07-02-2026

1001CJA106216250231 JA

PART-1 : PHYSICS

SECTION-I (i)

1) The K absorption edge for Y (Z = 39) is 0.7277 Å. In order to produce emission of the K series
from Y, an accelerating potential of at least 17.039 kV is required. Determine h/e from these data.

(A) 8.4 × 10–15 J-s/C

(B) 4.13 × 10–15 J-s/C
(C) 3 × 10–15 J-s/C
(D) 2.7 × 10–15 J-s/C

2) There is a uniform but variable magnetic field , in a cylindrical region, whose

boundary is described by x2 + y2 = a2. along the straight path is :-

(A) 0

(B)

(C)

(D)

3) Small metallic spheres A and B of radius r are kept fixed at a distance R apart. First, the switch
S1 is briefly closed and then opened. After that, the switch S2 is briefly closed and then opened.
Initially, both spheres have a charge of +Q. Given that R >> r, what are the final charges QA and
QB on the spheres ?

(A)
QA = ; QB =

(B)
QA = ; QB =

(C)
QA = ; QB =

(D)
QA = ; QB =

4) All surfaces are frictionless, ratio of acceleration of block B and acceleration of block A, is :-

(A) 1

(B)

(C) 3
(D) 2

SECTION-I (ii)

1) A researcher is analyzing the stability of different atomic nuclei based on their binding energy per
nucleon and exploring nuclear reactions that release or absorb energy.
Consider the following isotopes :
- Helium-4 ( ) : Binding energy per nucleon = 7.07 MeV
- Oxygen-16 ( ) : Binding energy per nucleon = 7.89 MeV
- Nickel-62 ( ) : Binding energy per nucleon = 8.79 MeV
- Uranium-238 ( ) : Binding energy per nucleon = 7.57 MeV
- Pallidum-119 ( ) : Binding energy per nucleon = 8.50 MeV
- Nickel-63 ( ) : Binding energy per nucleon = 8.75 MeV

(A) The energy released in a fusion reaction where 4 nuclei fuse to form is 14.56 MeV.

(B) The energy released in a fission reaction where breaks into two equal fragments is 221.34
MeV.

(C) The energy released in the reaction where a neutron of negligible energy is added to is
6.27 MeV.

(D) The energy required to break a nucleus into neutrons and protons and separate them from
each other by a large distance is 56.56 MeV.

2) A galvanometer has a resistance 100Ω and full scale deflection current 50 µA. It can be used as a
voltmeter or as a higher range ammeter provided a resistance is added to it. Choose the correct
range and resistance combinations from the following.

(A) 50 V range with 10 kΩ resistance in series.

(B) 10 V range with 200 kΩ resistance in series.
(C) 5 mA range with 1 Ω resistance in parallel.
(D) 10 mA range with 1 Ω resistance in parallel.

3) In a longitudinal stationary displacement wave :-

there is no transfer of energy in the direction of propagation of wave but the phase of oscillation
(A)
travels in the forward direction.
(B) maximum increase of pressure occurs at displacement nodes.
(C) maximum decrease of pressure occurs at displacement nodes.
(D) the pressure at displacement antinode is same as what is would be in absence of the wave.

SECTION-I (iii)

1) List-I contains different AC circuits with rms voltage of ac sources as shown. List-II contains the
corresponding rms currents supplied by the ac voltage sources. Then match the options of List-I
correctly with the options of List-ll.

List–I List–II

(P) (1) Irms = 25 A

 (Q) (2) Irms = 5 A

(R) (3) Irms = A

(S) (4) Irms = 20 A

(5) Irms = 10 A
(A) P → 4;Q → 1;R → 2;S → 3
(B) P → 4;Q → 1;R → 2;S → 4
(C) P → 3;Q → 2;R → 4;S → 1
(D) P → 4;Q → 4;R → 2;S → 3

2) A monatomic ideal gas of 2 moles was found to be undergoing a thermodynamics poly-tropic

process whose volume coefficient is varying with temperature as shown. (take : J/mol/K).

