16-11-2025

1803CJA101029250103 JA

PART-1 : PHYSICS

SECTION-I(i)

1) Find Req between points A and B.

(A) 1Ω
(B) 3Ω
(C) 4Ω
(D) 2Ω

2) A 1 kg mass stretches a spring by 49 cm. The system is immersed in a medium that impacts a
damping force equal to four times the instantaneous velocity of the mass. Particle is released from a
point 24 cm above the equilibrium. If upward direction is taken positive then equation of motion is -

(A)
(B)
(C)
(D)

3) A metal sphere of inner radius R and outer radius 2R is filled with a space charge of uniform
charge density ρ. How much energy is released if sphere is grounded ?

(A)

(B)

(C)

(D)

4) Two identical capacitor of capacitance 10 µF are charged to a potential 10 V as shown. At t = 0,

switch S1 is closed and at t = ln4 ms switch S2 is also closed. Current through resistor at t = ln8 ms
is nearly

(A) 44 mA
(B) 88 mA
(C) 53 mA
(D) 27 mA

5) A uniform but time variant magnetic field exists in a cylindrical region directed along the axis of
cylinder of radius R. The graph of induced electric field at a given time v/s. r is :- (r = distance from
axis)

(A)

(B)

(C)

(D)

6)

In series L C R circuit voltage drop across resistance is 8 volt, across inductor is 6 volt and across
capacitor is 12 volt. Then:

(A) voltage of the source will be leading current in the circuit

(B) voltage drop across each element will be less than the applied voltage
(C) power factor of circuit will be 4/3
(D) none of these

SECTION-I(ii)

1) Because of the effects of air drag abandoned satellites, at the end of their usual lives lose energy
in the upper layers of atmosphere, before finally burning up when they reach the denser lower
layers. It can be shown that satellites originally moving along circular trajectories will continue to
travel in approximately circular orbits, with their orbital radii slowly decreasing. Drag force acting
an satellite can be expressed as Fdrag = Cρv2 where ρ is density of air at the altitude of satellite and v
is the speed of satellite, C is a constant. Mark the correct statement(s).

During slow decrease in radius of orbit, gravitational force is not perpendicular to velocity of
(A)
satellite.
(B) Speed of satellite decreases as it approaches earth due to tangential drag force.
If change in orbital radius of Δr during a single revolution then expression for density of air is
(C)
.
If change in orbital radius of Δr during a single revolution then expression for density of air is
(D)
.

2) A capacitor is charged and battery is disconnected. Now the distance between the plates is
increased slightly

(A) Force between the plates will decrease

(B) The potential energy of the capacitor will increase
(C) Potential difference between the plates will decrease
(D) Potential difference between the plates will increase

3) For the resistance network shown in the figure, choose the correct option(s).

(A) the current through PQ is zero

(B) I1 = 3A
(C) The potential at S is less than that at Q
(D) I2 = 2A

4) In the figure shown a dipole is kept at the centre of a uniformly charged fixed ring. Charge on
ring is Q and dipole moment of dipole is p. Mass of dipole is m. dipole moment is along the axis of
ring. Dipole is now released. Which of the following is/are true ? (Neglect effect of gravity)

(A)
Kinetic energy of dipole is maximum at a distance from centre
(B) Kinetic energy of dipole is maximum at distance R from centre.

(C)
Maximum kinetic energy of dipole is
Maximum kinetic energy of dipole is
(D)

5) As shown in the figure below, a proton of charge +e moves with velocity v parallel to an infinitely-
long, thin wire, at a distance r from the axis of the wire. The wire carries a current I and its charge
per unit length is λ (assumed positive and uniform). Both the proton and the wire are in vacuum. (c

= speed of light)

(A)
Electric field experienced by proton is

(B)
Magnetic field experienced by proton is

(C)
Speed for which proton moves in a straight line is

(D)
Speed for which proton moves in a straight line is

6) Two parallel resistanceless rails are connected by an inductor of inductance L at one end as
shown in figure. A magnetic field B exists in the space which is perpendicular to the plane of the
rails. Now a conductor of length l and mass m is placed transverse on the rail and given an impulse J
towards the rightward direction. Then select the correct option (s):
 Velocity of the conductor is half of the initial velocity after a displacement of the conductor
(A)

