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Solution

The document contains various chemistry problems and solutions related to concepts such as normality, ppm, vapor pressure, freezing point depression, and osmotic pressure. It includes multiple-choice questions with calculations and theoretical explanations. The content appears to be aimed at students preparing for examinations in chemistry.

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0% found this document useful (0 votes)
6 views10 pages

Solution

The document contains various chemistry problems and solutions related to concepts such as normality, ppm, vapor pressure, freezing point depression, and osmotic pressure. It includes multiple-choice questions with calculations and theoretical explanations. The content appears to be aimed at students preparing for examinations in chemistry.

Uploaded by

anushka2008kundu
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
Topic : Solution 1 30% ig] 11,80, Preven aticrar oer (1) 3.061 N 2) 12.24N 3) 5.01N (4) 6.12N 2 CaCO, ¥ 1000 g Het FAeTATH 18 mg CaCO, # at freer’ : — (1) 18 ppm (2) 18 «10° ppm (3) 18 1073 ppm (4) 9% 10° ppm 3.30 g alan at 36g ae ct 1 Rr ar ae a, a ater (1) 0.2 (2) 04 (3) 06 (4) OB 4 Nar face 8 fae, a an agin fet wea ETE 4A — Ay. a eee A ATAT 30% & ate vip pris ara rT (1) 0775 1 as @) 4 (4) Soren 5. STP oC om H Ate ar ater sist 0.02 8 at et fearte aa eT (1) 2% 10? bar 2) 0.05 bar (3) 50 bar (4) 5* 10? bar L 2. Normatity of 30% S| H,S0, solution is wwaclys (1) 3061 @) 1224N @) 501N (4) 6.12N 1000 g aqueous solution of CaCO, contains 18 mg of CaCOs of the solution is == () 18 ppm (2) 18 10° ppm (3) 18 107 ppm (4) 9% 10° ppm 30 g Urea is dissolved in 36g water. The vapour pressure of solution relative to that of water will be @) 02 @ 04 3) 06 (4) 08 In a solution of A in B, A gets tetramerises as 4A — Ag. If degree of association is 30% then van't Hoff factor is approximately :- () 0.775 i ay b Qs @ 4 () Unpredictable ‘Mole fraction of a gas in water is 0.02 at STP, its Henry's Law constant is (1) 2* 10? bar 2) 0005 bar @) 50 bar (4) 510? bar © scanned wih onenscamer 6. apt rat gh - are free Match List - I with List - IL ate ten List-1 List-11 O.001M Na;SO, RIP (| st 0.003M rata] cy | seaweed fern aa ae wi ay wooo Na,SO, PER, 0.003M Olam fam & t waa aH F OOOIM © Na,SO, Fre, 0.01M Gi) © aS a u (d) | Free ere (ivy | safer Gi Jicst araratt (1) (a) - Gili), (6) - @), (©) - iv), @) - Gil) 2) (a) - Gi), () - (ili), (©) - Civ), () - Gi) (3) (a) - Gili), (b) - (iv), (©) - (, (A) - (i) (4) (a) - Civ), (b) - (ili), (e) - (D, (d) - (i) ee (A): sete sha, eo se AT aE TH sara es ER aA aL ROT (R) : a Te ara aT a a Si tah freer se tag A (1) Aste R dita 8 ste R, A Ara area a (2) Awa B ag Rare aL (3) A area toveg ket (4) A war R ae wa? APA RA A al ‘area et we fqn saga xy % afer ar Gener COPTER) sma SET SAT HET: 65.4 AMT 114.45 81 Sega sree xy ar Breer # Pater am (1) 75% 2) 80% 3) 50% (4) 90% ‘O.001M NazS0, solution and 003M alocose | | ©) solution att same | CP | Breton temperature '0.003M Na,SO, solution is swith 0,003M & Gi) Jicst ‘glucose