Soldering and Welding
Soldering and Welding
PRESENTED BY:
GUIDED BY:
Dental appliances in general, and orthodontic appliances in specific needs to be constructed in two
or more parts which are later joined.
Joining of metals and alloys is crucial in determining the efficacy of the appliance and of orthodontic
treatment as a whole.
RIVETING
SOLDERING (BRAZING)
WELDING
Riveting is not used in dentistry. Soldering finds considerable use in the form of brazing, and welding
is generally confined to the technique of spot welding.
TERMINOLOGIES
RIVETING:
Riveting is a semi-permanent and non-thermal joining method that involves using a mechanical
fastener/rivet (a metallic part with a dome-shaped head) to join sheet metal parts. Riveting
involves drilling a hole in the two sheet metal parts you want to join together and installing a rivet.
SOLDERING:
Joining of metals by fusion of filler metal, at a temperature below the solidus temp of the metals
being joined and below 450°C.
BRAZING:
Soldering operations at or above 450°C. Most dental soldering procedures are actually brazing.
Practically, the difference is that soldering is carried out where significant mechanical strength is not
required in the joint.
WELDING:
Process of fusing two or more metal parts through the application of heat, pressure or both, with or
without a filler metal , to produce a localized union across the interface between the parts.
CAST JOINING:
Process of combining two components of a FPD by means of casting molten metal into interlocking
region.
LIQUIDUS TEMPERATURE:
The solidus is the highest temperature at which an alloy is solid – where melting begins.
SOLDERING
INTRODUCTION
HISTORY OF SOLDERING
TECHNIQUES OF SOLDERING
STEPS IN SOLDERING
APPLICATION IN ORTHODONTICS
CONSIDERATION IN ORTHODONTICS
SOLDERING FAILURE
RECENT ADVANCES
A process that join metals by heating them to a suitable temperature below solidus of the substrate
metals and applying a filler metal having a liquidus not exceeding 450ºC that melts and flows by
capillary action between the parts without appreciably affecting the dimensions of the joined
structure.
• Technically correct term of brazing is used if liquidus temperature of filler metal is above
450ºC(850º F).
• In Dentistry, many metals are joined by brazing although the term soldering is commonly
used.
• Soldering is done using a Pb - Sn solder and Brazing uses a Ag-Cu solder to obtain
considerable strength.
HISTORY OF SOLDERING
The soldering technique is known to man for hundreds of years. However, during the industrial
revolution, the need for higher temperatures and user-friendly tools arose. The old methods of
heating metals with coal fires etc. were no longer practical.
Soldering and brazing were used more than 5,000 years ago to make jewelry.
The use of gold bridge work was in use as early as 500 to 700 B.C. by the Romans.
Other cultures like the Egyptians used gold wires to hold the frameworks.
The word solder is derived from the French word ‘soudre’ meaning to consolidate.
It was discovered that when the vapor from heated alcohol was ignited, it burnt with a concentrated
flame of high temperature suitable for different heating purposes.
These heating tools were generally called blow pipes. The first known patent is from France and is
dated January 7, 1791.
• During the early 1900`s, a great variety of blow lamps specially designed for different
purpose and applications came on the market.
• After the 1945 Second World War, the propane gas emerged as a cleaner and safer fuel for
different heating purposes.
The first appliances used had a metal frame work. The attachment of auxiliaries to bring about the
different type of tooth movements required soldering of these parts.
PARENT METAL
Also known as substrate metal, some times also called as base metal is the original pure metal or
alloy that is prepared for joining to other substrate metal or alloy.
The melting range and soldering operations should take place below solidus temperatures of
substrate metal.
1. Oxide formation – Composition of the alloy determines the oxides that form on it’s surface.
The flux used should be able to reduce, remove & inhibit further oxidation.
2. Wettability of the substrate - The solder chosen must wet the metal at as low a contact
angle as possible.
3. Melting range
A low temp soldering is preferred for Stainless steel to prevent carbide precipitation (sensitization)
and to prevent an excessive softening (annealing) of the wire.
FLUX
Purpose of flux is to remove any oxide coating on the substrate metal surface when the filler metal is
fluid and ready to flow into place.
Protection of the alloy surface from oxidation during soldering and dissolve metallic oxides as they
are formed.
While being fused it should not effloresce or move from the surface of the work.
