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The document contains various chemistry problems and solutions related to concepts such as normality, ppm, vapor pressure, freezing point depression, and osmotic pressure. It includes multiple-choice questions with calculations and theoretical explanations. The content appears to be aimed at students preparing for examinations in chemistry.
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Topic : Solution
1 30% ig] 11,80, Preven aticrar oer
(1) 3.061 N
2) 12.24N
3) 5.01N
(4) 6.12N
2 CaCO, ¥ 1000 g Het FAeTATH 18 mg CaCO, #
at freer’ : —
(1) 18 ppm
(2) 18 «10° ppm
(3) 18 1073 ppm
(4) 9% 10° ppm
3.30 g alan at 36g ae ct 1 Rr ar ae
a, a ater
(1) 0.2 (2) 04 (3) 06 (4) OB
4 Nar face 8 fae, a an agin fet
wea ETE 4A — Ay. a eee A ATAT 30% &
ate vip pris ara rT
(1) 0775
1
as
@) 4
(4) Soren
5. STP oC om H Ate ar ater sist 0.02 8 at et
fearte aa eT
(1) 2% 10? bar
2) 0.05 bar
(3) 50 bar
(4) 5* 10? bar
L
2.
Normatity of 30% S| H,S0, solution is
wwaclys
(1) 3061
@) 1224N
@) 501N
(4) 6.12N
1000 g aqueous solution of CaCO, contains 18
mg of CaCOs of the solution is ==
() 18 ppm
(2) 18 10° ppm
(3) 18 107 ppm
(4) 9% 10° ppm
30 g Urea is dissolved in 36g water. The vapour
pressure of solution relative to that of water will
be
@) 02 @ 04 3) 06 (4) 08
In a solution of A in B, A gets tetramerises
as 4A — Ag. If degree of association is 30%
then van't Hoff factor is approximately :-
() 0.775
i
ay b
Qs
@ 4
() Unpredictable
‘Mole fraction of a gas in water is 0.02 at STP, its
Henry's Law constant is
(1) 2* 10? bar
2) 0005 bar
@) 50 bar
(4) 510? bar
© scanned wih onenscamer6.
apt rat gh - are free
Match List - I with List - IL
ate ten
List-1 List-11
O.001M Na;SO, RIP
(| st 0.003M rata] cy | seaweed
fern aa ae
wi ay wooo
Na,SO, PER, 0.003M
Olam fam &
t
waa aH F OOOIM
© Na,SO, Fre, 0.01M Gi)
© aS a
u
(d) | Free ere (ivy | safer
Gi Jicst
araratt
(1) (a) - Gili), (6) - @), (©) - iv), @) - Gil)
2) (a) - Gi), () - (ili), (©) - Civ), () - Gi)
(3) (a) - Gili), (b) - (iv), (©) - (, (A) - (i)
(4) (a) - Civ), (b) - (ili), (e) - (D, (d) - (i)
ee (A): sete sha, eo se AT aE TH
sara es ER aA aL
ROT (R) : a Te ara aT a a Si
tah freer se tag A
(1) Aste R dita 8 ste R, A Ara area
a
(2) Awa B ag Rare aL
(3) A area toveg ket
(4) A war R ae wa? APA RA A al
‘area et
we fqn saga xy % afer ar Gener
COPTER) sma SET SAT HET: 65.4 AMT
114.45 81 Sega sree xy ar Breer # Pater
am
(1) 75% 2) 80%
3) 50% (4) 90%
‘O.001M NazS0, solution
and 003M alocose | |
©) solution att same | CP | Breton
temperature
'0.003M Na,SO, solution
is swith 0,003M
& Gi) Jicst
‘glucose solution at same
temperature
‘0.001M NaSO, solution
is with 001M
o (iit | tsotonie
‘glucose solution at same
temperature.
(a) | Osmotic pressure (i) | Hypertonic
Q) (a) Gil), (©) -(), ~Civ), @) - Gi)
(2) (a) (0), (b)- Gti), (€) = Civ), @) = Gi)
(3) (a) Git), () - iv), (€)-@), @) - Gi)
4) (a) (iv), )- iid, (©) =, @) -
Assertion (A) : Aquatic species are more comfortable
in cold water in comparison to warm water.
