LIBRARY 2.

O
By Aarif Bhaiya and Raghavendra bhaiya

MATHEMATICS TEST PAPER WITH SOLUTION

1. The number of real solution of equation y y2 
x x  4  3 x  2  10  0 is/are :  ln   1  2  = ln x + ln k = ln kx
x x 

(1) 1 (2) 2
(3) 3 (4) 4  y  x2  y2  k x2
Ans. (1) 0+1=k
Sol. Case I x < – 4
y+ x2  y2 = x
2

x  (x  4)  3  (x  2)   10  0

x2 + 7x – 4 = 0 y+ 9  y2 = 9
7  65 7  65 y=4
 x or 
2 2 11/2
Reject Acept
3. If  sin x   cosx5/2 dx
p1 p p p

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Case II – 4  x < – 2   cot x 9/2  2  cot x 5/2  3  cot x 1/2  4  cot x 3/2  C
q1 q2 q3 q4
x(x + 4) + 3  (x  2)  + 10 = 0
where H.C.F. {pi, qi } = 1 & i  {1, 2, 3, 4}.
x2 + x + 4 = 0
y2
4
D<0 No solution Then value of   pi  q i 
1
Case III x  – 1
x (x + 4) + 3 (x + 2) + 10 = 0 (1) 30 (2) 25
(3) 24 (4) 34
ar

x2 + 7x + 16 = 0
D<0 No solution Ans. (4)
11/2
 No. of solution = 1. Sol.   tan x  .sec8 xdx
br

2. If xdy – ydx =  
x2  y2 dx. If y = y(x) & y(1) = 0
=   tan x 
11/2
1  tan x  3sec
2 2
xdx
then y(3) is :
Li

Put tan x = t
(1) 1 (2) 2
   
3
(3) 3 (4) 4   t 11/2 1  t 2 dx   t 11/2 1  t 6  3t 2  3(4) dt
Ans. (4)
 t 
11/2
2 2
=  t1/2  3.t 7/2  3.t 3/2 dt
xdy – ydx x y
Sol.  dx
x2 x2 =  2  cot x 9/2  6  cot 5/2  6  cot x 1/2  2  cot x 3/2  C
9 5 3
2
y y 1  p1 = 2, p2 = 6, p3 = 6, p4 = 2
d    1  2 . dx
x x x & q1 = 9, q2 = 5, q3 =1, q4 = 3
y 4
d 
x 1    pi  q i 
 2
  dx
x
i 1
y = (2 + 9) + (6 + 5) + (6 + 1) + (2 + 3) = 34.
1  
x

1
4. Let M {1, 2, 3 ….., 16}, if a relation R defined on  1 1 
6. The no. of solution in x    ,  of
set M such that R = {(x, y) : 4y = 5x – 3, x, y  M}.  2 6 2 6
How many elements should be added to R to make

it symmetric. equation tan–14x + tan–16x = is :
6
(1) 2 (2) 3
(1) 0 (2) 1
(3) 4 (4) 5
(3) 2 (4) 3
Ans. (1)
Ans. (2)
Sol. R = {(3, 3), (7, 8), (11, 13)}
to make it symmetric (8, 7), (13, 11) must be added. 
Sol. tan 1 4x  tan 1 6x 
6
5. Image of point P (1, 2, a) with respect to line
x 6 y 7 z 7  4x  6x  
mirror   is point Q (5, b, c),  tan 1  2 

3 2 2  1  24x  6
then value of (a2 + b2 + c2) is : 10x 1
(1) 293 (2) 298  
1  24x 2
3
(3) 283 (4) 264
 24x 2  10 3x  1  0
Ans. (2)
10 3  300  96
P(1,2,a) x

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48

x–6 y–7 z–7 396  10 3

= = x
Sol. 3 2 –2 48
y2
 1 1 
Only 1 solution in   , 
Q(5,b,c)  2 6 2 6
 b ca cos2 48  sin 2 12   5
Point M   3,  1, satisfies the line
ar

 2 2  7. If the value of
sin 24  sin 6
2 2
is

then

b ca value of ( +  + )
1 7 7
36 2
br

  2 (where , ,   N and are in lowest form) :

3 2 2
(1) 3 (2) 4
b  12 c  a  14
–1=  (3) 5 (4) 6
Li

4 4
Ans. (4)
 b = 8 … (1) & c + a = 18 … (2)
Sol. Use sin(A + B) sin (A + B) = sin2A – sin2B
Now PQ  L 2 2
cos (A + B) cos (A – B) = cos A – sin B
 (4i + (b–2)j + (c – a)k) · (3i + 2j – 2k) = 0
cos60 cos36 5 1 5  1 ( 5  1)2
 12 + 2 (b – 2) – 2 (c – a) = 0   
sin30 sin18 5 1 5 1 4
 6 + (b – 2) – (c – a) = 0
 b–c+a+4=0 3 5

2
8–c+a+4=0
  c + a = 12 … (3) =3;=1;=2
From (2) & (3) So, ( +  + ) = 6
c = 15 & a = 3
So a2 + b2 + c2 = 9 + 64 + 225 = 298

