18-05-2025

1803CJA101002250001 JM

PART-1 : PHYSICS

SECTION-I

1) The potential energy of a particle varies with distance x from a fixed point as where A
and B are constants. Then the dimension of

(A)
(B)
(C)
(D)

2) Consider expression where P is power, x is position coordinates and t is time. What is

dimensional formula for the constant b.

0 0
(A) M-1L T
0
(B) M-1L T2
0
(C) M-1L1T
(D) M-1L1T2

3) Dimensional formula for the universal gravitational constant G is

(A) M–1L2T–2
0 0 0
(B) M L T
(C) M–1L3T–2
(D) M–1L3T–1

4) (V – b) = RT represents the equation of state of some gases. Where P is the pressure, V

is the volume, T is the temperature and a, b, R are the constants. The physical quantity, which has

dimensional formula as that of , will be :

(A) [M–1L2T–2]
(B) [M–1L–1T2]
(C) [M–1LT2]
(D) [M–1L–2T–2]
5)

The wavelength associated with a moving particle depends upon pth power of its mass m, qth power of
its velocity v and rth power of Planck's constant h. Then, the correct set of values of p, q and r is (E =
hν, E is the energy of a wave, ν is frequency & h is planks constant)

(A) p = 1, q = –1, r = 1
(B) p = 1, q = 1, r = 1
(C) p = –1, q = –1, r = –1
(D) p = –1, q = –1, r = 1

6) The vector sum of the forces of 10N and 6N can be

(A) 2N
(B) 18N
(C) 8N
(D) 20N

7) If and A = B + C, then the angle between and is :-

(A) 0

(B)

(C) π

(D)

8) If then find angle between and (in degrees)

(A) 90
(B) 80
(C) 70
(D) 50

9) Force on a particle is given by F = α log(βxt), where t is time and x is distance, then [α] and [β]
are respectively :

(A) LT–2, LT–1

(B) MLT–2, L–1T–1
(C) ML2T–1 dimensionless
(D) MLT–2, dimensionless

10) Amongst the following quantities, which is not a vector quantity?

(A) Force
(B) Acceleration
(C) Temperature
(D) Velocity

11) A gas bubble formed from an explosion under water oscillates with a period proportional to
PadbEc, where P is the static pressure, d is the density of water and E is the energy of explosion.
Then, a, b, c are respectively,

(A) 1, 1, 1

(B)
, ,

(C)
, ,

(D) , ,

12) The ratio of maximum and minimum magnitudes of the resultant of two vectors and is 4 : 3.
The relation between A and B is (A > B)

(A) A = 7B
(B) 7A = B
(C) A = 3B
(D) A = 4B

13) Position of particle is given as x = A + Bt + Esin(Ct + D) where x is in meter and t is in seconds.

The dimension of A × D is :

(A) [T]
(B) [LT–1]
(C) [L]
(D) [L–1T]

14) In a certain system of units, 1 unit of time is 20sec, 1 unit of mass is 20 kg and 1 unit of length is
20 m. In this system, one unit of power will correspond to

(A) 20 watts

(B)
watts
(C) 400 watts
(D) 1 watts

15) If the resultant of two forces of magnitudes P and Q acting at a point at an angle of is Q,
then P/Q is

(A) 1
(B) 3/2
(C) 2
(D) 4

16) Given where symbols have their usual meaning. The dimensions of a and b are
respectively.

(A) [ML–1T–1] and [MLT–4]

(B) [MLT–1] and [MLT–4]
(C) [MLT–1] and [ML]
(D) [MLT–1] and [ML–1T–]

17) If the velocity of light denoted by ' c ' , acceleration due to gravity ' g ' and atmospheric pressure
' p ' are taken as fundamental units , then the dimensions of length will be :

(A) c2/g
(B) c/p
(C) g/c
(D) c/g

18) Density of ice is 0.9 g/ cc in the CGS system of units. The corresponding value in MKS units is

(A) 900
(B) 9
(C) 0.9
(D) 9000

19)

Velocity of a particle depend on time t according to equation,

V= + bt + The a, b, c and d represents the following quantities in order :-

(A) Distance, distance, acceleration, time
(B) Acceleration, distance, time, distance
(C) Acceleration, distance, distance, time
(D) Distance, acceleration, distance, time

20) Which of the following equations holds true for the given vector triangle.

