£
Tat
Ae
* HOLA = High
xx
—where xx
~ Ho (0.5 %)
+ Fesreous Notfereoss
Steels Gast Troas
Hi Grrppcted Gro, Tron alle Dube) fae Vala
+ Alloy, eae
dow Hedlum et
Grbon Grben
Phin WS.A" Plan net ce Tool Stainless
Strength Low Alloy.
etal Alloys
eee ot
Ferreaus Nonfereous
~|_ Steels Gast. Irons
S44 thc 8-4 wt ZC & microstructure + fecite , graphite 1 cementite.
Fecreous
I
A ina
| Nemendlatore for. steels Caisi /sae)
Ploin Corben Steels
)
Oe een
Ni (.65~ 2.00%) ,.Cr-(0.H0 = 0.30!
ws uk ~C noo Stajaless Steel IZ Ge”
CamScanner ile tarandiWw Av :
Sy pepe GiNiytle nome, | loa Cea Ni de
+—j}4_+ - I Pi
—Bromple | toto a0 fono3no ose Aigo 304, KOS.
Hordnatil + + et sel 4 + +] lores 1
TTYo cee ee etc oties|
+ ° + = ala | dated
bridges crack. pistons weer drills high T.
touess _shalts gears. ype. sas apple.
press bolts. tear lies utbines
vessels hom applic. ‘Prnaces
blades New. cottes.
E resistant.
increasing. strength, cast, decreasing, Suctitity.
~ tows Corben Steel (< 0.15 wt% C)
“abwdant fe of steel is LOS —areatect quarts prada, east expensive
| (Net ¢ cespeasive 0 heat treatment ied to form mortensite; i:
aw needed to improve. the a \ I
dich hy, ond toughest
= Git “ode aa Tolel mac
CamScanner ile tarandttHediom Gubr. Steet (0.28 0.6 ut%c)
“Gane. heat headed ~ dusteritizing, quenching. ove then iongtig
Condition — fempereal_martensite
£ Host “often used in tempereal
~~ Hedluincortoon steels have low hardenability,
Addition: of — [Link], Ho improves the. heat reoding._ capacity
Heal eodedl alloys are stonge= Gut have, lower dachiliy
eae “opplicetion s ~ Baila, wheels and tracks, eons crontshafls +
— aedest_ord least ductile
|
| i
het inhardened onal dempered Condition +
~ corbide formers lite G,V, W ore added as alloging. {
zane to form carbides of these metal
~ Used as teol..and die steels oving to the high hardness aad
: al resistonce. property.
“BW Stainless. Steel
Stainless steels - A grovp of sleds that contain at least 1% Cr
Exhibits | extaordiry corrosion resistance due. to formation ofa
hia loyer of. G05 on. ne sotto L
ai
Three mai _classes | i a
Stainless Steel - Grpared of ait (cx) Hr
CamScanner ile tarandt|
dover _teltg. ent (a abet ton" lope thea pre “iren). de
Hebtectc paints i
-|
enna
CamScanner ile taADD. SMALL. Al AMOUNT of. [Link] Ag 10 GRAY CAST-TKON
Gmpacted.. Graphite Tron raat
= Reladvely “high themal Grchetivity,
= Geoel resistance thermal shock
[= Inner onidotion ot clevoted Lenpetoures
PROBUCTION. oF CAST IRONS
Temperature —>
i
ee oer |
|REEST_WHNE CT. 10H
- Peheat Feta]
—- Le222"e fbr Josh Gevmerciel
it ' ele
Cast iron. Fonge | —
Slou! ol de Gr
Pearlitie. Malet
, Applications of Qst Jtors 1
Grog. Iron. + Doctile CNodula-) hoa
+ Small cylinder blocks. cylinder heads, pistons d Frese contain pots eK: valve.
Diesel engine. castings, lia, coders Mh sy gar rd adie poet
Ls White Toh, + Halleable Trea ti
© Used as surce mofolals for. poduciny ML. * Railroadl, connecting rods...
= Coopacted Graphite. Iron {
Te Biesel engine blocks exhaust manilolols, bree des! far high speed 4
CamScanner ile tarandtLimitations of Ferrous Alloys
+} 4) Relatively high density
2) Relatively bus decdrieal conslictivities
a) Generally Per corrosion resistance.