2
8. If a line x + y = 1 does not intersect the hyperbola 5x
 1 & x < 10 & x  9
x2 – 9y2 = 9 then a possible value of  is : 2x  3
(1) 0.2 (2) 0.3 (5 – x)2 – (2x + 3)2  0 & x < 10 & 4x  9
(3) 0.4 (4) 0.5 (x + 8) (3x – 2) 0 & x < 10 & x  9
Ans. (4)
2 
Sol. y = 1–x   , 8   ,10   {9}
 3 
Put this is equation of hyperbola
 2 
 x2 – 9(1–x)2 = 9  ( +  +  + ) = 6  8   10  9 
 3 
i.e. x2(1-92) + 18x – 18 = 0
= 70
line does not intersect hyperbola
10. If (9 + 7 –7)20 + (9 + 7 – 7)20 + (9 + 7 – 7)20
D<0 20 10
+ (14 + 7 + 7) is m then the value of m is :
2
 2  0 1  i 3 1  i 3
9 (where   &  )
2 2
 2  2  (1) 50 (2) 49
    ,   ,  
 3   3
  (3) 46 (4) 48

.O
2 Ans. (2)
Here 0.47
3
 9  7  7     9  7  7 
20
2 20 2
Sol. +
9. If domain of
y2
 
20
 5x  1 40 9  7  72 + (14 + 7( + 2))20
f(x)  sin 1    is
 2x  3  loge (10  x)
 9  7  7  1       (14  7)
20
2 2 20
 720
(, ]  (,  )  {} then value of 6( +  +  + )
ar

= (49)10
is equal to :
Hence, M = 49
(1) 60 (2) 70 2
11. If the end points of chord of parabola y = 12x are
br

(3) 80 (4) 90
(x1, y1) and (x2, y2) and it subtend 90° at the vertex
Ans. (2)
of parabola then (x1x2 – y1y2) equals :
5x
Li

Sol. 1   & 10 – x > 0, 10 – x 1 (1) 288 (2) 280

2x  3
(3) 290 (4) not possible

3
Ans. (1) 2000
 25

  80 1/5   80   80 
5
 5
 1
Sol.  
(x1y1 )  3t12 ,6t1 & (x2 y2 )  3t 22 ,6t 2   f      
  81    81 
 
  81  
 
t1t2 = –4
 80 
400
  80 5 
x1x2 = 9(t1t2)2, y1y2 = 36t1t2       1
 81    81  
x1x2 – y1y2 = 9(16) – 36(–4)  
= 144 + 144 (80)400. (81)–395((80)5 – (81)5)
= 288 14. If the sum of first 4 terms of an AP is 6 and sum of
12. If probability distribution is given by first 6 terms is 4, then sum of first 12 terms of AP
is :
X 0 1 2 3 4 5 6 7
(1) – 22 (2) –20
P(x) 0 k 2k 2k 3k k2 2k2 7k2+k
(3) 22 (4) 20
Then find P(3 < x  6) Ans. (1)
(1) 0.33 (2) 0.22 Sol. Sum of first 4 term S4 = 6
(3) 0.11 (4) 0.44 4
Ans. (1)  2a  3d   6  2a  3d  3 ….. (1)
2
Sol.  P(x )  1 Sum of first 6 terms S6 = 4

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i

9k + 10k2 = 1 6 4
 2a  5d   4  2a  5d  ….. (2)
2 3
1
 10k2 + 9k – 1 = 0  k  eq. (2) – eq. (1)
y2
10
4
P(3 < x  6) = 3k + k2 + 2k2  2a  5d    2a  3d   3
3
3 3
   0.33 5
10 100
ar

d
6
= 0.33
13. f(x) = x2025 – x2000, x  [0, 1], then minimum value  5 11
 2a  3     3  a 
br

of f(x) is :  6 4

(1) (80)400. (81)–395((80)5 – (81)5) 12  11  5 

S12  2   12  1    
2  4  6 
Li

300 –295 5 5
(2) (80) . (81) ((80) – (81) )
–395 +400 4 4
(3) (80) . (81) ((80) – (81) )  22 
S12  6     22
(4) (80)–395. (81)+400((80)3 – (81)3)  6 
Ans. (1)  /2
dx
Sol. f(x) = x2025 – x2000 15. The value of  x  4
 /2
is, where [·] denotes
2024 1999
f'(x) = 2025x – 2000x
1999 5
greatest integer function:
25x (81x – 80) = 0
7 11  11
1/5 (1)  (2) 
 80  20 30 20 30
x 
 81  11 7 11 7
1/5
(3)  (4) 
 80  20 30 30 20
Minimum at x   
 81  Ans. (1)

4
 1  x 
 /2 101
1
Sol. I 
 /2  
x 4
dx = – coefficient of x 48
in
x2
 100 .

1  x 
101
1 0 0  /2
dx dx dx dx Coefficient of x in 48
I      x
 /2
2 1 3 1 4 1
5
= – 100 C49  101 101
C50
1  1 1   1
  1    1  1    1  18. If a line x = – 1 divide the area of region bounded
2 2 3 4 2 5
m
7 11 by {(x,y) :1  x 2  y  3  x} in the ratio then
=  n
20 30 (m + n) equal (where HCF of (m,n) = 1) :
16. If S={1,2…..50}, two numbers and  are (1) 25 (2) 26
selected at random find the probability that product (3) 27 (4) 28
is divisible by 3 : Ans. (3)
664 646 y = 1 + x2
(1) (2)
1225 1225
527 461
(3) (4)
1225 1225

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Ans. (1)
y=3–x
Sol. Req. probability = 1– (product not divisible by 3) Sol.
Multiple of 3 = 16 –2 x = –1 1
y2
Not multiple of 3 = 34
1

