09-11-2025

0999DJA161151250003 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A steel scale is calibrated at 0°C to measure accurately. If this scale measures the length of a
wooden rod at 0°C & 20°C as 10 cm and 9.975 cm respectively, find the scale reading at 50°C, by
this scale :-

(A) 9.9425 cm
(B) 9.9375 cm
(C) 10.0525 cm
(D) 9.875 cm

2) Water of volume 2 L in a closed container is heated with a coil of 1 kW. While water is heated, the
container loses energy at a rate of 160 J/s. In how much time will the temperature of water rises
from 27°C to 77°C ? (Specific heat of water is 4.2 kJ/kg and that of the container is negligible).

(A) 14 min
(B) 8 min 20 s
(C) 7 min
(D) 6 min 2s

3) Three rods of identical cross section area are made from same metal form sides of isosceles
triangle ABC right angled at B. The point A and B are maintained at temperature T and
respectively in the steady state. Assuming that only heat conduction takes place, the temperature of

point C is

(A)

(B)

(C)

(D)
4) The length of a metal wire is ℓ1 when the tension in it is T1 and is ℓ2 when the tension is T2. The
natural length of the wire is :-

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) The water equivalent of a copper calorimeter is 4.5. If the specific heat of copper is 0.09 cal/g/°C,

(A) mass of the calorimeter is 0.5 kg

(B) thermal capacity of the calorimeter is 4.5 cal/°C
(C) heat required to raise the temperature of the calorimeter by 8°C will be 36 cal
(D) heat required to melt 15 g of ice placed in the calorimeter will be 1200 cal

2) A and B are two points on a uniform metal ring whose centre is C. The angle ACB = θ. A and B are
maintained at two different constant temperatures. When θ = 180°, the rate of total heat flow from A
to B is 1.2 W.

(A) When θ = 90°, this rate will be 1.6 W

(B) When θ = 90°, this rate will be 0.9 W
(C) When θ = 120°, this rate will be 1.5 W
(D) When θ = 120°, this rate will be 1.35 W

3) Radiation from a point black body at the thermodynamic temperature T1 is measured by a small
detector at distance d1 from it. Now the temperature is increased to T2 and distance to d2.

(A)
The power received by the detector is twice in the second case if the ratio .

(B)
The power received by the detector is unchanged if the ratio .

(C)
The power received by the detector is twice in the second case if the ratio .

(D)
The power received by the detector is unchanged if the ratio .

4) The figure shows the stress-strain graphs for materials A and B. From the graph it follows that
(A) Material A has a higher Young’s modulus
(B) Material B is more ductile
(C) Material B can withstand greater stress
(D) Material A can withstand greater stress

SECTION-I (iii)

Common Content for Question No. 1 to 2

A substance is in the solid form at 0°C. The amount of heat added to this substance and its
temperature are plotted in the following graph. If the relative specific heat capacity of the solid
substance is 0.05 Cal/gm-°C, find from the graph

1) The mass of the substance :-

(A) 0.002 kg
(B) 0.02 kg
(C) 0.2 kg
(D) 2.0 kg

2) The specific latent heat of the melting process :-

(A) 40000 calkg–1

(B) 4000 calkg–1
(C) 400000 calkg–1
(D) 400 calkg–1

Common Content for Question No. 3 to 4

A metal block is placed in a room which is at 10°C for long time. Now it is heated by an electric
heater of power 500 W till its temperature becomes 50°C. Its initial rate of rise of temperature is
2.5°C/sec. The heater is switched off and now a heater of 100W is required to maintain the
temperature of the block at 50°C. (Assume Newtons Law of cooling to be valid)

3) What is the rate of heat loss per second when the block was 30°C?

(A) 100 W
(B) 80 W
(C) 50 W
(D) 30 W

4) What is the heat capacity of the block?

(A) 50 J/°C
(B) 100 J/°C
(C) 150 J/°C
(D) 200 J/°C

SECTION-I (iv)

1) Entries in List-I consists of diagrams of thermal conductors. The type of conductor and direction
of heat flows are listed below. Entries in List-II consists of the magnitude of rate of heat flow
belonging to any of the entries in List-I. If temperature difference in all the cases is (T1 – T2), then
match lists.

List-I List-II

(P) (1)

Thick cylindrical shell, flow along axis

(Q) (2)

Thick spherical shell, radial flow

(R) (3) πk0R(T1 – T2)

Thick cylindrical shell, radial flow

 (S) (4)

Solid cylinder, flow along axis, variable k as

k = k0(1 + x/(3R))
(A) P → 3;Q → 1;R → 4;S → 2
(B) P → 3;Q → 2;R → 1;S → 4
(C) P → 1;Q → 2;R → 4;S → 3
(D) P → 3;Q → 4;R → 1;S → 2

2) List-I describes about bodies kept in an environment where temperature of air is T0. In all cases
area, mass & specific heat of each body is same. List–II gives temperature of the body mentioned in
List–I.