Match List-I with List-II :

List-I List-II
 Work done by gas in joules for every 1 K rise in
(P) (1)
temperature if tan θ = 3

Internal energy rise of the gas in joules for every 1

(Q) (2) 25
K rise in temperature if tan θ = 2

Heat absorbed by the gas in joules for every 1 K

(R) (3)
rise in temperature if tan θ = 1

(S) Molar Heat capacity of gas if tan θ = 2 (4) 50

(5)

(A) P → 2;Q → 4;R → 3;S → 1

(B) P → 2;Q → 3;R → 1;S → 5
(C) P → 4;Q → 2;R → 3;S → 5
(D) P → 4;Q → 2;R → 3;S → 1

3) Match the force acting on the left wall of 2m wide (perpendicular to plane) tank which is
completely full in list-II to the acceleration of container and dimension of the container in list-I.

(atmospheric pressure is neglected.) (Take ρw = 103 kg/m3.)

List-I List-II

(P) ax = 6 m/s2, az = 0, h = 1.4 m (1) 64 kN

(Q) ax = 0, az = 6 m/s2, h = 2.4 m (2) 92.16 kN

(R) ax = 6 m/s2, az = 6 m/s2, h = 2 m (3) 94.08 kN

(S) ax = 6 m/s2, az = 2 m/s2, h = 1.4 m (4) 23.52 kN

(5) 52 kN
(A) P → 3;Q → 4;R → 5;S → 1
(B) P → 4;Q → 2;R → 1;S → 4
(C) P → 5;Q → 3;R → 4;S → 1
(D) P → 2;Q → 4;R → 5;S → 3

SECTION-II
1) An aluminium wire of cross-sectional area 10−6 m2 is joined to a steel wire of the same cross-
sectional area. This compound wire is stretched on a sonometer pulled by a weight of 10 kg. The
total length of the compound wire between the bridges is 1.5 m of which the aluminium wire is 0.6 m
and the rest is steel wire. Transverse vibrations are set-up in the wire by using an external source of
variable frequency. Find the lowest frequency (in Hz) of excitation for which the standing waves are
formed such that the joint in the wire is a node. Density of aluminium is 2.6 × 103 kgm−3 and that of
steel is 1.04 × 104 kgm−3. Take g = 10 ms−2.

2) In figure the velocity of point A is 5 m/s to the right and its acceleration is 8 m/s2 to the right. The

acceleration of point B (in m/s2) is :-

3) Ram and Shyam play a physics-themed wheel of fortune. The game's setup consists of 3 ideal
linear polarisers A, B and C arranged in a row. Polariser A is fixed in the upright orientation, while

polariser C is fixed at angle rad from polariser A. Polariser B is free to rotate. Unpolarised light of
intensity I0 enters polariser A, and the light intensity after the light passes through all 3 polarisers is

I. To play the game, each player spins polariser B. Once it stops spinning, the ratio is the
player's score. Ram plays first, and gets a score of αA = 0.03125 What is the probability that Shyam
can get a higher score? You may assume that polariser B is equally likely to be at any angle when it

stops spinning.

4) Three rods of equal length are joined to from an equilateral Δ ABC. The temperature coefficient of
linear expansion is α1 for AB, α2 for AC and BC. For α1 = kα2, ∠ABC remains constant for small
changes in temperature. Find K.

5) A Carnot cycle based ideal heat engine operates between two tanks each having same mass m of
water. The source tank has an initial temperature of T1 = 361 K and the sink tank has an initial
temperature of T2 = 289 K. Assume that the two tanks are isolated from the surrounding and
exchange heat with the engine only. Specific heat of water is s. Find the total work (in kJ) that the
engine will be able to deliver by the time two tanks reach common temperature. Take : m = 1 kg, s =

4200 J/kg–°C.

6) When classical pendulum clocks are moved, even very small differences in gravitational
acceleration become noticeable, for example, between the ground floor and the upper floors of high-
rise buildings. We adjust a pendulum clock with a steel second pendulum at sea level so that the
period of oscillation τ0 is two second. Then, we move it to an altitude h above sea level. Magnitude of
change in the number N of oscillations performed by the pendulum in one day change? Assume that
the Earth is a homogeneous sphere with a radius Rz. Ignore its rotation. Take h = 400 m, Rz = 6400
km,

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which is incorrect ?

