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Physics and Chemistry Problem Set

The document consists of physics and chemistry questions divided into sections, covering various topics such as electric fields, dimensional analysis, chemical reactions, and stoichiometry. Each question presents multiple-choice answers related to fundamental concepts in physics and chemistry. The content appears to be part of an examination or assessment for students in these subjects.
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0% found this document useful (0 votes)
18 views36 pages

Physics and Chemistry Problem Set

The document consists of physics and chemistry questions divided into sections, covering various topics such as electric fields, dimensional analysis, chemical reactions, and stoichiometry. Each question presents multiple-choice answers related to fundamental concepts in physics and chemistry. The content appears to be part of an examination or assessment for students in these subjects.
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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27-04-2025

9610WJA801593250003 JA

PART 1 : PHYSICS

SECTION-I

1)

If and , then the vector whose magnitude is equal to and parallel


to is :

(A)

(B)

(C)
(D)

2) A particle is in a unidirectional potential field where the potential energy (U) of a particle depends
on the x-coordinate given by Ux = a (1 – cos bx) & a and 'b' are constants. The physical dimensions of
'b'

0 0
(A) M LT
0 0
(B) M L–1T
(C) MLT–1
(D) ML2T–2

3) If force ‘F’, time ‘t’ and velocity v are taken as fundamental quantities then the dimensional
formula of mass will be :-

(A)

(B)

(C) Fv2t

(D)

4) The velocity of a particle varies as = ms–1 where t is in seconds. Find the

average velocity of the particle for a time interval between t = 0 and a time
when the speed (i.e. ) of the particle becomes minimum
(A)

(B)

(C)
(D)

5) Electric field at the centre of the square of side a:

(A)

(B)

(C)

(D) None of these

6) A wire, of length L( = 20 cm), is bent into a semi-circular arc. If the two equal halves, of the arc,
were each to be uniformly charged with charges ±Q, [|Q| =103 ε0 Coulomb where ε0 is the
permittivity (in SI units) of free space] the net electric field at the centre O of the semi-circular arc

would be :-

(A) (50×103 N/C)


(B) (50×103 N/C)
(C) (25×103 N/C)
(D) (25×103 N/C)

7) Charges Q1 and Q2 arc at points A and B of a right angle triangle OAB (see figure). The resultant
electric field at point O is perpendicular to the hypotenuse, then Q1/Q2 is proportional to :
(A)

(B)

(C)

(D)

8) A semi-infinite insulating rod has linear charge density λ. The electric field at the point P shown in

figure is :-

(A)
at 45° with AB

(B)
at 45° with AB

(C)
at 45° with AB

(D)
at perpendicular to AB

9) A charge q is placed at the centroid of an equilateral triangle. Three equal charges Q are placed
at the vertices of the triangle. The system of four charges will be in equilibrium if q is equal to :-

(A)

(B)

(C)

(D)

10) Two point charge of 100 μC and -4 μC are positioned at points (-2√3, 3√3, -4) and (4√3, -5√3, 6)
respectively of a Cartesian coordinate system. Find the force vector on the -4 μC charge? All the
coordinates are in meters.

(A)

(B)

(C)

(D)

11) A simple pendulum of length L is placed between the plates of a parallel plate capacitor having
electric field E, as shown in figure. Its bob has mass m and charge q. The time period of the

pendulum is given by :

(A)

(B)

(C)

(D)

12) Find the electric field at point P (as shown in figure) on the perpendicular bisector of a uniformly
charged thin wire of length L carrying a charge Q. The distance of the point P from the centre of the
rod is .

(A)

(B)

(C)

(D)

13) Two point charges and repel each other with a force of 40 N. If a charge of is
added to each of them, then the force between them will become

(A) –10N
(B) –5N
(C) –30N
(D) –20N

14) Two charges are placed as shown in figure. Where should a third charge be placed so that it
remains in equilibrium?

