29-12-2025

4602CJA105021250017 JM

PART-1 : PHYSICS

SECTION-I

1) The figure shows a system of two concentric spheres of radii r1 and r2 and kept at temperatures T1
and T2 respectively. The radial rate of flow of heat in substance between the two concentric spheres

is proportional to :-

(A)

(B) (r2 – r1)

(C)

(D)

2) Figure shows a copper rod joined to a steel rod. The rods have equal length and equal cross-
sectional area. The free end of the copper rod is kept at 0°C. and that of the steel rod is kept at
100°C. Find the temperature at the junction of the rods. Conductivity of copper = 390 W/m–°C and
that of steel = 46 W/m-°C :-

(A) 5.3°C
(B) 10.6°C
(C) 20.1°C
(D) 15°C

3) 540 g of ice at 0°C is mixed with 540 g water at 80°C. The final temperature of the mixture is :-

(A) 0°C
(B) 40°C
(C) 80°C
(D) less than 0°C

4) A cylinder of radius R made of a material of thermal conductivity K1 is surrounded by a cylindrical

shell of inner radius R and outer radius 2R made of a material of thermal conductivity K2. The two
ends of the combined system are maintained at two different temperatures. There is no loss of heat
across the cylindrical surface and the system is in the steady state. The effective thermal
conductivity of the system will be :-
(A)

(B)

(C)

(D)

5) In thermodynamic process pressure of a fixed mass of gas is changed in such a manner that the
gas releases 30 joule of heat and 18 joule of work was done on the gas. If the initial internal energy
of the gas was 60 joule, then, the final internal energy will be :-

(A) 32 joule
(B) 48 joule
(C) 72 joule
(D) 96 joule

6) 28 gm of N2 gas is contained in a flask at a pressure of 10 atm and at a temperature of 57°C. It is

found that due to leakage in the flask, the pressure is reduced to half and the temperature reduced
to 27°C. The quantity of N2 gas that leaked out is :-

(A) 11/20 gm
(B) 20/11 gm
(C) 5/63 gm
(D) 63/5 gm

7) The spectrum of a black body at two temperature 27°C and 327°C is shown in the figure. Let A1

and A2 be the areas under the two curves respectively. The value of is :-

(A) 1 : 16
(B) 4 : 1
(C) 2 : 1
(D) 16 : 1

8) Two rigid boxes containing different ideal gases are placed on a table. Box A contains one mole of
nitrogen at temperature 2T0. while box B contains one mole of helium at temperature (7/3) T0. The
boxes are then put into thermal contact with each other, and heat flows between them until the
gases reach a common final temperature (Ignore the heat capacity of boxes) Then, the final
temperature of gases, Tf, in terms T0 is :-

(A) 0
Tf = T
(B) 0
Tf = T

(C)

(D)

9) The pressure of an ideal gas varies with volume as P = αV, where α is a constant. One mole of the
gas is allowed to undergo expansion such that its volume becomes 'm' times its initial volume. The
work done by the gas in the process is :-

(A)

(B)

(C)

(D)

10) At 0°C, the densities of a cork and a liquid in which the cork floats are d1 and d2 respectively.
The coefficients of expansion for the material of the cork and the liquid are and 100 respectively.
If the cork sinks when termperature of liquid is t°C, then ratio (d2/d1) is :-

(A)

(B)

(C)

(D)

11) 2 kg of ice at –20°C is mixed with 5 kg of water at 20°C in an insulating vessel having a
negligible heat capacity. Calculate the final mass of water in the vessel. It is given that the specific
heat of water and ice are 1 kcal/kg-°C and 0.5 kcal/kg-°C respectively and the latent heat of fusion of
ice is 80 kcal/kg :-

(A) 7 kg
(B) 6 kg
(C) 4 kg
(D) 2 kg

12) A Polyatomic gas with six degrees of freedom does 75 J of work when it is expanded at constant
pressure. The heat given to the gas is :-

(A) 400 J
(B) 500 J
(C) 100 J
(D) 300 J

13) One mole of monoatomic gas is brought from state A to state B such that temperature at A is T0.