NONFeffeOus ALLOYS
Gy Alloys
“Al Alois
Brass: Zany subst. impurely
Ccestume jeodey coins c
| Cattosion revistat) i
~ low 9 (density) 2.9 glen
oN — Gs, Ay, Si, Ma, Dn ocdlions
\
\ = Solid sd. or precipilotion
\
Bronze: Sn,Ai, sinh | NONERROUS | Stunghened (auc. tall ports
ove. ast. inpries \ Aus | & pectaging)
(toustings loading yds My Ail loys
Gite: precip herdened a very @ (esi: 1 alot
“Tax stength - ijt» . cacy Pi
7 NY X Hoircoll missles
\* oT Al (Noble metals NN -
5 hoys, le. metals \
=relotwely lou @ | ~ Ag) Au, Pe Re metals
eek | 7 AU) | eftoc tory. etal
PA lem? ~[Okidadiok / ~ Nb, Mo, Ws, Ta,
> feactie. of high T 4 eorrasion setistant
~ high melting. fernporadures
~ Space applicotions
Cer |
aah tS a pct metol. Pute Cy i see and malleable ,
cit igh “dechtical sii second only 49 ‘silver (ag)
* Goppe- is tefited fo. high purty, for tran, f electrical applications.”
Excellent thermal cordyct
* Electrical, ond constiiclion indies Ore Ake largest uses of Cy.
~The. second, oye use OP Co is prbeely in coins
CamScanner ile tarandt‘Bpper Allous Fee ee AEEE
Brasses anol. Brontes cre most | coe cenponly. used alloys of Gol.
+ Bross is an alley with Zn. Bronzes fantain tin, alumiaurn silicon
Or Berylion
Other. copper alloy fomies inchde copper ~ nickels ancl mictl. silvers
| Ateying: Element [unis “nomibors 7
lee (2) b6u 00 — C6930
Tin (Sn) CH RGR
Aluavinn (AQ)
Phesphor
Gone
[Alumina
Cem ~ Ce4200
Siticon (9) CEUI09~ 666100
Nickel (Ni)
Copper Alloys C Brass)|_
+ Bross is the mest emma. alloy, of Gor Its an allay. wits Za
* Brass has higher ductility. than copper. or zinc
- Fasy, cost ~Felativelu. lw meting, point. ond sig /Buidity (200%)
Fasy. Relatively. low melting. polat. onal ved fluidity.
+ Propayrties can be.
a presence of O protective
‘thin oxide surface {len
+ Con be used as biomaterial
+ Lenitotion of pure Ti is its lower Strenads . Allegis is done. ah
tt
ab “improve strength.
Metal Fabrication. CCocceert
How do we fabricate. metals 1 ct |
Blacksmith ~ hammer (forged)
| Gast_riolter. metal into | mold
Form ee Operaction pat
° e Stock, pres +o final ‘shape.
Beformodion beby reetystell izodlion TP
+ Stfain_hordeningo¢ oeeaes.
+ Stall. deformation
CamScanner ile tarandtwe Spe ay naan, q
etal Fabricetion Methods
Forming.
C | +Forgiag_C Sahn) : + Pourde- Metal |
LIGUBE: contents Beet | lmatten | ofetat (net ottn oes lies) |
— get = Hetal melted fina, Presse Bt
ft ‘alloying_elenents odd, ‘
a. yt ra et ae et iat
be a - = Common ancl inexpensive t
cr ieteat Force, = Gives asec productina of L
“often of elev. | shopes. &
+ = Weaker lucts, laterno.l int
| Rolin (Wot ar Gl feltg) | detects eerie Clock ot
| C-beoms Fells, sheet & plete) = geod option for low T t
t a Gy bite materials | |
| > : " ify cy
=e Ga) |_ -Sano sting. | density. {
rH SS 1 [foal Jen] | +
rer orea. Contact
| Drawing [ nolo | K
(rods, wire, tubing) Save clenssficlotion by.
° dition at’
I |
do [orc A + Snvestment Casting, . higher torporedure
LJ} tensile | Clow solime., tome 1]
J a Welding,
Stage,
Force
Bie | Areivcation 4 one large
12 ienproctiall)
_+ Extrusion
(rods, teeing) ie : It
lie nA” = — Lax is malte
os Fe
ora) thea” powteol Lore wrald~ holler,
\ fold covity remains |
Stage - Motien wetol
Lis. poured into mold aval |
ram > billet. alloweal {> solidify.
| paola plaster of por
Oana
Cit.
“| Slextrusion
‘Heat =aGtected zone:
(region. in which the.