(A)
(B)
(C)
(D) None of these

SECTION-II

1) The resultant of two forces 3F and 2F is R. If the first force is doubled then the resultant is also
doubled. What is the angle between two forces (in degree)?

2) The maximum and minimum magnitudes of the resultant of two forces are 35 N and 5 N
respectively. Find the magnitude of resultant force when acting perpendicular to each other.

3)

The angle θ between directions of forces and is 90° where A = 8 N and B = 6 N. If the
resultant makes an angle α° with then find the value of ‘α’ ?

4) In a new system of units, the unit of mass is 100g, unit of length is 4 m and unit of time is 2 s. If
the numerical value of 10 J in this system is N fill the value of N.

5) A river, while flowing, sweeps along with it few boulders (stones). Assume that the maximum
mass m, of a boulder swept along by a river, depends on the speed v of the river, the acceleration
due to gravity g and the density ρ of the boulder. If m = kvagbρc where k is some dimensionless
constant, the value of (a + b + c) is ______.

PART-2 : CHEMISTRY

SECTION-I

1) The plane and point at which zero electron density exists is known as nodal plane and nodal point
respectively.
Nodal plane also refers as angular node. Number of angular nodes depends on shape of orbital only
and size of orbital has no role in it.
Based on the comprehension select the correct statement.

(A) In orbital 2 nodal planes are in xz and yz plane

(B) and have one common nodal plane
(C) one 4d orbital contains maximum 2 electrons of opposite spin
(D) one 3d orbital contains a total of 10 electrons

2) A transition metal X has a configuration in its +2 oxidation state. The metal refers to

(A) Cu
(B) Co
(C) Fe
(D) Ni

3) Which of the following element is not an isotone of ?

(A)
(B)
(C)
(D)

4) If aufbau principle is not used, 19th electron is Sc (Z = 21) will have

(A) n = 3, ℓ = 0
(B) n = 3, ℓ = 1
(C) n = 3, ℓ = 2
(D) n = 4, ℓ = 0

5) Which of the following is incorrect set of iso-diaphers?

(A) 13C and 15N

(B) 13C and 17O
(C) 17O and 14N
234
(D) Th90 and 238U92

6) The maximum number of e– with n = 4, mℓ = 0 will be:

(A) 10
(B) 8
(C) 6
(D) 12

7) Four electrons in an atom have the sets of quantum numbers as given below. Which electron in at
the highest energy level?

(A) n = 4, ℓ = 0, mℓ = 0, ms = + 1/2
(B) n = 3, ℓ = 0, mℓ = 0, ms = –1/2
(C) n = 3, ℓ = 2, mℓ = 0, ms = +1/2
(D) n = 4, ℓ = 1, mℓ = –1, ms = – 1/2

8) Spin only magnetic moment of dipositive ion of Ni is :-

(A) 2.82 B.M.

(B) 3.87 B.M.
(C) 4.89 B.M.
(D) 1.73 B.M.

9) Which of the following is correct set of isosters :

(A) CO and NO2

(B) CO and N2O
(C) N2O and NO2
(D) CO2 and N2O

10) Gaseous state electronic configuration of nitrogen atom can be represented as :

(A)

(B)

(C)

(D)

11) Which of the following has the maximum number of unpaired electrons ?