(A) 30cm from 9e


(B) 40cm from 16e
(C) 40cm from 9e
(D) Both (A) and (B)

15) ABC is an equilateral triangle. Charges q, q and 2q placed at corner of triangle. The electric
intensity at O will be

(A)

(B)

(C) Zero

(D)

16) A point charge of 100μC is placed at Find the electric field intensity due to this charge
at a point located at

(A) 8000 Vm–1


(B) 9000 Vm–1
(C) 2250 Vm–1
(D) 4500 Vm–1

17) Two infinite planes each with uniform surface charge density + σ are kept in such a way that the
angle between them is 30°. The electric field in the region shown between them is given by:

(A)

(B)

(C)

(D)

18) What is the net electric field at point P. Due to uniformly changed non-conducting sheet.
(A)

(B)

(C)

(D)

19) A negatively charged particle p is placed, initially at rest, in a constant, uniform gravitational
field and a constant, uniform electric field as shown in the diagram. What qualitatively, is the shape

of the trajectory of the electron ?

(A)

(B)

(C)

(D)

20) An oil drop of radius 2 mm with a density 3g cm–3 is held stationary under a constant electric
field 3.55 × 105 V m–1 in the Millikan's oil drop experiment. What is the number of excess electrons
that the oil drop will possess ? (consider g = 9.81 m/s2)

(A) 48.8 × 1011


(B) 1.73 × 1010
(C) 17.3 × 1010
(D) 1.73 × 1012

SECTION-II

1) Three charged small spheres are suspended from point O with help of strings of length ℓ as
shown. All three charges are in equilibrium. Tension in string is . Find x (m = 20 gm;) Take g =
10 m/s2

2) A thin rod of length L lies along X axis such that its one end is at origin. The charge density on the
rod is given by . The electric field at origin is given by αKλ0L. Write α in OMR sheet.

3) IF the angle between and is 60°. Then the value of is and is . Find the
value of (x + y).

4) Three forces (shown in figure) act on a body simultaneously. What will be magnitude (in newton)
of smallest additional force to make net force along west direction.

5)

In a new system of unit, unit of mass is 4kg, unit of length is 2m and unit of time is sec. How
much Newton is equal to 1 unit of force in this new system.

PART 2 : CHEMISTRY

SECTION-I

1) A sample of calcium carbonate is 80% pure. 25g of this sample is treated with excess of HCl. How
much volume of CO2 will be obtained at NTP.

(A) 4.48 litre


(B) 5.6 litre
(C) 11.2 litre
(D) 2.24 litre

2) What weights of P4O6 and P4O10 will be produced by the combustion of 31g of P4 in 32g of oxygen
leaving no P4 and O2.

(A) 2.75g, 219.5g


(B) 27.5g, 35.5g
(C) 55g, 71g
(D) 17.5g, 190.5g

3) The mass of N2F4 obtained by reaction of 2.0 gm of NH3 and 80 gm of F2 is 3.56 gm. The
percentage yield of reaction is [F = 19]
NH3 + F2 —→ N2F4 + HF

(A) 80.5
(B) 70.5
(C) 58.19
(D) 20.73

4) For reaction :
2Fe2S3 + 6H2O + 3O2 → 4 Fe(OH)3 + 6S
If 4 moles of Fe2S3 react completely with 2 mole of H2O and 3 moles of O2, then which of the
following statement (s) is incorrect-

(A) H2O is limiting reagent


(B) Moles of Fe(OH)3 formed is 4/3
(C) Moles of Fe2S3 remaining is 10/3
(D) Mass of O2 remaining is 32 gm

5) For a reaction, N2(g) + 3H2(g) → 2NH3(g); identify dihydrogen (H2) as a limiting reagent in the
following reaction mixtures.

(A) 28g of N2 + 6g of H2
(B) 14g of N2 + 4g of H2
(C) 56g of N2 + 10g of H2
(D) 35g of N2 + 8g of H2

6) Find out % of oxalate ion in a given sample of an alkali metal oxalate salt, 0.30 gm of it is
dissolved in 100 CC water required 90 CC of centimolar KMnO4 solution in acidic medium.

