27-04-2025

9610WJA801593250004 JA

PART 1 : PHYSICS

SECTION-II

1) Charges Q, 2Q, 4Q, 8Q and so on are fixed on the x-axis as shown. The magnitude of net force

experienced by 'q' charge placed on origin is . Find N.

2) A thin insulating uniformly charged (linearly charged density λ) rod is hinged about one of its
ends. It can rotate in vertical plane. If rod is in equilibrium by applying vertical electric field E as
shown in figure. Find the value of E(in N/C). (Given that mass of rod 2 kg, , ℓ=1m, g=10

m/s2)

3) Two point charges 2 μC and 8 μC are placed at position x = 0 and x = 4m respectively. The
distance of the neutral point form the smaller charge is found to be at x = α/β. Find the value of (α +
β).

4) If force (F), acceleration (A) and time (T) are taken as fundamental quantities, dimensions of

length in this system are [FaAbTc]. Find .

5) In a new system of units of speed (v), acceleration (A) and force (F) are considered as
fundamental quantities. Find summation of dimensions of new fundamental quantities in the formula
for Young's modulus?

6) A vector which has magnitude 10 unit is added to a vector which lies along the x-axis, the

sum of these two vector along y-axis and has magnitude times magnitude of . Find the magnitude
of .

7) A force moves a body of mass 10 kg from position (3, 4, 5) to a position (6, 7, 8).
Find the work done (in J).
8) Two identical balls of mass m = 0.9 g each are charged by the same charges, joined by a thread
and suspended from the ceiling (figure). Find the charge (in µC) that each ball should have so that
the tension in both the threads are same? The distance between the centers of balls is R = 3m.

SECTION-I (i)

1) An oil drop has a charge - 9.6 × 10–19 C and mass 1.6 × 10–15 gm. When allowed to fall, due to air
resistance force it attains a constant velocity. Then if a uniform electric field is to be applied
vertically to make the oil drop ascend up with the same constant speed, which of the following are
correct. (g = 10 ms-2)
(Assume that the magnitude of resistance force is same in both the cases)

(A) The electric field is directed upward

(B) The electric field is directed downward

(C)
The intensity of electric field is

(D)
The intensity of electric field is

2) A bead of mass m, charge q is at rest w.r.t. to rod PS which is accelerated towards right with
acceleration of a0 m/s2. A uniform electric field E0 is present towards the right. (Neglect friction) “N”
denotes normal reaction between bead and the rod. Which of the following equation is/are correct?

(A) m a0 cos θ = qE0 cos θ + mg sin θ

(B) N + qE0 sin θ = mg cos θ + ma0 sin θ
(C) N – qE0 sin θ = mg cos θ + ma0 sin θ
(D) N + ma0 sin θ = mg cos θ + qE0 sin θ
3) A wire, of length L( = 20 cm), is bent into a semi-circular arc. If the two equal halves, of the arc,
were each to be uniformly charged with charges ±Q, [|Q| =103 ε0 Coulomb where ε0 is the
permittivity (in SI units) of free space, the net electric field at the centre O of the semi-circular arc

would be :-

(50×103 N/C)
(A)
3
(B) (50×10 N/C)

(C) (25×103 N/C)

(D) (25×103 N/C)

4) An electron is placed just in the middle between two long fixed line charges of charge density +λ

each. The wires are in the xy plane (Neglect gravity).

(A) The equilibrium of the electron will be unstable along x-direction

(B) The equilibrium of the electron will be stable along y-direction
(C) The equilibrium of the electron will be neutral along y-direction
(D) The equilibrium of the electron will be stable along z-direction

5)

Two infinitely long line charge having linear charge density λ and –λ are placed at angle θ as shown
in figure. Find electric field at P, which is at a distance 'x' from point O along angle bisector of line
charges
(A)

(B)

(C)

(D)

6)

A half ring is charged with linear charge density λ = λ0 cos2θ. The electric field at (0,0) is :

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) Five identical charges are kept at five vertices of a regular hexagon. Match the following two
columns at centre of the hexagon. If in the given situation electric field at centre is E. Then,
 List-I List-II

I. If charge at B is removed, then

p. 2E
electric field will become

II. If charge at C is removed, then

q. E
electric field will become

III. If charge at D is removed then

r. Zero
electric field will become

IV. If charges at B and C both are

removed, then electric field will s.
become

t.

u. None of these
(A) I → s;II → q;III → r;IV → p
(B) I → p;II → q;III → r;IV → s
(C) I → p;II → r;III → s;IV → q
(D) I → s;II → p;III → q;IV → r