  3  x   1  x  dx
34
C 664 2
 1  50 2 
C2 1225 m 20
 1
1

n 7
  3  x   1  x  dx
ar

2
17. The coefficient of x48 in
 m + n = 20 + 7
11  x   2 1  x   3 1  x   .....  100 1  x 
2 3 100
br

= 27
is : 2 3
19. If A   2025 2024 2023
 then value of det (A – 3A + A ) :
(1) 100 C50  101 101
C49 (2) 100 C49  101 101
C50 3 5
Li

 
(3) 101
C46  100 (4) 101
C47 101 C46 Ans. (16)
Ans. (2) 2 3 13 21
Sol. A   A2   
Sol. Let 1 + x = r  3 5 21 34 
 S = 1.r + 2.r + 3.r + ……+ 100r ……. (1)
2 3 100
2025 2024 2023
|A – 3A +A |
(AGP)
2 3 100 101
rS = 1.r + 2.r + ..…+ 99r + 100r ….... (2) = A2023 A2  3A  I 
(1) – (2) gives 2023
= A A 2  3A  I
1  x  1 100 1  x 
101 101

S 2
 2
x x x 8 12
= 1. = 160 – 144 = 16
 coefficient x in S
48
12 20

5
 x 21. If two circles
20. If 6  f(x)dx = 3x f(x) + x3 – 4, x  1 then value of
x2 + y2 – 4x – 2y – 4 =0 & (x+1)2 + (y + 4)2 = r2
1
intersect at two distinct points and range of
 f(2)  f(3) is : r  (, ), then the value of  is :
Ans. (3) Ans. (25)
x
Sol. (x–2)2 + (y–1)2 =32 & (x+1)2 + (y+4)2 = r2
6  f(x)dx = 3x f(x) + x – 4
3
Sol.
1
|r1 – r2| < c1c2 < r1 + r2

 2  1  1  4 
2 2
Diff. both side r 3   r 3
2
6 f(x) = 3x f(x) + 3f(x) = 3x
r  3  34 & r + 3 > 34
3f(x) = 3x f(x) + 3x2
dy  34  r  3  34 & r  34  3
x  y  x 2
dx 
i.e. r  3  34,3  34    34  3,  
dy
x
dx
9 i.e. r   34  3, 34  3
 1
x2
   34  3 34  3
d y

.O
  1
dx  x  = 34 –9
y = 25
 x  C
y2
x
 f(x) = –x2 + Cx
at x = 1, y = 1 C = 2
f(x) = – x2 + 2x
ar

f(2) – f(3) = 3
br
Li

6
 LIBRARY 2.O
By Aarif Bhaiya and Raghavendra bhaiya

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A 4. Match the following and choose the correct option.
–
1. Number of unpaired e in low spin octahedral List-I List-II
complex formed by ions Mn3+, Cr3+, Fe3+ & Co3+ 
(a) [Ag(NH3)2] (i) Fehling solution
follows the order :
(1) Mn3+> Cr3+> Fe3+> Co3+ (b) Zn-Hg/HCl (ii) Clemmensen reduction

(2) Cr3+> Mn3+> Fe3+> Co3+ (c) NH2–NH2/KOH (iii) Tollen’s reagent

(3) Fe3+> Cr3+> Co3+> Mn3+ (d) Cu /OH (iv) Wolff-Kishner reduction
+2

3+ 3+ 3+ 3+
(4) Co > Fe > Cr > Mn (1) a  (i), b  (ii), c  (iii), d  (iv)
Ans. (2)
(2) a  (iv), b  (iii), c  (ii), d  (i)
Sol. Co → 3d  t 2,2,2
3+
e g0,0 ,unpaired electron = 0
6
2g (3) a  (iii), b  (ii), c  (iv), d  (i)
Fe → 3d 
3+ 5
t 2,2,1
2g e0,0
g unpaired electron = 1 (4) a  (i), b  (ii), c  (iv), d  (iii)

Cr → 3d  t1,1,1

.O
Ans. (3)
3+ 3 0,0
2g e g unpaired electron = 3
5. Statement-I An element ‘X’ of P-block forms a
Mn → 3d  t 2,1,1 0,0
3+ 4
2g e g unpaired electron = 2
hydride H–X, which has longest bond length then
y2
2. Four elements from second period Boron to Oxygen element ‘X’ will have the shortest covalent radius.
can have following IE1 values (in kJ mol–1) :
Statement-II An element ‘E’ of Group 15 forms
1086.5, 800.6, 1313.9, 1402.3
hydride EH3 that has least B.P. The Maximum
ar

The value of IE1 for "Nitrogen" is. covalency of E is 4.

(1) 1086.5 (2) 800.6 (1) Both statements are correct
br

(3) 1402.3 (4) 1313.9 (2) Statement-I is correct ; statement-II is incorrect

Ans. (3) (3) Statement-I is incorrect; statement-II is correct
Sol. IE1 : N > O > C > B
Li

(4) Both statements are incorrect.