(A) 66%
(B) 55%
(C) 44%
(D) 88%
7) Ratio of stoichiometric coefficients of CrCl3 to MnO4– in balanced chemical reaction in acidic
medium is :
MnO4– + CrCl3 –→ MnCl2 + Cr2O72– + Cl–

(A)

(B)

(C)

(D) 1

8) How many mililiters of 0.1 M H2SO4 must be added to 50 ml of 0.1 M NaOH to give a solution that
has a concentration of 0.05 M in H2SO4.

(A) 40 ml
(B) 50 ml
(C) 200 ml
(D) 100 ml

9) A solution of Na2S2O3 is standardized iodometrically against 0.167 g of KBrO3 [MW = 167 gm].
This process requires 50 mL of the Na2S2O3 solution. What is the normality of the Na2S2O3?

(A) 0.2 N
(B) 0.12 N
(C) 0.72 N
(D) 0.02 N

10) The volume of 0.2 M H2O2 that will be completely oxidised by 10 ml of 0.3 M KMnO4 solution in
faintly alkaline medium

(A) 7.5 ml
(B) 22.5 ml
(C) 12.5 ml
(D) 25 ml

0 0
11) What is the mole ratio of benzene (PB = 150 torr) and toluene (PT = 50 torr) in vapour phase if
the given solution has a vapour pressure of 120 torr ?

(A) 7 : 1
(B) 7 : 3
(C) 8 : 1
(D) 7 : 8

12) At 35oC, the vapour pressure of CS2 is 512 mm Hg and that of acetone is 344 mm Hg. A solution
of CS2 in acetone has a total vapour pressure of 600 mm Hg. The false statement amongst the
following is :
(A) Heat must be absorbed in order to produce the solution at 35oC
(B) Raoult’s law is not obeyed by this system
(C) A mixture of 100 mL CS2 and 100 mL acetone has a volume < 200 mL
(D) CS2 and acetone are less attracted to each other than to themselves

13) 1 g of non-volatile non-electrolyte solute is dissolved in 100g of two different A and B whose
ebullioscopic constants are in the ratio of 1:5. The ratio of the elevation in their boiling points,

, is :

(A) 5 : 1
(B) 10 : 1
(C) 1 : 5
(D) 1 : 10

14) In a solution, if three molecules of solute undergoes association as : 3A A3, then to


evaluate degree of association 'α' the formula will be :-

(A)
α=
α=
(B)

(C)
α=
α=
(D)

15) solution of potassium ferrocyante K4[Fe(CN)6] is 50% dissociated at 18°C. What will be its
osmotic pressure ?

(A) 5.23 atm


(B) 7.16 atm
(C) 3.38 atm
(D) 8.75 atm

16) For a process A + B → product, the rate of reaction is second order with respect to A and zero
order with respect to B. When 1 mole each of A & B are taken in 1 litre vessel, the initial rate of
disappearance of B is 1 × 10–2 mol/L-sec. The rate of reaction when 50% of the reactant have been
converted to product would be -

(A) 1 × 10–2 mol/L-sec


(B) 2.5 × 10–3 mol/L-sec
(C) 5 × 10–2 mol/L-sec
(D) 5 × 10–3 mol/L-sec

17)

For the reaction : 2O3(g) → 3O2(g)


Mechanism :

Step - I O3(g) O2(g) + O(g)


Step - II O(g) + O3(g) 2O2(g)
overall order of reaction based on mechanism is

(A) 1
(B) 2
(C) 3
(D) 1.5

18) For gaseous elementary reaction ; 2A(g) + B(g) → P(g) Initially A and B are present in
stoichiometric mole ratio and total pressure decrease from 120 torr to 80 torr in 5 minutes, than
average rate of reaction is .

(A) 8 torr /min.


(B) 6 torr /min.
(C) 2 torr /min.
(D) 4 torr /min.

