15-01-2025

6901CJA10102225005 JA

PHYSICS

SECTION-I (i)

1) A solid sphere, a cone and a cylinder are floating in water. All have the same mass, density and
radius. Let f1, f2, and f3 are the fraction of their volumes inside the water and h1, h2, and h3 are their

depths inside water. Then

(A)
(B)
(C)
(D)

2) A wooden cube of mass 2048 g is attached to the bottom of a cylindrical vessel with the help of a
spring. The vessel is filled with some amount of water so that the cube floats half submerged and the
spring is relaxed. The area of the bottom of the cylinder is 600 cm?, density of water is 1000 kg/m
and acceleration of free fall is 10 m/s?. Now additional water is slowly poured in the vessel until the
cube is fully submerged. Which of the following statements are correct?

(A) Length of a side of the cube is 16 cm

(B) The amount of additional water is 10.24 L
(C) Spring force when the cube is fully submerged is 20.48 N
(D) Displacement of the cube when it is fully submerged is 12.48 cm

3) A steel rod of cross-sectional area 16 cm2 and two brass rods each of cross-sectional area 10 cm2
together support a load of 5000 kg as shown in the figure. (Given, Ysteel = 2 × 106 kg/cm2 and Ybrass =

106 kg/cm2). Choose the correction(s).

(A) Stress in brass rod = 121 kg/cm2

(B) Stress in steel rod = 161 kg/cm2
(C) Stress in brass rod = 141 kg/cm2
(D) Stress in steel rod = 141 kg/cm2
4) A large wooden plate of area 10 m2 floating on the surface of a river is made to move horizontally
with a speed of 2 m/s by applying a tangential force. The river is 1 m deep and the water in contact
with the bed is stationary. Then choose correct statement(s). (coefficient of viscosity of water = 10-3
N-s/m2)

(A) velocity gradient is 2 s-1

(B) velocity gradient is 1 s-1
(C) force required to keep the plate moving with constant speed is 0.02N
(D) force required to keep the plate moving with constant speed is 0.01N

5) A ball of density ρ is dropped from a height on the surface of a non-viscous liquid of density 2ρ.

Choose the correct options.

(A) Motion of ball is periodic but not simple harmonic

(B) Acceleration of ball in air and in liquid are equal
(C) Magnitude of upthrust in the liquid is two times the weight of ball
(D) Net force on ball in air and in liquid are equal & opposite

6) The wires A and B shown in the figure are made of the same material, and have radii rA, and rB
respectively. The block between them has a mass 'm'. When the force F is mg/3, one of the wires
breaks;

(A) A will break before B if rA = rB

(B) A will break before B if rA < 2rB
(C) Either A or B may break if rA = 2rB
(D) The lengths of A and B must be known to predict which wire will break.

SECTION-I (ii)

1)

Column-I Column-II

Equal force acting perpendicular

Balance the net weight to
(A) to each point on a spherical (p)
be supported
surface
 Cross-sectional area of the rope Higher modulus of
(B) (q)
used in giant structures elasticity

Reduction in volume
(C) Steel in structural designs (r)
without change in shape

Inversely depends on the

(D) Stress-strain curve (s)
yeild strength
(A) A → q;B → p;C → p;D → q
(B) A → r;B → s;C → q;D → p
(C) A → r;B → ps;C → q;D → q
(D) A → r;B → p;C → p;D → q

2) A siphon tube is connected and liquid is draining out as shown. Points A, B and C are inside the
tube.

Column - I Column - II

(a) Pressure is maximum at (p) A

(b) Speed is maximum at (q) B

(c) KE/Volume is maximum at (r) C

Gravitational PE per unit volume is maximum same for A, B,

(d) (s)
at C
(A) a → r;b → r;c → r;d → q
(B) a → r;b → s;c → s;d → q
(C) a → p;b → s;c → s;d → s
(D) a → p;b → r;c → r;d → q

3) Water is filled in a spherical container of radius R as shown. The height of water is h and the level
of water is perfectly horizontal. Match the columns

Column - I Column - II

(a) h < R (p) Container is hydrophilic

(b) h > R (q) Container is hydrophobic

If the container is in free fall then

(c) water floats as a spherical drop (r) Angle of contact is acute
inside container

If the container is in free fall then

(d) water spreads on the inner walls (s) Angle of contact is obtuse
of the container
(A) a → r;b → s;c → q;d → p
(B) a → r;b → s;c → q;d → p
(C) a → ps;b → qr;c → ps;d → qr
(D) a → pr;b → qs;c → qs;d → pr

4) Two solid spheres A and B of equal volumes but of different densities da and db are connected by a
string. They are fully immersed in a fluid of density df.