Velocity of the conductor is half of the initial velocity after a displacement of the conductor
(B)

Current flowing through the inductor at the instant when velocity of the conductor is half of
(C)
the initial velocity is
Current flowing through the inductor at the instant when velocity of the conductor is half of the
(D)
initial velocity is

SECTION-II

1) An infinite ladder network of resistance is constructed with 1Ω and 2Ω resistance. The 6V battery
between A and B has negligible internal resistance. The current (in A) that passes through 2Ω

resistance nearest to the battery is :-

2) A parallel plate capacitor has two layers of dielectric as shown in figure. If this capacitor is
connected across a battery, then the ratio of potential difference across the dielectric layer is :
3) Initially the plates of the parallel plate capacitor shown in the figure are A and B containing
charge +2µC and –2µC respectively. Negatively charged plate B is connected to a spring of spring
constant 5000N/m at one end and the other end of the spring is connected to a rigid support. Now
the plate A is fixed and the system is released from rest. The maximum elongation produced in the

spring is m. The area of the plates is 2 cm2, the medium between the plates is air and

Electric permittivity of air is ∈ (in SI). Then the value of α.

4) An Earth satellite revolves on a circular orbit at a linear speed v0. A missile device increases the
absolute value of this speed to 1.5v0, and the satellite goes into an unknown path as shown (Fig).
With what speed will the satellite leave the gravitational field of earth ? The resistance of the cosmic

dust is not taken into account. Mass of earth is M. If your answer is , fill a in OMR sheet.

5)

A steady current I = 10 A goes through a wire loop PQRS. Part PQR is semi-circle of radius r = 1 m.
RS = SP and ∠RSP = 90°. Find the magnetic field at O in 10–6 T.

6) A point charge Q is kept at the centre of a hollow conducting sphere of inner radius a and outer
radius 2a. Conducting sphere is further coated with a dielectric medium having dielectric constant 3.

Inner radius of dielectric is 2a and outer radius is 3a. Potential at distance of from point charge is
 then x = ...........

PART-2 : CHEMISTRY

SECTION-I(i)

1) Basing on stability of the lower species to which they are reduced, identify the correct order of
oxidising power.

(A)
(B)
(C)
(D)

2)

The following complex are given

(1) trans-[Co(NH3)4Cl2]+
(2) cis-[Co(NH3)2(en)2]3+
(3) trans-[Co(NH3)2(en)2]3+
(4)
(5)
(6)
Choose the correct code :

(A) (1), (2) are optically active, (3) is optically inactive

(B) (2) is optically active; (1), (3) are optically inactive
(C) (4), (5) are coloured and (6) is colourless
(D) (4) is coloured and (5), (6) are colourless

3) Analyse the following reaction sequence.

 Which of the following compound(s)
on reaction with Cl2 can produce a compound X, That is used in quantitative estimation of
“Magnesium” using carius method?

(A) X
(B) W
(C) Z
(D) P

4) In the following sequence of reactions ‘Z’ will be :

(A) Acetic acid

(B) Acetone
(C) Methyl amine
(D) Ethyl amine

5)
Compound 'B' is :

(A)
(B)

(C)

(D)

6) Find the value of "n" in following reaction sequence :

(A) 1
(B) 2
(C) 3
(D) 4

SECTION-I(ii)

1)

Correct options regarding following reaction sequence is/are :

(A)
Z is

(B)
X is

(C)
Y is
(D) Formation of X is example of Hunsdicker reaction

2) The reaction sequence(s) that would lead to o-xylene as the major product is (are)
(A)

(B)

(C)

(D)

3) In which of the following reactions gemdihalide is obtained as a major product :

(A)
Pot. fumerate X1 (Major product)

(B)
B X2 (Major product)

(C)
(Major product)

(D) (Major product)

4) Which of the following statements are true for CH2 = CH2 and CH2 = SF4.