List-I List-II
(P) Black body is placed in shade (1) Temperature is T0.
Temperature is maximum amongst
(Q) Black body is placed in Sun light (2)
all bodies in List–I.
Grey body is placed in shade away from
(R) (3) Temperature is Greater than T0.
any radiations
Reflected energy
(S) Grey body is placed in Sun light (4) is maximum amongst all bodies in
List–I
(A) P → 1;Q → 2,3;R → 1;S → 3,4
(B) P → 1,3;Q → 2,3;R → 1;S → 3,4
(C) P → 1,3;Q → 3,4;R → 1,3;S → 3,4
(D) P → 1;Q → 1,3;R → 2,3;S → 3,4

SECTION-III

1) A thin ring of an alloy of inner diameter 20 cm and cross-sectional area 1 mm2, is heated until it
easily slides on a rigid cylinder of diameter 20.025 cm. [For the alloy : α = 10–5/°C, Y = 400 GPa].
When the ring cools down, the value of tension in it, is found to be a × 102 N. Find the value of a.

2) A glass flask contains some mercury at room temperature. It is found that at different
temperatures the volume of air inside the flask remains the same. If the volume of mercury in the

flask is 300 cm3, then find the volume of the flask. If your answer is N (in cm3), fill value of .
[Given that coefficient of volume expansion of mercury and coefficient of linear expansion of glass
are 1.8 × 10–4 (°C)–1 and 9 × 10–6 (°C)–1 respectively]

3) Two conducting rods are joined at P and end A and end B are kept at fixed temperature.
Temperature variation from A to B is given below (k1, k2 conductivity of rods). Find ratio of thermal
conductivities of the rods.

4) A solid sphere of diameter 0.1 m is at 427°C and is kept in an enclosure at 27°C. Take Stefan's

constant = × 10–8 W/m2K4, emissivity of the surface 0.84, specific heat 0.1 kcal/kg K, density =
9280 kg/m , J = 4200 J/k cal. If rate of decrease of temperature of the sphere is N × 10–3 °C/s, then
3

find .

SECTION-IV

1) Four rods of material X and three rods of material Y are connected as shown in figure. All the rods
are of identical lengths and cross–sectional area. Given thermal resistance of rod of material X is, Rx
= R and thermal conductivities of materials are related by relation KY = 2KX.

Column–I Column–II

Thermal resistance between B

(A) (P)
and E

Thermal resistance between A

(B) (Q)
and F

(C) Temperature of junction B (in °C) (R)

(D) Temperature of junction D (in °C) (S)

(T)

2) A load is supported using three wires of same cross section area as shown.
 Column–I Column–II

(A) Equal tensile stress in all wires (P) Y2 = 2Y1

(B) Equal tension in all wires (Q) Y2 = 4Y1

Equal elastic potential energy in all

(C) (R) Y2 = 8Y1
wires

Equal elastic potential energy per

(D) (S) Y2 = 16Y1
unit volume in all wires

Does not depend on

(T)
ratio of

PART-2 : CHEMISTRY

SECTION-I (i)

1)

If the ionization energy of He+ is 19.6 × 10–18 J per atom then the energy of Li2+ ion in the second
stationary state is :-

(A) –4.9 × 10–18 J

(B) – 44.1 × 10–18 J
(C) –11.025 × 10–18 J
(D) None of these

2) An electron in a hydrogen atom in its ground state absorbs energy equal to 26 eV. The wavelength
of the emitted electron is -

(A) 100 nm
(B) 250Å
(C) 3.48Å
(D) 50 nm

3) α-particles are projected towards the following metals, with the same kinetic energy. Towards
which metal, the distance of closest approach is minimum.

(A) Cr
(B) Ag
(C) Cu
(D) Pt

4) The K.E of an electron in the second Bohr orbit of a hydrogen atom is : (a0 is Bohr radius)
(A)

(B)

(C)

(D)

SECTION-I (ii)

1) If number of maxima in radial probability distribution curve are 3, then possible orbital will be :

(A) 4p
(B) 5d
(C) 6f
(D) 3s

2) In a H–like sample, K.E. of e– in 3rd excited state is 3.4 eV then identify correct statement(s).

(A) Binding energy of e– in 3rd excited state of sample is 3.4 eV.