Find the heat absorbed along the path ACB :-

(A)

(B)

(C)

(D)

14) A Carnot engine operating between temperatures T1 and T2 has efficientcy . When T2 is lowered

by 62 K, its efficiency increases to . Then T1 and T2 are, respectively :-

(A) 330 K and 268 K

(B) 310 K and 248 K
(C) 372 K and 310 K
(D) 372 K and 330 K

15) Water in a lake starts freezing at some time when the outside temperature –θ°C. The time taken
in freezing of initial x thickness of lake is 2 hrs. Then how much extra time it will take to freeze extra
2x thickness?

(A) 4 hrs
(B) 9 hrs
(C) 16 hrs
(D) 18 hrs

16) Two rods of different materials having coefficients of thermal expansion α1 and α2 and Young’s
moduli Y1 and Y2 are fixed between two rigid and massive walls. The rods are heated to the same
temperature. If there is no bending of the rods, the thermal stresses developed in them are equal
provided :-

(A)

(B)
(C)

(D)

17) The plots of intensity versus wavelength for three black bodies at temperatures T1, T2 and T3

respectively are as shown. Their temperature are such that :-

(A) T1 >T2 > T3

(B) T1 >T3 > T2
(C) T2 >T3 > T1
(D) T3 >T2 > T1

18) A fixed mass of air at 1 atmospheric pressure is compressed adiabatically to 5 atmospheres and
allowed to expand isothermally to its original volume. The process is represented in which one of the
following indicator diagrams :-

(A)

(B)

(C)

(D)
19) Three samples of the same gas A, B and C(γ = 3/2) have initially equal volume. Now the volume
of each sample is doubled. The process is adiabatic for A isobaric for B and isothermal for C. If the
final pressures are equal for all three samples, the ratio of their initial pressures are :-

(A)
(B)
(C)
(D)

20) A gas is filled in the cylinder shown in the figure. The two pistons are joined by a string. If the

gas is heated, the pistons will :-

(A) Move towards left

(B) Move towards right
(C) Remain stationary
(D) None of these

SECTION-II

1) During an experiment an ideal gas obeys an additional equation of state P2V = constant. The
initial temperature and volume of gas are T and V respectively. When it expands to volume 2V, then
its temperature will be , find x :-

2) A diatomic ideal gas is compressed adiabatically to 1/32 of its initial volume. If the initial
temperature of the gas is Ti (in Kelvin) and the final temperature is αTi, the value of α is :-

3) A thermodynamic process is shown in the figure. The pressures and volumes corresponding to
some points in the figure are :-
PA = 3 × 104 Pa, PB = 8 × 104 Pa and
VA = 2 × 10–3 m3, VD = 5 × 10–3 m3. In process AB, 600 J of heat is added to the system and in process
BC, 200 J of heat is added to the system. The change in internal energy (in joule) of the system in

process AC would be :-

4) A diatomic gas (γ = 1.4) does 2000 J of work when it is expanded isobarically. Find the heat given
to the gas in the above process (in kJ).
5) Five molecules of a gas are having speeds 1, 2, 4, 8 and m/s at some instant. The root mean
square velocity of the gas molecules is:- (in m/s)

PART-2 : CHEMISTRY

SECTION-I

1) Arrange pH of the given compounds in decreasing order :-

(i) Phenol (ii) Ethyl alcohol
(iii) Formic acid (iv) Benzoic acid

(A) i > ii > iii > iv

(B) ii > i > iv > iii
(C) iii > ii > iv > i
(D) iv > iii > i > ii

2) In which of the following compound steric inhibition of resonance effect will operate ?

(A)

(B)

(C)

(D)

3) Identify the pair in which Ist compound has higher resonance energy :-

(I)

(II)

(III)
(IV)

(A) I
(B) II
(C) III
(D) IV

4) Which one of the following compounds is non-aromatic ?