(A) In ethylene nodal plane lies in molecular plane

(B) In methyl sulphur tetrafluoride nodal plane lies in axial plane
(C) In methyl sulphur tetrafluoride nodal plane lies in equatorial plane
If nodal plane lies in equatorial plane the stability will be less then if it lies in axial plane in case
(D)
of CH2 = SF4
5)
Find A to G

(A) A = K2MnO4, B = NaCl, C = CrO3, D = AgNO2, E = (NH4)2CrO4, F = CaCO3, G = SO2

+
(B) A = K2Cr2O7, B = NH4Cl, C = CrO2Cl2, D = Ag2CrO4, E = [Ag(NH3)2] , F = AgCl, G = NH3
(C) A = K2CrO4, B = KCl, C = CrO2Cl2, D = HgI2, E = Na2CrO4, F = BaCO3, G = NH4Cl
(D) A = KMnO4, B = HCl, C = Cl2, D = HgI2, E = Hg(NH2)NO3, F = Hg2Cl2, G = N2

6)
Which option is/are correct
[Gas E is highly poisonous and D has blue flame]

(A)

(B) Gas 'D' has two π bonds

(C) Complex 'C' reacts with ZnCl2 solution gives bluish-white ppt.
(D) All group-V cations do not give white ppt. with complex 'C'.

SECTION-II

1) Purple solution
Gas Y has been allowed to react with following species in neutral/acidic medium :
(a) FeCl3 (b) CuSO4 (c) BaCl2 (d) SO2 (e) Cr2O72– (f) CH3COONa (g) Hg2+
Then calculate value of (P–Q)/R :
P : Number of species which undergoes redox reaction with gas Y.
Q : Number of species with which gas Y undergoes precipitation without going into redox reaction.
R : Number of species with gas Y produce no observable change.
2) Consider the given reaction sequence

(Where a, b is achiral monodentate ligand and (AA) is achiral symmetrical bidentate ligand.)
Number of Geometrical isomers of Complex - P, Complex- Q, and Complex-R are X, Y and Z
respectively. X, Y & Z are the 1st, 2nd and 3rd digits of your answer (X Y Z).
[For example : X = 1, Y = 2, Z = 3 then you have to fill 123 as your answer in OMR sheet]

3) Calculate the difference in net stabilisation energies (in kJ mol–1) of Fe2+ complexes with CN–
ligands (Δ0 = 25000 cm–1) and with H2O ligands (Δ0 = 10000 cm–1). Given that the pairing energy, P =
15000 cm–1 for Fe2+ ion for both the complexes.
(Given that h = 6 × 10–34 J sec., Avogadro Number = 6 × 1023 , Speed of light in vaccum = 3 × 108 m
sec–1).

4) In how many cases electron gain enthalpy is negative.

(i) H(g) + e → H– (g)
(ii) Li(g) + e → Li– (g)
(iii) Na (g) + e → Na– (g)
(iv) K(g) + e → K– (g)
(v) P(g) + e → P– (g)
(vi) O(g) + e → O– (g)
(vii) O– (g) + e → O2–(g)
(viii) N(g) + e → N– (g)
(ix) Ar(g) + e → Ar– (g)

5) The total number of oxygen atoms per molecule in each cytosine, thymine and uracil be x
The total number of free hydroxyl groups in glucopyranosyl-fructofuranose be y
The total number of free hydroxyl groups in Methyl 2-deoxyribopyranoside be z
What is (x+y-z)

6)

Total number of pairs of resonating structure in which second is more stable than first.