(B) Potential energy of e– in 1st excited state is –13.6 eV.
(C) I.E. of the sample is 54.4 eV.
(D) Potential energy of e– in 3rd excited state is –6.8 eV.

3) The kinetic energy of photoelectron emitted on irradiating a metal surface with frequency is
related by KE = – ϕ. The plots of KE vs. incidented frequency v shows :

(A) A straight line with slope equal to Planck's constant.

A straight line with intercept on x-axis equal to the product of threshold frequency and Plank's
(B)
constant
(C) A straight line with extrapolated intercept on y-axis equal to threshold energy
(D) A straight line with intercept on x-axis equal to threshold frequency

4)

Which of following has correct matching of curve and orbital

(A) I(2p) II(1s) III(4p)

(B) I(3p) II(3d) III(3s)
(C) I(4d) II(2p) III(5d)
(D) I(2s) II(4f) III(3d)

SECTION-I (iii)

Common Content for Question No. 1 to 2

Frequency = f, Time period = T, Energy of nth orbit = En, radius of nth orbit = rn, Atomic number =
Z, Orbit number = n

List-I List-II

(I) f (P) n3

(II) T (Q) Z2

(III) (R)

(IV) (S) Z

(T)

1) Which of the following is only correct combination.

(A) (III) → (R), (IV) → (Q,R)

(B) (III) → (Q,S), (IV) → (T)
(C) (III) → (Q,T), (IV) → (R)
(D) (III) → (Q,R), (IV) → (R,S)

2) Which of the following is only correct combination.

(A) (I) → (P), (II) → (S)

(B) (I) → (Q), (II) → (P)
(C) (I) → (Q), (II) → (S)
(D) (I) → (S), (II) → (T)

Common Content for Question No. 3 to 4

Match the entries in List-I for the spectral series of hydrogen atom with those given in List-II. The
symbols n1 and n2 are the quantum level in the expression.

List-I List-II

(I) Lyman series (P) n1 = 2 and n2 = 3, 4, 5,...

(II) Balmer series (Q) n1 = 4 and n2 = 5, 6, 7,...

(III) Paschen series (R) n1 = 5 and n2 = 6,7,....

 (IV) Pfund series (S) n1 = 1 and n2 = 2, 3, 4,...

(T) n1 = 3 and n2 = 4, 5 6, ,...

3) Which of the following CORRECT match?

(A) (I) → (P), (II) → (S)

(B) (I) → (S), (II) → (P)
(C) (I) → (Q), (II) → (P)
(D) (I) → (P), (II) → (Q)

4) Which of the following CORRECT match?

(A) (III) → (R), (IV) → (T)

(B) (III) → (T), (IV) → (R)
(C) (III) → (S), (IV) → (R)
(D) (III) → (P), (IV) → (R)

SECTION-I (iv)

1) Match the list -

List-I List-II

(P) Angular probability is independent of θ & ϕ (1) 5d

(Q) (2) 5p

(R) Two maxima in 4πr2R2 vs r graph. (3) 4s

(S) (4) 3p

(A) P → 3;Q → 4;R → 1;S → 2

(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 3;Q → 1;R → 4;S → 2
(D) P → 2;Q → 3;R → 4;S → 1

2) Match each List-I with an appropriate pair of characteristics from List-II and select the correct
answer using the code given below the lists.
 List-I List-II

maximum number of spectral

(P) Lyman series (1)
line observed = 6

maximum number of spectral

(Q) Balmer series (2)
line observed = 2

In a sample of H-atom for 5

(R) (3)
→ 2 transition. 2nd line has wave number

In a single isolated H-atom

(S) (4)
for 3 → 1 transition. 2nd line has wave number
(A) P → 3;Q → 4;R → 1;S → 2
(B) P → 1;Q → 2;R → 4;S → 3
(C) P → 3;Q → 1;R → 2;S → 4
(D) P → 2;Q → 3;R → 1;S → 4

SECTION-III

1) The ratio of wavelength of II line of balmer series and 1st line of Lyman series is-

2) The figure shows a sample of H-atoms having electron revolving in higher orbit ‘n’.
If this electron makes transition from this orbit ‘n’ to ground state, total possible Number of paschen
lines emitted are.

3) Electrons in the H-atoms jump from some higher level upto 3rd energy level. If six spectral lines
are possible for the transition, find the initial position of electron.