(A)

(B)

(C)

(D)

5) Compound(s) which will liberate carbon dioxide with sodium bicarbonate solution is/are :-

(A) B only
(B) C only
(C) B and C only
(D) A and B only

6) In the following molecules, Hybridisation of carbon a, b and c respectively are

:-

(A) sp3, sp, sp

(B) sp3, sp2, sp
(C) sp3, sp2, sp2
(D) sp3, sp, sp2

7) Which among the following is the strongest acid?

(A) CH3CH2CH2CH3
(B)

(C)

(D)

8) The decreasing order of basicity of the following amines is :-

(A) (I) > (III) > (IV) > (II)

(B) (III) > (I) > (II) > (IV)
(C) (III) > (II) > (I) > (IV)
(D) (II) > (III) > (IV) > (I)

9) Among the following compounds, which one has the shortest C—Cl bond ?

(A) H3C–Cl

(B)

(C)

(D)

10) The increasing order of boiling points of the following compounds is :-

(A) I < IV < III < II
(B) IV < I < II < III
(C) I < III < IV < II
(D) III < I < II < IV

11) Select the correct order of basicity :-

(A) CH3 > CH2 = CH– > HC ≡ C– > OH–

(B) CH3 > HC ≡ C– > CH2 = CH– > OH–
(C) CH3 > OH–> HC ≡ C– > CH2 = CH–
OH–> HC ≡ C– > CH2 = CH– > CH3
(D)

12) Which of the following molecule has some dipole moment :-

(A)

(B)

(C) PF3Cl2
(D) All

13) Which one of the following carbocation would you expect to rearrange:

(A)
(B)

(C)

(D)

14) Correct order of acidic strengths :-

(A) X > Y > Z

(B) Z > Y > X
(C) Y > Z > X
(D) X > Z > Y

15) Major product formation take place at which position in this reaction, when it undergoes

electrophilic aromatic substitution?

(A) 1
(B) 2
(C) 3
(D) 4

16)

The electrophile, E⊕ attacks the benzene ring to generate the intermediate σ–complex. Of the
following, which σ–complex is of lowest energy ?
(A)

(B)

(C)

(D)

17) Which is the major product of the following intramolecular F.C. acylation reaction?

(A)

(B)

(C)

(D)

18) The decreasing order of reactivity towards electrophilic substitution reaction of the following
compounds is :-

(A) 1 > 3 > 4 > 2

(B) 4 > 1 > 3 > 2
(C) 4 > 1 > 2 > 3
(D) 4 > 2 > 1 > 3

19) Increasing order of rate of reaction with Br2/AlCl3 is :-

(A) iii < i < ii < iv

(B) iv < ii < i < iii
(C) ii < iv < iii < i
(D) iv < ii < iii < i

20) Which of the following compound will most easily attack an electrophile?

(A)

(B)

(C)

(D)

SECTION-II
1) How many groups are ortho/para director in the electrophilic aromatic substitution?
(i) –NH2 (ii) –COH
(iii) –N = O (iv) –COOH
(v) –Et (vii) –SO3H

(viii) (xi)

2) How many group show –I effect among these group.

3) Number of aromatic compounds present in the following compounds is :-

4) From the list below how many of them are stronger acid than benzoic acid :-

I. II.

III. IV.

V. VI.

VII. VIII.
IX. X.

5) How many groups will show resonance with phenyl ring when attached with it?

PART-3 : MATHEMATICS

SECTION-I

1) The normal at three points P, Q, R of the parabola y2 = 4ax meet in (h, k). The centroid of triangle
lies on

(A) x = 0
(B) y = 0
(C) x = –a
(D) y = a

2) Length of intercept cut by line 4x + 4 y – 1 = 0 on the curve y2 = x will be

(A) 4 units
(B) 9 units
(C) 12 units
(D) 16 units

3) A(3, 6) is a point lying on parabola y2 = 4ax such that chord AB subtends 90° at origin, then
distance OB will, where O is origin

(A)
(B)
(C)
(D)

4) The common tangents to the circle x2 + y2 = 2 and the parabola y2 = 8x touch the circle at the
point P, Q and the parabola at the points R, S. Then the area of the quadrilateral PQRS is
(A) 3
(B) 6
(C) 9
(D) 15