19) The reaction Cis-X trans-X is 1st order in both direction. At 25ºC the equlibrium
constant is 0.10 and the rate constant Kf = 3 × 10–4 sec–1. In an experiment starting with the pure cis
form, how long would it take for half of the equilibrium amount of the trans isomer to be formed -

(A) 150 sec.


(B) 200 sec.
(C) 240 sec.
(D) 210 sec.

20) Calculate the half-life in min of the first-order reaction, C2H4O(g) → CH4(g) + CO(g). If the initial
pressure of C2H4O(g) is 80 mm of Hg and the total pressure at the end of 20 minutes is 120 mm of
Hg.

(A) 10 minutes
(B) 15 minutes
(C) 20 minutes
(D) 25 minutes

SECTION-II

1)
2 NO(g) + Cl2(g) → 2 NOCl(s)
This reaction was studied at –10°C and the following data was obtained
run [NO]0 [Cl2]0 r0
1 0.10 0.10 0.18
2 0.10 0.20 0.35
3 0.20 0.20 1.40
[NO]0 and [Cl2]0 are the initial concentrations and r0 is the initial reaction rate.
The overall order of the reaction is ______. (Round off to the Nearest Integer).

2) The activation energy of a reaction is given as where T is

temperature in kelvin. Find value of where k1 and k2 are rate constants at temperature 200 K
and 400 K respectively. (Use = 0.7 and R = 2 cal mol–1 k–1)

3) Number of correct statements are-


(i) Azeotrope obey Raoult's law
(ii) Minimum boiling point azeotrope is formed if ΔHmix < O
(iii) ΔHvap for ideal aqueous solution containing non-volatile solute is same as ΔHvap for pure water
(iv) When azeotrope is vapourised, composition of vapour formed is same as solution.

4) The weight of hydrogen gas obtained from 42 g of CaH2 by treatment with water is to give calcium
hydroxide along with H2.

5) When BrO3– ion reacts with Br– ion in acidic medium, Br2 is liberated. Calculated the ratio of
molecular mass and equivalent mass of KBrO3.

PART 3 : MATHEMATICS

SECTION-I

1) Let f : → be defined by ,x∈ . Then the range of f is :

(A) (–1, 1) – {0}

(B)

(C)

(D) R – [–1, 1]

2) If the domain of the function f(x) is [1, 3], then the domain of the function is
(A)

(B)

(C)
(D)

3) Let P(x) be polynomial of degree 4 with leading coefficient 1. Given that P(1) = 1, P(2) = 3, P(3) =
5 and P(4) = 7. The value of P(5) will be

(A) 9
(B) 5
(C) 24
(D) 33

4) Let f(x) = x2 – 2x – 1 ∀ x ∈ R and f:(–∞, a] → [b, ∞), where a is the largest real number for which
f(x) can be made bijective, then value of (a + b) is :

(A) –2
(B) –1
(C) 0
(D) 1

5) If functions f(x) and g(x) are defined on ℝ → ℝ such that

then (f – g)(x) is-

(A) one-one & onto


(B) neither one-one nor onto
(C) one-one but not onto
(D) onto but not one-one

6) Let [t] denote the greatest integer ≤ t. Then the equation in x, [x]2 + 2[x + 2] – 7 = 0 has :

(A) no integral solution


(B) exactly four integral solutions
(C) exactly two solutions
(D) infinitely many solutions

7) If the graph of f(x) and g(x) = 2αx + 3 intersect at two distinct points then the range of α is
equal to :

(A) (0, ∞)
(B)

(C)

(D)

8) If the domain of the function is (–∞, α) ∪ [β, ∞), then α2 + β3


is equal to :

(A) 140
(B) 175
(C) 150
(D) 125

9) Sum of the solutions of the equation [x2] – 2x + 1 = 0 is (where [.] denotes greatest integer
function)

(A)

(B) 2
(C) 3

(D)