(A) Mg2+
(B) Ti3+
(C) V3+
(D) Fe2+

12) Total number of possible shells in uranium atom (atomic no. z = 92)

(A) 7
(B) 1
(C) 6
(D) None of these

13) The correct set of four quantum numbers for the valence electrons of rubidium atom (Z = 37) is:

(A)

(B)

(C)

(D)

14)

Given
(a) n=5, ml= +1 (b) n = 2, l = 1, ml = – l, ms = – l/2

The maximum number of electron(s) in an atom that can have the quantum numbers as given in (a)
and (b) are respectively :
(A) 8 and 1
(B) 25 and 1
(C) 2 and 4
(D) 4 and 1

15) The numbers of protons, electrons and neutrons in a molecule of heavy water are respectively

(A) 10, 10, 10

(B) 8, 10, 11
(C) 10, 11, 10
(D) 11, 10, 10

16) A neutral atom of an element has two K, eight L, nine M and two N electrons then electronic
configuration of the element is

(A) 1s2 2s2 2p6 3s2 3p6 3d2 4s1

(B) 1s2 2s2 2p6 3s2 3p6 3d1 4s2
(C) 1s2 2s2 2p6 3s2 3d2 3p6 4s1
(D) 1s2 2s2 2p6 3s2 3p6 3d2

17) Choose the correct option for the quantum numbers of the last electron of K+.

(A) 4, 0, 0, +1/2
(B) 3, 1, –1, –1/2

(C)
4, 1, 0, –

(D)
3, 0, 1,

18) Which of the following is not a Dobereiner triad :

(A) H, F, Cl
(B) N, O, F
(C) P, As, Sb
(D) S, Se, Te

19) IUPAC name of the element placed just after actinide series :-

(A) Unniltrium
(B) Unnilpentium
(C) Unnilquadium
(D) Ununbium
20) The IUPAC symbol for the element with atomic number 119 would be :

(A) Unh
(B) Uun
(C) Une
(D) Uue

SECTION-II

1) Total number of elements which can accomodate in the 10th period of periodic table if present.

2) Group number of an element having atomic number 100.

3) The electronic configuration of an element is 1s2, 2s2 2p6, 3s2 3p3. What is the atomic number of
the element which is just below the above element in the periodic table.

4) Total number of degeneracies possible in 4th exited state of Li+2 ion

5) How many maximum number of electrons a subshell with n = 6, l = 2 can accommodate ?

PART-3 : MATHEMATICS

SECTION-I

1) If P and Q are distinct positive integers such that PQ = 64 . Which of the following can be the
values of P + Q.

(A) 16
(B) 20
(C) 35
(D) 67

2) If m and n are positive integers, then the digit in the unit 's place of 5n + 6m is :

(A) 1
(B) 5
(C) 6
(D) 7

3) What value will be obtained on simplifying

(A)
(B)
(C) 3
(D)

4) The expression simplifies to ,

(A) 4
(B) 6
(C)
(D)

5) If polynomial p(x) = x3 + kx2 + 3x + 5 is divided by (x – 2) then remainder is 10, then value of k is :

(A)

(B)

(C)

(D)

6) The total number of ordered pair (P, Q), so that 7 3 2 P 8 3 Q is divisible by 4 and 9, is:

(A) 1
(B) 2
(C) 5
(D) 4

7) If , then a is equal to

(A) 3
(B) –3
(C) 2
(D) –2

8) Given where a and b are rational numbers then the value of a4 – b2 is :

(A) 9
(B) 3
(C) 19
(D) 17
9) If then value of 4x2 + 2x – 1 is equal to:

(A) 4
(B) 5
(C) 6
(D) 7

10) If , then is equal to

(A) 5

(B)

(C)

(D)

11) The number of solutions of equation

is

(A) 3
(B) 4
(C) 5
(D) 6

12) The value of is equal to :

(A)

(B)
(C)
(D)

13) The solution of 4x – 3.2x+1 + 8 = 0 are :

(A) 2, 4
(B) 0, 1
(C) 1, 2
(D) 0, 4

14) is equal to
(A) 9
(B) 10
(C) 11
(D) 12

15)