(A) B2 > F2 > C2 > O2 > N2 Bond length

(B) NaHCO3 < KHCO3 water solubility
(C) of flouride of alkali metal become less –ve down the group
–
(D) [Co(H2NCH2CH2O)2Cl2] < [Pt(NH3)(H2O)Br(Py)]Cl number of geometrical isomers

2) AgBr(s) crystallises in rock-salt type structure. At temperature T, a sample of AgBr contains

simultaeneously both frenkel and schottky defects with the following properties.
2% Ag+ ions of ideal crystal exhibit frenkel defect and due to frenkel defect all interstitial Ag+ ions
occupy tetrahedral voids.
0.5% of formula unit (AgCl) are completely missing the crystal lattice due to schottky defect
The crystal remains electrically neutral.
Density of perfect AgBr crystal is ρ0 and and density of defective crystal is ρ.
If perfect crystal contains N formula units of AgBr, then how many following information’s are
correct ?
(i) Total number of Ag+ ions at normal sites are 0.975 N.
(ii) Total number of Ag+ at interstitial sites are 0.02 N.
(iii) Total number of Br– ions present are 0.995 N.

(iv) Value of .
(v) Fraction of tetrahedral voids occupies by Ag+ = 0.01 (ignore lose of tetrahedral voids due to
defects)
(vi) Coordination number of interstitial Ag+ ions due to Frenkel defects is 4

(A) 3
(B) 4
(C) 5
(D) 6

3) (A) (B) + (C) (D) (E) (F)

If B is more acidic than C, then compound F which is formed from sequential reaction of C is

(A) Anisole
(B) Lindane
(C) Mesitylene
(D) BHC

4)
Which of the following statement is correct for given chemical reactions?

(A) Compound E is Lactic acid.

(B) Total number of stereoisomers possible for E are 4.
(C) D will give +ve iodoform test with hypoiodite ion.
(D) All of these

SECTION-I (ii)

1) Which of followings is/are correct?

(A) In leaching of alumina, excess HCl(aq.) can not be used in place of CO2.
(B) CO & CO2 gases are evolved in Hall Heroult electrolytic process
(C) Tellurium is one of the components of anode mud in electrolytic refining of Cu.
(D) Zone refining is based on fractional crystallisation.

2) ;

Heat capacity of A(g), B(g) and C(g) are assumed to be temperature independent.

Which of the following is/are correct ?

Given ℓn5 = 1.6, ℓn 3 = 1.1, ℓn 20 = 2.98, R = 8Jmol–1K–1

(A) Reaction is non spontaneous at standard pressure and at 500K

(B) At 300K, ℓn KP = 4.17
(C) At near to 600K, KP will be equal to 1
At constant temperature, if volume of container is reduced, then there is no effect on
(D)
equilibrium concentrations of any component, since Δng = 0

3) m-chlorobenzaldehyde
Correct IUPAC name of B is/are

(A) 2-nitro-4-chloro Toluene

(B) 1-nitro-2-methyl-4-chloro Benzene
(C) 4-chloro-2-methyl-1-nitro Benzene
(D) 5-chloro-2-nitro Toluene

SECTION-I (iii)

1) Consider products of following reactions

List-I List-II

CoCl2 + KNO2 + CH3COOH One of product is d2sp3

(P) (1)
→ hybridised.

One of product is colored gas

(Q) Zn + HNO3 (conc.) → (2)
at room temperature.

One of product is white

(R) PbS + O3 → (3)
precipitate in water.

One of product is
(S) NaBH4 + I2 → (4) paramagnetic gas at room
temperature.
 None of the product is
(5)
paramagnetic.
(A) P → 1,3;Q → 2,4;R → 3,4,5;S → 2,4
(B) P → 1,2;Q → 2;R → 3,5;S → 2,5
(C) P → 1,4;Q → 2,4;R → 3,4;S → 5
(D) P → 1,5;Q → 3,4;R → 3,4;S → 5

2) At 298K, a galvanic cell is constructed as follows:

Pt(s) |H2(1atm)|HA(0.1M), NaA(0.1M)|| AgCl (saturated solution)| Ag(s)
Ka of HA = 10–5, Ksp of AgCl = 10–10, Kf of [Ag(NH3)2]+ = 108
Volumes of solution in both the compartments are 1L.