(a) (b)

(c) (d)

(e) (f)

(g)
 PART-3 : MATHEMATICS

SECTION-I(i)

1) Coefficient of x12 in (1 + x3)5 (1+ x4)8 (1 + x5)11 is -

(A) 496
(B) 501
(C) 440
(D) 56

2) Let a person walk along the grid as shown in figure from A to B along shortest path. The number
of ways in which he always goes through the point C but never goes through the point D is

(A) 282
(B) 220
(C) 180
(D) 422

3) Let ∀ n > m and n, m ∈ N. Consider a matrix A = [aij]3 × 3 where

. Then is :

(A) (15)2 × 242

(B) (15)2 × 234
(C) (105)2 × 238
(D) (105)2 × 236

4) Let f be a differentiable function such that , Then is equal

to

(A) 80
(B) 160
(C) 240
(D) 320

5)

If area bounded by curve

x-axis and is equal to

(where k ∈ I), then k is

(A) 1
(B) 2
(C) 3
(D) 4

6) Let and (where a and b are positive real numbers), then value of a
+ b is (where {.} denotes fractional part function)-

(A) 16
(B) 18
(C) 10
(D) 8

SECTION-I(ii)

1)

If , ∀ x, y ∈ R – {0} and , then

(A) α > β
(B) β is prime
(C) α < 2β
(D) (α + β) is prime

2) Consider the family of curves Ax2 + By2 = 1 (where A & B are arbitrary constants). If this family of
curve is represented by the differential equation Py'' + Q(y')2 = yy', where P and Q are functions of x

and y, here , then which of the following statement(s) is/are true ?

(A) P = xy
(B) Q = xy
(C) P + Q = x(y + 1)
(D) P – Q = y(x – 1)

3) A differentiable function satisfy the equation dt then which of

the following is/are true

(A) ƒ'(0) = –1

(B)

(C) ƒ'(0) = 1

(D)

4) 7 points are given in a plane (as shown in adjacent figure), then using these 7 points –

(A) Number of lines that can be formed is 10.

(B) Number of triangles that can be formed is 24.
(C) Number of quadrilateral that can be formed is 6.
Maximum number of circles that can be formed is 24, where each circle contains atleast
(D)
three of 7 points

5) Let M be a 3 × 3 matrix satisfying

M = ,M = and M =
then

(A) tr.(M) will be equal to 2.

(B) sum of all the elements of M will be 6.
(C) det. (M) is equal to –8.
(D) number of distinct elements in matrix M will be 6.

6)

Let ƒ,g : [–2,3] → R be continuous functions which are twice differentiable on the interval (–2,3). Let
the values of ƒ and g at the points –2,0,1 and 3 be as given in the following table :
In each of the intervals (–2,0), (0,1) and (1,3) the function (ƒ – 5g)" never vanishes. Then the correct
statement(s) is (are)
(A) ƒ'(x) – 5g'(x) = 0 has exactly three solutions in (–2,0) ∪ (0,1) ∪ (1,3)
(B) ƒ'(x) – 5g'(x) = 0 has exactly one solutions in (0,1)
(C) ƒ'(x) – 5g'(x) = 0 has at least one solution in (1,3)
(D) ƒ'(x) – 5g'(x) = 0 has at least two solution in (–2,0)

SECTION-II

1) Consider the data on x taking the values 0, 2, 4, 8, ..., 2n with frequencies nC0, nC1, nC2, ..., nCn

respectively. If the mean of this data is , then n is equal to ____________.

2) If f(x) = (x3 –1)|x – 1| + sin(πx) |x–2| + |||x|–3|–5| and λ be the number of points at which f(x) is
non-differentiable then last two digit of the number λ32 is :

3) If the number of real pairs of (x, y) satisfying is , then the unit digit of
is

4) Let g(x) = x5 ln(ƒ(x)) where ƒ(x) is a differentiable positive function on (0,∞) satisfying ƒ(3) = 1 &
ƒ'(3) = 2 then g'(3) is equal to -

5) For each positive integer n, let . For , let [x] be the

greatest integer less than or equal to x. If , then the value of [L] is_____.