Column - I Column - II

(a) Spheres are sinking with string taut (p) da > df

(b) Spheres are rising up with string taut (q) da < df

(c) Spheres are sinking with string loose (r) db > df

(d) Spheres stay in equilibrium with string loose (s) db < df

(t) da = db
(A) a → r;b → q;c → pr;d → t
(B) a → pr;b → qs;c → q;d → qr
(C) a → p;b → s;c → ps;d → t
(D) a → pr;b → qs;c → qs;d → qr

SECTION-II

1) Two narrow bores of diameters 3.0 mm and 6.0 mm are joined together to form a U-shaped tube
open at both ends. If the U-tube contains water, what is the difference in its levels in the two limbs
of the tube? Give your answer in cm. Surface tension of water at the temperature of the experiment
is 7.3 × 10–2 N/m. Take the angle of contact to be zero, and density of water to be 1000 kg/m3 (g =
9.8 m/s2).

2) The shape of an ancient water clock jug is such that water level descends at a constant rate at all
times. The water level falls by 4 cm every hour. The radius of the drain hole is 2 mm and can be
assumed to be very small compared to x. The equation of the shape of jar is y = axb. Determine a + b

3) A Pitot tube is mounted along the axis of a gas pipeline whose cross-sectional area is equal to 25
cm2. Assuming the viscosity to be negligible, find the volume of the gas flowing across the section of
the pipe in m3/s, if the difference in the liquid columns is equal to 10 cm, and the densities of the

liquid and the gas are in the ratio of 10000:1.

4) A uniform rod of length b capable of turning about its end which is out of water, rests inclined to
the vertical. If its specific gravity is 5/9, find the fraction of length immersed in water.
5) A spherical ball of density ρ and radius 0.003 m is dropped into a tube containing a viscous fluid
up to the 0 cm mark as shown in the figure. Viscosity of the fluid= 1.26 N-s/m2 and its density ρL =
ρ/2 = 1260 kg/m3. kg/ m . Assume that the ball reaches a terminal speed at the 10 cm mark. The
time in seconds taken by the ball to travel the distance between the 10 cm and 20 cm mark is (g =

10 m/s2)

6) A thin uniform rod of mass M and length L is free to rotate in a vertical plane about a horizontal
axis passing through one of its ends. The rod is released from the horizontal position shown in the
figure. Cross sectional area of the rod is A. The shear stress developed at the centre of the rod
immediately after it is released is Mg/nA. Calculate n. [For calculation of moment of inertia you can

treat it to very thin]

7) Three capillaries of same length, but internal radii r, 2r and 3r are connected in series and liquid
flows through them under streamline conditions. If the pressure across the whole system is 77 cm of
water, the pressure across the first capillary is x cm of water. Calculate x.

8) A horizontally oriented copper rod of length l = 1m is rotated about a vertical axis passing
through its middle. What is the number of r.p.s at which this rod ruptures?

CHEMISTRY

SECTION-I (i)

1)
Correct order of acidic strength of given hydrogens are

(A)
(B)
(C)
(D)

2) Which are valid tautomeric farms of given compound

(A)

(B)

(C)

(D)

3) The correct order of basic strength in the given option are

(A) [Gas phase]

(B)
(C)

(D)

4) The combination of plots which not represents isothermal expansion of an ideal gas is : (Vm =
molar volume)

(A)

(B)

(C)

(D)

5) Select correct statements about solubility of in a buffer solution of pH < 7.

(A) Solubility of increases with decrease in pH

(B) Solubility of decreases with decrease in pH
(C) Solubility of in a buffer solution of pH = 5 will be greater than that in pure water

(D) Solubility of in a buffer solution of pH = 6 will be smaller than where is

the solubility product of
6) Which of the following statements are false ?