3. An element of p-block forms a species of type Ans. (4)
EH 4 , which when passed through a basic solution Sol. Least B.P. is for PH3. Maximum covalency of P is 5.
of K2[HgI4], forms a brown ppt.
6. Two elements of p-block can form following
Select the correct option :
halides XF3 & YF3. XF3 can act as Lewis acid
(1) Element E has maximum covalency equal to 5.
while YF3 can act as Lewis base. Then
(2) Brown ppt. formed is HgO. Hg(NH2)I.
hybridization of ‘X’ & ‘Y’ in XF3 & YF3 is
(3) Element E has maximum electron affinity in its
respectively.
group.
(1) sp2, sp2 (2) sp3, sp2
(4) EH3 is phosphine.
Ans. (2) (3) sp2, sp3 (4) sp3, sp3
Ans. (3)
Sol. Element E is N, the species is NH 4
Sol. XF3 = BF3 ; YF3 = NF3

1
7. An element ‘M’ does not evolve H2 gas on 10. Compare rate of SN1
treatment with dilute HCl. MSO4 (1 mol) on
Br Br
treatment with [Link] forms a compound ‘P’. The Ph Me
amount of MS formed (in moles) when H2S gas is Ph Br Ph Br
passed through compound ‘P’ is -
Ph Ph
(1) 0 (2) 1 P Q R S
(3) 2 (4) 3
(1) P > Q > R > S (2) R > S > P > Q
Ans. (1)
(3) R > S > Q > P (4) S > R > Q > P
Sol. Cu 
[Link]
X
Ans. (2)
CuSO 4 
KCN
 [Cu(CN) 4 ]3 
H2S
no sulphide ppt
Sol. Rate of SN1 Stability of C
perfect complex

(CuS)
11. Statement-I :
8. Consider the structure of HNO3
II OH
O KOH
IV + CHCl3 Major + Minor
H N I product product
O O
III

Select the correct option having formal charge of I, .O Major product is ortho substituted product and
minor product is para substituted.
y2
Statement-II :
II, III & IV respectively
(1) –1, 1, +1, 0 (2) 0, 0, +1, –1 Ortho & Para substituted products can be separated
(3) –1, 0, 0, +1 (4) +1, –1, 0, 0 by steam distillation.
ar

Ans. (3) (1) Statement-I and Statement-II both are correct.

Sol. Formal charge = valence e’s – non bonding e’s (2) Statement-I and Statement-II both are incorrect.
br

 bonding electrons  (3) Only Statement-I is correct.

– 
 2 
(4) Only Statement-II is correct.

Li

9. CH3  Br 
 CH3OH/Nu:
Ans. (1)
Correct order of rate of this reaction for given Sol.
nucleophile
 OH OH O OH
Nu :  I, F, C2H5O, PhO C–H
KOH
+ CHCl3 +
(1) F > PhO > C2H5O > I
Reimer Tiemann
(2) C2H5O> PhO> I> F reaction CHO
(3) I> C2H5O>PhO> F Major Minor
(4) PhO> C2H5O> F> I (Intramolecular (Intermolecular
Ans. (3) H-bonding) H-bonding)
Sol. For the given substrate of nucleophiles : Steam Not steam
volatile volatile
Order of nucleophilicity :
Therefore can be separated by steam distillation
I> C2H5O>PhO> F

2
12. Statement-I : Sucrose is dextrorotatory upon by Sol.
hydrolysis it becomes laevorotatory. CH3 CH3 CH3
Statement-II : Sucrose on hydrolysis gives NaNO2
KOH
glucose and fructose such that the levorotation of Br2 HCl
glucose is more than dextrorotation of fructose. + –
(1) Statement-I is true and Statement-II is false. C–NH2 NH2 N2Cl
(2) Statement-I is false and Statement-II is true. O
CH3 CH3 CuCN
(3) Only Statement-I is correct. HOH
/ H HOH
(4) Only Statement-II is correct.
H
Ans. (1)
COOH CN
Sol. C12H22O + H2O 
HCl
 C6H12O6 + C6H12O6
Sucrose D-glucose + D-fructose
[]D = +66.5°, []D = +52.5°, []D = –92.4° Cl Cl

 Sucrose is dextrorotatory and hydrolysed 14.

product is laevorotatory.
P Q

.O
13. An organic compound with molecular formula Read the following statements :
C8H9NO when reacts with KOH/Br2 forms 'P' (A) Q has more – on chlorine than P.
which on diazotisation forms 'Q' followed by its
(B) Q has more dipole moment than P.
y2
reaction with CuCN forms 'R' which on hydrolysis
(acidic) formed 'S' (S can also be made by (C) In Q, C–Cl bond has double bond character.
hydrolysis of original compound (X) C8H9NO) (D) In Q, Cl is attached to sp2 hybridised carbon
3
'S' can reaction with KMnO4/H forms 'T' which but in P, Cl is attached to sp .
ar

has two types of hydrogen. X will be : (E) In Q, C–Cl bond length is more due to
repulsion between lone pair on chlorine and  e in
–
CH3
CONH2
br

aromatic ring.
(1)
The correct option is :
(1) A, B, D, E (2) C, D
Li

CH3
(3) B, C, D (4) B, C, D, E
(2) Ans. (2)
CONH2
Sol. Theory based
CH3

15. Cycloalkene (X) reacts with bromine. During

(3) reaction 1 mole of cycloalkane consumes 1 mole of
CONH2
Br2 then form a product (Y). The product (Y) has
CH3 O C, Br ratio is 3 : 1. The % of bromine in product
CH2–C–NH2 (Y) is :
(4) (1) 66.11 % (2) 65.11 %
(3) 76.11 % (4) 67.11 %
Ans. (3)