5) Let P be a variable point on the parabola y = 4x2 + 1. Then, the locus of the mid-point of the
point and the foot of the perpendicular drawn from the point P to the line y = x is

(A) (3x – y)2 + (x – 3y) + 2 = 0

(B) 2(3x – y)2 + (x – 3y) + 2 = 0
(C) (3x – y)2 + 2(x – 3y) + 2 = 0
(D) 2(x – 3y)2 + (3x – y) + 2 = 0

6) Let R be the focus of the parabola and the line intersect the parabola at two
points P and Q. Let the point G(10, 10) be the centroid of the triangle PQR. If c–m = 6, then is

(A) 325
(B) 317
(C) 396
(D) 346

7) The length of the latus rectum of the parabola

169 {(x + 1)2 + (y – 3)2} = (5x – 12y + 17)2 is

(A)

(B)

(C)

(D)

8) The equation to the line touching both the parabola y2 = 4x and x2 = –32y is

(A) x – 2y + 4 = 0
(B) x + 2y + 4 = 0
(C) 2x – y + 4 = 0
(D) 2x + y + 4 = 0

9) If the normal to a parabola y2 = 4ax at P meets the curve again in Q and if PQ and the normal at Q
makes angles α and β respectively with the x-axis then tan α (tan α + tan β) has the value equal to

(A) 0
(B) – 2
(C)

(D) – 1

10) The triangle PQR of area ‘A’ is inscribed in the parabola y2 = 4ax such that the vertex P lies at
the vertex of the parabola and the base QR is a focal chord. The modulus of the difference of the
ordinates of the points Q and R is

(A)

(B)

(C)

(D)

11) Locus of the point of intersection of the perpendiculars tangent of the curve y2 + 4y – 6x – 2 = 0
is

(A) 2x – 1 = 0
(B) 2x + 3 = 0
(C) 2y + 3 = 0
(D) 2x + 5 = 0

12) From the point (4, 6) a pair of tangent lines are drawn to the parabola, y2 = 8x. The area of the
triangle formed by these pair of tangent lines & the chord of contact of the point (4, 6) is

(A) 2
(B) 4
(C) 8
(D) None of these

13) Let L1 be the length of the common chord of the curves x2 + y2 = 9 and y2 = 8x, and L2 be the
length of the latus rectum of y2 = 8x then

(A) L1 < L2
(B) L1 > L2

(C)

(D) L1 = L2

14) Through the focus of the parabola y2 = 2px(p > 0) a line is drawn which intersects the curve at

A(x1,y1) and B(x2,y2). The ratio equals

(A) 2
(B) –1
(C) –4
(D) some function of p

15) Let L1 be a tangent to the parabola y2 = 4(x + 1) and L2 be a tangent to the parabola y2 = 8(x +
2) such that L1 and L2 intersect at right angles. Then L1 and L2 meet on the straight line

(A) x + 3 = 0
(B) x + 2y = 0
(C) 2x + 1 = 0
(D) x + 2 = 0

16) The locus of the mid-point of the line segment joining the focus of the parabola y2 = 4ax to a
moving point of the parabola, is another parabola whose directrix is

(A)

(B)

(C) x = 0
(D) x = a

17) If the normals at two points P and Q of a parabola y2 = 4ax intersect at a third point R on the
curve, then the product of ordinates P and Q is

(A) 4a2
(B) 2a2
(C) –4a2
(D) 8a2

18) The equation of a straight line passing through the point (3, 6) and cutting the curve y =
orthogonally is

(A) 4x + y – 18 = 0
(B) x + y – 9 = 0
(C) 4x – y – 6 = 0
(D) none of these

19) Let PQ be a double ordinate of the parabola, y2 = – 4x, where P lies in the second quadrant. If R
divides PQ in the ratio 2 : 1, then the locus of R is

(A) 9y2 = 4x
(B) 9y2 = – 4x
(C) 3y2 = – 2x
(D) 3y2 = 2x

20) Consider the parabola with vertex and the directrix . Let P be the point where the
parabola meets the line x = – . If the normal to the parabola at P intersects the parabola again at
the point Q, then (PQ)2 is equal to

(A)

