25-01-2026

1001CJA106216260033 JA

PART-1 : PHYSICS

SECTION-I (i)

1) If electric field is defined due to point charge as at a point P at position vector from
charge q then, electric field strength due to uniformly charged ring will be :

(A) Zero at centre only.

(B) Zero at every point on axis of ring.
(C) Zero at every point enclosed by ring, in the plane of ring.
(D) Zero at every point in space.

2) A point object is placed in front of a thin convex lens. A plane mirror is also kept at a distance

from convex lens. A medium of refractive index of is filled between lens and the plane

mirror. The radii of curvature of the lens is 30 cm and 10 cm and its refractive index is ‘x’ is
the distance of point object from the surface whose curvature is 10 cm. The value of 'x' so that image

coincides with the object is :

(A) 5 cm

(B)

(C)

(D)

3) A ray is incident on the first prism at an angle of incidence 53º as shown in the figure. The angle
between side CA and B'A' for the net deviation by both the prisms to be double of the deviation
produced by the first prism, will be

(A) 2 sin–1 2/3

(B) sin–1 2/3
(C) cos–1 2/3
(D) sin–1 1/3

4) Two smooth cylindrical bars weighing W each lie next to each other in contact. A similar third bar
is placed over the two bars as shown in figure. Neglecting friction, the minimum horizontal force on

each lower bar necessary to keep them together is-

(A)

(B) W

(C)

(D)

SECTION-I (ii)

1) A particle executes SHM along a straight line with mean position at x = 0, period 20 sec and
amplitude 5 cm. The time taken by the particle to go from x = 4 cm to x = – 3 cm can be

(A) 10 sec
(B) 15 sec
(C) 5 sec
(D) 25 sec

2) A particle of mass m is moving in a field where the potential energy is given by U(x) = U0(1 – cos
ax), where U0 and a are constants and x is the displacement from mean position. Then (for small
oscillations)

(A)
The time period is .
(B) The speed of particle is maximum at x = 0.
(C)
The amplitude of oscillations is .

(D)
The time period is

3) A bead of mass m is constrained to move along a rough rod in vertical plane. The rod can move in
horizontal or vertical direction without changing its orientation as shown in the figure :-

If rod moves up with acceleration a0, minimum coefficient of friction for bead to remain static
(A)
with respect to rod is cotθ

(B) If rod moves vertically down with minimum coefficient of friction for bead to remain
static with respect to rod is cotθ
If rod moves horizontally towards right with acceleration g cotθ, minimum coefficient of
(C) friction
for bead to remain static with respect to rod is zero
If rod moves horizontally towards left with acceleration g cotθ, minimum coefficient of friction
(D)
for bead to remain static with respect to rod is zero

SECTION-I (iii)

1) A prism of refracting angle A is made of material of refractive index 2. Assume rays are incident 'i'
at angle of incidence such that t 0 ≤ i ≤ 90°.

List–I List–II

(P) A = 15° (1) All rays are reflected back from second surface.

All rays are refracted into air from second

(Q) A = 45° (2)
surface.

Some rays are reflected back from second

(R) A = 70° (3)
surface.

Some rays are refracted into air from second

(S) A = 50° (4)
surface

No total internal reflection takes place at the

(5)
second surface.
(A) P → 2,5;Q → 3,4;R → 1;S → 3,4
(B) P → 3,4;Q → 2,5;R → 1,3,4;S → 1
(C) P → 3,4,5;Q → 3,4;R → 2,5;S → 2,3
(D) P → 2,5;Q → 1;R → 3,4;S → 2,5
2) Match the following : (Assume only electrostatic interaction forces) :

List-I List-II

The system may be in

Three charges are kept
(P) (1) equilibrium with proper choice
along a straight line
of the value of charges.

Three charges are kept at The system will be in

(Q) the vertices of (2) equilibrium for any value of the
an equilateral triangle charges.

Three charges are kept at

the three vertices of a
The system will not be in
square, and a fourth charge
(R) (3) equilibrium for any choice of
is kept at the point of
the value of charges.
intersection of the
diagonals.

Three charges are kept at

the vertices of
(S) an equilateral triangle with (4) The equilibrium is unstable.
the fourth charge at the
centroid.