10) Sum of all the integers in the range of the function , where , is

(A) 15
(B) 10
(C) 25
(D) None of these

11) If product of least and greatest value of the function is where a and b are
coprime then a + b =

(A) 5
(B) 10
(C) 15
(D) 20

12) Let R = {(1, 2), (2, 3), (3,3)} be a relation defined on the set {1, 2, 3, 4}. Then the minimum
number of elements, needed to be added in R so the R becomes an equivalence relation, is :

(A) 10
(B) 8
(C) 9
(D) 7

13) If = , then the value of a + b + c is (where a,b,c are


coprime)

(A) 10
(B) 11
(C) 12
(D) 13

14) The equation – = has

(A) no solution
(B) one solution
(C) two solutions
(D) more than two solutions

15) If then the value of x is

(A) ˜2
(B) 3
(C) Both (1) and (2)
(D) None of these

16) If , then sum of all possible values of x is

(A) 0
(B) 1
(C) 2
(D) 3

17) There is a group of 265 persons who like either singing or dancing or painting. In this group, 200
like singing, 110 like dancing, 55 like painting. If 60 persons like both singing and dancing, 30 like
both singing and painting and 10 like all the three activities, then the number of persons who like
only dancing and painting is

(A) 10
(B) 20
(C) 30
(D) 40

18) Let and


Then on N:

(A) Both R1 and R2 are equivalence relations


(B) Neither R1 nor R2 is an equivalence relation
(C) R1 is an equivalence relation but R2 is not
(D) R2 is an equivalence relation but R1 is not

19) If R is the smallest equivalence relation on the set {1, 2, 3, 4} such that {(1,2), (1,3)} R, then
the number of elements in R is ______

(A) 10
(B) 12
(C) 8
(D) 15

20) An school awarded 48 medals in event ‘A’, 25 in event ‘B’ and 18 in event ‘C’. If these medals
went to total 60 students and only five students got medals in all three events then how many
received medals in exactly two of three events.

(A) 15
(B) 10
(C) 9
(D) 21

SECTION-II

1) Find the value of expression


where [.] = Greatest Integer Function.

2) If 's' is sum of the roots of the equation 2[x+15]+5x–1 = 17{x+3}; where [.] represents greatest
integer function and {.} represents fractional part function, then the values of 4.|s| is equal to

3) The sum of integral value of x satisfying the inequality .

4) If function f : → (a, b] defined by is onto function, then [a] + [b] is


(where [.] is greatest integer function and {.} fractional part)

5) Number of integers in the range of function is


ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B D B A C C C A B A C A D A B B B D B

SECTION-II

Q. 21 22 23 24 25
A. 4 1 4 7 4

PART 2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A B C D C A A D B B A C C A B B A D D C

SECTION-II

Q. 46 47 48 49 50
A. 3 2 2 4 5

PART 3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A D B B D D C C A B D A A C A A B A D

SECTION-II

Q. 71 72 73 74 75
A. 289 25 21 3 33
SOLUTIONS

PART 1 : PHYSICS

1)

Required vector =

2)

[b] =

3)

4)

Speed = = is minimum at t = 3 s.

Average velocity = =

= =

5)
6)
Net electric field due to dq charge placed symmetrically about y-axis at O

ENet =

= [πR = L]

7)
E2 = electric field due to Q2

From diagram
8)

9)

in equilibrium,

10) Use
11) geff =

T=

12)

sin θ =

13)

14)
for eqm condition

3(70–x) = 4x
7x = 210
x = 30 cm
15)

So

16)

17)

Electric field due to each sheet is uniform and equal to


Now net electric field between plates

18)
19)
it will move in anet direction

20) qE = Mg

neE =
n × 1.6 × 10–19 × 3.55 × 105

= 3 × 103 × × π × (2 × 10–3)3 × 9.81


n = 173 × 10(3 – 9 – 5 + 19)
n = 1.73 × 1010

21)
T cos θ = mg
T = 2mg = 2 × 20 × 10–3 × 10

22)

23)

And
So, x + y = 4

24)
To have resulting along west, force towards north should be cancelled.