(A) Feasibility of a chemical reaction can not be explained by thermodynamics

(B) Thermodynamics cannot predict the time to attain the equilibrium
(C) A process where the Initial state & final state is same is called Reversible process
(D) Heat, work and total Energy are state functions

SECTION-I (ii)

1)

Column-I (Keto) Column-II % enol

I P 95%

II Q 60%

III R 10–3%

IV S 100%

T 10%
(A) I → P;II → Q;III → R;IV → S
(B) I → R;II → Q;III → T;IV → P
(C) I → R;II → S;III → P;IV → T
(D) I → R;II → T;III → S;IV → P

2)

Column - I Column - II
(Acid) Pka of marbed 'H'

I P 25

II Q 5

III R 13

IV S 15
 T 50
(A) I → Q;II → S;III → R;IV → P
(B) I → P;II → Q;III → R;IV → S
(C) I → Q;II → S;III → P;IV → R
(D) I → S;II → Q;III → P;IV → R

3) 0.01 mole of AgNO3 are gradually added to 1 litre of a solution, which is 0.1M in Na2CrO4 and
0.005M in NaIO3. (Ksp values of Ag2CrO4 and AgIO3 are 10–8 and 10–13 respectively) Now match the
values in list-II with list-I. (use )

List-I List-II

(I) Mole of precipitate formed (P) 0.0975

(II) Equilibrium concentration of Ag+ (in mol\L) (Q) 0.00032

–
(III) Equilibrium concentration of IO3 (in mol/L) (R) 0.0075

(IV) Equilibrium concentration of (in (S)

mol/L)

(T)
(A) I → Q;II → R;III → T;IV → P
(B) I → Q;II → P;III → T;IV → R
(C) I → R;II → S;III → Q;IV → P
(D) I → R;II → Q;III → S;IV → P

4) Match the options given in column 2 for processes given in column 1. Use R = 1/12 [Link]/mol. k

Column-1 Column-2

(A) (P)

(B) (Q)
 (C) (R)

(D) (S)

(T)
(A) A → P;B → R;C → P;D → Q
(B) A → T;B → P;C → R;D → R
(C) A → T;B → Q;C → S;D → P
(D) A → Q;B → T;C → S;D → P

SECTION-II

1) If 'x' hydrogen will be/replaced by deuterium on reacting the following compound with D2O/DO–,
then value of x/2 =?

2) One mole of compound is treated with 2moles of NaNH2, the volume of

NH3(g) evolved at 1atm, 273k is (in litres)

3)
How many octet complete (of all the atoms) resonating structure will be formed in above compound

4) How many 'H' can participate in hyperconjugation of above given

free radical

5) A system works in a cylic process. It absorbs 20 calories of heat and rejects 60J of heat during the
process. The magnitude of work done (J) is [1 calorie = 4.2J]

6) Calculate work done by 1 mole of ideal gas expand isothermally and irreversibly from pressure of
5 atm to 2 atm against a constant external pressure of 1atm at 300K temperature. Express the
magnitude of your answer (in KJ) after multiplying by 10.

7) What minimum [H+] must be maintained in a saturated H2S (0.1 M) to precipitate CdS but not
ZnS, if [Cd2+] = [Zn2+] = 0.1 initially?
Ksp (CdS) = 8 × 10–27; Ksp (ZnS) = 1 × 10–21; Ka (H2S) = 1.1 × 10–21 (Use )

8) An ideal gas undergoes isothermal compression from 5 m3 to 1m3 against a constant external
pressure of 4Nm–2. Heat released in this process is used to increase the temperature of 1 mole of Al.
If molar heat capacity of is 24 J mol–1K–1, the temperature of increases by

MATHEMATICS

SECTION-I (i)

1) Given . Let α, β, γ denote three values of x for

which and are coplanar, then

(A)
(B)
Global maximum value of volume of parallelepiped formed by three vectors whose coterminous
(C)
edges are is 4 for

(D)
(where [.] denotes greatest integer function

2) Let f is a differentiable function satisfying such

that then - (where C is constant of integration)

(A) f(x) is an odd function

(B)

(C) f (0.5) = f' (5.0)

(D) sin(f(x)) is a periodic function with period π

3) Let y = f(x) be a non-zero real valued differentiable function such that and
 , then which of the following statements is(are) TRUE?