(B)

(C)

(D)

SECTION-II

1)

The tangent drawn at any point P to the parabola y2 = 4ax meets the directrix at the point K. Then
the angle (in degree) which KP subtends at the focus is

2) If PSQ is the focal chord of the parabola y2 = 8x such that SP = 6, where S is focus of parabola.
Then the length SQ is

3) Let the curve C be the mirror image of the parabola y2 = 4x with respect to the line x + y + 4 = 0.
If A and B are the points of intersection of C with the line y = -5, then the distance between A and B
is

4) In the parabola y2 = 4ax, the tangent at the point P, whose abscissa is equal to the latus rectum
meets the axis in T & the normal at P cuts the parabola again in Q. If PT : PQ is a : b, find a + b (a, b
are coprime)

5) The radius of a circle passing through origin and touching the parabola y2 = 8x at (2, 4) is r, then
r2 is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B A B B D D B B A B D A C C D B C B B

SECTION-II

Q. 21 22 23 24 25
A. 2.00 4.00 560.00 7.00 8.258

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B A D A C C D C C A A D B D A B A C A D

SECTION-II

Q. 46 47 48 49 50
A. 4.00 3.00 6.00 6.00 5.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A A D B A D A B C D A A C A C D A B B

SECTION-II

Q. 71 72 73 74 75
A. 90.00 3.00 4.00 9.00 50.00
 SOLUTIONS

PART-1 : PHYSICS

1) Rate of flow of heat,

H = – K. 4πr2.

or

i.e.,

2) H1 = H2

(θ – 0)
θ = 10.6° C

3) Heat given by 540 g water to cool its temperature from 80°C to 0°C
= 540 × 1 × (80 – 0)
= 4.32 × 104 cal
Heat required to melt 540 g ice at 0°C = mL
= 540 × 80 = 4.32 × 104 cal
Hence the ice melts completely and the final temperature becomes 0°C

4) The two cylinders are in parallel. Therefore, equivalent thermal resistance is given by

where and
Here, l1 = l2 = l, A1 πr2;
A2 = π[(2R)2 – R2] = 3πR2
and A = π(2R)2 = 4πR2

∴
or

5) dQ = dU + dW
–30 = –18 + U2 – 60
U2 = 60 – 30 + 18 = 48

6) PV =
P ∝ MT

Leaked mass =

4
7) A ∝ T

8)

Ei = Ef

0
(1) R (2T ) + (1) R = (1)R(Tf) + (1) R (Tf)

0
RT = RTf

9)

P = α.V

10) d1' = d2'

11) Heat gained = Heat lost

Let m kg ice melts into water
m × 80 + 2 × 0.5 × [0 – (–20)] = 5 × 1 × [20 – 0]
80m + 20 = 100
Thus, final mass of water = 5 + 1 = 6 kg

12)

ΔQ = dv + dw
Δw = PΔv = nRΔT
For one mole Δw = RΔT = 75J

and dv =
here n = 1 F = 6
dv = 3RΔT
dv = 3 × 75 = 225
ΔQ = 225 + 75 = 300J

13) dQ = dU + dW

0 0 0 0
=1× R × (4T – T ) + 1 × P × V

0 0
= RT0 + RT = RT

14) η = 1 – =

⇒ =

η=1– =
On solving
T1 = 372 K
T2 = 310 K

15) time taken in freezing

x1 x2 time

0 x t = 2 hr

X x + 2x = 3x t'

16)

There are only 2 reflection if a > 60°

17) According to Wien's law and from the
figure therefore T1 > T3 > T2.

18) First of all, the air is compressed adiabatically, it is represented by curve ab in the figure.
bc represents the isothermal expansion to its original volume. It is to be noted that the
adiabatic curve is steeper than the isothermal curve.

19) Let the initial pressure of the three samples be

and , then ,
and
⇒

20) When temperature v of gas increases it expands. As the cross-sectional area of right piston
is more, therefore greater force will work on it (because F = PA). So piston will move towards
right.