25)

[F] = MLT–2 = nM1L1T1–2 = 1M2L2T2–2

n=1

PART 2 : CHEMISTRY

26)

Concept : In a chemical reaction involving impulse reactant only the pure reactant undergoes
chemical reactants. The impurity does not participate in the chemical reaction. The
calculations are done as per regular stoichiometry.

Solution : Mass of pure CaCO3 = 80% of 25

= × 25 = 20g

CaCO3 + 2HCl CaCl2 + H2O + CO2

No. of moles of CaCO3 =

Since, HCl is taken in excess so, the no. of moles of CO2 formed will be decided using CaCO3

Volume of 0.2 mole of CO2 = 0.2 × 22.4L


= 4.48L

Hence, the correct answer is option (A)

27) Concept : In a chemical reaction


aA + bB cC + dD
Let a0, b0 c0 and d0 be the number of molar of A, B, C and D reacted and formed respectevely

Then,
Solution :
2P4 + 8O2 P4O6 + P4O10

Moles

= = 1

using the reaction,


P4 = A, O2 = B, P4O6 = C & P4O10 = D

( )

Mole of mole P4O6 = (31 4 + 16 6) = 27.5g

Mass of mole P4O10 = (31 4 + 16 10) = 35g


Hence option (B) is correct.

28) NH3 is LR
2NH3 + 5F2 —→ N2F4 + 6HF
(2 × 17) gm NH3 gives 104 gm N2F4

2 gm NH3 will give = ×2= gm N2F4

Now %yield = × 17 × 100 = 58.19%

29)

use stoichiometry

30)

N2 + 3H2 → 2NH3
(A) 1 mole 3 mole
(B) 0.5 mole 2 mole
LR
(C) 2 mole 5 mole
LR
(D) 1.25 mole 4 mole
LR

31)

⇒ meq. of C2O42– = meq. of KMnO4


⇒ mmoles × nf = M × VmL × nf
∴ mmoles × 2 = 0.01 × 90 × 5
mmoles of C2O42– = 2.25
∵ Moles of C2O42– = 2.25 × 10–3
Mwt of C2O42– = (12 × 2) + (4 × 16)
= 88 g/mole
2–
∴ Mass of C2O4 = (Mwt) × Moles
= 88 × 2.25 × 10–3 g
= 0.198 g

%C2O42– =

=
= 66%

32) +7 +3 +2 +6
MnO4 + CrCl3 –→ MnCl2 + Cr2O7 + Cl–
– 2–

RHR
Mn+7 + 5e– —→ Mn2+ .............(i) × 6
OHR
2Cr3+ —→ Cr2+6 + 6e– (ii) × 5
6MnO4– + 10CrCl3 + 11H2O –→ 6 MnCl2 + 5Cr2O72– + 18Cl– + 22H+

33) H2SO4 + 2NaOH → Na2SO4 + 2H2O


0.1 × V 50 × 0.1 – –
0.1 × V – 2.5 5 – 5 2.5 5

= 0.05
0.1 V – 2.5 = 0.05 V + 0.05 × 50
(0.1 – 0.05)V = 2.5 + 2.5

V= = 100 ml

34) Eq. wt. of KBrO3 = of its mol. wt.

35) M1 = 0.2M , V1 = ? n1= 2 → for H2O2


M2 = 0.3M, V2 = 10 ml n2 = 3 (In slightly basic medium )
M1V1n1 = M2V2n2
0.2 × v1 × 2 = 0.3 × 10 × 3
V1 = 22.5 ml

36) P = PB°XB + PT° XT


120 = 150(XB) + 50 (1 – XB)
100XB = 70
XB = 0.7

YB = = = 0.875 ⇒
YT = 1 – 0.875 = 0.125

37)

Solution is showing positive deviation

38)

39) i = ,

α=

40) π = i × C × R × T ...(1)

