27-10-2025

4602CJA105021250014 JA

PART-A-PHYSICS

SECTION-I(i)

1) In the given figure table is smooth and pulley and string are ideal then acceleration of centre of

mass of the two blocks system is :-

(A)

(B)

(C)

(D)

2) A car of mass m moves in vertical plane with constant speed v. Normal force on car at A and B are
NA and NB then choose correct option. Radius of curvature at A and B are RA and RB :-

(A)
must be greater than or equal to g

(B)
must be less than g.

(C)
must be greater than g.

(D)
must be less than g.

3) A solid sphere of mass M and radius R is given velocity as shown. Then the value of angular
momentum of the sphere with respect to origin is given by :-

(A)

(B)

(C)

(D)

4)

Sixteen beads of equal mass in a light string are placed on a smooth inclined plane of inclination
sin–1(1/3) such that some of them lie along the incline whereas the rest hang over the top of the
plane. If acceleration of each bead is g/2, the arrangement of beads is that :-

(A) 12 hang vertically

(B) 10 lie along inclined plane
(C) 8 lie along inclined plane
(D) 10 hang vertically

5) The shown system is in equilibrium. Both spring have same spring constant and same natural
length. The tension in string is 10N in equilibrium. If string is burnt then find acceleration of block

(m = 5kg) :-

(A) 2 m/s2 upward

(B) 1 m/s2 upward
(C) 2 m/s2 downward
(D) 1 m/s2 downward
6) The angle between the two vectors and will be :-

(A) 90°
(B) 0°
(C) 60°
(D) 45°

SECTION-I(ii)

1) In the figure shown a uniform rod of mass m and length is hinged. The rod is released when the

rod makes angle θ = 60° with the vertical :-

The angular acceleration of the rod just after release is

(A)

The normal reaction due to the hinge just after release is

(B)

The angular velocity of the rod at the instant it becomes vertical is

(C)

(D)
The normal reaction due to the hinge at the instant the rod becomes vertical is mg

2) Consider a semi circular disc of radius R and mass M :-

(A)

(B)

(C)

(D)

3) Angular displacement of an object moving on a circle of radius 2m is given by where

θ is in radian and t is in s. For a time duration of t = 0 to t = 1s :-
(A)
Average angular velocity is rad/s

(B)
Average angular velocity is rad/s

(C)
Average velocity is m/s
(D) Average velocity is 2 m/s

4) In the given figure find the velocity and acceleration of B, if velocity and acceleration of A are as

shown. Choose the incorrect options :-

(A) vB = 1 m/s & aB = 1 m/s2↓

(B) vB = 0.5 m/s & aB = 0.5 m/s2↓
(C) vB = 1 m/s & aB = 0.5 m/s2↓
(D) vB = 0.5 m/s & aB = 1 m/s2↓

5) A 600 m wide river flows towards South at 4 m/s. A small motor boat travels at 5 m/s in still water

& points in such a direction so that it will travel towards East relative to land :-

(A) The speed of boat relative to land is 3 m/s.

(B) The speed of boat relative to land is m/s.
(C) The time taken by boat to cross the river is nearly 200 second.
(D) The time taken by boat to cross the river is nearly 100 second.

6) Assuming potential energy 'U' at ground level to be zero.

All objects
are made up of same material.
UP = Potential energy of solid sphere
UQ = Potential energy of solid cube
UR = Potential energy of solid cone
US = Potential energy of solid cylinder

(A) US > UP
(B) UQ > US
(C) UP > UQ
(D) US > UR

SECTION-III

1) Consider a semi circular ring of mass M and radius R. Moment of inertia about axis passing

through point C and perpendicular to plane of ring is . Then fill value of (a + b) :-

2) The figure shows the positions and velocities of two particles. If the particles move under the
mutual attraction of each other, then find the position of centre of mass (in m) at t = 1 s :-

3) In the setup shown, blocks of masses 3m and 2m are placed on frictionless horizontal ground and
the free end P of the thread is being pulled by a constant force F. Then the acceleration of the free

end P is . Find a

4) Ball A is projected from tower of height 30 m and B is projected horizontally at 6 m/s. A and B
collide in air. If separation between the towers is d = 10x. What is the value of x :-