Reason (R) : At a given pressure, the solubility of
oxygen gas in water increases with decrease in
temperature
(1) Both A and R are true and R is the correct
explanation of A.
(2) Ais true but R is false
(3) Ais false but R is true
(4) Both A and R are true but R is NOT the
correct explanation of A.
The value of observed and theoretical (normal)
molecular masses of certain electrolyte XY are
65.4 and 114.45 respectively. The electrolyte XY
in the solution has dissociation to be extent of
() 75% 2) 80%,
@) 50% (4) 90%
© scanned wth omen scamer10.
UL
12,
13.
14.
fret Re wa ae, Ky aT aR ATF ater &
fr.
(1) 3a fhe hy Perera afi 21
(2) 7a tray Pactra ar a
(3) AeA aaa Ky Baba e
(4) eh fet fore Ke HE Pe Pree
‘frre a
01M, 100m HU rer ot 10 a a Pm
‘aren, at aft Freres at arezar et?
(1) 001M (2) 0.1M
@) 1M (4) ai oferta set ee
we four a fenie (°C, frat 0.1 om
KGlFe(CN)] (EME 329), 100 se FAH ae
BOK;= 186 K ke mol) =
() 2.26% 107 @) -5.7« 10"?
3) -5.7 = 107% (4) =1.20 «107
fre fret or Pra Pare
ar aA ERAT = HteTTAT
(1)0.05 M NaNO; (Il) 0.075 M CuSO,
(il) 0.14 M gate (IV) 0.04 M Bact,
fis ea xo a 8
() I>tvemem Q) We>ivel
@) IVaMAI=I @) >> Ive
up faerie are #1 0.59 gm. cra &
100 wc, aera Bt area a rey Tee =~
(1) 59 Q) 118
©) 100
0.1 M wares area FaeraT aT 275C
pH = 18 get are oe ge fers ar vere
aa em
(1) 4.926 atm
@ 118
2) 0.2463 atm
(3) 2.463 atm (4) 0.4926 atm
10.
.
12,
1B.
4.
Higher the value of Ky at a given pressure,
suggests that :=
(1) Thehigher s the solubility ofthe gas inthe liquid.
2) The lowers the solubility ofthe gas in the liquid.
(3) Solubility of gases has no relation with Ky,
(4) All gases have same Ky values but different
solubilities
01M, 100ml HCI solution is diluted 10 times
‘what is the new concentration of the solution ?
@) 0.01M @) 01M
@) IM (4) No change
‘The freezing point (in °C) of a solution
containing 0.1 g of Ks[Fe(CN)g] (molecular
weight 329) in 100g of water
(Ky= 186 K kg mot
(1) 2.26% 107? (2) —8.7 x 107?
GB) -3.7 «107% (4) =1.20 «107?
Consider the following. solutions
(assume molarity = molality)
(0.05 MNaNOs (UD) 0.075 M CuSO,
(11) 0.14 M sucrose (IV) 0.04 M BaCl,
‘The correct order for decreasing freezing point is :-
() I>tvell> iQ) Wem iver
@) Ive m>1>Ul GM > IveL
0.59 gm. of a dibasic acid is present in 100 cc.
of § solution. What is the molecular weight of
the acid ?
a) 59 @) 118
@) 100 @) 118
‘A 0.1 Msolution of monobasic acid HA has pH = 1
at 27°C. The osmotic pressure of acid solution at
27°C will be
Q) 4.926 atm (2) 0.2463 atm
@) 2.463 atm (4) 0.4926 atm
© scanned wth omen scamer16.
17.
18.