(5) None of these

(A) P → 1, 4 ;Q → 3;R → 3;S → 1, 4
(B) P → 1, 4;Q → 3;R → 3;S → 1, 3
(C) P → 1, 3;Q → 2;R → 3;S → 1, 4
(D) P → 1, 3;Q → 3;R → 2;S → 1, 4

3) Three blocks of masses m1, m2 and M are arranged as shown in figure. All the surface are
frictionless and string is inextensible. A constant horizontal force of magnitude F is applied on block
of mass m1 as shown. Pulleys and string are light. Part of the string connecting both pulleys is
vertical and part of the strings connecting pulleys with masses m1 and m2 are horizontal.

List-I List-II

(P) Acceleration of mass m1 (1)

(Q) Acceleration of mass m2 (2)

(R) Acceleration of mass M (3) zero

 (S) Tension in the string (4)

(5) None of these

(A) P → 2;Q → 2;R → 3;S → 4
(B) P → 4;Q → 2;R → 1;S → 3
(C) P → 1;Q → 2;R → 4;S → 3
(D) P → 3;Q → 4;R → 1;S → 2

4) A bird in air is diving vertically over a tank with speed 5 cm s–1. Base of tank is silvered. A fish in
the tank is rising upward along the same line with speed 2 cm s–1. The water level is falling at rate of

2 cm s–1. (Take : μ = 4/3 )

List-I List-II

(P) Speed of the fish as seen by the bird directly (1) 8

Speed of the image of fish formed after reflection in the mirror as seen by the
(Q) (2) 6
bird

(R) Speed of bird relative to the fish looking upwards. (3) 3

(S) Speed of image of bird relative to the fish looking downwards in the mirror (4) 4

(5) 5
(A) P → 1;Q → 2;R → 4;S → 3
(B) P → 2;Q → 1;R → 4;S → 3
(C) P → 2;Q → 1;R → 3;S → 4
(D) P → 2;Q → 3;R → 1;S → 4

SECTION-II

1) There is a small air bubble inside a glass sphere (µ = 1.5) of radius 5 cm. The bubble is at 'O'

at 7.5 cm below the surface of the glass. The sphere is placed inside water (µ = ) such that the top
surface of glass is 10 cm below the surface of water. The bubble is viewed normally from air. The
apparent depth (in cm) of the bubble is x/2, find x

2) Consider a transparent semi cylinder of refractive index 2. Light is incident at grazing angle of
incidence on the plane face. This light comes out of only a part of curved surface. This part has area

. R is radius of cylinder and ℓ is it's length. Find x.

3) In the figure medium below horizontal interface has large extent. A point source of light revolves
along a verticle circle with constant speed. Centre of the circle lies on interface. If amount of light
which finally travel through medium in one complete revolution of source be 13n% of total emitted

light then find value of n.

4) Two thin rods of length 2L each, carry equal charges Q uniformly distributed along their lengths.
The rods are kept aligned along the same line, such that their nearer ends have a separation x. Then,

the force of electrostatic repulsion between them is given by . Find n

5) Four identical symmetrically located ideal inextensible strings (PA, PB, PC and PD) support a rod
PQ of mass m in vertical position as shown in the figure. The angle between two consecutive strings
is equal to 60°. Determine the normal force on the rod PQ given by the ground, assuming that the
tension in each string is mg/ Newton (ABCD is a square on the ground). If your answer is xmg,
then write x as the answer.

6) Two blocks A and B of masses mA = 2kg and mB = 4kg are kept on the table as shown in figure.
The coefficient of friction between A and B is 0.2 and between B and the surface of the table is also
0.2. The maximum force F that can be applied on B horizontally, so that the block A does not slide

over the block B is (Take g = 10 m/s)

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which of the following compounds has the lowest potential energy?

(A)

(B)

(C)
(D)

2) What is the correct order of acidic/basic strength :

(A)

(Acidic strength order)

(B)

(Acidic strength order)

(C)

(Basic strength order)

(D)

(Basic strength order)

3) Select INCORRECT option.

(A) Solubility of BeC2O4 is greater than BaC2O4.