4)

A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The number of photons
emitted per second by the bulb is x × 1020. The value of x is _________.
[Given : h = 6.626 × 10–34 Js and c = 3.0 × 108 ms–1]

SECTION-IV

1)

Column-I Column-II
 Electron moving in 2nd Radius of orbit in which moving
(A) (P)
orbit in He+ ion electron is is 0.529 Å

Electron moving in 3rd Total energy of electron

(B) (Q)
orbit in H-atom is (–)13.6 × 9eV

Velocity of electron is
Electron moving in 1st
(C) (R)
orbit in Li+2 ion
m/sec

De-broglie wavelength of
Electron moving in 2nd
(D) (S)
orbit is Be+3 ion
electron is Å

Potential energy of electron is (–)

(T)
27.2 × 9 eV.

2) Match the column -

Column-I Column-II

(A) ℓ (P) Indicates the distance from nucleus

(B) s (Q) It can have only two possible values.

(C) m (R) Possible values are 0 to (n – 1)

Indicates the possible orientations in

(D) n (S)
space.

Possible values are +ℓ to –ℓ including

(T)
‘Zero’

PART-3 : MATHEMATICS

SECTION-I (i)

1)

If , then k is equal to

(A) 102
(B) 99
(C) 105
(D) 104

2) Anmol has 8 friends then the number of ways he invite one or more of them to dinner is

(A) 28
(B) 28 – 1
(C) 28 + 1
(D) 8

3) If the coefficients of x7 and x8 in are equal, then n is

(A) 56
(B) 55
(C) 45
(D) 15

4)

Let x be the 7th term from the beginning and y be the 7th term from the end in the expansion of

. If y = 12x then the value of n is

(A) 9
(B) 8
(C) 10
(D) 11

SECTION-I (ii)

1) 2m white identical coins and 2n red identical coins are arranged in a straight line with (m + n)
coins on each side of a central mark. The number of ways of arranging the coins, so that the
arrangements are symmetrical with respect to the central mark.

m+n
(A) Cm
m+n
(B) Cn
m+n
(C) C|m – n|
m+n
(D) C|n – m|

2) There are 10 points on a plane of which 5 points are collinear. Apart from these five points no
three points are collinear. If m denotes the number of straight line joining these points and n
denotes the number of triangles formed joining these points then

(A) m = 36
(B) m = 110
(C) n = 110
(D) n = 36

3) If = I + f, where I is an integer and 0 < f < 1, then :

(A) I is an even integer

(B) I is an odd integer
(C) (I + f)(1 – f) = 1
(D) f2 – f + 1 = 0

4) If (1 + x + 2x2)20 = a0 + a1x + a2x2 + ... + a40x40, then a0 + a2 + a4 ... + a38 is equal to

(A) 219(230 + 1)
(B) 219(220 – 1)
(C) 239 – 219
(D) 239 + 219

SECTION-I (iii)

Common Content for Question No. 1 to 2

x is a four digit number formed by using digits 1, 2, 3, 4, 5, 6 without repetition. On the basis of
above information, answer the following questions :

1) Choose the correct statement(s) -

(A) The total number of such x is 360.

(B) The total number of such x is 720.
(C) The total number of such x which are even, is 360
(D) The total number of such x which are even, is 180.

2) Choose the correct statement(s) -

(A) The number of such x divisible by 4 is 72

(B) The number of such x divisible by 4 is 96
(C) The number of such x divisible by 25 is 12
(D) The number of such x divisible by 3 is 120

Common Content for Question No. 3 to 4

0
If n ∈ N and if (1 + 4x + 4x2)n = , where a , a1, a2, ..., a2n are real numbers.

3) The value of a2n–1 is divisible by

(A) 22n
(B) n. 22n
(C) (n – 1)22n
(D) (n + 1)22n

4) The unit place of can be

(A) 0
(B) 2
(C) 4
(D) 8

SECTION-I (iv)

1)

List-I List-II

The coefficient of x–9 in the expansion of

(P) (1) 1512
is

The term independent of x in the expansion

(Q) (2) 476
of is

The coefficient of x10 in the expansion of (1 +

(R) (3) 512
x2 – x3)8 is

The coefficient of x4 in the expansion of (3x +

(S) (4) 4320
1)7 (1 – 2x + 3x2) is
(A) P → 3;Q → 4;R → 2;S → 1
(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 1;Q → 3;R → 2;S → 4
(D) P → 3;Q → 4;R → 1;S → 2

2)

List-I List-II

The total number of three digit numbers the

(P) (1) 450
sum of whose digits is even is

The total number of proper divisors of

(Q) (2) 431
N = [Link] is

(R) Exponent of 11 in 2012! is (3) 143

The total number of selections of atleast one

(S) (4) 199
letter from word ALLEN CAREER is
(A) P → 1;Q → 2;R → 3;S → 1
(B) P → 1;Q → 3;R → 4;S → 2
(C) P → 1;Q → 4;R → 2;S → 4
(D) P → 4;Q → 3;R → 4;S → 3