CLASSIFICATION OF FLUX:
Surface protection: Flux covers metal surface and prevents access to oxygen so that no oxide can
form.
Reducing agent: Flux reduces any oxide present and exposes clean metal.
Solvent: Flux dissolves any oxides present and carries them away.
Borax fluxes
Fluoride fluxes
Borax (Na2B4O2)
Composition of most of commercial fluxes is formulated to accomplish two or more of the purposes.
Fluxes for use with noble metals are usually based on boric or borate compounds such as boric acid,
boric anhydride and borax they all are type I (protective fluxes).
There are also reducing fluxes for flow stability oxides such as copper oxide (Type II).
Oxides formed on base metal alloy are more stable. Fluorides are used to dissolve chromium, nickel,
and cobalt oxides. They usually contain borax as glass formers (protective) and fluorides dissolves
any metal oxide with which it comes in contact, acting as a solvent.
BORAX FLUX:
They are based on boric or borate compounds such as boric acid/boric anhydrate and borax.
They act as protective fluxes and reducing fluxes for low stability oxides such as copper oxide.
• Liquid form:
Paste form:
Powder form:
Fluoride flux:
These are used on base metal alloy and are usually combined with borates.
The oxides formed on base metal alloys are more stable and fluorides are used to dissolve chromium
and nickel oxides. So it acts as solvent.
Some fluoride containing flux include toxic fluorides when heated, so inhalation of fumes should be
avoided.
Super flux:
A combination of high melting salts is used as fluxes to create superior flux. A formula for efficient
flux is:
Silica - 10 parts
Borax:
Borax glass produces efflorescence when heated on the work as its water of crystallization is driven
off and as a result a part of surface may be exposed and pit may result.
Boric acid:
Reduces fusion point of the flux so that flows smoothly over flux at a lower temperature.
Silica:
Contributes to viscosity or toughness to film after fusion so that it stays on the work.
Application of flux:
Excess flux remains trapped within filler metal and cause a weakened joint.
Flux combined with metal oxides forms a glass during soldering process that is difficult to remove
completely.
ANTIFLUX
An antiflux is a material that will confine solder to a specified area and prevent its flowing where it is
not required.
Examples:
Simplest method is to draw a line with ordinary lead pencil about 2mm away from the joint and
cover metal beyond this line with a thin graphite film by scrubbing with a pencil.
Graphite burns off on prolonged heating at high temperature, in such cases rouge or whiting (CaCO3
in alcohol) is used.
SOLDER/FILLER METAL
A metal which used to join two pieces of metal is known as filler metal.
Good wettability.
High strength.
Acceptable color.
[Link] temperature:
The temperature at which the filler metal wets and flow on the substrate metal and produces a
bond. It is usually higher than the liquidus temperature.
ISO 9333 requires that the flow temperature of the filler metal should be lower than the solidus
temperature of substrate metal.
A rule of thumb is that flow temperature of filler metal should be 56ºc (100ºf) lower than the solidus
temperature of the substrate metal.
If the flow point of filler metal is close to or above the solidus of either substrate alloying can take
place. An alloy formed through diffusion can have properties different from filler metal and
substrate metal.
2. Fusion temperature:
3. Color:
Color of gold varies from deep yellow to light yellow to white. In practice most dental solder are
able to produce an inconspicuous joint.
[Link] properties:
Classification of solders:
SOFT SOLDERS:
HARD SOLDERS:
1. Gold solders
2. Silver solders
1. GOLD SOLDERS:
Easy flowing.
Composition:
Zinc: 2-4% -> Increases brittleness and decreases melting temperature. Scavenger.
Cadmium: 3-5% -> Replace zinc for clean surface.
Yellow solder- Depending upon gold content, color varies. It is used for soldering gold alloy.
White solder- For soldering chromium cobalt alloy, a color matching white 19 karat gold solder,
contains greater amount of palladium and lesser percentage of gold.
2. SILVER SOLDERS:
Composition:
Silver - 10-80 %
Copper - 15-30%
Zinc - 4-35%
Properties:
Adequate strength.
Used when low fusion temperature is required e.g. stainless steel, base metal alloys.
High silver content solders can be used for joining stainless steel but their fusion temperature is
high.
Elongation of silver solders is 10-15% so that appliance can be adjusted near soldered joint without
fear of being fractured.