(B) Dimer of AℓBr3 & AℓI3 are possible as well as melting point of AℓI3 is greater than AℓBr3.
(C) PbO2 has greater oxidizing and basic nature than SnO2.

(D) Both & having atleast one pπ-dπ type of bonding in same excitation state of
Chlorine atom

4) Which is the INCORRECT match for the energy distance function for following interaction ?

(A) Debye force : r(6⊝)

(B) Ion-induced dipole interaction : r(2⊝)
(C) London force : r(6⊝)
(D) Keesom force : r(3⊝)

SECTION-I (ii)

1) Two compounds are given below :

Which symmetry elements are present in both X and Y.

(A) POS
(B) COS
(C) C2 axis of symmetry
(D) C3 axis of symmetry

2)

In nucleophilic substitution reaction, if solvent itself act as a nucleophile, then the reaction is known
as solvolysis.
Then select CORRECT statement(s) regarding solvolysis.

Hydrolysis process of XeF2, XeF4 and XeF6 share a common product 'P', which has highest
(A)
boiling & melting point among similar kind of molecules of same group of periodic table.
Hydrolysis of Caro's acid and Marshall's acid follow same mechanism and give same non-planar
(B)
final products & one of the product has greater boiling point than pure solvent.
(C) XeF2 and XeF4 gives redox hydrolysis.
Hydrolysed product(s) of one mole of Mg3N2 , required 5 mole of HCl for complete
(D)
neutralization

3) Which of the following statement(s) is/are correct ?

(A) Eight Cs+ ions occupy the second nearest neighbour locations of a Cs+ ion in CsCl crystal.
(B) Each sphere is surrounded by six voids in two dimensional hexagonal close packed layers.
If the radius of cation and the anion are 0.3 Å and 0.4 Å respectively, then coordination number
(C)
of the cation of crystal is 6.
In AgCl, the silver ion is displaced from its lattice positions to an interstitial positions, such a
(D)
defect is called Frankel defect.

SECTION-I (iii)

1) Match the list:

List- II
List- I
Salt formed on reacting one molecule of
Oxy acid
oxyacid with two molecule of NaOH

(P) H4P2O7 (1) Sodium pyrosulphate

 (Q) H2SO4 (2) Sodium peroxodisulphate

(R) H3PO3 (3) Sodium sulphate

(S) H2S2O7 (4) Sodium phosphite

(5) Sodium dihydrogen pyrophosphate

The CORRECT option is

(A) P → 5;Q → 3;R → 4;S → 2
(B) P → 5;Q → 3;R → 4;S → 1
(C) P → 5;Q → 1;R → 4;S → 2
(D) P → 5;Q → 2;R → 4;S → 1

2) Match the list:

List-I List-II
(Compounds) (Undergo hydrolysis)

Hybridisation of underlined atom in

(P) POCl3 (1)
transition state is sp3

2 moles of H2O are used for complete

(Q) BF3 (2)
hydrolysis.

Basicity of one of the hydrolysed product in

(R) ClF3 (3)
water is 3

Undergo partial hydrolysis in presence of

(S) NCl3 (4)
excess of water

(5) On hydrolysis produce both acid and base

The correct option is
(A) P → 1;Q → 3;R → 4;S → 5
(B) P → 1;Q → 4;R → 5;S → 2
(C) P → 5;Q → 3;R → 2;S → 2
(D) P → 3;Q → 1;R → 2;S → 5

3) Given : Molar mass of Cl = 35.5 g/mol, P = 31 g/mol, I = 127 g/mol.

List-I List-II
(Reactions) (Value of KP in atmΔng)

PCl5(g) ⇌ PCl3(g) + Cl2(g)

(P) Mavg. = 166.8 gm/mol at 3 atm (1)
equilibrium pressure

N2O4(g) ⇌ 2NO2(g)
(Q) Mavg. = 57.5 gm/mol at 2/3 atm (2)
equilibrium pressure
 2HI(g) ⇌ H2(g) + I2(g)
On starting with HI(g) only,
(R) (3)
equilibrium mixture has 40% (by
mole) HI

N2(g) + 3H2(g) ⇌ 2NH3(g)

On starting with NH3(g) only,
(S) equilibrium mixture has 33.33% (by (4)
mole) NH3 at equilibrium pressure
= 4 atm.

