09-11-2025

9610WPE408574250010 PE

CHEMISTRY

SECTION-A

1) Which of the following reaction does not represent to calcination ?

(1) Al(OH) Al2O3

3

(2) ZnS + O ZnSO4

2

(3) [Link](OH)2 → CuO + CO2 + H2O

(4) MgCl .6H O MgCl2

2 2

2) An ore after levigation is found to have acidic impurities. Which of the following can be used as
flux during smelting operation ?

(1) Na2B4O7
(2) CaCO3
(3) SiO2
(4) Na3PO4

3) Which of the following statement is incorrect.

(1) Boiling point of H2O2 is greater than that of H2O.

(2) Ethylene glycol is less viscous than glycerol.
Orthonitrophenol can be separate from its meta and para isomer using its steam volatile
(3)
property.
In ice each oxygen atom is tetrahedrally surrounded by four hydrogen atoms, which are all
(4)
equidistant from oxygen.

4) In which of the following reaction given information is incorrect.

(1)
3CuS + 8HNO3 (conc.) Blue solution

(2)
Hg2(NO3)2 Black precipitate

(3)
(CH3COO)2 Pb + Na2CrO4 yellow precipitate

(4)
FeCl3 + → Blue solution.
5) Alkene obtained as a major product in the following reaction can show :

(1) Optical isomerism

(2) Only Geometrical isomerism
(3) Both Optical and Geometrical isomerism
(4) Neither Optical nor Geometrical isomerism

6) Which of the following does not have optical isomer ?

(1) [Co(NH3)3]Cl3
(2) [Co(en)3]Cl3
(3) [Co(en)2Cl2]Cl
(4) [Co(en)(NH3)2Cl2]Cl

7) In the given reaction sequence, major product 'T' is

P Q R S T

(1)

(2)

(3)
(4)

8) If Pd vs. P (where P denotes pressure in atm and d denotes density in gm/L) is plotted for He gas

(assume ideal) at a particular temperature. If , then the temperature will be

(1) 160 K
(2) 320 K
(3) 80 K
(4) none of these

9) 7 moles of a tetra-atomic non-linear gas 'A' at 10 atm and T K are mixed with 6 moles of another

gas B at then gas B is ? (Assuming all modes of energy are active)

(1) monoatomic
(2) diatomic
(3) triatomic
(4) tetra atomic

10) Which of the following does not exist ?

(1) T (I3)
(2) PbF4
(3) FeCl3
(4) SCl6

11) The gaseous decomposition reaction, A(g) → 2B(g) + C(g) is observed to first order over the
excess of liquid water at 25ºC. It is found that after 10 minutes the total pressure of system is 188
torr and after very long time it is 388 torr. The rate constant of the reaction (in hr–1) is :
[Given : vapour pressure of H2O at 25° is 28 torr (In 2 = 0.7, In 3 = 1.1, In 10 = 2.3)]

(1) 0.02
(2) 1.2
(3) 0.2
(4) none of these

12) The reaction, Sucrose Glucose + Fructose, takes place at certain temperature while the
volume of solution is maintained at 1 litre. At time zero the initial rotation of the mixture is 34°.
After 30 minutes the total rotation of solution is 19° and after a very long time, the total rotation is
–11°C. Find the time when solution was optically inactive.
(1) 135 min
(2) 103.7 min
(3) 38.7 min
(4) 45 min

13) A mixture of two salts, S1 and S2 of the same metal produces the following observations. :
1. An aqueous solution of (S1 + S2) in dilute HCl produces a white precipitate with BaCl2, which is
insoluble in dilute HNO3.
2. The mixture (S1 + S2), is insoluble in water but dissolves in dilute HCl with evolution of a
colourless, odourless gas (G), which turns lime water milky.
3. The solution of (S1 + S2) in dilute HCl does not precipitate with H2S, but yields a white precipitate
with NaOH, which dissolves in excess aqueous NaOH.
The salts S1 and S2 are :

(1) PbSO4 and PbCO3

(2) PbCO3 and ZnSO4
(3) ZnS and ZnSO4
(4) ZnSO4 and ZnCO3

14) In bora bead test, which of the following observations are correct ?

(1) Mn2+ gives an amethyst (violet) bead in oxidising flame.

(2) Fe2+ imparts a green colour in hot oxidising flame.
(3) Cr3+ imparts a yellow colour in hot reducing flame.
(4) Ni2+ gives a reddish-brown bead in reducing flame.