(Use : , , log3 = 0.50, log2 = 0.30)

List-I List-II

(P) Initial EMF of cell (1) 0.548V

(Q) Initial E(Anode) (2) 0.80V

EMF of cell if 0.05 moles of

(R) NaOH(s) is added to anodic (3) 0.30V
compartment

EMF of cell if 2 moles of NH3

(S) is added to cathodic (4) 0.83V
compartment

(5) 0.623V
(A) P → 2;Q → 3;R → 1;S → 4
(B) P → 2;Q → 4;R → 3;S → 1
(C) P → 2;Q → 1;R → 3;S → 4
(D) P → 2;Q → 3;R → 4;S → 1

3)

List –I List-II

(P) p-cresol (1) not give NaHCO3 test positive

(Q) p-hydroxy anisole (2) Highest pka

(R) Sulphanilic acid (3) Least acidic

(S) Carbolic acid (4) Least pka

(5) Exist as zwitter ion

(A) P → 2;Q → 3,4;R → 1,2,5;S → 2
(B) P → 3;Q → 2;R → 4,5;S → 1
(C) P → 1;Q → 2,3;R → 4,5;S → 1
(D) P → 1;Q → 4;R → 1,3,5;S → 3
 SECTION-II

1) (I) When chromite ore is fused with Na2CO3 in free excess of air, the mol ratio of combination of
chromite ore, Na2CO3, and O2 is x1 : x2 :x3 respectively in formation of sodium chromate (x1, x2 and
x3 are the smallest integer in balance reaction).
(II) Atomic number of 3d element with highest (except Sc) is x4,

then find the value of .

2) (I) Oxidation state of Mo in canary yellow precipitate is x1.

(II) When CuS is dissolved in HNO3, mol of NO produced per mol of CuS are x2.
(III) Sum of oxidation state of Fe atoms in colloidal solution of prussian blue is x3.
Then (x1 – x2 + x3) is?

3) If uncertainty in position of electron revolving in first orbit of hydrogen atom is a0/2. Where a0 is
Bohr’s radius. Find minimum uncertainty in kinetic energy of electron, in eV. Energy of electron in
ground state of H is – 13.6 eV.

4) 2 mole of a non-volatile solute ‘A’ are added to 216g of water at 27°C. Vapour pressures of
solution are observed as :

Time 0 min 10 min 20 min

Vapour pressure of solution 6P0/7 4P0/5 3P0/4

P0 = Vapour pressure of pure solvent.
A is dissociated as : A(aq) → 2B(aq) + C(aq)
‘B’ and ‘C’ are also non-volatile and soluble in water. Find rate constant for this reaction?
[Unit of rate constant should be mol min–1 or min–1 or mol–1 min–1 or mol–2 min–1]

5)
(Given: B is a structural isomer of Terephthalic acid.)
If number of contributing resonating structures of A are x and degree of unsaturation of D is y,
then x + y is?
6)
The Sum of oxygen atoms present in molecules D and H are ?

PART-3 : MATHEMATICS

SECTION-I (i)

1) If , then the
number of trailing zeros at the end of n is :

(A) 0
(B) 1
(C) 2
(D) 3

2) Let x, y, z be integers such that

0 ≤ x ≤ 80, 0 ≤ y ≤ 80, 0 ≤ z ≤ 80 and x + y + z ≥ 170.
The number of ordered triples (x, y, z) satisfying the above condition is :

(A)

(B)
(C)

(D) None of these

3) Let A(2, –1, 4) be a point in three-dimensional space. Let the plane P be given by 2x + y – z = 7

and the line L be defined as . The distance of the point A from the line L,
measured parallel to the plane P, is equal to :

(A)

(B)

(C)

(D)

4) Let f(x) = x3 + 3x2 + 6x + 2009 and then the number of

solutions of g(x) = 0 is/are :

(A) 0
(B) 1
(C) 2
(D) 3

SECTION-I (ii)

1) Let for n > 1, n ∈ N, I2n = and I2 = , then which of the

following is/are true :

(A) 4I2 + I4n = 4002

4I2 + I4n+2 =

(B)

(C) 4I2 + I4n = 2001

4I2 + I4n+2 =

(D)
2) Let h(x) = sin–1 and g(x) = x4 – 2x3 + x2 + 4.
h(x) increases in (–∞, a1) ; h(x) decreases in (a1, ∞)
g(x) decreases in (–∞, a1) ; g(x) increases in (a1, a2)
g(x) decreases in (a2, a3) ; g(x) increases in (a3, ∞)
Let A and B be the point of intersection of tangent at x = a1 to the curve g(x) with the line x = a1 and
x = a3 respectively.
Let D and C be the point of intersection of tangent at x = a2 to the curve g(x) with the line x = a1 and
x = a3 respectively.
Join BC and AD with straight line. Which of the following is/are true :

(A) Let number of points of non-differentiability of y = |h(x)| be a4. Then 2(a1 + a2 + a3 + a4) = 9
Area of quadrilateral ABCD is
(B)