(5) 3
(A) P → 1;Q → 5;R → 3;S → 4
(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 4;Q → 3;R → 2;S → 1
(D) P → 4;Q → 3;R → 2;S → 5

4) Salt and water is formed by acid-base neutralisation reaction. Assume no dissociation of water in
following reactions and assume volume of final solution = 1 litre.
(Atomic mass of Cs = 133, I = 127, Rb = 85.5, Sr = 88)

List-I List-II

CsOH + HI → CsI + H2O Molarity of H+ in resulting

(P) (1)
0.2 mol 0.4 mol solution = 0.2 M.

RbOH + HNO3 → RbNO3 + H2O Molarity of cation in

(Q) (2)
0.4 mol 0.1 mol resulting solution = 0.4 M.

Sr(OH)2 + H2SO4 → SrSO4(aq) + 2H2O Molarity of OH– in resulting

(R) (3)
0.4 mol 0.4 mol solution = 1.2 M.

Ba(OH)2 + 2HBr → BaBr2 + 2H2O Molarity of anion in

(S) (4)
1.6 mol 3.2 mol resulting solution = 0.4 M.

Molarity of cation in
(5)
resulting solution = 1.6 M.
Choose the correct combination :
(A) P → 1,3,4;Q → 2,5;R → 2,4;S → 5
(B) P → 1,2,4;Q → 2,4;R → 2,4;S → 5
(C) P → 1,2,4;Q → 2,4;R → 1,4;S → 3,5
(D) P → 3,4;Q → 1,3,5;R → 2,4;S → 2,5

SECTION-II

1)
For the given compound, calculate the value of (x+y+z), where
x = locant of –OH (according to IUPAC rules)
y = total asymmetric atoms
z = total stereoisomers

2)
The positive charge of carbocation can be delocalized over how many oxygen atoms in the
resonating structures ?

3) Consider the following species :

O3 , BaO2 , K2MnO4 , NO2 , O2 , S2 (Vapour) , Fe-atom , B2
Number of species having value of µ < 2 (Here µ = spin only magnetic moment in B.M.)

4) 2SO3(g) ⇌ 2SO2(s) + O2(g)

For the above reaction at equilibrium, partial pressures of SO2, O2 and SO3 are 2 atm, 3 atm and 6
atm respectively. Some moles of O2 has been added by doubling the volume of reaction vessel such
that partial pressure of O2 remains constant at new equilibrium. Then calculate the partial pressure
of SO3(g) at new equilibrium (in atm).

5) A sample of camphor used in a method for determining of molar mass had melting point of 450 K.
The melting point of a solution containing 0.5 gm camphor and 0.04 gm of an unknown non-volatile
non-electrolyte compound was 430 K. The molar mass of camphor is 152 and its ΔHfusion = 1.52 Kcal
mol–1. The molar mass of unknown compound in gm/mole is .........
(R = 2 cal mol–1 K–1).

6) The boiling point of benzene is 353.23 K. When 1.80 g of a non-volatile solute was dissolved in 90
g of benzene, the boiling point is raised to 354.11K. Calculate the molar mass (g/mol) of the solute.
Kb for benzene is 2.53 K kg mol–1.

PART-3 : MATHEMATICS

SECTION-I (i)

1) If |ƒ (x) + 6 – x2| = |ƒ (x)| + |4 – x2| + 2 then ƒ (x) is necessarily non-negative in -

(A)
(B) (–∞, –2) ∪ (2, ∞)
(C) [–2, 2]
(D) none of these
2) Consider a square OACB with side length a, where O is origin and sides OA and OB are along
positive x & positive y axis respectively. A circle having radius r (where r < a), touches sides OA, OB
and passes through C, then -

(A) r2 – 3ar + a2 = 0
(B) r2 – 4ar + 2a2 = 0
(C) r2 + 3ar – a2 = 0

(D)
2r2 – ar +

3) If x is an odd integer and y, z are even integers, satisfying x + y + z = 47 and x, y, z ≥ 0, then

number of solutions are

(A) 100
(B) 200
(C) 300
(D) 400

4) Tangent are drawn from the origin "O" to the circle x2 + y2 – 8x – 6y + 16 = 0 touches it at the
points A and B respectively, then choose the incorrect option/s :-