21) P2V = const

22) T1V1γ–1 = T2V2γ–1

Ti.V7/5–1 =
T2 = 4Ti = aTi
α=4

23)

By adjoining graph and

∴
Now,
From FLOT
⇒ ⇒

24) For a diatomic gas, Cv = R and Cp = R.

The work done in an isobaric process is W = p(V2 – V1)
 = nRT2 – nRT1 or T2 – T1 = .
The heat given in an isobaric process is Q = nCp (T2 – T1)

= W= = 7000 J.

25)

PART-2 : CHEMISTRY

26)

Question Explanation: Arranging the pH of the given compounds in decreasing order.

Concept: This question is based on comparison of acidic strength and pH.

Solution:

Acidic strength (Ka) ∝

Acidic strength ∝ Stability of conjugate base
Acidic strength order ⇒ Formic acid > Benzoic acid > Phenol > Ethylalcohol
Ka ⇒ iii > iv > i > ii
So, pH order ⇒ ii > i > iv > iii

Final Answer: Option (2)

27)

Explanation : To select the compound in which steric inhibition of resonance effect will
operate.

Concept : This question is based on steric inhibition of resonance.

Solution :

Due to repulsion of two –CH3 groups, –NO2 will go out of plane w.r.t. benzene ring
Known as steric inhibition in resonance.

In (2) also two Me groups are present but as -CN group is linear so it will not show SIR effect.

Final answer : Option (1)

28)

Both ring can be benune

29)

Question Explanation:
We need to find which compound among the given options does not satisfy aromaticity rules
and hence is non-aromatic.

Concept:
This question is based on Aromaticity, Hückel’s Rule, Planarity, Conjugation

Solution:
For a compound to be aromatic, it must be cyclic, planar, fully conjugated, and follow Hückel’s
4n+2 π electron rule (n = 0, 1, 2....).

If any of these conditions are not fulfilled (like loss of planarity or absence of conjugation), the
compound becomes non-aromatic.

For the following ion/compounds

– Non aromatic, not completely conjugated.

– Aromatic as 6 π electrons

– Aromatic 2π electrons

– Aromatic 14 π electrons

Final Answer: Option (1)

30)

Question Explanation: Identify the compound(s) that release CO2 when treated with
NaHCO3.

Concept: This question is based on acid base reaction with sodium bicarbonate and acidic
strength.

Solution:
Only acids stronger than H2CO3 react with NaHCO3 to produce CO2 gas along with the
corresponding acid salt.
Equilibrium favours in forward direction and CO2 ↑ is liberated.

Equilibrium favours in forward direction and CO2 ↑ is liberated.

Equilibrium favours in backward direction and CO2 ↑ does not liberate.

Final Answer: Option (3)

31)

32)

Question Explanation: Identify the strongest acid among the given compounds.

Concept: Acid strength is compared based on conjugate-base stability.

Solution:

A. Acidic strength (Ka) increases with the stability of the conjugate base.

B. Electron-withdrawing effects (–I, –M) increase acidity.

C. The strongest acid is the one whose conjugate base is most stabilized.

D. The conjugate base of compound (4) is aromatic, making it exceptionally stable.

 Hence, compound (4) is the strongest acid among the given hydrocarbons.

Final Answer: Option (4)

33)

Question Explanation: Arrange the given amines and heterocyclic compounds in decreasing
order of basicity.

Concept: This question is based on basicity and the availability of the lone pair on nitrogen.

Solution:

Basic strength (Kb) ∝ Electron donor tendency

Basic strength (Kb) ∝ Electron releasing effects (+M, +H, +I)

Basic strength (Kb) ∝

Basicity order: (III) > (II) > (I) > (IV)

Final Answer: Option (3)

34)

Question Explanation:
To identify the compound, which has the shortest C—Cl bond

Concept:
This question is based on bond length and resonance effect

Solution:

In option (3) C–Cl bond is shortest due to resonance of lone pair of –Cl with C=C

Due to resonance C–Cl bond acquire partial double bond character.

 Hence C–Cl bond length is shortest .

Final answer: Option (3)

35)

BP ∝ dipolemoment (m)
Alter
Increasing order of boiling point is :

Shows hydrogen bonding from –O–H group only

Shows strongest hydrogen bonding from both sides of –OH group as well as –NO2
group.