3
Ans. (1) 17. Which of the following graph is a correct between
log PCO v/s log x CO ? [given PCO = Partial Pressure
Sol. C6H10 
Br2
C6H10Br2 2 2 2

of CO2, X CO = Mole fraction of CO2 in solution]

2
Molecular mass of C6H10Br2 is :
(1) (2)

log PCO2
12 × 6 + 10 + 160

log PCO2
72 + 10 + 160 = 242
log X CO2 log X CO2
160
% or Br = 100 (3) (4)

log PCO2
log PCO2
242
% of Br = 66.11 %
log X CO2 log X CO2

Ans. (4)
16. When sodium fusion extract of an organic
Sol. PCO2  K H XCO2
compound was treated with CHCl3 then violet
log PCO2  logK H  log X CO2
colour of halogen appears. If 0.15 gm of the
y = c + mx
organic compound gives 0.12 gm of the silver 18. For the reaction
halide, then find the percentage of halide in organic

.O
A2(g) 2A(g) Gf (A2 )  100KJ / mol
compound.
Gf (A)  50.8625KJ / mol
(1) 43.23% (2) 45.55% At 300K and 1 atm. pressure degree of dissociation
y2
–2
(3) 42.32% (4) 44.12% of A2 gas at equilibrium is x × 10 . Find x.
-1 -1
[R = 8.3 Jmol K ]
Ans. (1) Ans. (58)
3
Atomic weight of I m Sol. –1.725 × 10 = –8.3 × 300 lnKP
ar

Sol. % of I =   100
Molecular weight of AgI W lnKP = 0.693
KP = 2
42 P0
br

127 0.12 2
   100 1  2
235 0.15
1

Li

% of I = 43.23 % 3
100 -2
  10 2 = 57.736 × 10
3

4
19. Statement-I : KH for ideal dilute solution does not 22. If Ecell of following reaction is x × 10–1. Find x
change with varying the concentration of solute.
Pt/ HSnO2–/ Sn(OH)62–, OH–/ Bi2O3/ Bi/ Pt
Statement-II : KH for solution having same gas
[Reaction Quotient, Q = 106]
solute is independent of nature of solvent?

(1) Both statements are correct Given E[Sn(OH) ] 2
/HSnO2
 0.90V
6

(2) Statement-I correct ; Statement-II incorrect

EBi2O3 /Bi  0.44V
(3) Statement-II correct; Statement-I incorrect
(4) Both statements are incorrect Ans. (4)
Ans. (2)
Sol. Ecell  0.44  (0.90)
Sol. Statement-I is correct but statement-II is incorrect.
As KH depends on the nature of gas & solvent. = + 0.46 V
Applying Nernst equation :-
20. Three experiments are running in separate vessel, 0.06
following 1st order kinetics E cell  E cell  log Q
n
Experiment-(A) 100 ml, 10 M
0.06
Experiment-(B) 200 ml, 10 M E cell  0.46  log10 6
6

.O
Experiment-(C) 100 ml, 10 M + 100 ml H2O
Ecell = 4 × 10-1
Select correct order of rate of reaction in above
experiments x=4
y2
(1) A = B = C (2) A = B > C
(3) A > B > C (4) A > B > C
23. Find temperature (in kelvin) at which rate constant
Ans. (2)
are equal for the following reaction ?
Sol. Rate  [concentration of Reactant]1
ar

24000
21. For an ideal gas volume is made 8 times and A → B, K = 10 4
e T
temperature is decreased 4 times, and heat
br

30000
exchanged during process is zero (q = 0), select the
P → Q K = 106 e T
correct gas
(1) CH4 (2) He Ans. T 
Li

(3) CO2 (4) NH3 24000 30000

4 6
Ans. (2) Sol. 10 e T  10 e T

Sol. Using TV–1 = K 6000

e T  100
T1V1–1 = T2V2–1
6000
1  2 ln10
T1  V2  T
 
T2  V1 
6000
T
4 = (8) –1 2  2.303

2 = 3( –1) T = 1302.64 K

T 
 = 5/3

5
24. 25. For Balanced chemical reaction
2Al(s) + 6HClaq. → 2AlCl3 + 3H2(g) which of the
List-I List-II
following is correct.
(KJ)
(1) With excess of Al, volume of H2 gas produced
(I) Isothermal reversible (1mole (A) 8.32
per mole of HCl reacted will be 33.6 L at 1 atm &
ideal gas, T = 300K, 2dm3to
3
273K.
20dm ) calculate |w|
(2) With excess of Al, volume of H2 gas produced
(II) Isothermal irreversible (B) 6
per mole of HCl reacted will be 11.2 L at 1 atm &
[3KPa, 1m3 to3m3] calculate
273K.
|w|
(3) With excess of HCl, moles of AlCl3 produced
(III) 1 mole gas undergoes (C) 4
per mole of Al reacted are 2.
constant pressure process in
(4) At given P and T, 12 L HCl produce 6 L H2
which change in temperature
gas.
is 400K, Cp = 5R/2, H will
be Ans. (2)

(IV) 1 mole ideal gas having (D) 5.74

Cv=3R/2 and T = 320K, .O
Sol. 6 moles HCl → 3 mol H2

3
y2
1→ mole H2 = 11.2 L at (1atm and 273K)
calculate U 6

Select the correct match 4th option is incorrect since, HCl is in aqueous

(1) I-A: II-B: III-D: IV-C medium.