Length of chord of contact AB is

(A)

(B)
If ∠AOB = α, then sinα is
(C) Radius of circle circumscribing ΔOAB is 5
(D) Length of tangent from O to the circle is 4

SECTION-I (ii)

1) If , then x can be-

(A) [–4,–3]
(B) [–3,–2]
(C) [–2,2]
(D) [3,4]

2) Let , where , then identify the correct

statement(s) -

(A) g(x) is an odd function

(B) g(x) is an even function
(C) g(x) is neither even nor odd
(D) g(x) is a bounded function

3) Consider a function ƒ(x) = , then choose correct option(s) regarding function ƒ

(A) many one

(B) odd function
(C) bounded function
(D) range contain exactly three integers

SECTION-I (iii)

1) Match the following List-I and List-II

List-I List-II

If set of all possible values of k for which every solution of

the inequation x2 – (3k – 1) x + 2k2 – 3k – 2 ≥ 0 is also a
(P) (1) 3
solution of the inequation x2 – 1 ≥ 0 is [ℓ, m], then ℓ + m is
equal to

If a , b, c and d are four positive real numbers such that

(Q) abcd = 1 and minimum value of (1 + a) (1 + b) (1 + c) (1 + (2) 1
d) is 16λ, then λ + 2 is equal to

If complete solution set of the inequality

(R) (3) 4
x+2
5 is (ℓ, ∞), then ℓ is equal to

Let . Then the value of

(S) (4) 2
is equal to then
value of λ is

(5) 0
(A) P → 2;Q → 1;R → 5;S → 4
(B) P → 2;Q → 3;R → 1;S → 5
(C) P → 5;Q → 4;R → 2;S → 3
(D) P → 4;Q → 2;R → 3;S → 1

2) Match the following List-I with List-II

List-I List-II

Four dice (six faced) are rolled, The

(P) number of possible outcomes in which (1) 210
at least one dice shows 2 is
 Let A be the set of 4 - digit number
(Q) a1 a2 a3 a4 where a1 > a2 > a3 > a4 Then (2) 750
n(A) is equal to

The total number of three - digit

(R) numbers, the sum of whose digits is (3) 671
even, is equal to

The number of four-digit number

without repetition that can be formed
(S) (4) 450
from the digits 0,1,2,3,4,5,6,7 so that
each number contains digit 1 is

(5) 510
(A) P → 4;Q → 2;R → 1;S → 3
(B) P → 3;Q → 1;R → 4;S → 2
(C) P → 1;Q → 3;R → 2;S → 4
(D) P → 3;Q → 4;R → 1;S → 5

3) Match the following:

List–I List–II

(P) The solution of 1 + secx = cot2 Is given by x = Kπ , (1) 2

then K is/are

If α,β are roots of equation A (x2 +m2) + Amx + Cm2x2

(Q) (2) 3
= 0 then A(α2 + β2) + Aαβ + Cα2β2 + 3 is /are equal to

The sum of binomial co – efficient in expansion of

(R) , (where m is positive integer) lies (3) 4

between 200 and 400 & the term independent of x
equal to 448, then n5 divisible by

If last digit of the number 2999 is α and last digit of

(S) (4) 8
35α is µ, then µ + α

(5) 9
(A) P → 1,3;Q → 3;R → 2,5;S → 4
(B) P → 2,5;Q → 2;R → 1,3,4;S → 5
(C) P → 3;Q → 1,3;R → 5;S → 2
(D) P → 1,4;Q → 3,4;R → 5;S → 1,3

4) Consider the family of lines ax + by + c = 0 where 4a2 + 9b2 – c2 + 12ab = 0. Let 'p' denote
distance of R(6,8) from the line ax + by + c = 0
Match the following Lists where List-I contains values of p and List-II contains different number of
lines possible.