6) Let and , then the value of equals

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. D C C A A D

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. A,C B,D A,B,C,D A,C A,B,C A,C

SECTION-II

Q. 13 14 15 16 17 18
A. 1.50 3.00 4.00 2.00 7.14 100

PART-2 : CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22 23 24
A. D B D C D B

SECTION-I(ii)

Q. 25 26 27 28 29 30
A. A,B,C A,B A,D A,B,D B A,B,C,D

SECTION-II

Q. 31 32 33 34 35 36
A. 0.50 232.00 280.00 to 282.00 6.00 11.00 4

PART-3 : MATHEMATICS

SECTION-I(i)

Q. 37 38 39 40 41 42
A. B B C A D A

SECTION-I(ii)

Q. 43 44 45 46 47 48
A. A,B,C,D A,C A,B A,B,C,D A,B,C A,B,C
 SECTION-II

Q. 49 50 51 52 53 54
A. 6.00 25 3.00 486 1.00 10.00
 SOLUTIONS

PART-1 : PHYSICS

2) mg = kx ⇒ N/m b = 4 kg/s
when damping is present

→
Characteristic equation

S2 + 4S + 20 = 0
S = –2 ± 4i –2 ± 4i

at t = 0 v = 0 and x = 0.24 m
solving this we get A = 0 .24 m and B = 0.12 m
Final equation

3) When sphere is grounded electric field outside the sphere will becomes zero.

so loss of energy

where

Loss

4) After closing switch S1

On closing switch S2 both capacitors will share their charge. After sharing
5)

(out side)
For inside

E∝r

6) Since, cosθ = = = =
(Also cosθ can never be greater than 1)
Hence (C) is wrong.
Also, IxC > IxL ⇒ xC > xL .
∴ Current will be leading.
In a LCR circuit

v= =
v = 10 ; which is less than voltage drop across capacitor.

7)

8)

Since plates are isolated hence charge is constant.

(a) force is constant

(ii)

(iv)

9) By Symmetry VP = VQ and VS = VT

10)

Maximum kE at

11) Solution

13) Question Explanation :

We have to calculate the current passes through 2Ω resistance nearest to battery in the given
infinite ladder network.

Concept :
This question is based on Equivalent Resistance and Circuit Analysis.

Solution :
Let x → equivalent resistance
 On solving x = 2Ω

∴ i =

∴ i1 = =
= 1.5 A

Hence,
Correct answer : Current through 2Ω resistance is 1.5 A.

14)

15) ×x= Kx2

⇒x=

16) ... (1)

... (2)

17)
= 7.14 × 10–6T

18)

PART-2 : CHEMISTRY

19)
 Conceptual

20)

21)

Ca(OH)2 + CO2 → CaCO3

Milky solution

22)

Explanation Question: Question is asking about the final product (Z) in the following
sequence of reaction.
Concept:

A. Oxidation of alcohol with KMnO4

B. Nucleophilic addition elimination reaction
C. Hofmann's bromamide reaction

Solution:

Final Answer:
option (3)

23)
24)

25) Explanation Question: Question is asking about the products and name of the given
reactions.
Concept: Based on HVZ reacion and nucleophilic substitution reaction
Solution:

option 1,2 and 3 are correct but option 4 is wrong

Final answer 1,2,3

26)
(A)

(B)

(C)

(D)
27)

28)

29)

The compound are

A = K2Cr2O7, B = NH4Cl, C = CrO2Cl2, D = Ag2CrO4, E = [Ag(NH3)2]+, F = AgCl, G = NH3
30)

31)

(a)

(b)

(c)
(d)

(e)

(f)

(g)
∴ P = 3; Q = 2; R = 2

32)
GI of complex (P) ⇒ 2 = X
GI of complex (Q) ⇒ 3 = Y
GI of complex (R) ⇒ 2 = Z
So xyz = 232

33) Net stabilization energy of Fe2+ will CN–

ligands
C.F.S.E. = –0.6 × (nt2gΔ0) + 0.4 × (negΔ0) + np
= – 2.4 Δ0 + 2P
= (– 2.4 × 25000 + 2 × 15000) cm–1
= – 30000 cm–1

Net stabilisation energy of Fe2+ ions with H2O ligands

C.F.S.E. = –0.6 × (nt2gΔ0) + 0.4 × (negΔ0) + np
 = – 0.4 Δ0
= 4000 cm–1
so required difference = 26000 cm–1
= 26 × 105 m–1
= 6 × 10–34 × 3 × 108 × 26 × 105 × 6 × 1023 × 10–3 kJ/mole
= 2808 × 10–1 kJ/mole
= 281 kJ/mole
= 280.8 kJ/mol

