Seminar Script: P-Block Elements
Respected teacher and my dear friends,
Good morning to everyone.
Today I will present a JEE-oriented seminar on the topic “P-Block Elements”, which forms a very
important part of Class 11 inorganic chemistry and is frequently tested in JEE Main and Advanced.
1. Introduction
Based on the subshell into which the last electron enters, elements are divided into [Link] p-block
elements are those in which the last electron enters a p-orbital.
They are placed in Groups 13 to 18 of the periodic table and include metals, non-metals, metalloids, and
noble gases.
Because of this diversity, p-block elements show maximum variation in chemical behavior.
2. Electronic Configuration
The general electronic configuration of p-block elements is:
ns² np¹ to ns² np⁶
Group 13: ns² np¹
Group 14: ns² np²
Group 15: ns² np³
Group 16: ns² np⁴
Group 17: ns² np⁵
Group 18: ns² np⁶
Oxidation States
P-block elements show variable oxidation states.
Group-wise trend
Group 13: +3, +1
Group 14: +4, +2
Group 15: +5, +3, −3
Group 16: −2
Group 17:
In this today we are going to dive deep into the BORON FAMILY
Boron Family (Group 13)
Elements
B, Al, Ga, In, Tl
General Electronic Configuration
ns² np¹
Nature of Elements
Boron → Non-metal (metalloid)
Aluminium → Metal
Ga, In, Tl → Metals
size B<Ga<Al<In<Tl
I.E B<Tl<Ga<Al<In
M.P B>Al>Ga>In>Tl
density B<Al<Ga<In<Tl
rxn with o2
M+O2==M2O3
EXCEPT
Tl+o2==Tl2o
rxn with n2
ga,in,tl nnot
b/al+n2==nal/bN
rxn with h2o
nohing react except al
al +h2o(hot)==al2o3 +h2
rxn wit halogens
m+H==mH3
Importance of P-Block in JEE
Direct questions from periodic trends
Assertion-reason questions
Matching type questions
Conceptual questions based on exceptions
Conclusion
To conclude, p-block elements show the maximum variety of properties due to changes in size,
electronegativity, and oxidation states.
A strong understanding of trends, exceptions, and reasoning makes this chapter very scoring for JEE.
Thank you for listening patiently.
Have a great day!