2) Variation of electric field along the line joining two charges is given in list-I. Relation between
charges is given in list-II. Match the proper variation. Take electric field along right as positive

List-I List-II

|q1| > |q2|

(P) (1)
q1 < 0; q2 > 0

|q1| = |q2|
(Q) (2)
q1 > 0; q2 > 0
 |q1| = |q2|
(R) (3)
q1 < 0; q2 > 0

|q2| > |q1|

(S) (4)
q1 > 0; q2 > 0

(A) P → 3;Q → 1;R → 2;S → 4

(B) P → 1;Q → 4;R → 2;S → 3
(C) P → 4;Q → 3;R → 2;S → 1
(D) P → 2;Q → 3;R → 4;S → 1

3) A set of 2 vectors is given in each option of List–I. Match List–I and II.

List-I List-II

(P) (1) Sum of 2 vectors is a unit vector.

(Q) (2) Magnitude of sum of two vectors is .

(R) (3) Magnitude of difference of two vectors is 5.

The resultant has a positive rectangular component in the

(S) (4)
direction +X.

(5) None of these

(A) P → 3;Q → 4;R → 2;S → 1
(B) P → 2;Q → 3;R → 1;S → 4
(C) P → 1;Q → 4;R → 2;S → 3
(D) P → 4;Q → 1;R → 3;S → 2
4) Match the column where symbols have their usual meaining :—

List-I (Quantity) List-II (Unit)

(P) Energy density (Energy per unit volume) (1) Dyne/cm2

Force constant k of a spring (F = kx ; F is force and

(Q) (2) kg m–1s–1
x is extension)

(R) Pressure (Force per unit area) (3) Erg/cm2

(S) Coefficient of viscosity η (F = 6πηrv) (4) Pascal

(5) kg m–2s–1
(A) P → 1,4;Q → 3;R → 1,4;S → 2
(B) P → 1;Q → 4;R → 3;S → 2
(C) P → 2;Q → 4;R → 1;S → 3
(D) P → 1;Q → 5;R → 2;S → 3

PART 2 : CHEMISTRY

SECTION-II

1) The rate of first-order reaction is 0.04 mol litre–1 s–1 at 10 minutes and 0.03 mol litre–1 s–1 at 22
minutes after initiation. The half life of the reaction (in seconds) is (ln2 = 0.7, ln3 = 1 .1).

2) Consider the kinetic data given in the following table for the reaction A + B + C → Product.

The rate of the reaction for [A] = 0.15

mol dm , [B] = 0.25 mol dm and [C] = 0.15 mol dm is found to be Y × 10–5 mol dm–3 s–1. The value
–3 –3 –3

of Y is –––––––– .

3) A catalyst decreases activation energy of a reaction from 42 kJ mol-1 to x kJ mole-1. The rate of
reaction in the absence of the catalyst at 500 K is equal to the rate of the reaction in the presence of
catalyst at 450 K. The value of x is:

4) For a reaction A + B → C the rate constant at 300 K is 10 min–1. Calculate its rate constant at 310
K in term of min–1 if activation energy of the reaction is 2T2 cal where T is temperature on absolute
scale.
[Take ℓn10 = 2.3]
[Express your answer as 10x min–1 & fill x in OMR]
[Round off answer to two digits after decimal]
5) A mixture contains 61.2% BaO, 28% CaO and 10.8% (Silica) impurities. What volume of 3.00
MHCl could be required to react completely with 1g of the mixture.

6) Basic solution of Na4XeO6 is powerful oxidants. How many millimoles of Mn(NO3)2 · 6H2O reacts
with 62.5 ml of a 0.04 M basic solution of Na4XeO6 that contains an excess of sodium hydroxide if the
products include Xe and a solution of sodium salt of manganese containing anion? (Mn = 55)

7) An aqueous solution containing 288 gm of a non-volatile compound having the stoichiometric

composition CxH2xOx in 90 gm water boils at 101.38°C at 1.00 atmospheric pressure. Find value of 'x'
? Kb(H2O) = 0.52 K mol–1 kg

8) Phenol associates in benzene to a certain extent to form a dimer. A solution containing 18.8 × 10–3
kg phenol in 1 kg of benzene has its freezing point depressed by 0.768 K. Calculate the fraction of
phenol that has dimerised. Kf for benzene = 5.12 kg mol–1K.