TURBINE SOLDER:
A solder containing less silver and which fuses at a lower temperature is called, TURBINE SOLDER.
Composition:
Ag: 45%
Cu: 25%
Zn: 15%
Cd: 15%
SOLDERS IN DENTISTRY:
HEAT SOURCE
1. Flame brazing
2. Oven brazing
3. Infrared soldering
TYPES OF FUEL:
bridge.
Propane – It is the best choice. Have highest heat content(2385ºc) & good flame
temperature(2850ºc).
Butane - has similar flame temperature and heat content. Uniform in quality, virtually water free and
burns clean.
FLAME BRAZING:
Reducing zone
Zone A: Consists of air coming up from the compressed air supply through the jet in the centre of the
blowpipe. It contains unburned gas
Zone B: Combustion area in which mixture of gas and air is ignited, its temperature is greatest at the
tip.
Zone C: It is the part of flame with maximum reducing atmosphere and should be used for all
soldering operations.
Zone D: It is oxidizing atmosphere and alloys being soldered must not be brought into this area of
the flame.
The flame that is used to heat the soldering assembly should be the neutral or slightly reducing part,
because this produces the most efficient burning process and most heat.
Improperly positioned flame can lead to oxidation of the substrate or filler metal and a poorly
soldered joint.
If unburned portion of flame is used carbon may be introduced in to the substrate or filler metal.
To prevent oxide formation the flame should not be removed once it has been applied until
soldering process is complete.
INFRARED SOLDERING:
The unit uses light from a 1000 watt tungsten filament, quartz- iodine bulb which is mounted at the
primary focal point of a gold plated elliptical reflector.
The material to be soldered is placed at the reflector’s secondary focal point at which the reflected
infrared energy of tungsten light source is focused.
• Temperature: prior to placement of the solder, the parent metal is heated till it is hot
enough to melt the filler metal as soon as it touches.
• Time: The flame should be kept in place until the filler metal has flowed completely into the
connection and a moment longer to allow the flux or oxide to separate from the fluid solder.
TECHNIQUES OF SOLDERING
Investment soldering
Autogenous soldering
Jig soldering
Investment soldering
It is carried out whenever the area of contact between the metallic parts being joined is large and
whenever precision is needed in joining the metals.
The parts are placed on the master cast with a gap of at least 1mm. The parts are fastened with
sticky wax before placing soldering investment.
Soldering is carried out with reducing flame at 750- 870°C. the investment is cooled 5 min before
quenching.
The process involves soldering two metallic parts together after adequate stabilization, without the
use of investment, to precisely hold the parts together.
Torches placed on a bench & hands are used to hold the parts in position.
Jig soldering
soldering.
Parts to be soldered, are already bent into shape, cleaned and assembled in position on the model.
Autogenous soldering
Two pieces are heated, until they just begin to melt, at which stage they are approximated and the
heat is removed.
POINT CONTACT
Wrapping the wire
Increased area
STEPS IN SOLDERING
Application of flux
APPLICATION IN ORTHODONTICS
Wire to wire: one wire is turned around the other to form a reliable joint because of the extra bulk
allowed by turning.
Soldering lingual arch or palatal arch: a blob of wet pumice is placed over the middle portion of the
model to hold the arch during soldering. (F.G. Thompson, JCO 1969 April).
Attachment of springs to arch wire. A gold solder is used with a MP < 800°C.
CONSIDERATIONS IN
ORTHODONTICS
Low temperature solder is used to prevent carbide precipitation and to prevent excessive softening
of the wire.
Low fusing silver solders with a soldering temp range of 620-655°C are used.
Fluoride fluxes are used for stainless steel and other base metal alloys.
Free hand soldering technique with a needle like gas air flame is used.
The work should be held at the tip of the blue cone in the reducing zone.
Soldering should be observed against a black background, so that the temp can be judged by the
color of the work.
Flux must cover all the areas to be joined before heat is applied.
As soon as the flux fuses solder is added and heating continued until metal flows.
The work is then removed from the heat and quenched in water.
Hydrogen-Oxygen torch, electric resistance heating & indirect heating with brass wire intermediary
are also used as heat source.
SOLDERING FAILURES
CAUSES:
Improper fluxing
Over heating of the solder can lead to pitted joint of low strength
Porosities and brittleness from oxides, gases, or foreign matter and flux inclusion are a cause.