(C) Area enclosed by y = h(x) and x-axis is loge 4

(D)
Area enclosed by y = h(x) and x-axis is – ℓn2

3) Let < an> and < bn > be the arithmetic sequences each with common differences 2 such that a1 <

b1 and let cn = , dn = . Suppose the point An (an, cn) and Bn (bn , dn) for every 'n' (n ≥ 1) are
2
lying on the parabola C : y = px + qx + r where p, q, r are constant. Then which of the following
is/are true

(A)

(B)

(C) If r = 0, then (a1, b1) = (0, 2)

(D) If r = 0, then (a1, b1) = (1, 3)

SECTION-I (iii)

1) A variable plane cuts positive x-axis, y-axis and z-axis at points A, B and C respectively such that
volume of tetrahedron OABC remains constant and equal to 32 cubic units where O is origin of the
coordinate system.

List–I List–II

(P) Locus of centroid of tetrahedron is (1) xyz = 24

(Q) Locus of point equidistant from O, A, B, C is (2) (x2 + y2 + z2)3 = 192 xyz

(R) Locus of foot of perpendicular from origin to plane is (3) xyz = 3

If PA, PB and PC are mutually perpendicular then locus

(S) (4) (x2+ y2 + z2)3 = 1536 xyz
of P is
 (5) xyz = 12
(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 3;Q → 2;R → 1;S → 4
(C) P → 3;Q → 1;R → 2;S → 4
(D) P → 3;Q → 1;R → 4;S → 2

2) If x + [y] + {z} = 12.7

[x] + {y} + z = 4.1
{x} + y + [z] = 2 then ([.] = G.I.F. , {.} = F.P.F.)

List–I List–II

(P) {x} + {y} = (1) 3

(Q) [z] + [x] = (2) 7.7

(R) x + {z} = (3) 1

(S) z + [y] – {x} = (4) 2

(5) 1.1
(A) P → 1;Q → 3;R → 2;S → 5
(B) P → 3;Q → 1;R → 2;S → 5
(C) P → 3;Q → 1;R → 5;S → 2
(D) P → 2;Q → 1;R → 3;S → 5

3) If Z is any complex number and z2 + az + b = 0, (b ≠ 0) has two roots and each of which has unit
modulus, then :

List –I List-II

(P) Greatest value of |a| (1) 0

(Q) |b| (2) 1

(R) (3) 2
Least value of , where [.] denotes G.I.F.

(S) (4) 3
Greatest value of , where [.] denotes G.I.F.

(5) 4
(A) P → 3;Q → 2;R → 1;S → 5
(B) P → 2;Q → 3;R → 1;S → 5
(C) P → 3;Q → 1;R → 2;S → 5
(D) P → 3;Q → 2;R → 5;S → 1

SECTION-II
1) Two persons A and B decide to meet at a particular place between 9 AM and 1 PM. Each person
arrives at a random time during this interval, independently of the other, and waits for no longer
than 1 hour for the other to arrive. If the other person does not arrive within this waiting time, they
leave. If the probability that A and B meet is P, find the value of 64P.

2) If a1, a2, a3, ......... are in HP. ai > 0 for each i then is (where a
and b are co-prime natural number then determine (b –a). (where a1 = 1, an+1 = 8).

3) Let there be two circles with one touching x-axis at A(2, 0) and has radius 1 unit and other
touching x-axis at B(6, 0) such that x-axis is the internal common tangent of two circles. Let C and D
be the centre of first and second circles respectively. Again let P(6, 2) be a point on a line
perpendicular to CD and bisecting AB. If PA and PB intersect circles at E and F respectively then
find the length PF.

4) Solution of differential equation x3 = y3 + y2 is cxy = y + k (c is arbitrary

constant) then find the value of k.