SECTION-III
1) 6 lecturers A,B,C,D,E,F want to deliver lecture in a particular batch (one by one), such that A
wants to take class before B and B wants to take class before C (not necessarily consecutive), if total

number of ways are , then n is equal to (where n ∈ N)

2) If the value of 55C5 – 5C1. 44C5 + 5C2.33C5 – 5C3. 22C5 + 5C4. 11C5 is (ab), where a and b both are prime
numbers, then the value of (a – b) is equal to

3) There are 4,5 and 6 points lying on 3 parallel lines L1,L2 and L3 respectively such that no three
points lying on different lines are collinear, then maximum K number of triangles can be formed by
joining given points. Sum of digits of K is equal to

4) If number of solutions of equation x + 2y + z = 13 is nCr where x & z are even natural number & y
is positive number, then least value of (n + r) is

SECTION-IV

1) Consider the word "BREAKAGE". The number of ways in which the letters of this word can be
arranged such that

Column-I Column-II

(A) The two A's are not together is (P) 720

The two E's are together but no two A's

(B) (Q) 1800
are together is

(C) Neither two A's nor two E's are together is (R) 5760

(D) No two vowels are together is (S) 7560

(T) 5050

2)

Column–I Column–II

(A) In the expansion of , if the number of (P) 29

irrational terms is λ then λ is greater than

If numerically greatest term in the expansion of (1 – 3x)8

(B) (Q) 58
for is Tr, then (9r + 4) is factor of

The coefficient of x10 in (1 + x2 – x3)8 is K,

(C) (R) 82
then is greater than or equal to
 If the sum of coefficients in the expansion of

(D) (17x – 17x5 + 3)2017 is n, then the (S) 97

n
number of dissimilar terms in the expansion of (1 + x) is
less than

(T) 98
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B B A C

SECTION-I (ii)

Q. 5 6 7 8
A. B,C,D A,D C,D A,D

SECTION-I (iii)

Q. 9 10 11 12
A. C B C D

SECTION-I (iv)

Q. 13 14
A. A A

SECTION-III

Q. 15 16 17 18
A. 5 8 3 5

SECTION-IV

Q. 19 20
A. A->R,B->S,C->Q,D->P A->Q,B->Q,C->R,D->S

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 21 22 23 24
A. C C A C

SECTION-I (ii)

Q. 25 26 27 28
A. A,B,C,D A,C,D A,D B,C

SECTION-I (iii)

Q. 29 30 31 32
A. D B B B
 SECTION-I (iv)

Q. 33 34
A. C A

SECTION-III

Q. 35 36 37 38
A. 4 3 6 2

SECTION-IV

Q. 39 40
A. A->S,B->R,C->QT,D->P A->R,B->Q,C->ST,D->P

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 41 42 43 44
A. D B B A

SECTION-I (ii)

Q. 45 46 47 48
A. A,B A,C B,C B,C

SECTION-I (iii)

Q. 49 50 51 52
A. A,D B,C,D A,B A,B

SECTION-I (iv)

Q. 53 54
A. A B

SECTION-III

Q. 55 56 57 58
A. 3 6 7 8

SECTION-IV

Q. 59 60
A. A->S,B->Q,C->R,D->P A->PQR,B->Q,C->PQRST,D->ST
 SOLUTIONS

PART-1 : PHYSICS

1)

20°C → 10.025 = 10(1 + α × 20)

10.025 = 10 + 10α × 20
0.025 = 200 × α ⇒ α = 0.025
50°C → x = 10(1 + α × 50)
x = 10 + 10 × α × 50

x = 10 + 500 ×

= 10 + 2.5 × = 10 +
= 10 + 0.0625 = 10.0625
Scale reading = 10 – 0.0625 = 9.9375 cm

2)

dQ = mC dT

840 = 103 × 10–3 × 2 × 4.2 × 103 ×

3)
Rate of heat flow in BC = Rate of heat flow in CA
4) Let the natural length of wire = ℓ
Change in length (ℓ1 – ℓ) when tension T1.
and change in length (ℓ2 – ℓ) when tension T2.