ar

(2) I-D: II-B: III-A: IV-C

(3) I-B: II-A: III-C: IV-D
br

(4) I-A: II-B: III-C: IV-D

Ans. (2)
Li

 V2 
Sol. (I) w  nRT ln  
 V1 

8.314  20 
 1  300  ln    5.74KJ
1000  2 

(II) w = –Pext (V2– V1)

= –3 × 103 Pa × (3 – 1)
= –6KJ
1  5  8.314
(III) H   400  8.32KJ
2  1000

1  3  8.314
(IV) U  nCv T   320  3.99 4KJ
2  1000

6
 LIBRARY 2.O
By Aarif Bhaiya and Raghavendra bhaiya

PHYSICS TEST PAPER WITH SOLUTION

1. A particle is projected at an angle of 60° with the Sol.
ground. When projectile makes an angle 45° with 2Esin30°
the horizontal, its speed becomes 20 m/s, then E E
E
initial velocity is : 30° 30°  kQ 
(1) 20 2 m/s (2) 10 2 m/s 2Ecos30° 30°
E  R2 
 
E
(3) 5 5 m/s (4) 10 5 m/s
Ans. (1)  
Enet  2Ecos30o ˆi  2Esin30o ˆj 
Sol.
 3kQ ˆ kQ ˆ
20 R2

i  2 j
R

45° 20 3. As shown in the figure, six rods of same geometry

.O
2
are connected, and maintained at temperatures
60°
100°C and 40°C. The temperature at points A and
B are :
y2
20
u cos 60° = K K
2 A
3K B K
100°C 40°C
u 20 T1 T2
 3K 3K
2
ar

2
40 (1) TA =73°C, TB = 89°C
u=
2
br

(2) TA =85°C, TB = 75°C

u = 20 2 m/s (3) TA =89°C, TB = 73°C
2. Find electric field intensity E at centre of circle : (4) TA =74°C, TB = 88°C
Li

y Ans. (3)
 
Sol. Let  R  
–Q +Q  3KA 
30° x
30°
+Q R 3R
+Q 3R
R TA TB 3R
100 40
KQ KQ  3KQ ˆ KQ ˆ
(1) 2 ˆi  2 ˆj (2) i 2 j R R
R R R2 R
KQ ˆ 3KQ ˆ 3KQ ˆ 3KQ ˆ
(3) 2
i j (4) i j 11R/2
R R2 R 2
R2 100 40
Ans. (2)

1
   m1 
v

f
u = +9cm f = – 4cm
 100  40  u uf
H  11R  … (1)
  f 4
 2  m'  
uf 5
100  TA
 ….. (2)
20
 1  
R 4 4
 m2 = mm' = 
120 = 1100 – 11TA 10  20  5 5

using (1) and (2) 2 m1 2 5 5

   
TA = 89°C 3 m2 3 4 6

TB  40 5. Escape velocity from a planet of radius R and


3R
density  is given as 10 km/s. Find the escape
using (1) and (3)
R
TB = 73°C velocity from a planet of radius and density
10
4. A convex lens of focal length 5 cm and a concave

lens of focal length 4 cm are placed in contact and :
10
a point object is placed at 10 cm from system. In
this arrangement magnification is m1. Now keeping
system as it is concave lens is moved 1 cm away
and now magnification becomes m2. Find m1/m2 : .O
(1) 10 100 m/s

(2) 110 10 m/s

y2
(1) 5/6 (3) 100 10 m/s
(2) 4/7 (4) 90 10 m/s
(3) 6
ar

Ans. (3)
(4) 7
4
Sol. Ve = 10 km/s = 10 m/s
Ans. (1)
br

Sol. Initial configuration New configuration 2GM

  10 4
+5cm –4cm R
Li

+5cm –4cm O 10cm

10cm  4 
O G   R 3 
1cm   3   10 4
R
1 1 1 1
  
st
1 refraction
f 5 4 20 8
 G   R 2  10 4 …(i)
f = –20 cm u = –10 cm, f = +5cm 3

uf 3
u = –10cm v  10cm 2G 4   R 
uf
2GM' 10 3  10 
 v'e  
1 1 1 R' R
  m = –1
v u f 10
uf
v 2nd refraction 8G R 2 v
uf v'e  3
 e
3 10 103

2
 10 4 7. In the figure the LED will glow for input of A, B,
 10
4 3/2 
v'e   105/2
10 3 C, D : (0 is low potential and 1 is high potential)
A
v'e  100 10m / s
P
6. Figure shows a meter bridge B
R2
R1
G
LED
C Q
D
(1) 0 0 10 (2) 0 0 0 0
(3) 1 1 0 0 (4) 1 0 0 0
Initially null point was achieved at a distance of 40 Ans. (1)
cm. When a resistance 16  is attached in parallel Sol. LED will glow in forward biasing :
with R2, new balance point was achieved at 50 cm. P higher potential – 1
Then find value of R1 and R2 :
Q lower potential – 0
(1) R1 = 8, R2 =
16
3
(2) R1 = 16, R2 = 8


.O
8. A closed tube filled with ideal gas is rotating with
'' along axis passing through end A. Find pressure
y2
16 at other end B (M is molar mass of the gas,  is
(3) R1 = , R2 = 8
3 length of tube and T is the temperature of gas) :
(4) R1 = 8, R2 = 16 