SECTION-I (i)

1)

For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the mole
fraction of M in solution is shown in the following figure, here XL and XM represent mole fractions of
L and M, respectively, in the solution. the correct statement(s) applicable to this system is(are)

Attractive intramolecular interactions between L–L in pure liquid L and M–M in pure liquid M
(A)
are stronger than those between L–M when mixed in solution
(B) The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed when XL → 0
(C) The point Z represents vapour pressure of pure liquid L and Raoult's law is obeyed when XL → 1
The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed from XL = 0
(D)
to XL = 1

2) One litre of 2 molar solution of complex salt CoCl3 .4NH3 ([Link] = 233.5), shows an osmotic
pressure of 96 atm at 300 K. The solution is now treated with 2 litre of 1 M AgNO3, which of the
following statement(s) is/are correct ? (R = 0.08 l atm/mol K)
(A) Mass of AgCl precipitated is 287 g
(B) The clear solution will show an osmotic pressure of 96 atm
(C) The clear solution will show an osmotic pressure of 32 atm
(D) 2 moles of [Co(NH3)4 .Cl2]NO3 will be present in solution

3) In a bimolecular reaction, the steric factor P was experimentally determined to be 4.5. The
correct option(s) among the following is(are)

(A) The activation energy of the reaction is unaffected by the value of the steric factor
Experimentally determined value of frequency factor is higher than that predicted by Arrhenius
(B)
equation
(C) Since P = 4.5, the reaction will not proceed unless an effective catalyst is used
The value of the frequency factor predicted by the Arrhenius equation is higher than that
(D)
determined experimentally

4) For the reaction the rate law expression is If initial concentration of [A]
is [A]0, then

The integrated rate expression is

(A)

(B)

The graph of Vs t will be

(C)
The half life period

(D)
The time taken for 75% completion of reaction

5) Two flask of equal capacity contain NH3 & SO2 gases respectively, are kept under similar
conditions of temperature & pressure. Select the correct option on the basis of above information:

(A) More moles are present in flask contain NH3

(B) Flask of SO2 has more mass
(C) Flask of NH3 has more number of atoms.
(D) Both flask contain same number of molecules of NH3 & SO2 respectively

6) Which of the following statements is/are correct :

(A) 0.2 moles of KMnO4 will oxidise one mole of ferrous ions to ferric ions in acidic medium.
1.5 moles of KMnO4 will oxidise 1 mole of ferrous oxalate to one mole of ferric ion and carbon
(B)
dioxide in acidic medium.
 0.6 moles of KMnO4 will oxidise 1 mole of ferrous oxalate to one mole of ferric ion and carbon
(C)
dioxide in acidic medium.
1 mole of K2Cr2O7 will oxidise 2 moles of ferrous oxalate to ferric ions and carbon dioxide in
(D)
acidic medium.

SECTION-I (ii)

1)

Column–I Column–II

A. P.

B. Q.

C. R.

D. S.

T.

(A) A → P;B → Q;C → R;D → T

(B) A → Q;B → S;C → R;D → P
(C) A → S;B → Q;C → T;D → R
(D) A → S;B → Q;C → R;D → P

2) Match the List -

List-I List-II

(P) (1) x = 0.56 g

(Q) (2) x = 1.333 g

(R) (3) x = 1.125 g

(S) (4) x = 0.11 g

(5) x = 1.214 g
The correct option is :-
(A) P → 3;Q → 5;R → 1;S → 2
(B) P → 4;Q → 5;R → 3;S → 4
(C) P → 1;Q → 4;R → 5;S → 3
(D) P → 1;Q → 4;R → 3;S → 5

3) Match the solutions List-I with change in their properties in List -II and select correct code.
[Assume no change in volume on addition of solute/reagent]

List-I List-II

10 milli moles of HgI2 are added to Osmotic pressure of

(I) (P)
10 ml of 2 M aqueous KI. solution increases

50 milli moles of KI are added to 20 Freezing point of

(II) (Q)
ml of 0.5 M aqueous CuSO4. solution increases

10 milli moles of FeCl2 are added to Vapour pressure of

(III) (R)
20 ml of 3 M aqueous KCN. solution increases

10 milli moles of HgCl2 is added to Boiling point of

(IV) (S)
10 mL of 1 M solution increases

No change in
(T)
colligative properties
(A) I → Q;II → R;III → R;IV → S
(B) I → R;II → S;III → P;IV → T
(C) I → S;II → T;III → R;IV → P
(D) I → Q;II → S;III → R;IV → P

4) For the reaction 2A(g) → B(g) , starting with 4 moles of A in a 5 litre container at 400 K.
For different possible orders of reaction half-life is 40 seconds. Now match following :

List-I List-II

If reaction follows first order kinetics then initial rate of

(P) (1) 3.46 × 10–4 M/s
reaction

If reaction follows zero order kinetics then rate of reaction at

(Q) (2) 6.93 × 10–3 M/s
time : t = 40 sec.