5) Position-time graph of a particle of mass 2 kg is shown in figure. Total work done on the particle
from t = 0 to t = 4s is :-

PART-B-CHEMISTRY

SECTION-I(i)

1) Which of the following is not the correct relationship :-

(A) II & IV are not functional isomers

(B) I & II are functional isomer
(C) I & III are chain isomer
(D) I and IV are positional isomer

2) The principle functional group in following compound for IUPAC naming :-

(A) Aldehyde
(B) Ketone
(C) Amine
(D) Amide

3) pH of the aq. solution of 0.05 M Ca(CN)2 at 25°C is :

(A) 10.63
(B) 9.37
(C) 8.63
(D) 8.37

4) For the reaction N2 + O2 ⇌ 2NO, KC is 100 then KC for reaction 2NO ⇌ N2 + O2 will be :-

(A) 0.01
(B) 0.1
(C) 10
(D) 100

5) For a gas obeying vander Waal's equation of state, select incorrect statement.

(A) TC(critical temperature) < TB(Boyle's temperature).

(B) If volume of one gas molecule = x cm3, then the 'b' value = 4x cm3mol–1.
(C) PVm = RT, when Z = 1.

(D)
At critical conditions,

6) An ideal diatomic gas is caused to pass through a cycle shown on the P–V diagram in figure,
where V2 = 3.00 V1. If P1,V1 and T1 specify the state 1, then the temperature of the state 3 is :-

1
(A) (T1/3)
4
(B) (T1/3)
0.4
(C) T1/(3)
2
(D) (T1/3)

SECTION-I(ii)

1) Which of the following is/are correct matchings?

(A)

and → Metamer

(B)
and → Position isomer
(C)
and → Functional isomer

(D)

and → Chain isomer

2)

Which of the following compound has equal number of 1º , 2º & 3º carbons ?

(A)

(B)

(C)

(D)

3) Which of the following solutions will not have pH close to 1.0 ?

(A) 100 ml of (M/10) HCl + 100 ml of (M/10) NaOH

(B) 55 ml of (M/10) HCl + 45 ml of (M/10) NaOH
(C) 10 ml of (M/10) HCl + 90 ml of (M/10) NaOH
(D) 75 ml of (M/5) HCl + 25 ml of (M/5) NaOH

4)

For the gas phase reaction, C2H4 + H2 ⇌ C2H6 (ΔH = – 32.7 kcal), carried out in a closed vessel, the
equilibrium moles of C2H4 can be increased by :-

(A) increasing the temperature

(B) decreasing the pressure
(C) removing some H2
(D) adding some C2H6

5) Two moles of an ideal gas (Cv, m R) The correct statement is/are :-

(A) The pressure at B is 2.0 bar

(B) The temperature at D is 450 K
(C) ΔHCD = 1000 R
(D) ΔUBC = 375 R

6) The orbital angular momentum of an electron is . Which of the following should not be the
permissible value of orbit angular momentum of this electron revolving in Bohr orbit?

(A)

(B)

(C)

(D)

SECTION-III

1) Write all structurally isomeric ethers with molecular formula C5H12O :-

2) How many carbons are present in parent carbon chain of following compound :-

3) The number of chiral centres present in the following compound is

4) Air is trapped in a horizontal gas tube by 36cm mercury column as shown below :-

If the tube is held vertical keeping the open end up, length of air
column shrink to 19cm. What is the length (in cm) by which the mercury column shifts down ?

5) Consider y-axis as inter-nuclear axis, how many of following will lead to π bond formation?
(a) py – py (b) px – px (c) pz – pz (d) dxy – dxy
(e) dyz – dyz (f) px – dxy (g) dxy – pz (h) dxz – dxz

PART-C-MATHEMATICS

SECTION-I(i)

1) The value of is

(A) 3n – 1
(B) 3n + 1
(C) 3n
(D) 3(3n – 1)

2) If r, s, t are prime numbers and p, q are the positive integers such that their HCF is rs2t and their
LCM is r2s3t, then the numbers of ordered pair of (p, q) is

(A) 4
(B) 18
(C) 36
(D) 72

3) The number of ways to distribute 30 identical candies among four children C1, C2, C3 and C4 so
that C2 receives atleast 4 and atmost 7 candies, C3 receives atleast 2 and atmost 6 candies, is equal
to

(A) 205
(B) 615
(C) 510
(D) 430

4) What is the coefficient of x100 in (1 + x + x2 + x3 +.... + x100)3 ?