Shows stronger hydrogen from both side of –OH group as well as –NH2 group.

Shows stronger hydrogen bonding from one side –OH–group and another side of –

OCH3 group shows only dipole-dipole interaction.

⇒ Hence correct order of boiling point is:

(I) < (IV) < (III) < (II)

36) Basic strength

37)

38)

39)

40)

Conceptual...

41)

EWG – NO2 destablise 1, 3 & 4th cation in s-complex.

42) Enolic form is more stable than keto form due to more aromatic characters in enolic form.

43) –CH3 is electron donating group, shown + I effect.

–NO2 is electron withdrawing group as well as shown – M effect.
– Cl shows –I effect and is a weak deactivating group so the order of reactivity towards
electrophilic substitution reaction is
44) Conceptual

45) Higher the electron density in the benzene ring more easily it will be attacked by an
electrophile. Phenol has the highest electron density amongst all the given compound.

46) Question Explanation :

Question is asking about No. of ortho/para director in electrophilic aromatic substitution.

Concept :
This question is based on ortho/para directors group in ESR are lone pair containing group.

Solution :

–NH2, –N=O, –Et, are ortho/para director in ESR

Final Answer :
Option (4)

47)

Number of bonds in enolic form

=3+1+1+1+1+2=9
Number of π bonds in enolic form = 1
Number of lone pairs of electrons in enolic form = 2.

48) Fact

49) Acids, I, III, IV, VII, VIII and IX are all stronger than benzoic acid. I is stronger because of
stabilisation of conjugate base by intramolecular H-bonding.

III is stronger because from meta position, —OH exert

only – I-effect, its electron donating resonance effect has no role on acidic strength.
IV is stronger acid due to loss of planarity of —COOH with phenyl ring, hence absence of
electron donating resonance effect as phenyl rings on —COOH increases acidic strength.
VII is stronger because a sulphonic acid is stronger than a carboxylic acid.
VIII is stronger because electron withdrawing inductive effect of one —COOH over other
increases acidic strength.
IX is stronger due to only – I-effect of methoxy group operate from meta position but not its
 electron donating resonance effect.

50) (d), (e), (f), (g), (h)

PART-3 : MATHEMATICS

51) Any normal to y2 = 4ax at (am2, – 2am)

y = mx – 2am – am3 if it passes through (h, k)
then k = mh – 2am –am3
⇒ am3 + m(2a –h) + k = 0 ⇒ Σmi = 0

y= =0

52) Given line is focal chord for parabola and its slope is tan α =

∴ Length = 4acosec2 α = 4. .(2)2 = 4.

53)
t1 t2 = – 4
A(3,6)
t1 = 1
⇒ t2 = –4
So B ≡ (48, –24)
OB = 24

54)

y = mx +
⇒ 2 = m2(1 + m2) ⇒ m = ±1
TP : –x + y = 2
So P(–1, 1) & Q(–1, –1)

&

So

55)

⇒x=
y = 4x2 + 1

56) Explain Question : Question based on chord of a parabola

Concept : Parametric points on a parabola & length of a chord
Solution :

centroid of triangle PQR = 10

10t1 + 10t2 = 30
⇒

C=m+6=

Final Answer : option (1)

57)

Given parabola is

By definition of parabola
Focus : (–1, 3)
Directrix : 5x – 12y + 17 = 0
LR = 4a = 2 (2a)
= 2 (distance of focus from directrix)

58)

Equation of any tangent to the parabola y2 = 4x is

Solving it with the parabola x2 = –32y,

we get,

It has equal roots.

Equation of tangent :

59)

Let

Also,
60)

Difference of the ordinate.

Now Area

So option (3) is correct.

61) y2 + 4y – 6x – 2 = 0
y2 + 4y + 4 = 6x + 2 + 4
(y + 2)2 = 6(x + 1)
y2 = 4AX

here 4A = 6 ⇒
equation of directrix X = –A

x+1

x
2x + 5 = 0
Since locus of the perpendicular tangent are the points on directrix.
⇒ option (D) is correct.