Number of positive integers x for which f (x) = x3 – 8x2 + 20x – 13, is a prime number, is

(A) 1
(B) 2
(C) 3
(D) 4

16) If a, b, c are real and distinct numbers, then the value of is :

(A) 1
(B) –2
(C) 2
(D) 3

17) The number of rational numbers in the list e, π2, e2, , 3.14 are

(A) 1
(B) 2
(C) 3
(D) 4

18) The expression is simplified to :

(A) a16
(B) a12
(C) a8
(D) a4

19) If the expression N = (2 + 1) (22 + 1)(24 + 1) (28 + 1) .... (21024 + 1) is equal to 2n – 1 then n is
equal to

(A) 1023
(B) 4096
(C) 2048
(D) 2047
20) If p(x) is a polynomial of degree 3 with leading coefficient unity such that p(1) = 2, p(2) = 3, p(3)
= 4, then the value of p(4) is equal to

(A) 1
(B) 11
(C) 5
(D) None of these

SECTION-II

1) If , then find the value of x

2) If the polynomial and leave the same remainder when divided

by (x–3), then find the value of a+9

3) If , then the value of 2x3 + 6x is :-

4) The number of integral values of b satisfying the equation a – ab + 5b + 2 = 0, a ∈ I is

5) Let where p & q are coprime, then p – q is :

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B C C D C C A B C C A C D C B A A D A

SECTION-II

Q. 21 22 23 24 25
A. 120 25 37 25 4

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B D C C B D A D A D D C A A B B B C D

SECTION-II

Q. 46 47 48 49 50
A. 72 3 33 25 10

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A C B A B C D B D C A C A C D B D C B

SECTION-II

Q. 71 72 73 74 75
A. 2 8 3 4 7
 SOLUTIONS

PART-1 : PHYSICS

1) [B]2 = [X]
[B] = L1/2

[A] = [M1L2T–2]L1/2 = [M1 L5/2 T–2]

[A] [B]2 = M' L7/2 T–2

2)
By homegeneity ⇒ [a] = [x2] = L2

So, ⇒

0
⇒ M–1L T2

3)

5)

Given The dimensions of right hand side and left hand side terms should be
equal.

So,

or
Now, comparing powers M, L and T, we get
p + r = 0 (i), q + 2r = 1 (ii), – q – r = 0 (iii)
After solving, p = –1, q = –1 and r = 1.
Putting these values, we get

which is the required relation.

6)
7) and A = B + C

8)

9) [α] = [F] = [MLT–2]

[βxt] = 1 ⇒ [β] = L–1T–1

10) Temperature is not a vector quantity because it has magnitude only.

However, force, acceleration and velocity have both a magnitude and a direction. So, these are
vectors in nature

11)

Let
Writing dimensions on both sides.
0 0
[M L T] = [ML–1T–2]a [ML–3]b [ML2T–2]c
0 0
⇒ [M L T]=Ma+b+cL–a–3b+2cT–2a–2c
Thus a+b+c=0, –a–3b +2c =0, –2a–2c=1

On solving these equations, we get ,b= and c =

12) ,

so = ⇒ A = 7B.

13)

[x] = [A] = [Bt]

[A] = [x] = L
[D] = 1 ([Angel = 1]
∴ [A × D] = [A] [D] = L

14)
15)

16)

17) Let L α ca gb pc
L = k ca gb pc
Putting dimensions on both sides :
0 0
[M L T ] = [LT–1]a [LT–2]b [ML–1 T–2]c
0 0
[M LT ] = [Mc La+b+–c T–a – 2b – 2c]
Comparing dimensions of both sides
c = 0, a + b – c = 1
–a – 2b – 2c = 0
solving we get a = 2, b = –1
hence [L] = [c2/g].