-tieeetuctore, hes been
—|chonged. J.) tt
CamScanner ile tarandt“Therma
Processing
= Shas felie? fealce L
“at | Metals. -
al. Heat 40 %, oneal p hold. i Miele | then Gol down
Ss hereicize- Gteels):
SAresses resulting, from late very soft steels |
plastic. \"eformetion Sor _ovod machinidg_ . Heat \ |
= = nonudiferm cooling. ee te Tyas B hold
|
| +Process. Aenea,
4 Neoadtive effects.
L of catd wor na
by (recovery /*
teerystelizatten)
phase. transform
Types. of Anwealing.
Normalize (teels)
Uscel to refine the gtawns
onda more uniform Gaal
desirable size disterbution,
Heot to get yp thea aac took
+ Fall Ameal. (steels)
h Mate SoSt steels
or poool Porraing_« Heat
to gel he} ‘then
furnace~ cool {o obtain
Coarse — peor hte:
Heat “Treatment “Temperacot t- Time Paths | r
a) Fal peer
by eat:
_c) Tem ering.
ce
140 t0*
ae
gt
CamScanner ile tarandtHerc ane oe Seals |
ore Mortensite..|—-
“ordenabil y_ = measure of the abit | to
querer 4 tse useal female ardent —
erst {
— Flot goon. t+
: oe enol
a feet ale
"ee vole ae
{Diet hordness versus. distance tem. the querched endl —— ==
Bilence flow queried end r
Hordaess MAC
Reason Why. Haralness Changes with. Distance
av Ror perched ond
"The. caaling rete decreases
E
Hordness Mee
= Mactensite + Pooclite
> Fine Poarlite
=> Peorlite
wo | ft
Time (s) Jott
CamScanner ile tarandti mt
firos quenched. end.
" Lk Gen)
‘Alloy. Steels "
(xt40, 4340, 51d, C64)
=eontoin Ni, (er, Me |
(o.24> 2wt%)
La these elements shift
+1. the" acre’ habia
Limes (lon Ato)
= mortenide
+ Effect 9? specimen
hen surface orea.— “Lo — vole)
== coring. tod dhoughout. inbube| incroies
horace tiosghout © interiar. inbseoses
PekiloA (Gold da
Beet | Cele ta
CamScanner ile tarandiP pitation Hardesing. | | I
+ Partices impedt astocotina eatin
Ale Co system |
[Dipl |
: [IPRA soliton. herd leat
(get foi soltibr) \
i
|B) be) do 4.80
| ©] |
compasstion cone ouailable.
preciprlétion “herdeaing.
~ Pk B+ quench ta) room Lemp.
(retain. oi splvtioa)
= PEC: ccheat {0 nucleate
Small & porticles willua
phase. =
+ Other _ alloys
hetdeas
“Co-Be-
a “Co=Sn
= Hg AL
: re | I r
Tnfence of Precipitation Heat “Treatment on TS , % EL
+ ora AL Allow
* Aoxima o,
roe ;
{ os a
+ 2 |
ae i
ttt tt tual tied Jip |e Aeig t ddAnvo
bbb tb pweclpHadion: Heat pleapitatiot heat
tty reat tune | beat dine
plot tt | 1
rit
H+} | i
t i itt
rat}
+-+
os a ri
rit im
} fad i et
ttt 1 PE ET
CamScanner ile tarandi= tonic sieuclre
i
+ Atoms oce_composedl of
~ Photons > positively rege
= Neuhons 7 nevtial purlicles a
+ Blecttons > negetively, cher
—-Suevading the’ vel ee
+ Every. differ atom. ho
protean” in the nucleus
ae » Aeonic: number (2) = snomber of protons
qi + Far on. electrically. neutral. atom s
+ Number of = number of electtons a d :
+ Number of electrons = atomic. aumbe- eae
© Z ronggs Ram 1 for Marogen {0 82. Por Lroniuns (lhe dag
neturaliy occuring. demands}
aaa oe The dtomic. «oss (A) of a, specific fabs i
The sum of | the mosses 0! oe iuawaas iy
| the puceos ! r
bis ah NF | a
Fl
mnber of nevtrans. (NY ata. bs soli
# nevtions de! ope inner |
~ camscanner ile tarand|_| me. elements. have. bh0 or more | different
LI tomic. masses)
| Callécl| listrtope. |
a have. the Same, tombe ot poten: Lut, diptrert. #.of
Ltt ie, weight + Weighted average of the atomic: messes of the
« a otairing, Isedopes. The odgmic. weight is
‘oflen specified “in
mass. berate a
= +Ateenle mass tit Cams) + 42. 96 the etomit mass of the
most commen. isotope ere ttre 26.) # nevivon=6)
Ths = Moen = 1.69 x10” Mg. = (ome
The etomic mass of the pe ‘alom is Lamu.