∴ (ℓ1 – ℓ) = ...(i)

ℓ2 – ℓ = ...(ii)

⇒ ℓ1T2 – ℓT2 = ℓ2T1 –ℓT1

5)
–1
B- Thermal capacity of the calorimeter is 4.5 cal°C
C- Heat required to raise the temperature of the calorimeter by 8°C will be 36 cal
D- Heat required to melt 15 gm of ice placed in the calorimeter will be 1200 cal

(b) Thermal capacity = ms

(c)
(d)

6)

HII = =
Similarly HIII = 1.35 W

7)

Intensity in first case

I1 =
Intensity in second case
For I1 = I2 ⇒

Similarly for I2 = 2I1

8)

The slope of the linear portion of the curve gives the Young’s modulus of the material. The
slope of the linear portion OP for material A is greater than that of the linear portion
of material B. Hence, statement (a) is correct. The plastic region for material A (from P to Q) is
greater than that (from R to S) for material B, which indicates that material A is more ductile.
Hence, statement (b) is incorrect. The breaking stress for material for material B (i.e. stress
corresponding to point S) is less than that for material A (i.e. stress corresponding to point Q),
which implies that material B can break more easily than material A. Hence, choice (c) is also
incorrect. Material A is stronger than material B because it can withstand a greater stress
before it breaks. The breaking stress is the stress corresponding to point Q for material A and
to point S for material B. Hence, the correct choices are (a) and (d).

9)

10)

11) Given at 50°C : Newton’s Law of cooling

Power Loss = 100 = k(50 – 10)

⇒k= =
∴ At 30°C

PLoss = k(30 – 10) = × 20 = 50 W

12) Pheater = Pgiven to block + PLoss to surroundings

Initial PLoss = 0

∴ 500 = C +0
500 = C × 2.5
∴ C = 200 J/°C

13)
(P) Thick cylindrical shell, along the axis:
Length: L = 3R

(Q) Thick spherical shell, radial flow:

(R) Thick cylindrical shell, radial flow:

(S) Solid cylinder, along the axis:

A = πR2
Length: L = 3R

14) • In shade temperature of body would be equal to the surrounding (in steady state).
• When body is placed in sun-light its temperature is more than surrounding due to indent
radiations.
• Energy flow is more in black body due to radiation than convection.
• Reflection is more in grey body then black body. (Reflection in perfectly black body is zero.)

15)

16)

We have
Vflask = VHg + Vair
As (ΔV)air = 0
∴ (ΔV)flask = (ΔV)Hg
∵ Cavity having same expansion co-efficient for material
∴ Vf gf ΔT = VHg γHg ΔT

∴
∴ Volume of flask = 2000 cm3

17)

Slope of temperature graph = temperature gradient

Temperature gradient =

0
18) σeA (T4 – T 4) = mS

∴ =

=
On putting values and solving, we get

= 200 × 10–3 °C/s

19)

For (A)

No heat current flows through rod CD so

For (B)

For (C) Total heat current form A to F, I =

let temperature of B be TB then ⇒ °C

For (D) As heat current is inversely proportional to heat resistance

so heat current in BD = I= I

°C
 20)

σ1 = σ2
⇒ Y1∈1 = Y2∈2 ⇒ 4Y1 = Y2

U1 = U2

(S) u1 = u2

PART-2 : CHEMISTRY

21) EH in first orbit =

in second orbit = –
⇒ – 11.025 × 10–18 J

22)

Etotal = IEH + KEe

26 = 13.6 + KEe
KEe = 12.4 eV

23) Question Explanation:

In metal, the distance of closest approach is minimum.
Concept:
This question is based on Rutherford model.
Solution:
Distance of closest approach is given by

r=
For rminimum, z should be minimum
Final Answer:
The correct option is (1).

24) Centripital force = Coulombic force of attraction

K.E (for x = 2 and Z = 1)

25) In Radial probability distribution

n – ℓ – 1 = maxima – 1
n–ℓ–1=2
(A) 4p ⇒ 4 – 1 – 1 = 2
(B) 5d ⇒ 5 – 2 – 1 = 2
(C) 6f ⇒ 6 – 3 – 1 = 2
(D) 3s ⇒ 3 – 0 – 1 = 2

26) For H–like sample, T.E. = –K.E.

I.E. = 13.6 Z2 = 13.6 × 22 = 54.4eV

⇒ P.E. = 2 × T.E. = –27.2 eV

PE of 3rd excited = –6.8 e.V

27) Question Explanation:

Find slope & intercept of graph between kinetic energy and ν.

Concept:
This question is based on photoelectric effect.
 Solution:
K.E. = hν – ϕ
y = mx – c

Graph is straight line with slope = h

and intercept on x-axis equal to ν0.

Final Answer:
The correct options are (1 & 4).

28)

Question Explanation: Question is asking about correct matching of curve with given orbital.

Concept: This question is based on Schrödinger equation.