solution at same temperature ‘0.001M NaSO, solution is with 001M o (iit | tsotonie ‘glucose solution at same temperature. (a) | Osmotic pressure (i) | Hypertonic Q) (a) Gil), (©) -(), ~Civ), @) - Gi) (2) (a) (0), (b)- Gti), (€) = Civ), @) = Gi) (3) (a) Git), () - iv), (€)-@), @) - Gi) 4) (a) (iv), )- iid, (©) =, @) - Assertion (A) : Aquatic species are more comfortable in cold water in comparison to warm water. Reason (R) : At a given pressure, the solubility of oxygen gas in water increases with decrease in temperature (1) Both A and R are true and R is the correct explanation of A. (2) Ais true but R is false (3) Ais false but R is true (4) Both A and R are true but R is NOT the correct explanation of A. The value of observed and theoretical (normal) molecular masses of certain electrolyte XY are 65.4 and 114.45 respectively. The electrolyte XY in the solution has dissociation to be extent of () 75% 2) 80%, @) 50% (4) 90% © scanned wth omen scamer 10. UL 12, 13. 14. fret Re wa ae, Ky aT aR ATF ater & fr. (1) 3a fhe hy Perera afi 21 (2) 7a tray Pactra ar a (3) AeA aaa Ky Baba e (4) eh fet fore Ke HE Pe Pree ‘frre a 01M, 100m HU rer ot 10 a a Pm ‘aren, at aft Freres at arezar et? (1) 001M (2) 0.1M @) 1M (4) ai oferta set ee we four a fenie (°C, frat 0.1 om KGlFe(CN)] (EME 329), 100 se FAH ae BOK;= 186 K ke mol) = () 2.26% 107 @) -5.7« 10"? 3) -5.7 = 107% (4) =1.20 «107 fre fret or Pra Pare ar aA ERAT = HteTTAT (1)0.05 M NaNO; (Il) 0.075 M CuSO, (il) 0.14 M gate (IV) 0.04 M Bact, fis ea xo a 8 () I>tvemem Q) We>ivel @) IVaMAI=I @) >> Ive up faerie are #1 0.59 gm. cra & 100 wc, aera Bt area a rey Tee =~ (1) 59 Q) 118 ©) 100 0.1 M wares area FaeraT aT 275C pH = 18 get are oe ge fers ar vere aa em (1) 4.926 atm @ 118 2) 0.2463 atm (3) 2.463 atm (4) 0.4926 atm 10. . 12, 1B. 4. Higher the value of Ky at a given pressure, suggests that := (1) Thehigher s the solubility ofthe gas inthe liquid. 2) The lowers the solubility ofthe gas in the liquid. (3) Solubility of gases has no relation with Ky, (4) All gases have same Ky values but different solubilities 01M, 100ml HCI solution is diluted 10 times ‘what is the new concentration of the solution ? @) 0.01M @) 01M @) IM (4) No change ‘The freezing point (in °C) of a solution containing 0.1 g of Ks[Fe(CN)g] (molecular weight 329) in 100g of water (Ky= 186 K kg mot (1) 2.26% 107? (2) —8.7 x 107? GB) -3.7 «107% (4) =1.20 «107? Consider the following. solutions (assume molarity = molality) (0.05 MNaNOs (UD) 0.075 M CuSO, (11) 0.14 M sucrose (IV) 0.04 M BaCl, ‘The correct order for decreasing freezing point is :- () I>tvell> iQ) Wem iver @) Ive m>1>Ul GM > IveL 0.59 gm. of a dibasic acid is present in 100 cc. of § solution. What is the molecular weight of the acid ? a) 59 @) 118 @) 100 @) 118 ‘A 0.1 Msolution of monobasic acid HA has pH = 1 at 27°C. The osmotic pressure of acid solution at 27°C will be Q) 4.926 atm (2) 0.2463 atm @) 2.463 atm (4) 0.4926 atm © scanned wth omen scamer 16. 17. 18. (8) AT.