62) y2 = 8x ... (1)

equation chord of contact from R on y2 = 8x
6y = 4(x + 4)
3y = 2x + 8 ... (2)
Solving (1) & (2)
we have
y2 – 12y + 32 = 0
(y – 8)(y – 4) = 0
⇒ y = 4, 8

corresponding & 8 respective

so coordinate of P & Q are & (8, 8)

so are at ΔPQR are

= 2 square unit
Final Answer: option (1)

63) Point of intersection of parabola and circle

as x2 + y2 = 9 & y2 = 8x
x2 + 8x – 9 = 0
x2 + 9x – x – 9 = 0
x(x + 9) –1(x + 9) = 0
∴ x = 1, –9
y2 = 8x
⇒ y2 = 8 & y2 ≠ –72
∴ x = 1,
&
AB = (L1 length of the common chord)
y2 = 8x
L2 : length of latus recturn
⇒ 4a = 8
L1 < L2

64) Suppose

⇒ x1x2 = a2t12t22
y1y2 = 4a2t1t2

As AB is a focal chord
⇒ t1t2 = –1

65) y2 = 4(x + 1)

equation of tangent y = m(x + 1)

y = mx + m
y2 = 8(x + 2)

equation of tangent

since lines intersect at right angles

∴ mm' = –1

Now y = mx + m + ...(1)

...(2)
From equation (1) and (2)

mx + m +
∴ x+3=0

66)

67)

Let and
2
and let R ≡ (at , 2at)

Then

and

⇒ t1t2 = 2
∴ Product of ordinates 4a2t1t2 = 4a2 . 2 = 8a2.

Final Answer: option (4)

68)
⇒ y2 = x

Equation of normal
y = mx – 2am – am3

y = mx – ... (1)
(1) is passing through (3, 6)

6 = 3m –
24 = 10m – m3
m3 – 10m + 24 = 0
⇒ m = –4

∴ y = – 4x +
4x + y – 18 = 0
option (A) is correct.

69) y2 = –4x
P(–t2, 2t), Q(–t2, –2t)

R⇒
locus at R(h, k)

h = –t2, k =

⇒ 9k2 = –4h
locus ⇒ 9y2 = –4x
70) ... (1)

For x = –

⇒y= ⇒

Now At x =

⇒ mT = – 2, mN =
Equation of Normal is

y=
Now put y in equation (1)

⇒ x=2&–
⇒ Q(2, 3)

Now (PQ)2 =
Option (2)

71)

Let P be the point (at2, 2at)

Tangent at 't' to the parabola y2 = 4ax is
ty = x + at2
This meets the directrix x = -a when

ty = a(t2 - 1) i.e.,

K is . Focus is S(a, 0)

Slope of KS =
slope of PS =

Product of slopes
so KP subtends an angle of 90° at the focus

72) 2a =

73) Let there be a point (t2, 2t) on y2 = 4x

Clearly its reflection in x + y + 4 = 0 is given by

x = -(2t + 4) & y = -(t2 + 4)

Now, y = -5 t= 1
x = -6 or x = -2
Distance between A & B = 4

74) Equation of tangent at P(4a, 4a)

yy1 = 2a (x + x1)

Equation of PQ y - 4a = -2 (x - 4a)
(we can also use means normal drawn at t1 meets parabola again at t2)

So,

&

So

75) Hint : Equation of circles touching the line lx + my + n = 0 at (x1, y1) is (x - x1)2 + (y - y1)2 +
λ(lx + my + n) = 0 where λ is a parameter
Sol : Equation of tangetna at (2, 4) is
y.4 = 4(x + 2)
∴x-y+2=0
∴ Equation of required circle is :
(x - 2)2 + (y - 4)2 + λ(x - y + 2) = 0
⇒ x2 + y2 + (λ - 4)x + (-λ - 8)y + (20 + 2λ) = 0
∴ It passes through origin. Hence λ = -10.
∴ Equation of circle is x2 + y2 - 14x + 2y = 0
∴ Radius of circle = r = =
∴ r2 = 50