List-I List-II

(P) (1) 1
 (Q) (2) 2

(R) (3) 3

(S) (4) 4

(5) 5
(A) P → 5;Q → 4;R → 1;S → 3
(B) P → 4;Q → 2;R → 5;S → 4
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 3;Q → 5;R → 1;S → 3

SECTION-II

1) A circle C1 lying completely in first quadrant is such that it touches the lines x = 1, y = 1 and the
circle x2 + y2 =1 externally, and the radius of C1 is r then is :

2) If a, b, c are distinct positive real numbers different from 1 such that

(logba . logca – logaa) + (logab . logcb – logbb) + (logac . logbc – logcc ) = 0, then abc is equal to :-

3) Let sum of binomial coefficient in the expansion of (x + 2y)n is 1024 (n ∈ N), then number of
divisors of (120)(n) divisible by 75 is

4) If α, β, γ are the roots of the equation x3 – 5x2 + 3 = 0, then the value of (α – 2)3(β – 2)3(γ – 2)3 is

5) If L.C.M. of (a, b) = 52 × 34, L.C.M. of (b, c) = 53 × 34 & L.C.M. of (c, a) = 53 × 34, then possible
ordered triplets of (a,b,c) are k then (k – 58) is equal to

6) The number of possible straight lines passing through (2, 3) and forming a triangle of area 12 sq.
unit along with the coordinate axes, is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. C B A D

SECTION-I (ii)

Q. 5 6 7
A. B,C,D B,C,D A,B,D

SECTION-I (iii)

Q. 8 9 10 11
A. A A A D

SECTION-II

Q. 12 13 14 15 16 17
A. 27 6 5 2 3 24

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. A D D B

SECTION-I (ii)

Q. 22 23 24
A. A,C B,C B,D

SECTION-I (iii)

Q. 25 26 27 28
A. B D C B

SECTION-II

Q. 29 30 31 32 33 34
A. 9 2 4 3 162 58

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. C B C C

SECTION-I (ii)

Q. 39 40 41
A. A,C,D C,D A,B,C,D

SECTION-I (iii)

Q. 42 43 44 45
A. A B B C

SECTION-II

Q. 46 47 48 49 50 51
A. 3 1 5 729 7 3
 SOLUTIONS

PART-1 : PHYSICS

1)

Given or
At any arbitrary point P, field due to two diametrically opposite elementary charge elements
dE1 ∝ dE2
Net field dE1 – dE2

⇒ (λ = ) = 0
Hence, field at energy point inside ring is zero.

2)

Correct answer is (B)

3) Let be the angle of emergence from the first prism be ‘e’

calculating step by step we get e = sin–1 2/3
Then for net deviation to be double, the incident ray on side A'B' of second prism should make
angles i or e with normal.

Hence the angle between the given then will be 2e or i + e.

4) Correct answer is (D)

5) B to C → 5 sec

A to D → 15 sec
B to B to C → 25 sec

6)

(For small oscillations)

Potential energy is maximum at x =

amplitude is
Speed of particle is maximum at x = 0
( PE is minimum) (b), (c) and (d)

7) For (A) & (B), minimum cofficient of friction require for which bead remain static w.r.t. road
is µ = tan 90 – θ = cot θ
[∵ condition for no relative motion µ ≥ tan (90 – θ)]
when rod moves left with acceleration a0 & for zero friction and no relative motion a0sinθ =
gcosθ

8)

A < θC – All rays transmitted from 2nd surface.

θC < A < 2θC – Some transmitted from 2nd surface.
A > 2θC – No transmitted from 2nd surface.
Here

9)

Correct answer is (A)

10) FBD's
F–T = m1a
F = (m1 + m2) a T = m2a

11)

Correct answer is (D)

12)
For first refraction, (at the glass-water interface)

= ⇒ v = –8 cm
For second refraction : (at air-water interface)

Apparent depth =

= = = cm.
13)
2sinθ = 1sin90°
θ = 30°
If TIR occurs,
2sinϕ = 1sin90°
⇒ ϕ = 30°
α + 90 + 30 + 30 = 180°
α = 30°
and
60° + β + 30° = 180°
β = 90°

So are =

14) for motion in medium

∴ % of light coming out

∴ % of light travel through medium = 40 %

Now for motion of source in vacuum half of emitted light will travel through medium i.e. 25%.
∴ In one complete revolution % of light through medium = 40+25 = 65%

15)

Correct answer is (2)

16)

Correct answer is (3)

17) fA = µmAg = 0.2 × 2 × 10 = 4N

fB = µ(mA + mB)g = 0.2 × 6 × 10 = 12N
For B to slide over table F > fB = 12 N
 One B slides
(Assuming A & B more together)

Now

As (fA)max = 4 we have

PART-2 : CHEMISTRY

18) In option (A) all methyl groups are equatorial, it is most stable and has least PE.