Ans. (3)
ar

Sol. Initially :
A B
R1 40 2 2
   R1  R 2
br

R 2 60 3 3 Given pressure at 'A' is PA :

Again 2 2 M 2 2 M
(1) PAe 2RT
(2) PAe RT
Li

R1 2 16R 2
 1  R2   R 2  8
16R 2 3 16  R 2 2 2 M 2 2 M
16  R 2 (3) PAe 3RT
(4) PAe 4RT

16 Ans. (1)
R1  
3
Sol.
dx

x  ac = 2x
P (P + dP)

A[(P + dP) –P] = (dm) (2x)

(dm) 2
dP = x
A

3
 ()(A)(dx)2 x 10. A simple pendulum with bob of mass m carrying
dP =
A charge q is in equilibrium in presence of horizontal
also [PM = RT] electric field E, then tension in the thread is :
PM

RT 
 PM  2 E
dP =    xdx
 RT 
PB
(1) T  (qE)2  (mg)2
dP  M 2


PA
P

RT 0
xdx
(2) T = mg + qE tan

 P  2 2 M (3) T  (qE)2  (mg)2

n B  
 PA  2RT
(4) T = mg – qE tan
2 2 M
PB = PAe 2RT
Ans. (1)
9. For an ideal gas in a reversible process (Q = 0), Sol.

.O
volume becomes 8 times and temperature becomes
1  T
times the initial value. Identify the gas : E qE
4
y2
(1) CO2 mg
(2) O2
T  (qE)2  (mg)2
ar

(3) NH3
11. There is a glass sphere of refractive index 1.5, on
(4) He which a parallel beam of light falls. Find distance
br

Ans. (4) of final converging point of final emergent ray

from centre of the sphere. Radius of sphere is 50
Sol. PV = constant cm :
Li

TV–1 = constant (1) 75 cm

(2) 70 cm
T
TV–1 =   (8V)( 1) (3) 80 cm
4
(4) 65 cm
4 = 8(–1)
Ans. (1)
2 3–3
2 =2 Sol.
2 = 3(–1)

5
= u=1.5
3

Gas is a monoatomic gas

1st refraction
Answer is He.

4
 1.5 1 1.5  1 13. A rod of mass 'm' and length 'L' is released on a
  rail placed in uniform magnetic field B. What will
v  50
be the terminal velocity of rod :
1.5 1 R
  v  150cm or
v 100 B
= 50 cm from 2nd surface L

2nd refraction
 Rail
1 1.5 1  1.5
 
v 50 50
mgR mgR
(1) (2)
= –2 B2 L2 B2 2
1 1 3 mgR mg
  (3) (4) 2 2
v 100 100 B 2 B R
4 Ans. (2)

100
v = 25 cm
 Distance from centre = 75 cm Sol. Terminal velocity

.O
12. Statement-1 : Liquid pressure is only exerted on
Bi ()
solid surface in contact and is exerted in between
the layers of liquid.
y2
Statement-2 : Surface tension arises due to mg
difference in potential energy of molecules in bulk (B)(v)( )
of liquid and at surface. i
R
ar

(1) Both Statement-1 and Statement-2 are incorrect.

B(i) () = mg
(2) Statement-1 is correct but Statement-2 is incorrect.
 Bv 
B   mg
br

(3) Statement-1 is incorrect but Statement-2 is correct.

 R 
(4) Both Statement-1 and Statement-2 are correct. B2 2 v
 mg
Ans. (4)
Li

R
Sol. Theory mgR
v
B2 2

5
 16. A photon is incident on particle having mass m =
1
14. Find energy density at the instant current is 15.356 amu. What should be the frequency of
e
 photon so that particle of mass 'm' breaks into four
. Find .
times maximum value. If value is 
e2 -particles :
(Given :  = 10 volt, R = 10, L = 10 mH, (given : m = 4.004 amu ;h = 6.6 × 10–34 Js)
N
 10000 .) (1) 14.9 × 1019 kHz
(2) 12.9 × 1019 kHz
I R L (3) 9.9 × 1019 kHz

 (4) 10.9 × 1019 kHz

Ans. (1)
Ans. 20
Sol. hv = (4 × 4.004 – 15.356) amu ×c2
I0
Sol.  I  I 0 (1  e  Rt /L ), where I0 = /R
e 0.66
v  931  106 eV
1 B2 1 h
 0 nI 
2
Energy density = 
2 0 20 v = 14.9 × 1019 kHz
1 17. Match the following :
 0 n 2 I 2
2
1
 0 n 2
2
I
e
2
0
2
.O (1)
(2)
Spring constant
Thermal Conductivity
(i)
(ii)
2
ML T K
MLT K
–2

–3
–1

–1
y2
0 –2
2 (3) Boltzman constant (iii) ML T
1 2  10  1

2
 
  4   10 7 10000    2
 10  e (4) Inductance (iv)
2
ML T A
–2 –2

 (1) (1) (ii), (2) (iii), (3) (i), (4) (iv)
ar

 2  10 1   2 
e  (2) (1) (iii), (2) (i), (3) (ii), (4) (iv)
  (3) (1) (i), (2) (ii), (3) (iii7), (4) (iv)
 20  2  20
br

2
e e 
(4) (1) (iii), (2) (ii), (3) (i), (4) (iv)
15. The energy required to excite electron from first Ans. (4 )
Li