5) If two of the lines represented by ax4 + bx3y + cx2y2 + dxy3 + ay4 = 0 bisects the angle between
the other two and vice versa, then (c + 6a)2 + (b + d)2 equals :

6) Let a, b, c, d be the roots of x4 –x3 –x2 – 1 = 0. Also consider g(x) = x6 – x5 – x3 – x2 – x. Then find the
value of g(a) + g(b) + g(c) + g(d).
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B D D D

SECTION-I (ii)

Q. 5 6 7
A. B,C B,C B,C,D

SECTION-I (iii)

Q. 8 9 10
A. A D B

SECTION-II

Q. 11 12 13 14 15 16
A. 163.40 to 163.50 22.22 to 22.25 0.66 to 0.67 1.00 16.80 2.70

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. D C C C

SECTION-I (ii)

Q. 21 22 23
A. A,B,C,D A,B C,D

SECTION-I (iii)

Q. 24 25 26
A. C D C

SECTION-II

Q. 27 28 29 30 31 32
A. 5.80 10.33 to 10.34 27.00 to 28.00 0.05 7.00 7.00

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 33 34 35 36
A. B A C C

SECTION-I (ii)

Q. 37 38 39
A. B,C A,B,C A,B,C

SECTION-I (iii)

Q. 40 41 42
A. C B A

SECTION-II

Q. 43 44 45 46 47 48
A. 28.00 3.00 8.00 1.00 0.00 6.00
 SOLUTIONS

PART-1 : PHYSICS

1)

= 4.13 × 10–15

2)

= =

3)

After S1 is closed,

After S2 is closed,
4)
For A, mgsinθ – T = ma1 ....(1)
For C, T = ma1 ......(2)
For B, Tension at all points ultimately cancels
2mgsinθ = 2ma2 .......(3)
⇒ a2 = g sin θ
Solving (1) and (2),

a1 =

5)

(A)
= 16 × (7.89 – 7.07) = 13.12 MeV
(B)
= 238 × (8.50 – 7.57) = 221.34 MeV
(C)
= 63 × 8.75 – 62 × 8.79 = 6.27 MeV
(D) Energy required to disintegrate
= 4 × 7.07 = 28.28 MeV

6) (A) 50 × 10–6 × 10 × 103 = 0.5 V

(B) 50 × 10–6 × 200 × 103 = 10 V

(C)

7)

The phase difference between pressure standing wave and displacement standing wave is .

8)

(1) z = |8i – 4i + 3| = 5
(2)

(3)

(4)

9) where m = tanθ
= constant

= constant

10)

(P)

(Q)
(R)

(S)

11)

T = 100 N

ℓ1 = 0.6, ℓ2 = 0.9

3n = m
⇒ n = 1, m = 3

12) , x = 8 m, y = 6 m
x2 + y2 = 102

16 × 5 + 12 =0

m/s

8 × 8 + 52 + 6 × + =0

6 = – 64 – 25 –

= m/s2 = – 22.24 m/s2

Hence, magnitude of acceleration of B is 22.24 m/s2

13)

sin2(2ϕA) = 8 × 0.03125 = 0.25

2ϕA = 30°
ϕA = 15°
0 < ϕ < 15° ⇒ α < αA
15° < ϕ < 45° ⇒ α < αA

⇒ required probability =

14)

No change in angle ⇒ no change in shape

⇒ same change in all three sides
⇒ same α for all sides
⇒K=1
 15)

⇒ Q1 = c(361 – 323) = 38 c
Q2 = c(323 – 289) = 34 c
⇒ W = 4c = 4 × 1 × 4200 J = 16.8 kJ

16)

PART-2 : CHEMISTRY

17) [Co(NH2CH2CH2O)2Cl2]– = 5
[Pt(NH3)(H2O)Br(Py)]Cl = 3

18) Ag+ displaced to interstitial sites

Ag+ missing due to schottky defect

Br– missing due to schottky defect

No. of Ag+ at lattice sites = N – 0.02N – 0.005N = 0.975N
Total number of Br– = N – 0.005N = 0.995N

Total number of tetrahedral voids = 2N

Fraction of tetrahedral voids occupied

Coordination number of tetrahedral void = 4
19)

20)

21)

Refer class notes.

22) (A)

= – 90 J mol–1 K–1
ΔG° = ΔH° – TΔS°

(B) ΔG° = ΔH° – TΔS° = – RT ℓn KP

= 16.67 – 12.5 = 4.17

(C) ΔG° = – RT ℓn KP = 0
 ΔG° = ΔH° – TΔS° = 0 ∴ ΔH° = TΔS°

– 40000 + 20(T – 300) = T(–100 + 20 ℓn )

20T – 46000 = T(–100 + 20 ℓn )

T – 2300 =

T – 2300 + 5T =

6T – 2300 =

(D) on decreasing volume concentrations increases

23)

24)

