VSEPR Lab
Part A
Molecule Created
Formula: XeF₄
Electron Geometry: Octahedral
Molecular Geometry: Square Planar
Lewis Dot Structure: Xenon is the central atom with four Xe–F single
bonds and two lone pairs on Xe positioned opposite each other
(trans), giving six electron domains total.
Electron vs. Molecular Geometry
• Electron geometry describes the arrangement of all electron
domains (bonding pairs + lone pairs) around the central atom.
• Molecular geometry describes the arrangement of only the
bonded atoms, ignoring lone pairs.
Difference: Lone pairs take up space and affect shape but are not
counted as atoms in molecular geometry.
Bond Angles
• Bond–bond angles: 90° (and 180° across the square)
• Bond–lone pair angles: Slightly less than 90°
Explanation: Lone pairs repel more strongly than bonding pairs,
slightly compressing angles between bonds near lone pairs.
Part B
Water (H₂O)
• Electron Geometry: Tetrahedral
• Molecular Geometry: Bent
• Model bond angle: ~109.5°
Real bond angle: 104.5°
Explanation: In the real toggle, lone pair–lone pair and lone pair–
bond repulsions are stronger and unequal, compressing the H–O–H
angle below the ideal tetrahedral value.
BrF₅
• Electron Geometry: Octahedral
• Molecular Geometry: Square Pyramidal
Bond Angles: Approximately 90° and 180°
Discrepancy? A smaller discrepancy than water. BrF₅ has only one lone pair, so the
distortion is less dramatic than in water, which has two lone pairs.
Why No Discrepancy in Part A?
In XeF₄, the two lone pairs are opposite each other, balancing repulsion evenly. This
symmetry prevents significant bond angle distortion.
Part C – Ammonia (NH₃)
• Electron Geometry: Tetrahedral
• Molecular Geometry: Trigonal Pyramidal
Explanation: The electron geometry is tetrahedral because there are four electron domains
(3 bonds + 1 lone pair). The molecular geometry is trigonal pyramidal because the lone pair
is not counted as an atom, leaving three bonded atoms forming a pyramid.
Part D – Triple Bond Molecule
Molecule Created
Example: CO₂ or N₂
Hybridization
Hybridization: sp
Explanation of Hybridization
Hybridization describes how atomic orbitals mix to form bonding domains. In sp
hybridization, one s orbital and one p orbital mix to form two linear bonding domains,
resulting in a linear electron geometry with 180° bond angles.