15) Fe(Finely powdered) + HCl(dil) → P + Q

Compound 'P' does not precipitate with

(1) AgNO3
(2) K3[Fe(CN)6]
(3) (NH4)2S
(4) NH4Cl + NH4OH

16) How many chiral centres are present in a compound known as codenies?
(1) 8
(2) 4
(3) 5
(4) 6

17) Which of the following compounds when treated with PCl5 does not produce POCl3?

(1) SO3
(2) H2O
(3) P4O10
(4) CO2

18) Ammonia can be dried by using

(1) CaCl2
(2) H2SO4
(3) CaO
(4) P4O10

19) P4 + SOCl2 → X + Y + Z
P4 + SO2Cl2 → M + Y
Compound 'Y' is :

(1) PCl3
(2) PCl5
(3) SO2
(4) S2Cl2

20) The most appropriate method to obtained isopropoxy isopropane as a major product in reaction :

(1)
(2)

(3)

(4)

21) An element undergoes a reaction as shown :

X + 2e– → X2–, energy released = 30.87 eV/atom. If the energy released, is used to dissociate 4g of
H2 molecules, equally into H+ and H*, where H* is excited state of H atoms where the electron
travels in orbit whose circumference equal to four times its de Broglie's wavelength. Determine the
least moles of X that would be required :
Given : I.E. of H = 13.6 eV/atom, bond energy of H2 = 4.526 eV/molecule.

(1) 1
(2) 2
(3) 3
(4) 4

22) If the energy of H-atom in the ground state is –E, the velocity of photo-electron emitted when a
photon having energy Ep strikes a stationary Li2+ ion in ground state, is given by :

(1)

(2)

(3)

(4)

23) The major product obtained in the following reaction is

(1)

(2)

(3)

(4)

24) Combustion of sucrose is used by aerobic organisms for providing energy for the life sustaining
processes. If all the capturing of energy from the reaction is done through electrical process (non P-
V work) then calculate maximum available energy which can be captured by combustion of 34.2 gm
of sucrose
Given : ΔHcombustion (sucrose) = – 6000 kJ mol–1
ΔScombustion = 180 J/K mol–1 and body temperature is 300 K

(1) 600 kJ
(2) 594.6 kJ
(3) 5.4 kJ
(4) 605.4 kJ

25) For the hypothetical reaction

A2(g) + B2(g) 2AB(g)
ΔrG° and ΔrS° are 20 kJ/mol and –20 JK–1 mol–1 respectively at 200 K.
If ΔrCp is 20 JK–1 mol–1 then ΔrH° at 400 K is :

(1) 20 kJ/mol
(2) 7.98 kJ/mol
(3) 28 kJ/mol
(4) None of these
26) The correct option for the following reaction is

(1) 10 monochlorinated product will be obtained

(2) 7 fractions will be obtained on fractional distillation.
(3) 3 enantiomeric pair will be obtained
(4) 6 resolvable products will be obtained

27) A salt "P" gives black ppt. with H2S in a medium of dil. HCl. Solid powder of same salt on heating
produces a brown gas "E". "P" gives deep blue solution with excess NH4OH. Addition of KCN to "P"
gives a white ppt. "Q" and as as "D'
Which of the following is correct

(1) Gas E & Gas D have linear sturcutre.

(2) Slat P forms precipitate with NaOH which dissolves in ex. reagent.
(3) White ppt. "Q" dissolves in excess KCN
(4) Salt 'P' decolorizes aq. KMnO4 solution.

28) At a certain temperature and 2 atm pressure equilibrium constant (Kp) is 25 for the reaction
SO2(g) + NO2(g) SO3(g) + NO(g)
Initially if we take 2 moles of each of the four gases and 2 moles of inert gas, what would be the
equilibrium partial pressure of NO2?

(1) 1.33 atm

(2) 0.1665 atm
(3) 0.133 atm
(4) None of these

29) 0.020 g of selenium vapour of equilibrium occupying a volume of 2.463 mL at 1 atm and 27°C.
The selenium is in a state of equilibrium according to reaction
3se2(g) Se6(g)
What is the degree of association of selenium? (At. mass of Se = 79)

(1) 0.250
(2) 0.315
(3) 0.14
(4) None of these
30) The final product 'Q' is

(1)

(2)

(3)

(4)

31) The number of possible optically active products obtained on monochlorination of following

compound is

(1) 2
(2) 3
(3) 4
(4) 5

32) The major product 'S' obtained in the following reaction is

(1)

(2)

(3)

(4)

33) Halogen means salt producers. Then identify CORRECT statements(s) regarding salt producers
& their compounds : -

(1) I2O4 disproportionates on heating and produces I2 and I2O7.