Gas entrapment can also be generated by gases formed from electrochemical processes.
silver-solder joints.
RECENT ADVANCES
Newer silver solders with improved corrosion resistance is available. Eg: B-Ag 18 & B-Ag 21.
They have slightly higher Cu contents, with 10% tin for wetting SS and about 3% nickel for immunity
to crevice corrosion and cadmium and zinc free.
Some companies also manufacture a prefluxed solder, eliminating the need for a separate step.
REFERENCE:
Kenneth J. Anusavice and Paul Cascone, chapter 19 dental casting and soldering alloys, phillips’
science of dental materials 11th Ed.
Stephen T. Rasmussen, O’Brein and Ryge, An outline of dental materials and their selection, Chapter
26.
C.P. Adams and W. John, S. Kerr, The design construction and use of removable orthodontic
appliances.
Phillip’s, Skinners science of dental materials Chapter 33 Gold alloy solders, Soldering procedures.
WELDING
Introduction
History of welding
Principle of welding
Methods of welding
Improper welding
Clinical application
Welding of TMA
Recent advances
Biocompatibility
Conclusion
INTRODUCTION
HISTORY OF WELDING
Welding in orthodontics became popular after the arrival of spot welders. It became popular
because of the short time required, the ease of welding and the absence of elaborate equipments.
Welding is preferred over soldering if the heating cycle must be very short, in order to prevent any
changes in physical property of components to be joined.
Principle of welding
Correct voltages,
When the current is applied through the two wires, a melting process occurs.
This is not just a surface weld, but an actual merging in which one wire has "set down" about 80%
into the second wire.
Butt weld
(parallel)
Edge weld
(edge angle)
If two plates are placed in contact (a close square butt joint) they can be welded with full
penetration by one run of weld metal deposited by a manual welding process from each side
provided that the plate thickness does not exceed approximately 6 mm.
However, plate above 6 mm thickness is generally beveled and the Vee edge preparation formed is
filled by depositing a number of runs of weld metal.
All 108º butt joint specimens were fabricated by gas metal arc welding process with a combination
of 80% argon (Ar) and 20% carbon dioxide (CO2).
The parts may be joined by fillet welds or butt welds made by an arc welding process.
Fillet welding refers to the process of joining two pieces of metal together when they are
perpendicular or at an angle. These welds are commonly referred to as tee joints, which are two
pieces of metal perpendicular to each other, or lap joints, which are two pieces of metal that overlap
and are welded at the edges.
These are commonly used for sheet metal up to about 3 mm thick in which one sheet is overlapped
by another.
This type of joint is used for soldering, brazing, resistance spot or seam welding, and for arc spot
welding, plug welding, as well as for adhesive bonding.
For material of 3 mm or thicker (even up to 10 mm) lap joints are occasionally used and fillet welds
are deposited at the plate edges by arc welding.
Methods of welding
1. Pressure welding (Cold welding): done by hammering or pressure. E.g.: gold foil filling.
2. Fusion welding (Hot welding): uses heat to melt the metals being joined. The heat source is
oxyacetylene flame or high amperage electricity.
Pressure welding
Gold foil, mat gold, or powdered gold restorations are pressure welded by hand or mechanical foil
condenser.
• Gas welding
• Arc welding
• Laser welding
Gas welding
Most popular fuels used with oxy-acetylene, Mapp (methylacetylene propadiene) gas, and
hydrogen.
This is the only gas flame that is hot enough to melt all commercial metals.
Oxy-acetylene welding is simple in concept where two pieces of metals are brought together and the
touching edges are melted by the flame with or without addition of filler rod.
• Easy to learn
What is an ARC?
It is sustained by the presence of a thermally ionized column of gas (called a plasma) through which
current flows.
The distance between the electrodes, however, is small, and the applied voltage is high, so that a gas
discharge, i.e., the formation of an arc, may occur.
Arc welding
used.
Plasma welding
Plasma is an ionized gas at a very high temperature. Plasma is generated by sending a jet of gas
through an electric arc.
Plasma welding is used where deep narrow welds are needed and where attention is focused on
thermal distortion and welding speed.
Because of the very focused heat source a combination of thin and thick plates can be welded.
Laser welding
a) Co2 laser
b) Diode laser
c) Excimer laser
d) Nd : YAG laser.