Solution:

(I)

n – – 1 = 1, 2p ⇒ 2 –1 –1 = 0 × A
3P Þ 3 – 1 – 1 = 1 B
4d Þ 4 – 2 – 1 = 1 C
2s Þ 2 – 0 – 1 = 1 D
Possible Answer B,C,D we will check further

(II)
n – – 1 = 0, 1S ⇒ 1 – 0 – 1 = 0
3d → 3 – 2 – 1 = 0
2P → 2 – 1 – 1 = 0
4f ⇒ 4 – 3 – 1 = 0
All possibilities, but from option (A)
 so, far
we can conclude only option B,C,D.

(III)
n – – 1 = 2, 4p → 4 – 1 –1 = 2 A
3s → 3 – 0 – 1 = 2 B
5d → 5 – 2 – 1 = 2 C
3d → 3 – 2 – 1 = 0 × D
2, 3 are common.
Final Answer:
options (2) & (3)

29) Ans. (I) → (Q), (II) → (P), (III) → (Q,R), (IV) → (R,S)

30) Ans. (I) → (Q), (II) → (P), (III) → (Q,R), (IV) → (R)

31) Ans. (I) → (S), (II) → (P), (III) → (T), (IV) → (R)

32) Ans. (I) → (S), (II) → (P), (III) → (T), (IV) → (R)

33) (P) For s-orbital angular probability is independent of θ and ϕ.

(Q) Radial nodes = 2
Radial nodes = n – ℓ – 1
For 5d ⇒ 5 – 2 – 1 = 2
For 5p ⇒ 5 – 1 – 1 = 3
For 4s ⇒ 4 – 0 – 1 = 3
For 3p ⇒ 3 – 1 – 1 = 1
(R) Number of maxima in 4πr2R2 v/s r graph = n – ℓ

34)

P : For Lyman series, for second line (3 → 1) = R(1)2 = , (3).

Q : For Balmer series, for second line (4 → 2) = R(1)2 = , (4).

R : In a sample of H-atom for 5 → 2 transition, maximum number of spectral lines observed

= =6, (1).
S : In a single isolated H-atom for 3 → 1 transition, maximum number of spectral lines
observed = 2 (3 → 2, 2 → 1) (2).
35)

36) Orbit number = 6

Number of paschen lines emitted = (6 – 3) = 3

37)

Question Explanation: Find initial position of electron

Concept: Bohr Model

Solution: Number of spectral lines =

6= ⇒ 12 =

∴ n22 – 5n2 – 6 = 0.

∴ n2 = 6 or – 1.

Since n2 = –1 is not possible. Hence n2 = 6.

Final Answer: 6

38)

P = 50 W
λ = 795 nm
n = x1020

39) (A) (S)

(B) (R)
(C) (Q) T.E. = –13.6 × 9 eV
(T) P.E. = –27.2 × 9 eV.
(D) (P) R = 0.529
Alternating
(A) n = 2, z = 2
 = 0.529 × 2

TE
so K.E. = 13.6 ev

&

so A → S
(B) z = 1, n = 3

so
hence B → R
(C) n = 1, z = 3

K.E. = 13.6 × 9 so
so C → Q,T
(D) z = 4, n = 2

K.E. = 13.6 × 4 ev so
hence D → P

40)

The correct answer is A → R , B → Q , C → S,T , D → P

PART-3 : MATHEMATICS
41) =

= 20 × 29 + 3 × 210 = 13 × 210

42)

Every friend have two options either he comes or does not

So, (2 × 2 × 2 × …… × 2) – 1 (when no one comes)
= 28 – 1

43) nC72n–7

44) x = T7 = nC6(31/3)n–6(4–1/3)6
y = Tn–5 = nCn–6(31/3)6(4–1/3)n–6
y = 12x
n
Cn–6(31/3)6(4–1/3)n–6 = 12· nC6(31/3)n–6(4–1/3)6
⇒ 12 = (121/3)12–n ⇒ n = 9

45) S2 :
Arrangements will be one side

46) m = 10C2 – 5C2 + 1

n = 10C3 – 5C3

47) I + f =

f' =
I + f + f' = 2k,
f + f' = 1
So I = (2k – 1)
(I + f)(1 – f) = (I + f)f' = 1

48) (1 + x + 2x2)20 = a0 + a1x + ... + a40x40

x = 1, then a0 + a1 + ... + a40 = 420
x = – 1, then a0 – a1 + a2 – ... + a40 = 220
220 + 240 = 2[a0 + a2 + ... + a38 + a40]
 ⇒ a0 + a2 + ... + a38 = 219 + 239 – 220 = 219(220 – 1) ∴ a40 = 220

49)

(A) 6C4 × 4! = 6 × 5 × 4 × 3
(D) These are 3 ways to fill units place.