100
(A) C3
102
(B) C3
102
(C) C2
(D) None of these

5) If x, y, z ∈ R+ such that x5y4z = 9–5 then least value of is

(A) 32
(B) 30
(C) 128
(D) 60

6) Range of the function

(A) R
(B)

(C)

(D) None of these

SECTION-I(ii)

1) If x + y + z = 30 then

33
(A) The number of non-negative integral solution is C2
29
(B) The number of natural number solution is C2
17
(C) The number of even non-negative integral solution is C2
18
(D) The number of even non-negative integral solution is C2

2) The linear permutation of the word BARAAKOBAMA can be done (using all letters)
(A)
in ways if there is no constraint
6
(B) in C2 . 5! ways if A's are together & B's are separated
(C) in 6! 2! ways if all consonants & all vowels are together

(D)
in ways if letter of BARAAK are arranged, keeping OBAMA fixed at extrem right position

3) Consider

(A) If x = 5, y = 2, z = 100, then number of irrational terms in expansion of E is 98

(B) If x = 5, y = 2, z = 100, then number of rational terms in expansion of E is 4
(C) If x = 16, y = 1 & z = 6, then I = 197

(D)
If x = 16, y = 1 & z = 6, then

4) Consider f(x) = sin (x + kr) where k1, k2....., ∈ R. If f(x) = 0 has two distinct roots α and β
then |α – β|can be equal to

(A) 2024π
(B) 2023π
(C) 2012π

(D)

5) Let α and β be the roots x2 – x – 1 = 0, with α > β. For all positive integers n, define

Then which of the following options is/are correct?

(A)

(B)

(C)

(D)

6) Two adjacent sides of a rhombus are 2x + 3y = a – 5 and 3x + 2y = 4 – 2a and its diagonals

intersect at the point (1,2), then a can be

(A) –16
(B) 16

(C)
(D)

SECTION-III

1) The equations of the sides AB, BC and CA of a triangle ABC are 2x + y = 0, x + py = 15a and x – y

= 3 respectively. If its orthocentre is (2, a), <a <2, then p is equal to

2) Consider the number N = 24 34 52 72 112, then the sum of all the odd divisiors which are divisible

by '5' but not by '7' is 112(133λ) then is equal to

3)

Number of rational terms in the expansion of (21/8 + 31/4)56 is equal to

4) If log615 = x, log1218 = y such that log2524 is then |α + β + γ| is

5) If then value of is _____. (where [.] denotes greatest integer

function)
 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. B B B D C A

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. B,C,D B,D A,D A,B,C A,C A,B,D

SECTION-III

Q. 13 14 15 16 17
A. 6 6 5 3 0

PART-B-CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21 22 23
A. D D B A B C

SECTION-I(ii)

Q. 24 25 26 27 28 29
A. C,D A,B,C A,B,C A,B,C,D A,B,C A,B,C

SECTION-III

Q. 30 31 32 33 34
A. 6 5 9 9 5

PART-C-MATHEMATICS

SECTION-I(i)

Q. 35 36 37 38 39 40
A. A A D C D C

SECTION-I(ii)

Q. 41 42 43 44 45 46
A. B,C A,B,D A,C A,B,C A,B,D A,D
 SECTION-III

Q. 47 48 49 50 51
A. 3 6 8 3 2
 SOLUTIONS

PART-A-PHYSICS

1)
2mg – T = 2ma
T = ma

a=

2) At A

3) We have

4) Question explanation: The problem describes a system of sixteen beads of equal mass on
a smooth incline plane with an inclination angle θ = sin–1(1/3). Some beads are on the incline
while the rest hang over the top. The acceleration of each beed is given g/2. we need to
determine the arrangement of the beads.
Concept :- Newton's second law of motion.
Solution :-
Let n beads each of mass m are hanging vertically, then
n mg – T = nm . g/2

_______(1)
also,

Final Answer: The correct option is (4)

5) Explanation Question: In this question a block is hung using two springs and a string. It is
asked to find acceleration of block if string is burnt given that initially system is in
equilibrium.