18)

19)

[b] = ⇒ acceleration
[c] = LT–1T = L ⇒ Distance
[d] = T ⇒ Time

[a] = ⇒ Distance

20) From triangle law of vector addition,

21)
....(1)
and

....(2)
divide eq. (2) by (1)

On squaring and cross multiplication

52 + 48 cosθ = 40 + 24 cosθ
24 cosθ = –12

θ = 120

22) Let forces be a & b & a > b

a + b = 35
a–b=5
a = 20, b = 15

At 90º

23)

tan α =

tan α = =

tan α = α = 37 Ans.

24) [Energy] = ML2T–2

In new system

1 unit of energy =

=
 = kgm2/s2 = J

Now J = 1 unit energy in new system

1J = unit

10 J = unit
= 25 unit

25) [m] = [vagbρc]

0 0
M1L T = (LT–1)a(LT–2)b(ML–3)c
⇒ a + b – 3c = 0 .....(1) comparing L
a + 2b = 0 ......(2) comparing J
C = 1 .......(3) Comparing M
From (1), (2) and (3)
a = 6, b = –3, c = 1
a+b+c=4

PART-2 : CHEMISTRY

26)

An orbital can accomodate maximum two electrons with opposite spin.

27)

28)

Concept : Isotones are elements that have the same number of neutrons but can have different
atomic number and mass numbers.
number of neutrons in 36Kr86 is 86 − 36 = 50
(A) neutrons in 38Sr88 is 88 − 38 = 50
(B) neutrons in 39Y89 is 89 − 39 = 50
(C) neutrons in 42Sr92 is 92 − 42 = 50
(D) neutrons in 40Sr91 is 91 − 40 = 51

29) If Aufbau rule is not followed then

[Sc] = 1s2 2s2 2p6 3s2 3p6 3d3
Last e– enters in 3d
n = 3, ℓ = 2

30) Species with same (A – 2Z) values are iso-diapher.

31) For n = 4
ℓ = 0, 1, 2, 3
i.e. 4s, 4p, 4d, 4f each contains 2e– with m = 0
∴ Maximum number of e– = 8

32) (A) n + ℓ = 4
(B) n + ℓ = 3
(C) n + ℓ = 5 where n = 3
(D) n + ℓ = 5 where n = 4 ; (higest energy)

33) Ni+2 → di positive nickel ion

Electronic configuration = 3d8, number of unpaired electron(n) = 2

spin only magnetic moment =

= = 2.82 B.M.

35) (B), (C), (D) have opposite spin electron in 'p' orbitals so these arrangements are unstable.

36)

unpaired e–
Mg2+ → [Ne] ⇒ 0
Ti+3 → [Ar] 3d1 ⇒ 1
V+3 → [Ar] 3d2 ⇒ 2
Fe2+ → [Ne] 3d6 ⇒ 4

37) In an atom maximum no. of possible shells may be infinite.

38)

Rb = [Kr] 5s1 n = 5, ℓ = 0, m = 0, s = ±1/2

39) n = 5, ml = +1 means orbital in 5th shell

So e– having n = 5, mℓ = 1⇒ 5p, 5d, 5f, 5g ⇒ 8 electrons.
n = 2, ℓ = 1, mℓ = –1, ms = –1/2means an electron .
e– having n = 2, ℓ = 1, mℓ = –1, ms = –1/2 ⇒ 1

40) Heavy water = D2O so no. of protons = 10

no. of electrons = 10
no. of neutrons = 10

41) 2 electrons in'K' shell ⇒ 1s2

8 electrons in 'L' shell ⇒ 2s2 2p6
9 electrons in'M' shell → 3s2 3p6 3d1
2 electrons in 'N' shell → 4s2

42) last electron of K⊕ enters into 3P subshell

So for 3P subshell → n ℓ m s

3 1 –1/1/0 + /
So according to given options answer is (B)

43)

In Dobereiner triad, atomic weight of middle element is nearly equal to the average atomic
weight of first and third element when they are in arranged in increasing order of atomic
weight and this triad rule is applicable for those elements which belong to same group ( not a
same period).
Some dobereiner triads are : (H, F, Cl), (P, As, Sb) (S, Se, Te) (Cl, Br, I) (Li, Na, K) (Ca, Sr, Ba)

I.e. (N, O, F) is not a Dobereiner triad because of N, O and F belongs to same period.