19)

(A) SIR
(B) H-bond
(C) SIP
(D) SIR

20) The correct answer is option (D)

21) Question Explanation: Find which intermolecular force does not match its potential
energy distance dependence (E α r–n).
Concept: Intermolecular Force and Potential Energy Function.

Solution : Ion-induced dipole interaction α

22)

X has POS, C2
Y has POS, C2, C3

23) B.P. → H–F > HI > HBr > HCl

M.P. → HI > HF > HBr > HCl
XeF2 & XeF4 gives hydrolysis product by redox reaction
Mg3N2 + 6H2O → 3Mg(OH)2 + 2NH3

24) (A) Second nearest neighbours of Cs+ are 6 and not 8 (in CsCl crystal).

(B)
There are 6 triangular voids around a sphere in two dimensional hcp layer.
(C) which indicates that cations are present in cubic void of a simple cubic
unit cell, so its coordination number is 8 and not 6.
(D) Definition of Frenkel defect.

25)

The correct answer is option (B)

26)

The correct answer is option (D)

27) (P) PCl5(g) ⇌ PCl3(g) + Cl2(g)

(Q) N2O4(g) ⇌ 2NO2(g)

(R) 2HI(g) ⇌ H2(g) + I2(g)

(S) N2(g) + 3H2(g) ⇌ 2NH3(g)

28) (P) CsOH + HI → CsI + H2O

0.2 mole 0.4 mole – –
0 0.2 mole 0.2 mole
Base is L.R., [H+] = 0.2 M [Cs+] = 0.2 M [I–] = 0.4 M
(Q) RbOH + HNO3 → RbNO3 + H2O
0.4 mole 0.1 mole – –
0.3 mole 0 0.1 mole
Acid is L.R. [OH–] = 0.3 M [Rb+] = 0.4 M [NO3–] = 0.1 M
(R) Sr(OH)2 + H2SO4 → SrSO4 + 2H2O
0.4 mole 0.4 mole – –
– – 0.4 mole
[Sr2+] = [SO42–] = 0.4 M
(S) Ba(OH)2 + 2HBr → BaBr2 + 2H2O
1.6 mole 3.2 mole – –
– – 1.6 mole
[Ba2+] = 1.6 M [Br–] = 3.2 M

29)
x = 2, y = 3, z = 4

30)

–OCH3 (ortho and para only)

31) O3 , BaO2 , K2MnO4 , NO2

32) 2SO3(g) ⇌ 2SO2(s) + O2(g)

KP = atm

KP =

3 + P = 3 – 3P
4P = 0
P=0

33) Kf (of camphor) = = = 40.5

ΔTf = i × Kf × m

450 –430 = 1 × 40.5 ×

Msolute = = 162

34) Question Explanation:

Question is asking about molar mass (g/mol) of the solute.

Concept:
This question is based on elevation of boiling point.

Solution :
ΔTb = Kb.m

ΔTb = 354.11 – 353.23 = 0.88

ΔTb = 0.88 = (2.53) ×

Msolute = 57.5 g/mole

Final answer : 58
PART-3 : MATHEMATICS

35) |ƒ (x) + 6 – x2| = |ƒ (x)| + |4 – x2| + 2

|ƒ (x) + 4 – x2 + 2| = |ƒ (x)| + |4 – x2| + 2
ƒ (x).(4 – x2) . 2 ≥ 0
∵ ƒ (x) ≥ 0
∴ 4 – x2 ≥ 0 ⇒ x2 – 4 ≥ 0
x ∈ [–2, 2]

36)
Equation of circle is (x – r)2 + (y – r)2 = r2
(a – r)2 + (a – r)2 = r2
r2 – 4ar + 2a2 = 0