(I) CoCl2 + KNO2 + CH3COOH → K3[Co(NO2)6]↓ (yellow) + NO + KCl + CH3COOK + H2O

(II) Zn + 4HNO3 → Zn(NO3)2 + 2NO2 + 2H2O
(III) PbS + O3 → PbSO4 + 4O2
(IV) NaBH4 + I2 → B2H6 + NaI + H2

25) (A) H2 + 2Ag+ → 2H+ + 2Ag

PH = 5
[H+] = 10–5M
[KSP] = S2 = 10–10M
[Ag+] = S = 10–5M

Ecell = 0.80V

(B) = – 0.06 log[H+] = 0.06 × 5 = 0.30 V

(C) HA + NaOH → NaA + H2O
0.1 0.05
0.05 0 0.15
 = 0.80 + 0.06 log3 = 0.83V
+ –
(D) AgCl(s) Ag (aq) + Cl (aq)
Ag+ + 2NH3 [Ag(NH3)2]+ Kf = 108
S 2
x 2–2S S

KSP × Kf = x × S ×

⇒ S = 0.2 – 0.2S
1.2S = 0.2

x = 6 × 10–10

= 0.80 – 0.06 × (5 – log6)

= 0.80 – 0.06 × 4.2
= 0.548V

26) (1) (2)

(3) (4)

27) (I) 4FeCr2O4 + 8Na2CO3 + 7O2 → 8Na2CrO4 + 2Fe2O3 + 8CO2

(II) x4 = 29

28) x1 = 6

x2 = (3CuS + 8HNO3 → 3Cu(NO3)2 + 2NO + 3S + 4H2O)

x3 = 5

29)
30) t = 0 = ;

t = 10
x = 0.5
A → 2B + C
2 – 0.5 1 0.5

t = 20
x=1
A → 2B + C
2–1 2 1
So reaction follows zero order kinetics.
x = kt
0.5 = k × 10
k = 0.05 molmin–1

31)
 32)

PART-3 : MATHEMATICS

33)
Using the standard binomial summation identify,

The number of trailing zeros equals the power of 5 in n.

υ5(51!) = 12, υ5(10!) = 2, υ5(41!) = 9
υ5(n) = 12 – (2 + 9) = 1

34) Define
x = 80 – x, y = 80 – y, z = 80 – z.
Then x, y, z ≥ 0 and
x + y + z ≥ 170 ⇒ x + y + z ≤ 240 – 170 = 70
So we count non-negative integer solution of
x + y + z ≤ 70
Introduce a slack variable t ≥ 0.
x + y + z + t = 70
Number of solutions:

35) Take a general point on L:

Q(1 + 3t, – 2 – 2t, 5 + t)
Since distance is measured parallel to plane P,

(3t – 1, – 2t – 1, t + 1).(2, 1, –1) = 0

⇒ 3t = 4 ⇒

Thus,

36) f'(x) = 3(x + 1)2 + 3 > 0

f(x) be an increasing function
f(1) < f(2) < f(3)
let f(1) = a
f(2) = b
f(3) = c
a<b<c

g(x) = 0
⇒ (x – b)(x – c) + 2(x – a)(x – c) + 3(x – a)(x – b)
Now
(x – b)(x – c) + 2(x – a)(x – c) + 3(x – a)(x – b) = 0

Two solutions.

37)

I2 =

⇒ 4I2 =

4I2 + I4n =
= dx

= = 4002 – 2001 = 2001

4I2 + I4n+2 = dx

⇒ =

= dx

put 2x = t ⇒ =2⇒ . dt

38) h(x) = – cos–1

h(x) =
Clearly a1 = 0

g'(x) = 4x3 – 6x2 + 2x

⇒ 2x(2x2 – 3x + 1)
= 2x(2x – 1)(x – 1)
⇒ a1 = 0, a2 = ,a3 = 1, a4 = 3

g = – + +4= +4

∴ BC = , AB = CD = 1

∴ Area of ABCD is = ×1=

Area = dx = dx

=π – 4

39)

cn = a1 + a2 + .... + an(d = 2)
dn = b1 + b2 + ...... + bn(d = 2)
cn = + qan + r
cn–1 = + qan–1 + r
from (1) and (2)
cn – cn–1 = p( – ) + q(an – an–1)
an = (p(an + an–1) + q)(an – an–1)
put n = 2 a2 = d[p(a2 + a1) + q]
a3 = d[p(a3 + a2) + q]
a3 – a2 = d[p(a3 – a1)]

cn = + qan + r
a1 = c1 = + qa1 + r
c2 = a1 + a2 = + pa2 + r
a2 = a1 + 2
2a1 + 2 = p(a1 + 2)2 + q(a1 + 2) + r
2a1 + 2 = ( + qa1 + r) + 4a1p + 4p + 2q
2a1 + 2 = c1 + a1 + 1 + 2q
2a1 + 2 = 2a1 + 1 + 2q

