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The document discusses various chemical reactions and methods for preparing aldehydes and ketones from different organic compounds, including alkynes and aromatic compounds. It details specific reactions such as the Gatterman-Koch formylation and the use of Grignard reagents, along with catalysts and conditions required for these transformations. Additionally, it covers reduction reactions and aldol condensation processes relevant to the synthesis of these carbonyl compounds.

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Vidya nayak
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5 views13 pages

Notes

The document discusses various chemical reactions and methods for preparing aldehydes and ketones from different organic compounds, including alkynes and aromatic compounds. It details specific reactions such as the Gatterman-Koch formylation and the use of Grignard reagents, along with catalysts and conditions required for these transformations. Additionally, it covers reduction reactions and aldol condensation processes relevant to the synthesis of these carbonyl compounds.

Uploaded by

Vidya nayak
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
2s\ a Preparatfon_ot Wy = v PAN : goon \ tricavboxyire Actd ony noes “tthe actd” A \-on 4 aldehyde ¢— lexpiate Kenn “Reduttfan renctfon: oe _ gavolves the _converston of acythagde fro _atdehyde ding the catalyst Htodlar (Haba =< =C and Ba,50u}guolte ‘A_snte teacRoon BaS0y ofeon'A_ fhe small: Rot 20 - — Lada _aaaenenes _ te [Pa-c [Bas Het + ma c fo (Undlar catalyst 7 CS aldenyde) - 8 DL wnt, oo -Pd- lavinoltne i C+ - “(Benz adeh yde_ by ths method. Both. “aromotfe and _altpnatte “aldenyde can be prepara Expain. tne preparation ck_aldehyde a ANd ketone from. Alkyne using mercurous sulphate and dilute 1250, (USNG tavtomerigen method - CShifing 4 TW bond on Rest_carbon ato rn gives der metten _ S{_betore, ARE 2nd C atom .aldeny de-) : | gprwrerrerreseeweggp ts os” Ans. Whee alkyne teach wth mercuyour sulphate ang Adute Uysay TH unetar goes Nayetvetyate 1O TO) enol Oo Tovthoy tavtomertany th forrs atdehqde Gr Ketyyy eR weer nut! . \ “ Mar PE HN tO Rae Magen Leen, AL (propane) hor My 804 Kevortoat alhynve) Chyavoty ats) o Sy Wo Y Mace cs ce tts » Mace ch cet (enol formattor) own . v| Hac ~ te cu Qetrernmy tgc~ a Clg (Ketone) a\nac- cf cn WNQ" Propyns MAN HASOy ron Mace CF Cm tHed Fe tec~ Je Coat athe Yoni " LS = CH Xautonon ? tHgC— tt -H HR, mee eC reductton reaction: - in Stephen reduction reaction AURYL Mtr che! Qley) suntds ts Conwerted into aldehyde + se ~ Reaction takes place tn the Presence ef nascent Audrogen and Act actd using when Cyotde ox ntertas react with ariqnard seogent Ht giwes tormartien Oj —_____kstene “RU requires ameiss of water fer formatien gy + + RCC SN UM 8 fb LL Ces Same tex 9A at st —_ 5 = Cry 9 LRetene) S 7 Name 8 | cS pte ~ —* Ma Be Nt 4 0) TEE hy Q > camlin [Link] alkyl cytntde veacl with gtgnard reagent 1 aives the formation of Complex {N the PTESCNCE of avy ether on further hydrotysts it gtves the Formers, of ketone a] Expiain the preparation of ketone from griqnard meagent using cadmtum chloride and Acyl nalide Ans WHEN griqnard reagent react wth cadmium chlorfde % the presence ef dry etner to Jorn Harkurcadmtum on furthur reach with acy! haltde Cadmium ichlortde fs regenerated and ketone ‘s formed: - : ap ca : a dry - 2 - / 943) .2H3¢ —Mg-Br + 04 E coees het oe Axiqnard reagnord HOG He Oncan, -Zttge® “2mngBr —_ (Codrntum chtortde)._ “R78-8) hi T : cls br . BFIRO or ganometaic CA + Qing 4 Hy ry 4 Compound _& dkmethyleadceturs) ° var We e 22h cms tun 2\ Cac 2 Wargo dig <0” iat “ 7 CHS (acy) chloride) ‘ - \ (Bfenethyt codent etl : O04) chlortde 7 Cd etyt2 (Hs fay, (aryl atyite ketony) i = Ce it] HaC-mg -@r ii phe ~a . eo t 4, SMa BY 4 ep Me pet ay My & eth i ° ped Cy da rcacls CHy~ 8 ~cy zl (ace chiorfde) 2 4 8] Deparation of aldenyde. A Explain gatterman= Koch formylatton Acs} When Benzene reacts ufth Carbon monaxtde tn presence OF H¢l_endas reagent win presence of Anhydrous ACs “ft _qives Aormarton_ef Benzaidehyde - beg - - Q —————> a — mS Rivhye AIC ah _-[Bemene) (eavton mncnoxide) cand) (Benza\denyde) - | ___ Mechantom’-) Protonation of aca Bete. of. acajpon mene 0 form ——— €alton_and_jormyt eniortde CH=C=0} - 2 ® or, , f= =O eet f= ceo. AE ue Cae8 = ‘Comenmennte ~ Cl & Explain Etaya reactfon Crd When toviene reacts ufth chromy) chioride fn dhe Preserce of carbon dfsulphtte . ft gives the fortro. of chromium complex on further actd hy drolysts |p, atves formation of bentytadenyde n fad at , Both By Uf Z\ bis Co oe - \l +- an * Qt + Ft aN {Toutene) _ _(ehromytchlorte) ~ Hw = aiaeeee ee : CS a A Ta Ct oe,cl,4) etae chain _chiorination: _ - Jn ants reactan tovlene veacts with ehtovtne Yn the presence of UV Kant hy photochemical read’ it dives tne formation of benzal chloride on further hydrolyss — tr dives fornation of ben2aldeh ycte = 4 aa" + ct=a a a A_ dt. nen ratton) a fea aie? (Ben2al chloride n He -E=6 2c hud os Ke Benzaidenyde (comin nr} Aldol condensa\tan-In aldol condensation tnere must ibe presence Of & Wydrogen cttom: In setf aldol condenacah Acelataehude react with sodtum Nydroxtde to form atdo\ taduct whfch on fumher dehydration undergoes d6 Lelioinadtton +0 fore enal+ 2 _ Setf aldol Condensation: Cénal) sf Mechanism- _ “ =i Remaxat_of_ SoRators from decarbon. aterm 48 focm_€arbore 4 = nw _ R—o7c=8 BE 0 + 9) 1 6 _ u ) h ~ - | tt . ke y arbor) - = : _.| Cacetaidenyde) ; Cenotate fon) — Es a oS ~ Asatte st 7 gn ts 6 —— Hac—cHach~CM0 Cenal) , 1 Gossed aldol:- 4 nr 0 CH 4 H-d— rot Naol Scr cab 72 FT Heg To mcHg Tr gle HE C=O WOH i on 4 CAidenyde) (Ketone) TROY Hao + Hye - C= Co CHO Cs 4 (onal) ¥ Mecharitamt- JJRemovat of 4Hatom from d-carbon atom, Xo form “carboanton':- 4 woo tag NO ete y ¢ =O ——4#— + Ht Ccavboanton) —_Cacetaldenyad 2) FYtack of elecrophtie_ + —__ Cea HOW i M43 8 Mec e ea da deg —— Hac - to § —¢ \ 8 _ (Ketone) Ccarboanton) | Cenol atefon) » 3 ‘Hetongiton: 3A Mac~ = ca cho Hac=thCXe=0 + Noon we oye fe (ad aldol pad avet) - Ms, A Bettattn ——” ; on 1 Hoos Ha c-e =t-c=0 (3> methy, But -2-en-!-al) Anc\\whe 9 alkyl eftride reacts wth ucter % unde eces Bisa ct \} Expats ine pr@oar Jateur ottyile ar ta. foren a Compound oxime: Tt undergoes tasters afro farm _amfde and on further nydrotuss Tt CarPoxulfte actd and ammenta fonr< Wherated tn fore o= Victg— can 4+ 4,0 - Hgc -C=N—« Son } a QOH Coxime —| Cmetnyteynice) at = cexime = - pe —* wec—e2 —@¢2y_ automersn — Juin = figco Canon SO Hse ER Coxtme) Camere) Near eycte ,—* SCI + HO Ge 8 = [Wselwt tac Hon + NH T IN We OWT (care xyitc acta): Cehenet cynide) ‘ - Hoo > KA flon yNWaA | “Cay box ytte Qe) Cannizavo Reactton Tn thts veactton 2 meies of 2 RN madison reacts wilh & SO Males OT saxtfOr Puetrortde to Foon arcmace ANA BOATUAY Ball OF CarhEryite Acti HVE favolves the absentee of I ydegen atoor A, An “VV rhe QNaeH ACH eet Ect yy ON Moroat rented WY tet) Ny | Nevnnratlelqae SVG vad aad SEEN CAG Aa Si + Mechantsm Attack of otf fon on formatdenude ot _carbonyit carbon to form alkorfde - 4 oO eo \ 2 nec—y OR, yd -u ormaldenyde) OH . ; 6 3} Formation of hydride ton (ii) and Carboxylte acta. i 62° $ ° q Ween aH? on He dt ee dan o-\ (Hydride 0H Yormte_acfd). Calvoxt de on) Yon) : 3) ; te | § pyde ett carbony } Pttack of hydrtae (oan fend sen ¢ & * att ~ a — =~ p) eco: t a x Qanlee ne es a r « H * Hs = (Huaraz one} eur 1 dia «pA ee Nat Tt CHy Bis HL, “i ye sie hase ae (methane) : Sa si sigue Smear A, Aerie Wy + tC CH Es

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