None of the inter halogen compound is paramagnetic having more than 2 different halogen and
(2)
gaseous in nature.
With aqua regia, gold & platinum gives complex species having coordination number 4, nitrous
(3)
oxide (neutral oxide) and water.
Reaction of halogen with dilute and cold NaOH has less n-factor of halogen as compared to
(4)
reaction of halogen with hot and conc. NaOH (Halogens = C2/Br2/I2)

34) What is the hydrolysis product of hypo phosphoric acid.

(1) H2PO3, H4P2O7

(2) H3PO4
(3) H3PO3
(4) H3PO3, H3PO4

35) When borax is dissolved in water

(1) Only B(OH)3 is formed

–
(2) Only B(OH)4 is formed
(3) Both B(OH)3 and B2O3 are formed
–
(4) Both B(OH)3 and [B(OH)4] are formed

36) The product obtained in the following reaction is:

(1)

(2)

(3)

(4)
37) To a 10 mL, 1 M aqueous solution of Br2, excess of NaOH is added so that all Br2 is
disproportionated to Br– and BrO3–. The resulting solution is free from Br–, by extraction and excess
of OH– neutralised by acidifying the solution. The resulting solution is sufficient to react with 2g of
impure CaC2O4 (M = 128 g/mol) sample. The % purity of oxalate sample is :

(1) 85.3%
(2) 12.5%
(3) 90%
(4) 64%

38) 0.10 g of a sample containing CuCO3 and some inert impurity was dissolved in dilute sulphuric
acid and volume made up to 50 mL. This solution was added into 50 mL of 0.04 M KI solution where
copper precipitates as CUI and I– is oxidized into I3–. A 10 mL portion of this solution is taken for
analysis, filtered and made up free I3– and then treated with excess of acidic permanganate solution.
Liberated iodine required 20 mL of 2.5 mM sodium thiosulphate solution to reach the end point.
Determine mass percentage of CuCO3 in the original sample.

(1) 7.41
(2) 74.1
(3) 61.75
(4) None of these

39) An ideal solution contains two volatile liquids A (P° = 100 torr) and B(P° = 200 torr). If mixture
contain 1 mole of A and 4 mole of B then total vapour pressure of the distillate is :

(1) 150
(2) 180
(3) 188.88
(4) 198.88

40) The vapour pressure of two pure liquids A and B, that form an ideal solution are 100 and 900
torr respectively at temperature T. This liquid solution of A and B is composed of 1 mole of A and 1
mole of B. What will be the pressure, when 1 mole of mixture has been vaporized ?

(1) 800 torr

(2) 500 torr
(3) 300 torr
(4) None of these

41) The compound which do not show haloform reaction is

(1)
(2)

(3)

(4)

42) A solution of weak acid HA was titrated with base NaOH. The equivalent point was reached
when 40 mL of 0.1 M NaOH has been added. Now 20 mL of 0.1 M HCl were added to titrated
solution, the pH was found to be 5.0. What will be the pH of the solution obtained by mixing 20 mL
of 0.2 M NaOH and 20 mL of 0.2 M HA?

(1) 7
(2) 9
(3) 11
(4) None of these

43) A buffer solution 0.04 M in Na2HPO4 and 0.02 M in Na3PO4 is prepared. The electrolytic oxidation
of 1.0 milli-mole of the organic compound RNHOH is carried out in 100 ml. of the buffer. The
reaction is RNHOH+H2O→RNO2 + 4H+ + 4e– The approximate pH of solution after the oxidation is
complete is:
[Given: for H3PO4, = 22; = 7.20 =12]

(1) 6.90
(2) 7.20
(3) 7.5
(4) None of these

44) When a 20 mL of 0.08 M weak base BOH is titrated with 0.08 M HCl, the pH of the solution
at the end point is 5. What will be the pOH if 10 mL of 0.04 M NaOH is added to the resulting
solution?
[Given: log(2) = 0.3 and log(3) = 8.48 ]