If r = 0 c1 = p + qa1
c1 = a1 = + a1
2
a1 – 2a1 = 0 ⇒ a1 = 0, 2
d1 = p + qb1 (d1 = b1)

b1 = + b1
b1 = 0, 2
a1 < b1 (a1 = 0 & b1 = 2)

40)

(P) Given abc = 32 ⇒ abc = 192

where A(a, 0, 0), B(0, b, 0), C(0, 0, c)

(α, β, γ) = ⇒ 64 αβγ = 192

⇒ locus is xyz = 3

(Q) (α, β, γ) =
As abc = 192 ⇒ 8αβγ = 192 ⇒ xyz = 24

(R) Equation of plane is

foot of perp = (α, β, γ) =

⇒ 192 xyz = (x2 + y2 + z2)3

(S) Let P ≡ (x, y, z)
PA ⊥ PB ⇒ (x – a)(x) + y(y – b) + z(z) = 0
⇒ x2 + y2 + z2 = ax + by ........ (i)
PB ⊥ PC ⇒ x2 + y(y – b) + z(z – c) = 0
⇒ x2 + y2 + z2 = by + cz ........ (ii)
PC ⊥ PA ⇒ x(x – a) + y2 + z(z – c) = 0
⇒ x2 + y2 + z2 = ax + cz ........ (iii)
⇒ ax + by = by + cz = ax + cz
⇒ ax = cz and by = ax ⇒ ax = by = cz
from (i) 2ax = x2 + y2 + z2
As abc = 192 ⇒ 8(192)xyz = (x2 + y2 + z2)3

41)
(i) + (iii) – (ii) gives 2{x} + 2[y] = 10.6
⇒ {x} = 0.3, [y] = 5
from (i) [x] + 0.3 + 5 + {z} = 12.7
⇒ [x] + {z} = 7.4 ⇒ [x] = 7, {z} = 0.4
from (ii) 7 + {y} + [z] + 0.4 = 4.1
⇒ [z] + {y} = – 3.3 ⇒ [z] = – 4, {y} = 0.7

42) z1 + z2 = –a ; z1z2 = b
|a| ≤ |z1| + |z2|
⇒ |a| ≤ 2 ; |z1||z2| = |b| = 1
iα iβ
z1 = e , z2 = e

= = + + 2 = 2 + 2cos(α – β)

⇒ is non negative real number

43)

Let x and y be the arrival times (in minutes after 9 AM) of A and B respectively.
Then 0 ≤ x, y ≤ 240.
They meet if the difference in arrival times is at most 60 minutes:
|x – y| ≤ 60
The sample space is a square of area 2402.
The non-meeting region consists of two right triangles of side 180, total area 1802.

Hence,

44) E =

let =A =B

E= =

E=n

– =d

E= ⇒ E= =–

also = + nd ⇒d=–
E= =

45)
clearly P lies on radical axis
⇒ [Link] = [Link]

⇒ = = =
[Link] = PT2

⇒ PE = =

46) =

= + put =v

v+x = v3 + v2

⇒ x = v(v2 – 1) + v2

log(v + ) – log v = log x + c

log (v + ) = log y + c

log – log y = c

log =c

y+ = cxy
47)

We know bisectors are mutually perpendicular

⇒ ax4 + bx3y + cx2y2 + dxy3 + ay4
= (ax2 + pxy – ay2) (x2 + qxy – y2)
comparing b = aq + p ; c = pq – 2a ; d = –p – aq
⇒ b + d = 0, pq = c + 2a

is same as x2 + qxy – y2 = 0

⇒ pq = – 4a ⇒ –4a = c + 2a
c + 6a = 0

48)

x4 – x3 = x2 + 1
g(x) = x6 – x5 – x3 – x2 – x = x4 – x3 + x2 – x2 – x = x2 – x +1
g(a) + g(b) + g(c) + g(d) = Σa2 – Σa + 4
= (Σa)2 – 2Σab – Σa + 4
= 1 – 2(–1) – 1 + 4 = 6