(A) if f(–1) = 0, then f(x) = (x + 1)ex

(B) if f(–1) = 1, then f(x) = (x + 1) + e(x+1)

(C)
for some

(D)
for some

4) Let be a function defined by where Q is set of rational

c
numbers and Q is set of irrational numbers. Then which of the following options are correct

(A) f(x) is continuous at finite number of points

(B) f(x) is discontinuous at finitely many points
(C) f(x) is discontinuous at infinitely many points
(D) f(x) is continuous at x = 0 only

5) The angle θ between two non-zero vectors satisfies the relation

, then the least value of is

less than or equal to (where

(A) 1/2
(B) 2
(C)
(D) 4

6) If are the pv's of the points A, B, C & D respectively in three dimensional space &
satisfy the relation , then:

(A) A, B, C and D are coplanar

(B) the line joining the points B and D divides the line joining the point A and C in the ration 2 : 1
(C) the line joining the points A and C divides the line joining the points B and D in the ratio 1 : 1
(D) the four vectors are linearly dependent

SECTION-I (ii)

1) Consider the following Lists

List - I List - II

(I) (P) has two elements

 (II) (Q) has three elements

(III) (R) has four elements

(IV) (S) has five elements

(T) has six elements

The correct option is
(A) I → P;II → S;III → Q;IV → T
(B) I → R;II → T;III → Q;IV → T
(C) I → R;II → T;III → Q;IV → S
(D) I → P;II → S;III → S;IV → T

2)

Let where

Match List-I with List-II and select the correct answer using the code given below the list.

List -I List -II

(P) is increasing in (1)

(Q) is decreasing in (2)

The set of values of 'a' for which g(x)

(R) (3)
does not possess critical point is

The set of values of 'a' for which g(x)

(S) (4)
possess critical point is

(5)
(A) P → 2;Q → 3;R → 1;S → 4
(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 3;Q → 2;R → 1;S → 4
(D) P → 3;Q → 2;R → 4;S → 1

3) Match the statements / expressions given in Column I with the values given in Column II.

Column-I Column-II

(A) Root(s) of the equation (P)

Points of discontinuity of the function

(B) (Q)
where [y] denotes the largest
integer less than or equal to y
 Volume of the parallelepiped with its edges
(C) (R)
represented by the vectors and

Angle between vectors and where and are

(D) (S)
unit vectors satisfying

(T)
(A) A → QS;B → PRST;C → T;D → R
(B) A → PRST;B → T;C → R;D → QS
(C) A → T;B → R;C → QS;D → PRST
(D) A → R;B → QS;C → PRST;D → T

4)

List -
List - I
II

Let O be an interior point of ΔABC such that

(A) then the ratio of the area of ΔABC (P) 0
to the area of ΔAOC, is with O is the origin

Let ABC be a triangle whose centroid is G, orthocentre is

H and circumcentre is the origin 'O'. If D is any point in
the plane of the triangle such that no three of O, A, B, C
(B) and D are collinear satisfying the relation (Q) 1

then the value of the scalar

'λ' is

If and are non zero vectors such that no three of

them are in the same plane and no two are orthogonal
then the value of the scalar
(C) (R) 2

is

(S) 3
(A) A → Q;B → R;C → Q
(B) A → R;B → Q;C → S
(C) A → Q;B → S;C → Q
(D) A → S;B → R;C → Q

SECTION-II

1) Number of integers in the domain of the function is

2) Let f: R→R, g: R→R and h: R→R be differentiable function such

that , and then the value of h'(1) is equal to
3) If then is

4) If and are perpendicular unit vectors and vector is such that then

is

5) Let f(x) be even periodic function with period '3' such that . The

number of solutions of the equation in [–3, 100] is

6) If A is the area of triangle formed by the lines where ,

& then is equal to

7) Let and be three non-coplanar unit vector such that the angle between every pair of them

is . If where p, q, r are scalars; then the value of

is

8) Let volume of a tetrahedron ABCD is and volume of parallelopiped whose three

coterminous edges are line segments joining centroid of any face of tetrahedron with centroids of its
other three faces is , then is
 ANSWER KEYS

PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,C,D A,B,C,D A,B A,C A,C,D A,B,C

SECTION-I (ii)

Q. 7 8 9 10
A. C B D A

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 0.50 4.40 0.35 0.33 5.00 16.00 71.64 80

CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A,C,D A,B,C,D A,B,C B,D A,C A,C,D

SECTION-I (ii)

Q. 25 26 27 28
A. B A D C

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 5.5 44.8 4 9 24 7.40 to 7.50 1.04 to 1.05 0.66 to 0.67

MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. B,D B,C,D B,C A,C,D B,C,D A,C,D

SECTION-I (ii)

Q. 43 44 45 46
A. D A A D
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 184 1216 1 1 103 18 950 2
 SOLUTIONS

PHYSICS

CHEMISTRY

MATHEMATICS