= Kym (1) ater were Q) abaadade Q) acardate 4) baad eee frafafad aAfirei % 0.01 M aefia freer % Tae ara FT Be ae ETT - (i) Al{SO4)3 (71) (ii) NasPO4 (772) Gi) BaCl; (43) ivy REA (a) (1) mg> > my> my Q) m,>a,>m,>m, @) (4) my > my> my> Ty 20 gm NaOH # wate er FT 60 gn a PET aga ire 1.2 gm co! here tee sare (1) 0.833 > mi> p> me 2) 100M @) 12M (4) 09M frafafiad # @ fea 92 # faces A anger aT ae Finke ah arch @ =~ (1) Brera (2) sueeter Q) Few (4) aftera arr (wiv) 15, 16, 17. 18, Of the following expressions := (a) n= CST ware N(Solvent) P? —n(Solutey+ NSolvent) = Tats ON ee () ATS = Kym (1) aand b are correct (2) a, band d are correct (3) a, cand d are correct (4) band d are comect ‘What is the correct sequence of osmotic pressure 0F0.01 M aqueous solution of (AlYSO4s (HL) Gi) NaxPO, (x2) (ii) BaCl, (3) (iv) Glucose (2) CY my> a> My> my Q) > my> a> m 8) > m)> > m4 (8) my > my> > My 20 gm NaOH dissolved in enough water to make 60 gm solution of density 12 gm ce! then calculate molarity > () 0.833 M 2) 100M @) 12M (@) 09M In which of the following expression the concentration of the solution remains independent of temperature = Q) Molarity (2) Normality (3) Mole fraction (4) Percentage strength (w © scanned wth omen scamer 19. 21. ‘af St at & rer & ar ret eee serait err eas, Tee saat F gaaaTa B eq eT wae (1) aces raw a errors fared waft ea (2) rae Fae 8 amr fre weir aca aL 3) atest oraen wefia aca ft 4) Fare ‘Peet sieita facta ar feiss -3.72°C Bat see eerie a saa eh (K y= L86 K kg mol” (Ky = 0.512 K kg mol") (1) 0.186°C @ osi2c (3) 1.024°C (4) 0.0s12°¢ 0.01 m BEgtas aeitags, difsay actress ae difean acke % sefia freer # feate & ae args t- () lsdel (2) 1:2:3 3) 1:2:4 (4) 2:2:3 festa ater par ad ty () Farsi rarer arate rare = 1 (aft Fae a oem & safer B) Q) Letemns este Weaawt aaa (afe Hae at ea a softer 8) G) feat Te 7 faded the Free He Pree ee (4) site sands 2gctors % 10 mL a 10 mk at fer oe ora cra ar arama 8 = (2) <20 ml () =20mi () saree eT “22.4V" HO, Freres te a et? 2) 05M (1) > 20 ml «1M @) 2M (4) 224M 19, 2. 22, 23. ‘An azcotropic mixture of two liquids has a boiling point higher than boiling points of its components, then it (2). Shows positive deviation from Raoult’s law (2) Shows negative deviation from Raoult’s law (3) Shows ideal behaviour (4) is saturated An aqueous solution freezes at ~3.72°C. What is elevation in boiling point ? (Ky= 1.86 K kg mot) (Ky = 0.512 K kg mol) () 0.186% @ 012°C (3) Lo2a°c (4) 0.0812°C The depression in freezing point of 0.01 m aqueous solution of hydrogen chloride, sodium chloride and sodium sulphate is in the ratio :- Q) beth @) 1:2:3 @) 12d 4) 22253 Which of the following is correct? Mole fraction of | + mole fraction of I= 1 (If only two components are present) (2) _Mole fraction of 1 Mole of | Mole fraction of I Mole of I (Ifonly two components ate present) (3) Mole fraction of solute Moles of solute Moles of solute + moles of solvent (4) Allof the above On mixing 10 mL of carbon tetrachloride with 10mL of benzene, the (otal volume of solution is:= Q) > 20m! Q) <20ml @) =20ml (4) Can't say ‘What will be the molarity of 22.4" H,0, solution’ a iM 2) 05M @) 2M (4) 224M © scanned wth omen scamer

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