,A),I

Number of ways

43) Given word 'HARSHITA'


consonants (H,H), R,S,T vowels → (A,A),I

Number of ways

44) (1 – x + x2)30
= a0 + a1x + a2x2 +.........+ a60x60 ......(1)
x → –x
(1 + x + x2)30 = a0 – a1x + a2x2 + .... + a60x60

(1 + x + x2)30
= a0x60 – a1x59 + ....... + a60 ......(2)
Multiply (1) and (2)
(1 + x2 + x4)30
= a0 + a1x2 + a2x4 + ..... + a60x120 .....(3)

= coff. of x60 in (1 + x2 + x4)30 = a30

45) (1 – x + x2)30
= a0 + a1x + a2x2 +.........+ a60x60 ......(1)
x → –x
(1 + x + x2)30 = a0 – a1x + a2x2 + .... + a60x60
(1 + x + x2)30
= a0x60 – a1x59 + ....... + a60 ......(2)
Multiply (1) and (2)
(1 + x2 + x4)30
= a0 + a1x2 + a2x4 + ..... + a60x120 .....(3)
Put x = 1 & –1 (1) add
2(a0 + a2 + .....) = 1 + 330

46) Put x = 3 and x = 7 in given equation


to get ƒ(3) = 11 & ƒ(7) = –1
2ƒ(3) + 4ƒ(7) = 18
ƒ(7) + 2ƒ(3) = 21

47) x2 + kx + k ≥ 0 ∀ x ∈ R
D ≤ 0 ⇒ k ∈ [0, 4] .....(1)
Also, x2 + k ≠ 0 ∀ x ∈ R
(1) ∩ (2)
k ∈ (0, 4]

48) ƒ–1(x) = ⇒ ƒ(x) = ƒ–1(x)


⇒ ƒ(ƒ(x)) = x
⇒ ƒ(x) + 2ƒ–1(x) + 2 = ƒ(ƒ(x)) reduces to


⇒ 2(x – 2)(2 – x) = 0 ⇒ x=2

49) ƒ(x) + ƒ(x + 2) = ƒ(x + 1) ......(i)


⇒ ƒ(x + 1) + ƒ(x + 3) = ƒ(x + 2) ......(ii)
adding (i) & (ii) we get
ƒ(x) + ƒ(x + 3) = 0
⇒ ƒ(x) = –ƒ(x + 3)
x→x+3
⇒ ƒ(x + 3) = –ƒ(x + 6)
⇒ –ƒ(x) = –ƒ(x + 6)
⇒ ƒ(x) = ƒ(x + 6)
⇒ Period of ƒ(x) is 6
Now ƒ(–5) = ƒ(5) = ƒ(5 – 18) = ƒ(–13) = 4 & ƒ(1) = ƒ(–1) = ƒ(–1 – 12) = ƒ(–13) = 4
⇒ ƒ(–5) + ƒ(1) = 8
50) Circle (x – r)2 + (y – r)2 = r2
(x1, y1) lies on it (x1 – r)2 + (y1 – r)2 = r2
r2 – 2r(x1 + y1) +

51)
Point F lies on median CF


and point E lies on median BE

∴ B = (1, 2) and C = (5, –4)


∴ equation of BC is 3x + 2y = 7

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