44) In f-block Actinide series is from atomic no. 90 to 103

IUPAC name of atomic no. (z) 104 is Unnilquadium that is element Rutherfordium (Rf)

45) Ununennium (Uue)

(Uue) → Symbol

46) 2M2 ⇒ M =
2 × (6)2 = 72

47)

Atomic Number = 100 → 'f-block elements'

Lanthanoid : 58 — 73
Actinides 90 — 103.
Both lies in group no.3.
Ans. 3

48) Electronic configuration of an element

(Phosphorous) 15P ⇒ 1s2, 2s2, 2p6, 3s2 3p3
Atomic no. of the element which is just below the above element in periodic table
= 15 + 18
 = 33
Ans. (33)

49) 4th excited state i.e. in 5th shell

5s 5g 5ƒ 5d 5p
1 + 9 + 7 + 5 + 3 = 25

50)

Ans : (10)
n=6
ℓ=2
subshell ⇒ 6d
Maximum no of e–s = 10

PART-3 : MATHEMATICS

51)

P = 4 and Q = 16
P = 16 and Q = 4

52) Unit place of 5n can be '5'

Unit place of 6m can be 6
∵ Unit place of 5n + 6m is 1

53)

54) =3+ &

=6

55) P(2) = 23 + 22(k) +2(3) + 5 = 10

⇒ 19 + 4k = 10
⇒ 4k = –9

⇒k=–

56)
3Q → 32 ⇒ Q = 2, 6
→ 36
Q = 2, P = 2 Q = 6, P = 7

57)

58) Comparing rational and irrational terms.

a=3 b=8
4 2
a – b = 81 – 64 = 17

59)
⇒ 2x2 + x – 3 = 0
⇒ 2x2 + x = 3
⇒ 4x2 + 2x = 6
⇒ 4x2 + 2x – 1 = 5

60)

...........(i)
3x – 2 = 7 –

2(3x – 2) = 14 – 2.3. =
.............(ii)

Now

61) Case - I : x2 – 3x + 2 = 0
x = 1,2
Case - II : x2 – 5 = 1 ⇒
Case - III : x2 – 5 = –1 ⇒ x = ±2
solution are

62) Let

⇒
⇒
⇒
⇒

⇒ ( x > 0)
∴

63) Put 2x = t
t2 – 6t + 8 = 0 t = 2, 4
2x = 2 ⇒ x=1
2x = 4 ⇒ x=2

64) =
and

65)

f(x) = (x – 1)(x2 – 7x + 13)

for f (x) to be prime at least one of the factors must be prime.
Hence x – 1 = 1 ⇒ x = 2
x2 – 7x + 13 = 1 ⇒ x2 – 7x + 12 = 0
⇒ x = 3 or 4
⇒ x = 2, 3, 4 ⇒ (C)

66)
since (a – b) + (b – c) + (c – a) = 0
(a – b)3 + (b – c)3 + (c – a)3
= 3(a – b) (b – c) (c – a)

E=

67) and 3.14 are rational number

68) = [(a9/6)1/3]4 [(a9/3)1/6]4 = (a1/2)4 (a1/2)4 = a4

69)

N = (24 – 1) (24 + 1) ...... (21024+1)

24 – 1 = 22048 –1 ⇒ n = 2048

70)
p(x) – x – 1 = (x – 1) (x – 2) (x – 3)
⇒ P(4) = 6 + 5 = 11

71) ⇒
⇒ (x – 2) (x+1) = 0
⇒ x=2 ( x>0)

72)
⇒
⇒
∴ a = –1

73)

74)

⇒ b–1=±1
b – 1 = ±7
⇒ 4 values.

75) 1.23 = 1.2 +