(8) AT.= Kym
(1) ater were
Q) abaadade
Q) acardate
4) baad eee
frafafad aAfirei % 0.01 M aefia freer %
Tae ara FT Be ae ETT -
(i) Al{SO4)3 (71) (ii) NasPO4 (772)
Gi) BaCl; (43) ivy REA (a)
(1) mg> > my> my
Q) m,>a,>m,>m,
@)
(4) my > my> my> Ty
20 gm NaOH # wate er FT 60 gn a PET
aga ire 1.2 gm co! here tee
sare
(1) 0.833
> mi> p> me
2) 100M
@) 12M
(4) 09M
frafafiad # @ fea 92 # faces A anger aT
ae Finke ah arch @ =~
(1) Brera
(2) sueeter
Q) Few
(4) aftera arr (wiv)
15,
16,
17.
18,
Of the following expressions :=
(a) n= CST
ware N(Solvent)
P? —n(Solutey+ NSolvent)
= Tats
ON ee
() ATS = Kym
(1) aand b are correct
(2) a, band d are correct
(3) a, cand d are correct
(4) band d are comect
‘What is the correct sequence of osmotic pressure
0F0.01 M aqueous solution of
(AlYSO4s (HL) Gi) NaxPO, (x2)
(ii) BaCl, (3) (iv) Glucose (2)
CY my> a> My> my
Q) > my> a> m
8) > m)> > m4
(8) my > my> > My
20 gm NaOH dissolved in enough water to make
60 gm solution of density 12 gm ce! then
calculate molarity >
() 0.833 M
2) 100M
@) 12M
(@) 09M
In which of the following expression the concentration
of the solution remains independent of temperature =
Q) Molarity
(2) Normality
(3) Mole fraction
(4) Percentage strength (w
© scanned wth omen scamer19.
21.
‘af St at & rer & ar ret eee serait err
eas, Tee saat F gaaaTa B eq eT
wae
(1) aces raw a errors fared waft ea
(2) rae Fae 8 amr fre weir aca aL
3) atest oraen wefia aca ft
4) Fare
‘Peet sieita facta ar feiss -3.72°C Bat see
eerie a saa eh
(K y= L86 K kg mol”
(Ky = 0.512 K kg mol")
(1) 0.186°C @ osi2c
(3) 1.024°C (4) 0.0s12°¢
0.01 m BEgtas aeitags, difsay actress ae
difean acke % sefia freer # feate & ae
args t-
() lsdel (2) 1:2:3
3) 1:2:4 (4) 2:2:3
festa ater par ad ty
() Farsi rarer arate rare = 1
(aft Fae a oem & safer B)
Q) Letemns este
Weaawt aaa
(afe Hae at ea a softer 8)
G) feat Te
7 faded the
Free He Pree ee
(4) site
sands 2gctors % 10 mL a 10 mk at
fer oe ora cra ar arama 8 =
(2) <20 ml
() =20mi () saree eT
“22.4V" HO, Freres te a et?
2) 05M
(1) > 20 ml
«1M
@) 2M (4) 224M
19,
2.
22,
23.
‘An azcotropic mixture of two liquids has a
boiling point higher than boiling points of its
components, then it
(2). Shows positive deviation from Raoult’s law
(2) Shows negative deviation from Raoult’s law
(3) Shows ideal behaviour
(4) is saturated
An aqueous solution freezes at ~3.72°C. What is
elevation in boiling point ?
(Ky= 1.86 K kg mot)
(Ky = 0.512 K kg mol)
() 0.186% @ 012°C
(3) Lo2a°c (4) 0.0812°C
The depression in freezing point of 0.01 m
aqueous solution of hydrogen chloride, sodium
chloride and sodium sulphate is in the ratio :-
Q) beth @) 1:2:3
@) 12d 4) 22253
Which of the following is correct?
Mole fraction of | + mole fraction of I= 1
(If only two components are present)
(2) _Mole fraction of 1 Mole of |
Mole fraction of I Mole of I
(Ifonly two components ate present)
(3) Mole fraction of solute
Moles of solute
Moles of solute + moles of solvent
(4) Allof the above
On mixing 10 mL of carbon tetrachloride with
10mL of benzene, the (otal volume of solution is:=
Q) > 20m! Q) <20ml
@) =20ml (4) Can't say
‘What will be the molarity of 22.4" H,0, solution’
a iM 2) 05M
@) 2M (4) 224M
© scanned wth omen scamer