VRfuture - Love to Learn Subject: Chemistry, Standard 11th, Chapter 2 & 4
Q1 A 100-watt bulb emits monochromatic light of wavelength 400 nm. Calculate the number of
photons emitted per second by the bulb.
Q2 Calculate the energy associated with the first orbit of He+. What is the radius of this orbit?
Q3 What are the frequency and wavelength of a photon emitted during a transition from n = 5 state to
the n = 2 state in the hydrogen atom?
Q4 The mass of an electron is 9.1×10–31 kg. If its K.E. is 3.0×10–25 J, calculate its wavelength.
Q5 Explain the discovery of electrons & protons
Q6 What will be the wavelength of a ball of mass 0.1 kg moving with a velocity of 10 m s–1 ?
Q7 Write the complete symbol for the atom with the given atomic number (Z) and atomic mass (A) (i) Z
= 17, A = 35. (ii) Z = 92, A = 233. (iii) Z = 4, A = 9.
Q8 Explain Heisenberg uncertainty principle
Q9 Explain Principal, Azimuthal, Magnetic & spin quantum numbers and its
significance. What is the total number of orbitals associated with the principal
quantum number n = 3
Q10 Explain Pauli exclusion & Hund’s rule
Q 11 A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal
being 2.13 eV. Calculate (i) the energy of the photon (eV), (ii) the kinetic energy of the emission, and (iii)
the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
Q12 A 25 watt bulb emits monochromatic yellow light of wavelength of 0.57µm. Calculate the rate of
emission of quanta per second.
Q13 What is the wavelength of light emitted when the electron in a hydrogen atom undergoes
transition from an energy level with n = 4 to an energy level with n = 2?
Q14 i) An atomic orbital has n = 3. What are the possible values of l and m?
(ii) List the quantum numbers (m and l) of electrons for 3d orbital.
(iii) Which of the following orbitals are possible? 1p, 2s, 2p and 3f
Q15 (i) The energy associated with the first orbit in the hydrogen atom is –2.18 × 10–18 J atom–1.
What is the energy associated with the fifth orbit? (ii) Calculate the radius of Bohr’s fifth orbit for
hydrogen atom.
Q16 Calculate the wavenumber for the longest wavelength transition in the Balmer series of atomic
hydrogen
Q17 Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 m s–1.
Q18 The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength
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Q19 Write the significance/applications of dipole moment
Q20 What is the total number of sigma and pi bonds in the following molecules? (a) C2H2 (b) C2H4
Q 21 Draw diagrams showing the formation of a double bond and a triple bond between carbon atoms
in C2H4 and C2H2 molecules
Q 22 Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) K
Q23 Compare the relative stability of the following species and indicate their magnetic properties; O 2,
O2+, O2- (superoxide), O22- (peroxide)
Q24 Explain the structure of CO32- ion in terms of resonance.
Q25 Distinguish between a sigma and a pi bond
Q26 Write the important conditions required for the linear combination of atomic orbitals to form
molecular orbitals.
Q27 Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to
equatorial bonds?
Q28 Differentiate between covalent bond & ionic bond with examples
Q29 Draw the Lewis structures for the following molecules and ions : H2S, SiCl4,
BeF2, CO3 2− , HCOOH
Q30 Discuss the shape of the following molecules using the VSEPR model: BeCl2,
BCl3, SiCl4, AsF5, H2S, PH3
Q31 Although both CO2 and H2O are triatomic molecules, the shape of H2O
molecule is bent while that of CO2 is linear. Explain this on the basis of dipole
moment.
Q32 Explain why BeH2 molecule has a zero dipole moment although the Be–H
bonds are polar.
Q33 Which out of NH3 and NF3 has higher dipole moment and why ?
Q34 What is meant by hybridisation of atomic orbitals? Describe the shapes of sp,
sp2, sp3 hybrid orbitals
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9737026000/8849620478
Website: [Link]