Concept: springs force and newton's laws of motion.

Solution: Since initially block is in equilibrium so after burning the string tension becomes
zero. that means net force on block is 10N downwards.
Fnet = ma

a= = 2 m/s2 ↓ downwards

Final Answer: The correct option is (3)

6)

= cosq = 0,
∴ θ = 90°

7)
(A) mg sin 60° = α

α=

(B) N2 – mg cos 60° = 0 ⇒ N2 =

mg sin 60 – N1 = m

mg – . = N1

N1 =

N= = =

(C) mg (1 – cos 60°) = =

w=

(D) N – mg =

N= mg

8)

9) Explain question : Angular displacement as a function of time is given we have to find

average angular velocity and average velocity in given time.
Concept : This question is based on kinematics of circular motion
10) Explain the Question :
We are given acceleration and velocity of block 'A' for given problem choose the incorrect
equation.
Concept : This question is based on constraint motion.
Solution :
The virtual work done by the tension force for the system will be zero i.e.
and
∴ 2TaA – 4T aB = 0

and also vA = 2vB

–1 = 2 × vB

= 0.5 upwards
Final Answer : 1, 2, 3

11) Sol.

vb = 3m/s
12)

UP = mgR = =

(A) US > UP

(B)
∴ UQ > US
(C) UP < UQ
(D) US > UR

13)

Explanation Question: Considering a semicircular ring and we have to find its moment of
inertia

Concept: This question is based on rotational inertia

Solution:
ICOM + M

ICOM + M

IC = =
Final Answer: 6

14) (xcm)i

(ucm)i
∴
∴ At t = 1 sec
(xcm)f = (xcm)i + (ucm)it + 0 = 5 + 1 × 1 = 6m

15)

Power method

16)

VAB =

T=
30 = 24T
d = 30 m
x=3

17)

Total work done = change in kinetic energy

= mv22 – mv12 = (2) × (1)2 – × 2 × (1)2 = 0

PART-B-CHEMISTRY

18) (I) & (IV) are functional isomers.

19)
(D) Amide

20) Explanation:
Calculation of pH of 0.05m ca(CN)2 solution at 25°C
Concept:
This Question is based on Salt hydrolysis
Solution:

Final answer: Option: (2)

21)

Explain Question : Given the equilibrium constant Kc for a reaction, we are asked to find the
Kc for the reverse reaction.

Concept : For a reversible reaction, the equilibrium constant of the reverse reaction is the
reciprocal of the forward reaction's constant: Kc(reverse)=1/Kc(forward)

Solution : Forward reaction: N2 + O2 2NO, Kc=100

Reverse reaction: 2NO N2 + O2, Kc=1/100=0.01

Final Answer : option (1)

22) b = 4x × NA cm3mol–1.

23) V2 = 3V1
= Constant.
γ
RTV /V = Constant
Vγ–1 . T = Constant
(γ for diamotic gas = 7/5)

24) Explanation Question: To select correct celationship

Concept: Structual isomerism
Solution:
1) CH3 – COOH HCOOCH3 Functional isomes

2) and Chain isomers

 3) Functional isomers

4) Chain isomers
Final Answer : (3), (4)
A is functional group isomer & B is chain isomer

25)

26)

Explaining the Question :- Question is asking about solution which not have pH close to 1.0

Concept:- This question is based on mixture of acid & base

Solution :-

(1) Complete neutralization (2) ⇒ pH = 2

(3) OH- is in excess ⇒ pH > 7

(4)
Final Answer :- 1, 2, 3

27)

High temperature favours backward reaction.