A laser generates a coherent, high intensity impulse of light that can be focused.
By selecting the duration and intensity of impulse, metals can be melted in small regions without
extensive microstructural damage to the metal.
Owing to the expansion from the local high temperature and the change of state, the two liquid
surfaces contact and form a weld on solidification.
a) Optical hazard (the beam can burn the skin or damage the retina if focused by the eye),
c) Fume generation.
The heat is generated within the material being joined by the resistance to the passage of current
through the metal parts, which are held under a pre-set pressure.
Typical value for pulse are 2-6 volts for 1/25th to 1/50th of a second at 250 to 750 amperes.
Thus, in orthodontic welding, the resistance at the junction between the two pieces of SS much
greater than that of either the electrode or the SS masses.
Because of this differential resistance, essentially all of the heat generated by the current flow is
contained within the weld area.
As sufficient heat is generated at the interface, the stainless steel components soften, flow and fuse
together under the influence of mechanical pressure, forming a weld nugget.
Brusse and Carman L introduced spot-welding to the profession at the 1933 AAO meeting in
Oklahoma City.
Making bands
Broad, flat electrodes, rather than the thin, pointed electrodes are used.
This assures that the parts are properly held together before the welding process and during
heating.
If a very low voltage is used, the welded parts will not stick together.
Greater voltages leading to increased heat may lead to increased wire brittleness; however,
springback properties would not be affected.
The welded joint should then be tested by twisting one wire torsionally with a plier.
The greater the contact area, the higher the voltage required.
Smaller contact areas between parts are desirable because higher localized heats are produced,
giving an excellent weld without influencing the remainder of the wire.
Round wires are very simple to weld and require slightly lower voltages than other wires.
A "T" joint is preferable for most orthodontic applications because it has the smallest contact areas.
It is important that the basic weld be accomplished with only one pulse, and that the pulse is of very
short duration.
If a weld is not strong enough because of low voltage, a second or third pulse is rarely successful in
producing the desired weld.
The welding is done by gripping the seam between two snub-nosed electrodes made of hardened
copper, and passing low voltage high amperage current.
A flat-to-flat electrode configuration produced joints with considerably less distortion than a point-
to-point configuration.
A satisfactorily welded joint is one which is strong, has not undergone oxidation (blackening), and
has not been over compressed during fusion.
Satisfactory welding of orthodontic attachments depends on the proper use of each of the following
three variables:
Improper welding
Overheating – 100% settling in to the main arch wire. The wire will begin to melt and flow.
A weakening can occur because of the reduction in the cross-section of the wire.
- Insufficient current.
- Inadequate Pressure.
Over welding:
Overheating SS wire will reduce the spring back and weaken the wire.
This condition when brought about by overheating during welding is called weld decay.
Welding is affected by many factors including electrode pressure, voltage setting, and duration of
impulse, contact resistance, wire cross-section, joint design, and orientation of the wires.
Good welds are characterized by slight discoloration, a small amount of weld flash, and no distortion
of the wires.
During welding, the temperature exceeds various critical temperatures at which phase
transformations occur in the metals involved.
The parent metal melts and then resolidifies into a cast structure. The microstructure of a weld joint
reveals three distinct zones:
CLINICAL APPLICATION
The surface of each electrode must be smooth, flat, and perpendicular to its long axis.
When the electrodes are together, they should be in total contact. Sparking and localized over
welding will result if interface contact is not uniform.
A broad electrode for thin material & narrow one for thick material is used. This allows sufficient
heat to reach the weld area, but not over weld or oxidize the weldmates.
If too narrow electrode is used in welding a bracket (thick) to a band (thin), localized over welding
will occur in the band and under welding in the bracket.
Insert the weldmates between the electrodes, close them together, and depress the weld button.
If sparking is observed, localized over welding has occurred. The electrodes should be checked for
size and/or contact.
If black areas are seen at the points where the electrodes contacted the weldmates, over welding
has occurred.
To make a molar band, it is necessary to have them overlap less than 1mm and then weld.
The overall depth of fusion should not be less than 50% of the combined thickness of the two
sheets, or more than 80%.
If the weld fails by rotational shear at an angle less than 70° the fusion has been too shallow.
WELDABILITY OF ORTHODONTIC
ARCHWIRE ALLOY
The alloys used in orthodontics are many and varied. Among the archwires stainless steel, beta
titanium, nickel titanium and cobalt chromium are the predominant ones.