(1) 5.40
(2) 5.88
(3) 4.92
(4) None of these

45) The major product obtained in the following reaction is

(1)

(2)

(3)

(4)

46) The correct option regarding following reaction is

(1) Resolvable product will obtain

(2) Product is optically inactive due to external compensation
(3) Product has centre of symmetry
(4) Product is optically inactive due to internal compensation
47) Equivalent conductivity of BaCl2, H2SO4 and HCl, are x1, x2 and x3Sem–1eq–1 at infinite dilution. If
conductivity of saturated BaSO4 solution is xScm–1, then Ksp BaSO4 is:

(1)

(2)

(3)

(4)

48) The conductivity of 0.001 M Na2SO4 solution is 2.6 × 10–4 Scm–1 and increases to 7.0 × 10
–4
Scm–1, when the solution is saturated with CaSO4. The molar conductivities of Na+ and Ca2+ are 50
and 120 Scm2 mol–1, respectively. Neglect conductivity of used water. What is the solubility product
of CaSO4?

(1) 4 × 10–6
(2) 1.57 × 10–3
(3) 4 × 10–4
(4) 2.46 × 10–6

SECTION-B

1) All group - 14 members are solid in which Carbon is non metal and silicon shows significantly non-
metallic character, Germanium is metalloid. But Sn & Pb are soft metals.
The CORRECT study regarding group - 14 elements & their compounds : -

Reactions of Carbon with steam and carbon with air, at higher temperature produce, producer
(1)
gas and water gas respectively.
(2) Single chain silicates & ring silicates have same general formula.
Using R3SiCl, we can control the chain length of silicones but using RSiCl3, we can control the
(3)
hardness of the same.
(4) 'Si' is added to steel to improve its thermal shock resistance.

2) The reaction in which primary amine is obtained as one of the product is

(1)
(2)

(3)

(4)

3) Select correct statement(s) with respect to geometry of hybrid orbitals.

(1) sp3 and d3s have identical shape.

(2) spz has linear geometry along z-axis.
(3) different geometry may be formed from sp3d.
If pz orbital is replaced by dx –y in sp3 hybridization, non-planar geometry changes to planar
2 2

(4)
geometry.

4) Select the correct order according to their giver properties.

(1) F > Cl > Br > I [Order of Electronegativity]

(2) F– > Cl– > Br– > I– [Order of Hydrated radii]
(3) F– > Cl– > Br– > I– [Order of Ionic radii]
(4) F– < Cl– < Br– > I– [Order of Electrical Conductivity]

5) Which of the following statement is CORRECT?

(1) gives positive Red-AzO dye test only in very dilute solution.
(2) PbBr2 dissolves in hot water but precipitate re-appears on cooling.

(3) Treating with Zn+ dil. NaOH produces H2S gas.

(4) Potassium Tri-iodide Azide test for sulphide cannot be done in presence of

6) The sample A participates in the transformations in given scheme. Only the products containing A
are shown in the scheme.
Information about compounds used in above scheme.
(i) Substance A is a solid, non metallic element and insoluble in water.
(ii) Substances B and C are gases.
Select correct statements(s) are per given information

(1) Substances B can turns filer paper moistened with K2Cr2O7/H2SO4 green.
Substances A(vapour) and Aluminium(vapour) yields a black solid that readily hydrolysed on exposure
(2)
to air.
(3) Compound H can decolourize a brown solution fo KI3 in acidic medium.
(4) Compound H produces violet precipitate with FeCl3 solution.

7) Consider the following reaction and choose the correct option(s) :

(I)

(II)

(1) Both (P) and (Q) are same

(2) (Q) is first member of alkenyne family
(3) (P) is red colour compound
(Q) on reaction with HCl at 80°C will give
(4)

8) Which of the following are correct statement(s).

(1) Bond angle order (X—S—X) is OSF2 < OSCl2 < OSBr2
2–
(2) (O—O) bond length in O2 is more than O2F2
(3) dC—Cl bond length in CH3Cl > CF3Cl

(4) angles are equal to 90° in P4 molecule.

9)
(P) is soluble in polar solvents while (Q) are in organic solvents. Choose the incorrect option(s) :

(1) (P) is soluble in aq. NaOH as well as in aq. NaHCO3

(2) Order of reactivity is : HCl > HBr > HI
(3) (P) has 5 resonating structures and known as haloarenes
(4) Both (P) and (Q) can interact with Na metal

10) Which of the following reaction(s) will produce enantiomeric products ?