So, number of even x are 3 × 5 × 4 × 3

50)

B) Last two digits can be 12, 16, 32, 24, 52, 36, 56, 64 (8 possibilities)
So, required answer = 8 × 4 × 3 = 96
(C) Last two digits must be 25.
So, required answer = 4 × 3 = 12
(D) There are six digits (whose sum is 21) and we need to choose four digits leaving two digits.
So, either we can leave 3 & 6, or one-one from each set {1,4} and {2,5}.
So, number of ways in which we can leave two digits = number of ways in
which we can choose four digits = 1 + 2 × 2 = 5
So, required answer = 5 × 4! = 120

51) (1 + 4x + 4x2) = a0 + a1x + a2x2 + ........ + a2n–1 x2n-1 + a2nx2n

n
......(1)
(1 + 4x + 4x2) = (1 + 2x)2n

is divisible by 22n, n 22n

52) (1 + 4x + 4x2) = a0 + a1x + a2x2 + ... + a2nx2n ......(1)

put x = 1
⇒ (1 + 4 + 4)n = a0 + a1x + a2 + ...+ a2n
⇒ a0 + a1 + a2 + ... + a2n = 9n ........(2)
Now put x = – 1
⇒ a0 – a1 + a2 + ... + a2n = 1 ........(3)
(2) + (3) ⇒
unit place can be 0, 2

53) (P)
so 18 – 3r = –9 ∴ 3r = 27 ⇒r=9

so T10 = T9 + 1 = 9C9 = 512x–9

so cofficient of x–9 is 512

(Q)
6 – 2r = 0 ⇒ r = 3
T4 = T3 + 1 = 6C3 . 23 . 33 = 20 × 8 × 29 = 4320
(R) (1 + x2 – x3)8 = [(1 + x2) – x3]
 = 8C0(1 + x2)8 + 8C1(1 + x2)7 (– x3) + 8C2(1 + x2)6(–x3)2 + 8C3(1 + x2)5 + (–x3)3 + ... so
coefficient of x10 = 8C5 + 8C2 × 6C2 = 56 + 28 × 15 = 56 + 420 = 476
(S) coefficient of x4 in (3x + 1)7 (1 – 2x + 3x2)
= 7C3 .34 – 7C4 . 33(2) + 7C5 32 . 3 = 35 × 81 – 35 × 54 + 21 × 27 = 1532

54) (P) The number of three digits numbers

= 9 × 10 × 10
Half of which will have sum of digits even.
(Q) Total divisors of N
= (5 + 1)(3 + 1)(2 + 1)(1 + 1)
= [Link] = 144
⇒ Number of proper divisors = 144 –1 = 143

(R) Exponent of 11 = = 182 + 16 + 1 = 199

(S) 2A, 3E, 2L, 2R, N, C
Selections of atleast one alphabet can be done in (2 + 1)(3 + 1)(2 + 1)(2 + 1)22 – 1
= [Link].4 – 1 = 431

55) Order at A,B,C is one

6
C3.3! = ∴n=3

56) Given series

= coefficient of x5 in
((1 + x)55 – 5C1(1 + x)44 + 5C2(1 + x)33 – 5C3
(1 + x)22 + 5C4(1 + x)11 – 5C5)
= coefficient of x5 in
(t5 – 5C1t4 + 5C2t3 – 5C3t2 + 5C4t – 1)
where t = (1 + x)11
= coefficient of x5 in (t – 1)5
= coefficient of x5 in ((1 + x)11 –1)5
= coefficient of x5 in
((1 + 11C1.x + 11C2.x2 +....)–1)5 = 115 = ab
∴ a – b = 6.

57)
No of Δ's formed
= 4+5+6C3 – 4C3 – 5C3 – 6C3
= 421
∴ sum of digits = 4 + 2 + 1 = 7

58) 2y must be odd natural number

So take 2y = 2k – 1 & k ≥ 1
⇒ x + (2k – 1) + z = 13
2m + 2k + 2n = 14
⇒ m + k + n = 7 m, n & k ≥ 1
⇒ Total solutions = 7–1C3–1 = 6C2

59)

(A) Arrange A's in gaps

∴
(B) Arrange and then two A's in gaps.
∴
(C) Ans.(P) – Ans.(Q) = 7560 – 1800 = 5760
(D) Arrange B, R, K, G and vowels in gaps

60) (A)

For

For
∴ 4 rational and 97 irrational terms

(B)
27 > 5r
for r = 5, T6 > T5
for r = 6, T7 < T6
∴ T6 is numerically greatest
Hence, (9r + 4) = 58.
(C) Coeff of .
(D) Put x = 1, to get n = 81