Bohr's orbit of Hydrogen atom to second Bohr's

orbit in J is : Sol. F = K.x
(1) 1.634 × 10–18 J (2) 1.2 × 10–18 J K = F/x
–18 –20
(3) 0.2 × 10 J (4) 1.2 × 10 J
[MLT 2 ]
[K]   MT 2 (iii)
Ans. (1) [L]
13.6 (A) (iii)
Sol. En  eV
n2
n = 1; E1 = –13.6 eV (B) Thermal conductivity :  MLT 3K 1   (ii)
13.6
 n = 2; E 2   3.4eV (C) Boltzman constant :  ML2 T 2K 1   (i)
22
 E = E2 – E1 = – 3.4 – (–13.6) (D) Inductance :  ML2 T2 A2   (iv)
 10.2 eV
 E = 10.2 × 1.6 × 10–19
 E = 1.634 × 10–18 J

6
18. An -particle is projected towards a fixed gold M1R12 M 2 R 22

nucleus (Z = 79) with kinetic energy 7.9 MeV. If 2 2
particle is just able to touch the nucleus boundary. R12 t1R12 R 2 t R 2
Find diameter of nucleus :   2 2 2
2 2
(1) 57.6 fm (2) 45.6 fm t1 R 24
 4  24
(3) 36.6 fm (4) 20.6 fm t 2 R1
Ans. (1) t1
 16
Sol. Kf + Ui = Kf + Uf t2
[Link] 21. If initially force on m0 = F0 . When position of 4m
7.9 MeV + 0 = 0 
r & 3m are interchanged, force become F'. If F0/F' =
9 109  79e.2e / 5 . Find :
7.9 106  e 
r 4m L 3m

r = 9 × 103 × 10 × 2 × 1.6 × 10–19

m0 L
= 28.8 × 10–15 = 2.88 × 10–14 m
d = 2r = 5.76 × 10–14 m m 2m

.O
= 57.6 fm (1) 1 (2) 2
(3) 3 (4) 4
Ans. (2)
19. A ray of light is incident at angle of incidence 'i' on
y2
an equilateral prism. If the ray emerges grazing the Sol. Initial configuration
second surface, find angle of refraction (in degree)
4m L 3m
at first surface. Refraction index is 2 .
Ans. (15) m0
ar

L
Sol. Equilateral prism.
A = 60° m 2m
br

e=/2
r r2
1
m0
Li

Sinr2 =[Link] =1 Gmm 0

F2 2
1 1 r2
Sinr2 = 
 2
New configuration
r2 = 45°
3m L 4m
 r1 = A – r2 = 15°
20. Two discs having same moment of inertia about m0
L
their axis. Their thicknesses are t1 and t2 and they
have same density. If R1/R2 = 1/2, then find t1/t2 : m 2m
(1) 1/16 (2) 16
(3) 1/4 (4) 4
m0
Ans. (2)
Sol. I1 = I2 Gmm 0
F '  10
r2

7
 F 1 2 24. Find the moment of inertia about given axis.
  2 2. 
F' 10 5 Two solid spheres
= 2
22. Two coherent loudspeaker L1 and L2 are placed at
separation of 10 m parallel to the wall at distance
40 m as shown in the figure. On width AB on the m1 = 10 kg m2 = 5 kg

wall, 10 maximas and minimas are found. If R1 = 20 cm R2 = 10 cm

velocity of sound is 324 m/s. find frequency of

(1) 0.63 kg m2 (2) 0.61 kg m2
sound ( 5  2.23 ) :
(3) 0.62 kg m2 (4) 0.60 kg m2
L1 B
Ans. (1)
25 m
2 2
10 m A Sol. I = m1R12  m1R12  m 2 R 22  m 2 R 22
40 m 5 5
L2 7
 m1R12  m1R 22 
5
(1) 600 Hz (2) 500 Hz 7

.O
 10  (20)2  5(10)2   10 4
(3) 400 Hz (4) 700 Hz 5
Ans. (1) 7
 10  4  5  102  10 –4
y2
5
Sol. L1B = 202  402  20 5m  44.6m
7
  45  10 –2
L2B = 302  402  50m 5
I = 63 × 10–2 kg m2
x = 50 – 44.6 = 5.4 m = 10for 10 cycles
ar

I = 0.63 kg m2
 = 0.54 m 25. If potential is v = 500 volts at (10, 20) and electric
v 324 field given E  10xiˆ  5yjˆ N / C . Find potential at
br

f   600Hz
 0.54 origin.
(1) 1000 volt (2) 2000 volt
23. As shown three coils are given having equal
(3) 1500 volt (4) 3000 volt
Li

current in first and last coil, choose the correct

Ans. (2)
option for the 2nd inductor to have clockwise
Sol. V =  [Link]
current :
(10,20)
L1 L2 L3 V(10,20) – V(0,0) =  
(0,0)
(10xdx  5ydy)
I II III
Clockwise current 10,20
Anti-clockwise current  5 
500 – V =  5x 2  y 2 
(1) Move L1 to words L2 & L3 away from L2.  2  0,0
(2) Move L1 away from L2 & L3 away from L2.  5 
=  5(10)2  (20)2  0 
(3) Move L1 to words L2 & L3 towards L2.  2 
(4) Move L1 away from L2 & L3 towards L2. 500 – V = –1500
Ans. (1) V = 500 + 1500
Sol. Theory V(0,0) = 2000 volt