“Healt = ITopal_|
%
“For exemple, the atime, exh of iron is 99-85 aa ea = gl
+ Agente weight ob Ci aout omu,
Bogan emis GE Ble apa CCCeeeeerr jolae
5 499-% Beto (Sparta). and 8.3% bu (5p=6n) | CT
+ otemic. weight for Boron? CCCer Tt
© Be [l94« 0) +0340) ] /oo= 0.8 oma [ECO
= Bromine i isotopes
"90.4% Br-73. and 42
—+ atomic weight. for Bromine, cE aol
“refs 98) + Cues 9) oo = ane CCeer er
CamScanner ile tarandt, ic “Simuche
rlike, choracdesistic
Elictons| hove wove|ite and porticle
election in en. atom iis chosecterized by fuel
peels caled Guar antes
= Qunhon tRbebe CCI ‘Deslption [Vals
n prac. all (shell ) Kib MiNe 10 (4242)
Pech “tel ) g { ( e H oh
tie Coo. of stat 4d % *
OR fh A PCr 4 | Wa ~
Oo, ve mg = t/a 112 | m= O24 dowitet
as t=s) 3 orbital |
~@elpa4 orbital myst) 0,1 9 Borbitals |
“Pp FE Bis ee if "C1 ¢0 €) tt
2d S52 docbitol — mg -21,0,f,2 2Forbitals
- tt (lo4)
Number: _ NOMBEL oF BEETCONS
laf stele felsutshel’ —__pa-shelll
a fa Tat
{if 2/
Coe
3G
ce
CamScanner ile tarandtgl
es
which myst have _ op,
ee
vty)
CamScanner ile tarandt_ >
+ Tnterafomle spacing, is the
te center of two” atoms
i 2 Ginding, energy Cor bond ene
Seperate?” tuo’ atoms trom
Jon intaite — distance. apart «
0) The de
repulsive,
tie net forces on
inkesctomic Sept
tuo isololed tors - ++}
{|
equilibrium spacing: Onice in this
| posi
|
_ InteraitomicsegesoAton re
ndence. of | |
‘attractive ond
dich IB (ee
Inlerofeme. sepeotin =
~ b) the [Link]
repulsive, attrachve, and
ad potential mnergics_oA
intel atomic. sepetation
for two isolated. atoms.
1a, he tui. athens ill .cquateract
jt —t Defame
perate them buon attiachve
por Spt tT it
ssh them together by a.
sive for ce
-©
rep
equiliérium spacing between
is the ener
required to
1 eavilieriur ais
spacing. te}
CamScanner ile tarandtI
_-& acqui
allie.) ~
stable. ete
tals by. troaslerring. (ion
lence. eleckens
CamScenner ile tarandt“atoms ia such ui “trot! each atom te over sp boda
me ities, TR be ite @ vakace. of ey praeit! bore I
Gudleté biad inecti bls it is| between specific. atoms
| and | nasa only, 34- nk] -dlteccHtod_betuleen-cnel abba
-—andl_anather_t err! pales in the electron -shbeog.
a ti ‘e
fat TT Tt
CamScanner ile tarandttrheket eleckon: ore fot bound. to. ony |
— specific atom but ore. fe o. it Proighest
the. material et tt
+ Active. = bonding elec:
applied toa metal,
— the election) ia_the electron Sea_can
© @_ easily move gad
Lt}
© Bust baleen alaiast all atoms anol “reolecules
~ = Bot its presence. may. be paseced
oF any. oF primary. ooh. -
+ Sezondory betel i is evidenced
For. ine gases | j— i
» Betueea riBiecules in a Soles thet ore,
ant covalett ly. bonded | tt
Gal ah belgie lore Indie her by
“bbs. Thereire, the Saye oh a
move easil. over each | coin
ET tner onal his imports. | SG
she bring paper
cis in. for
1s tt ay
CamScanner ile tarandtbond Sad.