28)
For process CD

TD = 450K

Also, ΔHCD = nCpΔT =

29)
∴ l=3
So value of n > 3

∴ Angular momentum =

So angular momentum >

So

30) Explain question : to find out no. of structurally isomeric ethers with mol. for C5H12O
Concept : This question is based on no. of structural isomers.
Solution : There will be 6 structurally isomeric ethers are possible with C5H12O
C5H12O structure isomer of ether

(i) (ii)

(iii) (iv)

(v) (vi)
Final answer : 6

31)
5 carbon chain
 32) Explain question : To count no. of chiral centers in the given compound.
Concept : This question is based on counting of chiral centres.
Solution :

The star shown indicates chiral centre.

Total 9 chiral centres.
Final answer : 9

33)

P final = final height = 19cm

P initial = 1atm, initial length = hi cm
according to Boyle’s Law
Pivi = Pfvf

hi = 28cm
The length by which the Hg column shifts down = hi - hf = 28 - 19 = 9cm

34)

py – py → σ-bond
px – px → π-bond
pz – pz →π-bond
dxy – dxy →π-bond
dyz – dyz → π-bond
Px – dxy → π-bond
dxy – dxz → δ-bond
dxy – pz → no-bond

PART-C-MATHEMATICS
35)
n
C1 (1C0 + 1C1) + nC2 (2C0 + 2C1 + 2C2) + nC3 (3C0 + 3C1 + 3C2 + 3C3) + ... + nCn (nC0 + nC1 + ... +
n
Cn)
n
C1 21 + nC2 22 + nC3 23 + ... + nCn 2n
(1 + 2)n – 1
3n – 1
Option A is correct.

36)

37) No. of ways =

38) Question Explanation: Find coefficient of x100 in (1 + x + x2 +.....+ x100)3.

Concept: This question is based on sum of n terms of G.P. =

coefficient of xr in (1 – x)–n = n+r–1Cr
n
Cr = nCn–r

Solution: 1 + x + x2 +.....+ x100 = (1)

to find coefficient x100 in

coefficient x100 in (x101 – 1)3 (x – 1)–3
coefficient x100 in (–1)(x101 – 1)3(1 – x)–3
= (–1)(–1)3 3+100–1C100
= 102C100 = 102C2

Final answer: The correct option is (3).

39)

Using AM ≥ GM

⇒
40)

Since x is near,

41)

Total number of Non negative integral solutions ofx + y + z = n is n+3–1C3–1

x + y + z = 30
(A) Total number of non-negative integral solutions = 30+3–1C3–1
(B) The number of natural number solutions is 27+3–1C3–1
(C) x = 2p, y = 2q, z = 2r
So, p + q + r = 15 then total number of integral solutions is 15+3–1C3–1
i.e. 17C2

42) (B) A's are together & B's are separated

| × | × | × | × | × | = 6C2 · 5!

(C) all consonants BRKBM & AAAAAO is

(D)

43)
(A) x = 5, y = 2, g = 100

[Total terms = 101]

General Term

And Whole Number

For r = 5K Let

r = 5k
since
k = 4, 12, 20 0 ≤ r ≤ 100 ........ (A)

Thus possible values of k for which and are whole no. k = 4, 12, 20 Thus here are 3
rational terms and 98 irrational terms. Thus (A is correct) and (B is wrong)
(C) .... (1)

Consider ....(2)

Add (1) and (2)

I + f + F = 198

I + 1 = 198
I = 197
Now f + F = 1

f=1–F=1–
Hence D is wrong

44)

=
Let f(x) = a sin x + b cos x ; a, b ∈ R
∵ f(α) = 0 ⇒ a sinα + b cosα = 0
∵ f(β) = 0 ⇒ a sinβ + b cosβ = 0
∴ tanα = tanβ
⇒ α = β + nπ
∴ |α – β|= nπ
45)
46)

Conceptual

47)
Coordinates of A(1, –2), and orthocentre H(2, a)
Slope of AH = p
a+2=p ...(1)
Slope of BH = –1
31a – 2ap = 15a + 4p – 2 ...(2)
From (1) and (2)
a=1&p=3

48)
S = 121 × 20 × 133.
λ = 30

49)

Now & must be non-negative integers

∴ r = 0, 8, 16, 24, 32, 40, 48, 56
so, No. of rational terms = 8

50) Ans. 3

Sol.

⇒ ⇒

51)