37) x + y + z = 47
⇒ The problem is similar to put 47 identical things in 3 diff. boxes, Let x' = x – 1
⇒ x' + y + z = 2(23)
⇒ 23+3–1C3–1 = 25C2 = 300

38)
sinα = sin2θ

39) is real if 0 ≤ |x| ≤ 2 or |x| ≥ 3

is real if 0 ≤ | x| ≤ 4
⇒ ƒ(x) is real for 0 ≤ |x| ≤ 2 or 3 ≤ |x| ≤ 4
⇒ x ∈ [–2, 2] ∪ [3, 4] ∪ [–4, –3]
40) =

g(x) =
g(x) = 2
⇒ g(x) is a constant function

41)
See answer from graph

2 2
42) (P) x – (3k – 1)x + 2k – 3k – 2 ≥ 0
⇒ [x – (k – 2)] [x – (2k + 1)] ≥ 0

Hence 2k + 1 ≥ 1 and k – 2 ≤ –1
i.e. k ≥ 0 and k ≤ 1
∴ k ∈ [0, 1]
∴ℓ+m=1
(Q) 1 + a ≥ 2 (AM ≤ GM)
1+b≥2
1+c≥2
1+d≥2
∴ (1 + a) (1 + b) (1 + c) (1 + d) ≥ 16 = 16
∴ Minimum value = 16
(R)

(S)

So,
 Similarly

⇒
⇒λ=2

43) (P) total – No dice shows 2

64 – 54
= 671
(Q) 10C4 = 210
(R) Let N = abc (a ≠ 0)

For any choice for a and b c always has 5 choices

(S) Case - I

Case - II

6 × 6 × 5 × 3 = 540 ways
210 + 540 = 750

44) (P) It sec x = cot2

⇒ cos =0

(Q) α + β =
∴ A(α + β)2 – Aαβ + (α2 β2 + 3)
= 3 (after simplification)
(R) 200 < 2m < 400

Term independent of x

2333 List digit = 8

340 = (81)10 = (80 + 1)10

45) (2a+3b)2 – c2 = 0
2a + 3b + c = 0
↓
Family of lines passing through A(2, 3)
or
2a + 3b – c = 0
Family of lines passing through B(–2, –3)
AP = , & BP =
If P < ⇒ 4 lines (2 lines from both families)
P= ⇒ 3 lines (1 line from 1st family)
(2 lines from 2nd family)
<P< ⇒ 2 lines (2 lines from 2nd family)
P= ⇒ 1 line (from 2nd family)
P> ⇒ 0 line

46) Let radius of C1 be ‘r’ then AB = r,

BC =
⇒ OC = OA + AB + BC
⇒

47)
(loga)3 + (logb)3 + (logc)3 = 3(loga) (logb) (logc)
 ⇒ loga + logb + logc = 0
abc = 1

48) 2n = 1024 ⇒ n = 10
number is 1200 = 24 × 3 × 25
ways are 5

49) (α – 2)3. (β – 2)3. (γ – 2)3

= ((α – 2)(β – 2)(γ – 2))3
∵ α, β, γ are the roots of the equation
x3 – 5x2 + 3 = 0
∴ Equation having roots (α – 2), (β – 2), (γ – 2)
will be : (y + 2)3 – 5(y + 2)2 + 3 = 0
Product of roots of above equation
(α – 2)(β – 2)(γ – 2) = –(8 – 5(4) + 3) = 9
∴ ((α – 2)(β – 2)(γ – 2))3 = 729

50) Let

&

α1 α2 α3

2 0 3

2 1 3

2 2 3

0 2 3

1 2 3
α1,α2,α3 can be selected in 5 ways
where β1,β2,β3 can be selected in
13 ways
∴ Total ways = 5 × 13 = 65

51) The equation of straight line through (2, 3) with slope m is y – 3 = m(x – 2) or mx – y = 2m
–3

or

Here, or OB = 3 – 2m
The area of ΔOAB = 12

or
or (2m – 3)2 = ± 24m
Taking positive sign,
we get 4m2 – 36m + 9 = 0
Here D > 0, This is a quadratic in m which given two value of m, and taking negative sign, we
get (2m + 3)2 = 0.

This gives one line of m as .

Hence, three straight lines are possible.