K4[Fe(CN)6] 4K⊕ + [Fe(CN)6]4⊝

i = 1 + (n – 1)α = 1 + (5 – 1) × = 1 + 4 × 0.5 = 3
π = 3 × 0.1 × 0.0821 × 291
π = 7.16 atm

0
41) r = K [A]2 [B]
0
10–2 = K(1)2 (1) ⇒ K = 10–2
0
finally, r = 10–2(1/2)2 (1/2)
= 2.5 × 10–3

42) r = Knet [O3]2 [O2]–1

43) 2A(g) + B(g) → P(g)


Initially 2a a ntotal = 3a
moles

Ptotal/initially = 120 torr


PB = 40 torr
Initially 80 40
presence
time = t 80–2P 40–P P
(Ptotal)t = 120 – 2P = 80
P = 20

Average rate of reaction =


= 4 torr/min.

44)

Kf + Kb =

t= ln
t = 210 sec.

45) C2H4O CH4 + CO


t=0 80
t = 20 min 80 – P P P
80 – P + P + P = 120
P = 40
Hence, t1/2 = 20 min

46)

rate = k[NO]2 [Cl2]1 {Ans : 3rd order}

47)

=1+1 =2

48) (i) Incorrect : → Azeotropes are non-ideal solutions so do not obey Rault’s law.
(ii) Incorrect : → for minimum boiling azeotropes ΔHmix > 0.
(iii) Correct : → addition of non-volatile solute decreases vapour pressure However ΔHvap
remains unaffected.
(iv) Correct : → In case of azeotropes, composition of vapours formed is same as solution after
vapourisation.
Correct statement =
49) The reaction of hydrolyth with water is

1 mol 2 mol
1×42g 2×2g
∴ 42 g CaH2 will be give 4 g H2.

50)
n–factor = 5

PART 3 : MATHEMATICS

51)

ƒ(0) = 0 & ƒ(x) is odd.


Further, if x > 0 then

Hence,

52)

53) Consider Q(x) = P(x) – (2x – 1)


Clearly Q(1) = Q(2) = Q(3) = Q(4) = 0
Q(x) = P(x) –(2x–1) = (x–1) (x–2) (x–3) (x–4)
P(x) = (x – 1) (x – 2) (x – 3) (x – 4) + (2x – 1)
P(5) = [Link] + 9 = 33

54) f(x) = x2 – 2x – 1
for injective f '(x) = 2x – 2
f '(x) ≥ 0 f '(x) ≤ 0 ∀ x ∈ (–∞, a]
= 2x – 2 ≤ 0 = x ≤ 1
so largest value of a is 1
for surjective → f(x) = (x – 1)2 – 2
at x = 1 f(x) = –2
so f is surjective if f(x) ∈ [–2, ∞)
a = 1, b = –2
a + b = 1 – 2 = –1
55)

many – one
Also, (f – g)(x) = 3 – is not possible. As 3x – will not allow x = 1
So, into

56) [x]2 + 2[x + 2] – 7 = 0


⇒ [x]2 + 2[x] + 4 – 7 = 0
⇒ [x] = 1, –3
⇒ x ∈ [1, 2) ∪ [–3, –2)

57)
Case - I : if α > 0 then it has two intersection points.

Case - II : if α < 0 then


⇒ 2αx2 + 3x – 2 = 0 the for two distinct solution D > 0 ⇒ 9 + 16α > 0

58)
Domain : x2 – 25 ≥ 0 ⇒ x ∈ (–∞, –5] ∪ [5, ∞)
4 – x2 ≠ 0 ⇒ x ≠ {–2, 2}
x2 + 2x – 15 > 0 ⇒ (x + 5) (x – 3) > 0
⇒ x ∈ (–∞, –5) ∪ (3, ∞)
∴ x ∈ (–∞, –5) ∪ [5, ∞)
α = –5; β = 5
∴ α2 + β3 = 150