oF ent int I
Petal ¥ nyeet in t +
= The bond original nee lelectrostatia Inder deraction belueen 1 {
mr gen are Xo and © eet", ‘of high eee i +H {
seh as, oan | it
= ater Enyeninde cramp ore amected by. beep
(dashed lines ia the. oon
_ Gartribution of Bond | Types
~ Gruaket semiconductors)
- f 5 prigerers = : E
i Ko -secprcory) Chycleage + ra de bas it
jonic. ceramics. icamae 1
STRUCTURE ano PR
* Bonding ! i
=Can Toe ionic_ond lor covelentia_choracter
=% ionic Choracter inceoses_ wiih olifference in|
electronegativiiy. of atom Phir
Ceramics ore bernpbs ob at (cost -tuio elemeats or more
ystal stuchres ore |-qertraly. ore. pple thon thase the metals
: ipsot sttuctures. 9 compas of clecheally, dronges. ions
oP atoms |
he metallic lon | Or cons =» positivel coe i
he oe a fons, oF “paints eget? gs
CamScanner ile tarandtmea ions
i idainedaance, of Chos
= Net. ast ia coras ie should
= beflected Un chemical Hen
‘The relotive. sizes of the cations Lonel onions
—-t Cations 9 gives dectron, getting “sealer radius
1 Anions. > tales dectton, ettin lage rodlivs.
Typically re / Ta + less Uhett_uni
+ Each cation prefers la have oS “mony. eae
anion os possible > coorclinetion faleaber.
Focmotion of SteblesAruclue
CamScanner ile tarandiSbterehine. jarinienten Fea! Fc it a vei
tg { CN 6)
_ rumber of colin in unt cele o « feglrel__ [Link]®
| cm. #
Ng number of prions i unit cell Fool
Ac 2 atorne weight Sor dhe cation .
Aa 7 atomic weght for Ure onion :
i , Determine the crystal strecture Gh Ae and colevlate s
E the density of MgO”
Valence | tone Atooc | ~
ty _|Flemeit | Atomic :
tedius Coml| Redlss (nai) | Alas Cg rel) et
if 1604, +2 | 0.092 | | 2u.3r2_
| 1 0,06 22
aut 1 fo} 4 + + 2
2 SL glam
4
ri Ax 24.312 gimrol + AX Ie afore
x 6.024
Silicate Ceramics
+ Silicstes are materials compocecl primarily of ‘silicoon(Si)
ord oxygert (o) phi
+ the Hing most obuadert elements in the gorth's crust ae
* Bother than chor: the crystal. structure of =
these. moterials ia unibeell , dus Prey :
Convenient 49 us2 various a1ragement of an S10, a
LW tetrahedron (basic unit of the silicates) 3b
Silica Coon
ote material is silion_ t
_ Chemically. , the oct simple
dioxide (Si silica. \
+ Structurally, , tis o Yaree~dimensionol network that {
is generoted when the corner. oxygen atoms in
-tetraihedron ore Shared _b' adjacent p eiohedda. -
+ Ure ratio of Si tO Sows a cE L
2 the material is electeicaliy. seitial
CamScanner ile tarandtThe chon Si-' Ea abl He wo a | Pile rei
peracine- NHC). for us materiad
Silica. can also be mode 0 exist asa. roncrystalline
or seg he gl deqree. ot atomic
fegcmbess.
silico, the telralsovron el 5 Mee
ts slluchwe, poet. cht ckists.
“Peed bet dalon lalate tes
feat. oa itt S ewe % ancl L
CamScanner ile tarandt| Polymorphic Forms of Carbon
“Biamond
— = Tétranedral bondling, 0
corban
+ hardest material Lrowa
«very high tesmat
conductivity ©
if
Tiarge. Single crystols~
gamstanes
— Small crystals — used to
arindl /cot “other materials
= Diomond thin filars
shard — surface Coecti ngs — used for cutting tools, medical devices, ete
~ Grophite
. uz
pal iy ;
3} aot yw ye carbon atom
i NCVON is
fee ae or cae
alec ven ler Wo PH HR OS
Trees between boy! Vn Se ay a
1 A Al
Se 24a ee Be
Planes slide cosily. 1 eee tee
over one enother — ont boy be
good lubricant . it ema)
as \
| Eetereres Fullerenes
_ Spherical cluster of GO corkon atoms, Coo
+ Like a seccer ball
= Sheet of graphite rolled ato a tube
Ends copped with follerene hemispheres
:
CamScanner ile tarandt