Krishnan and Kumar conducted a study aimed at evaluating the two most commonly used
orthodontic archwire alloys, stainless steel and beta titanium, and the newly introduced, Timolium,
for their weld characteristics in terms of tensile strength, surface characteristics and microstructural
changes.
Beta titanium was the only one to show clinically useful weld joint strength values.
The weld surface of beta titanium exhibited smooth flow of the melted alloy with an almost intact
weld interface.
The study concluded that, beta titanium with superior strength, better surface characteristics, and
metallographic features was ranked superior to the other two archwire alloys.
Welding of TMA
Beta titanium wires, Titanium Molybdenum Alloy (TMA) in particular, has been proven to be the only
truly weldable archwire alloy available to the orthodontist.
Welded joints of TMA wires have been shown to be able to sustain high torsional loads yet not fail in
the mouth under clinical loading conditions.
Beta titanium (TMA) wire can be directly welded without solder, producing joints that have high
springback and strength.
TMA offers the potential for many applications, particularly where welding is required for active
tooth movement.
The recent and promising use of titanium (Ti) alloys in dentistry has been driven mainly by the desire
to produce structures of low weight and high resistance to chewing efforts, since titanium presents
favorable biological and mechanical properties, including: low density, excellent biocompatibility,
good resistance/weight ratio, and low modulus of elasticity.
However, its high melting temperature, which is close to 1,700°C, and high reactivity with the
nitrogen, hydrogen, and oxygen from air, when subjected to high temperatures, end up making it
more fragile. Titanium, therefore, requires argon gas for inert gas protection during its
manufacturing process.
Laser welding in argon gas atmosphere is preferred because of lower thermal influence on parts
being joined.
An advantage is that the welded joint will comprise of the same pure titanium as the substrate
components there by preserving the excellent bio-compatibility potential and avoiding galvanic
corrosion effects.
Recent advances
TMS electrodes (Titanium, Molybdenum, and Steel wires) are made of space-age materials.
Coated with a chemical agent that both, protects the electrodes and assures smooth, parallel
surfaces.
The electrodes are compatible in any common welder, whether in capacitor or transformer mode.
Can be used with any orthodontic wires, including SS, titanium, molybdenum, and multistranded
wires.
Biocompatibility
orthodontic wires.
growth.
Laser welding was well tolerated by all cells tested, thus showing its high biocompatibility.
Conclusion
The choice of solder material has extreme importance in determining the properties of the soldered
joints.
In orthodontics, silver solders are popular because of their lower fusion temperatures and easy-
handling characteristics.
The breakage of soldered components is one of the pitfalls associated with this joining procedure.
Even after following the guidelines solder failures are not rare.
Although welding is one of the technical procedures most commonly used by orthodontists, the
process is poorly understood and not employed efficiently.
In the final analysis, however, the combination of techniques which offer optimum mechanical,
physical, and chemical properties must be selected.
One kind of electrode is ample for spot welding in the construction of orthodontic appliances.
REFERENCE:
Kenneth J. Anusavice and Paul Cascone, chapter 19 dental casting and soldering alloys, phillips’
science of dental materials 11th Ed.
Stephen T. Rasmussen, O’Brein and Ryge, An outline of dental materials and their selection, Chapter
26.
C.P. Adams and W. John, S. Kerr, The design construction and use of removable orthodontic
appliances.
Phillip’s, Skinners science of dental materials Chapter 33 Gold alloy solders, Soldering procedures.
My dental technology notes, notes from lectures during the course of dental technology, soldering,
brazing and welding in dentistry, by: dentulous32wmt, august 26, 2018.
Pocket dentistry fastest clinical dentistry insight engine, chapter 22: soldering and welding, jan 5,
2015 | posted by mrzezo in general dentistry.
Pubmed central, micromachines (basel),2018 may; 9(5): 209, published online 2018 apr
28, doi: 10.3390/mi9050209, applications of laser welding in dentistry: A state-of-the-art review,
asma perveen, carlo molardi, and carlo fornaini.
Journal of clinical orthodontics, archive home 1987 september, welding of tma wire: clinical
applications, charles j. Burstone dds, ms.
Welding pros, welding through history: historical events that dawn the new age, by adam mason,
in: welding career, last updated on: may 10, 2022.