59) x2 – 1 < [x2] ≤ x2


[x2] = 2x – 1
2
⇒ x < 2x ⇒ 0 < x < 2
60)
where
f(0) = 5
f(2) = 1
f(3) = 2
Range
Sum of all integers = 1 + 2 + 3 + 4 + 5 = 15

61)
x2y–xy+2y = x2+x+1
(y–1)x2–(y+1)x+2y–1 = 0
D≥0
(y+1)2–4(y–1) (2y–1) ≥ 0
–7y2+14y–3 ≥ 0
7y2–14y+3 0
7(y–1)2–22 0

Given product is

⇒ A + b = 3 + 7 = 10

62) A = {1, 2, 3, 4}
For relation to be reflexive
R = {(1,2), (2, 3), (3,3)}
Minimum elements added will be
(1,1), (2,2), (4,4) (2,1) (3,2) (3,2) (3,1) (1,3)
∴ Minimum number of elements = 7
63)

64) – = .....(i)
squaring both sides
(x + 1) + (x – 1) – 2 = 4x – 1
(1 – 2x) = 2 .....(ii)
squaring both sides
1 + 4x2 – 4x = 4x2 – 4

4x = 5 ⇒ x = does not satisfy equation (i)


∴ No solution

65)

x2 – x – 6 = 0
x(x – 3) + 2(x – 3) = 0
(x + 2) (x – 3) = 0
x = – 2, x = 3

66)

Let

Let
⇒ t1 t2=1

⇒ x1 + x2 = 0

67) n(D ∪ P ∪ S) = n(D) + N(P) + n(S) – n(D ∩ P)


–n(P ∩ S) – n(S ∩ D) + n(D ∩ P ∩ S)
265 = 110 + 55 + 200 – n(D ∩ P) – 30 – 60 + 10
n(D ∩ P) = 20
∴ = n(D ∩ P) – n(D ∩ P ∩ S)
= 20 – 10
= 10 Ans.

68)

For R1 :
Reflexive relation
→ it is reflexive
Symmetric relation
→ it is symmetric
Transitive relation
(1, 3) ∈ R1, (3, 16) ∈ R1, but (1, 16) ∉ R1
It is not transitive.
For R2 :
Reflexive relation

Symmetric relation
If is

Transitive relation

(1, 3) ∈ R2, (3, 14) ∈ R2, but (1, 14) ∉ R2


It is not transitive.

69) Given set {1, 2, 3, 4}


Minimum order pairs are
(1, 1), (2, 2), (3, 3), (4, 4), (3, 1),(2, 1), (2, 3),(3,2), (1, 3), (1, 2)
Thus no. of elements = 10

70) n(A∪B∪C) = Σn(A) – Σn(A∩B) + (A∩B∩C)


Sn(A∩B) = 36
Number of students who got exactly 2 medals
⇒ 36 – 15 = 21
71) ....(1)

....(2)

⇒ N = 17(17) = 289

72) 2[x + 15] + 5x – 1 = 17 {x + 3}


⇒ 2[x] + 30 + 5[x] +5{x} – 1 = 17{x}

⇒ {x} = .............(i)
but {x} ∈[0, 1] so

but [x] is an integer, so possible value of [x] are –4, –3

for [x] = –4, {x} = so

for [x] = –3, {x} = so x =

s=

73)

⇒ 6x + 10 – x2 > 3
⇒ x2 – 6x – 7 < 0
(x – 7) (x + 1) < 0
∴ x ∈ (–1, 7)
Integral values : x = 0, 1, 2, 3, 4, 5, 6
sum = 0 + 1 + 2 + 3 + 4 + 5 + 6
= 21

74) (i) 0 ≤ x < 1 ⇒ ⇒

(ii) 1 ≤ x < 2 ⇒ ⇒ y ∈ (1, 2]

(iii) 2 ≤ x < ⇒ ⇒ y ∈ (2, 3]

,b=3
[a] + [b] = 3

75) f(x) =
1 ≤ x6 + 12x4 + 5x2 + 1 < ∞

∴ f(x) ∈
∴ Number of integers = 33

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