34)

ΔH (KJ/mole)
–
(i) H(g) + e → H (g) –73
–
(ii) Li(g) + e → Li (g) –60
–
(iii) Na (g) + e → Na (g) –53
(iv) K(g) + e → K– (g) –48
(v) P(g) + e → P– (g) –72
(vi) O(g) + e → O– (g) –141
– 2–
(vii) O (g) + e → O (g) –798
(viii) N(g) + e → N– (g) + 6.8
(ix) Ar(g) + e → Ar– (g) + 34

35)

36) (a, c, d, e)

PART-3 : MATHEMATICS

37) Possible powers of x in

(1 + x3)5 = 0, 3, 6, 9, 12, ...
(1 + x4)8 = 0, 4, 8, 12, ...
(1 + x5)11 = 0, 5, 10, ...
Possibilities for x12 is

⇓ ⇓ ⇓
56 + 440 + 5
⇒ 501

38)
= 20 × (20 – 9) = 220

39)
J6+i, 3 – Ji+3,3 ; i ≤ j

aij = j6+i, 3 – ji+3, 3 =

⇒ (210.218)2
(105)2 × 238

40)

Differentiate the given equation

41)

Area

42)

so

and
Now and

so a + b = 16

43)

Putting y = x in given functional equation

Let ⇒

When x = 2,

x = 3,

∴ Integral
α = 10, β = 7

44) Ax2 + By2 = 1 ⇒

differentiat both sides
0 = x2(–2Byy') – (1 – By2).2x

1 – By2 = –Byxy' ⇒

= y2 – yxy' ⇒ 2yy' – yxy" – yy' – x(y')2 = 0

x(y')2 – yy' + yxy" = 0
xyy" + x(y')2 = yy'
⇒ P = xy, Q = x

45)
ƒ'(x) = ƒ(x) cosx – cosx
ƒ'(x) – ƒ(x) cosx = – cosx, I.F. = e–sinx
e–sinx. ƒ(x) = e–sinx + c
ƒ(x) = 1 + cesinx, Now ƒ(0) = 0 ⇒ c = –1
⇒ ƒ(x) = 1 – esinx

46) (A) 7C2 – 3C2 – 5C2 + 2 = 10 (B) 7C3 – 3C3 – 5C3 = 24

(C) There is no use of point’3’
6
C4 – 4C4 – 4C3 . 2C2 = 6
(D) 7C3 – 3C3 – 5C3 = 24

47) Let M=

∵ M = = ⇒ a = –1, d = 2, g = 3

and M = = ⇒ b = 1, e = 1, h = –1

and M = = ⇒ c = 0, f = –1, i = 2

∴ M=
= –1 (2 –1) – 1 (4 + 3) = – 8 Ans.

48) Let h(x) = ƒ(x) – 5g(x)

h(x) is continuous, differentiable & ƒ'(x) is also continuous, differentiable
h(–2) = 6 = h(0) = h(1) = h(3) & (ƒ – 5g)"
never vanishes
⇒ exactly one root in (–2, 0), (0, 1) & (1, 3)

49)
⇒ 3n = 729 ⇒ n = 6

50) Here (x3 –1)|x – 1| is differentiable at x =1

Similarly sin πx|x–2| is differentiable at x =2
f(x) is not differentiable at x = 0, 3, –3, 8 –8
⇒λ=5
Last two digit of no. 532 = 25

51) We know,

...(i)
By,

...(ii)
From Eqs. (i) and (ii) equality holds when all terms are equal, i.e., .

Unit digit of is 3.

52)

g'(x) = x5 ⋅ f'(x) + ln (f(x)) 5x4

g'(3) = 243 × 1 ⋅ 2 + ln (1) 5 34
g'(3) = 486

53)
54) (i)

Also (ii)
∴ On adding (1) and (2), we get
2S100 = 100t100