(1)

(2)

(3)

(4)

11) In the following reaction sequence, the correct statement(s) is/are :

(1) On acidic hydrolysis both R and T gives same product

(2) T can evolve CO2 with NaHCO3
(3) R and T are functional isomers
(4) On basic hydrolysis both R and T gives the same product

12) The major product (R) can be obtained by

(P) (Q) (R)

(1)

(2)

(3)

(4)
 ANSWER KEYS

CHEMISTRY

SECTION-A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 2 2 4 3 4 1 3 1 2 4 2 2 4 1 4 4 4 3 3 3
Q. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A. 2 3 2 4 1 1 3 3 2 4 2 3 4 4 4 4 4 2 3 3
Q. 41 42 43 44 45 46 47 48
A. 3 2 2 2 3 4 3 1

SECTION-B

Q. 49 50 51 52 53 54 55 56 57 58 59 60
A. 2,3 1,2,3,4 1,2,3,4 1,2,4 1,2,4 1,2,3 2,3,4 1,2,3 1,2,3 3,4 1,3 1,2,3,4
 SOLUTIONS

CHEMISTRY

1)

ZnS + O2 ZnSO4

2)

CaCO3

3)

In ice each oxygen atom is tetrahedrally surrounded by four hydrogen atoms, which are all
equidistant from oxygen.

4)

(CH3COO)2 Pb + Na2CrO4 yellow precipitate

5)

Neither Optical nor Geometrical isomerism

6)

[Co(NH3)3]Cl3

7)

8)

160 K

9)
diatomic

10)

SCl6

11)

1.2

12)

103.7 min

13)

ZnSO4 and ZnCO3

14)

Mn2+ gives an amethyst (violet) bead in oxidising flame.

15) NH4Cl + NH4OH

16) 6

17) CO2

18) CaO

19) SO2

20)

21) 2

22)
23)

24)

605.4 kJ

25) 20 kJ/mol

26)

10 monochlorinated product will be obtained

27) White ppt. "Q" dissolves in excess KCN

28)

0.133 atm

29) 0.315

30)

31)

32)

33)

Reaction of halogen with dilute and cold NaOH has less n-factor of halogen as compared to
reaction of halogen with hot and conc. NaOH (Halogens = C2/Br2/I2)
34)

H3PO3, H3PO4

35)

Both B(OH)3 and [B(OH)4]– are formed

36)

37)

64%

38)

74.1

39)

188.88

40)

300 torr

41)

42)

43)

7.20

44)

5.88
45)

46)

Product is optically inactive due to internal compensation

47)

48)

4 × 10–6

49)

Single chain silicates & ring silicates have same general formula.
Using R3SiCl, we can control the chain length of silicones but using RSiCl3, we can control the
hardness of the same.

50)

51)

sp3 and d3s have identical shape.

spz has linear geometry along z-axis.
different geometry may be formed from sp3d.
If pz orbital is replaced by dx –y in sp3 hybridization, non-planar geometry changes to planar
2 2

geometry.
52) F > Cl > Br > I [Order of Electronegativity]
F– > Cl– > Br– > I– [Order of Hydrated radii]
F– < Cl– < Br– > I– [Order of Electrical Conductivity]

53) gives positive Red-AzO dye test only in very dilute solution.
PbBr2 dissolves in hot water but precipitate re-appears on cooling.
Potassium Tri-iodide Azide test for sulphide cannot be done in presence of

54) Substances B can turns filer paper moistened with K2Cr2O7/H2SO4 green.
Substances A(vapour) and Aluminium(vapour) yields a black solid that readily hydrolysed on exposure
to air.
Compound H can decolourize a brown solution fo KI3 in acidic medium.

55)

(Q) is first member of alkenyne family

(P) is red colour compound
(Q) on reaction with HCl at 80°C will give

56)

Bond angle order (X—S—X) is OSF2 < OSCl2 < OSBr2

(O—O) bond length in O22– is more than O2F2
dC—Cl bond length in CH3Cl > CF3Cl

57)

(P) is soluble in aq. NaOH as well as in aq. NaHCO3

Order of reactivity is : HCl > HBr > HI
(P) has 5 resonating structures and known as haloarenes

58)
59)

On acidic hydrolysis both R and T gives same product

R and T are functional isomers

60)