If reaction follows first order kinetics then rate of reaction at

(R) (3) 5 × 10–3 M/s
95% completion.

If reaction follows second order kinetics then rate of reaction at

(S) (4) 10–6 M/s
99% completion

(5) 6.25 × 10–5 M/s

(A) P → 2;Q → 3;R → 1;S → 4
(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 5;Q → 1;R → 2;S → 4
(D) P → 2;Q → 1;R → 4;S → 3

PART 3 : MATHEMATICS

SECTION-II

1) Number of solution of the equation 2x |2 – |x|| = 1 is _______

2) The number of integers in the domain of is

3) The number of solutions of the equation |[x] − 2x| = 4, is (where [x] denotes the greatest integer
function)

4) Find the number of integral value(s) in the domain of f(x) = ?

5)

Value of largest possible x for which 5x = 7[x] is - (where [.] denotes greatest integer function)

6) If the range of the function is then find the value of

7) Let solution of equation |x2 – 3x – 4| + |x2 + 2x – 3| = |5x + 1| is x ∈ [a, b] ∪ [c, d], then value of |a|
+ |b| + |c| + |d| is

8) If ƒ : R → R, is a bijective function then sum of all possible

integral value of k will be :

SECTION-I (i)

1) There are three sets A, B & C such that n(A) = 12, n(B) = 10, n(C) = 11, n(A ∩ B) = 5, n(B ∩ C) =
5, n(C ∩ A) = 3. If universal set n(U) = 28, then which of the following is/are true ?

(A) Maximum possible value of n(A ∪ B ∪ C) is 23

(B) Maximum possible value of n(A ∩ B ∩ C) is 3
(C) Minimum possible value of n(A ∪ B ∪ C) is 20
(D) Minimum possible value of n(A ∩ B ∩ C) is 0

2) On the set of real numbers, let R be a relation aRb iff is an irrational no, then R is

(A) not symmetric relation

(B) not reflexive relation
(C) not transitive relation
(D) equivalence relation.

3) In a certain town 25% families own a phone and 15% own a car, 65% families own neither a
phone nor a car, 2000 families own both a car and a phone. Which of the following statements is
(are) correct in this regard
(A) 10% families own both a car and a phone.
(B) 35% families own either a car or a phone.
(C) 40000 families live in the town.
(D) 60000 families live in the town.

4) A polynomial P(x) leaves remainders 2, 3, 4, when divided by (x – 1), (x – 2), (x – 3) respectively. If

P(x) leaves remainder ax2 + bx + c, when divided by x3 – 6x2 + 11x – 6, then

(A) a + b + c = 0
(B) a + b + c = 2
(C) 4a + 2b + c = 1
(D) 4a + 2b + c = 3

5) The equation |x+2|–|x+1|+|x–1|=K, x∈R has two solutions if K is equal to

(A) 4
(B) 3/2
(C) 5/2
(D) 3

6) Which of the following options are true.

(A) Range of f(x) = 5 + 7sinx will be [–2, 12]

(B) Range of f(x) = 5 + 7sin2x will be [5, 12]
(C) Range of f(x) = sin2x – 3sinx + 8 will be [0, 1]

(D)
Range of f(x) = will be

SECTION-I (ii)

1) If 'n' is number of solution for ||x| – 10| = k, List-I contains value of 'n'. List-II contains range of 'k'.

List-I List-II

(I) n=0 (P) k ∈ (–∞, 0)

(II) n=2 (Q) k ∈ (–∞, 0]

(III) n=3 (R) k ∈ (0, 10)

(IV) n=4 (S) k ∈ {10}

(T) k ∈ (10, ∞)

(U) k ∈ (10, ∞) ∪ {0}

Which of the following is the only CORRECT combination ?
(A) I → Q
(B) II → U
(C) III → R
(D) IV → P

2) Matching List

List-I List-II

(I) (P) [1, 9]

Range of

(II) Range of y = cos2x – 4cosx + 4 (Q) (0, 1]

(III) (R) [0, 1]

Range of

(IV) (S) [0, ∞)

Range of

(T) (0, ∞)
(A) I → P;II → R;III → S;IV → Q
(B) I → S;II → Q;III → P;IV → R
(C) I → Q;II → S;III → R;IV → P
(D) I → R;II → P;III → Q;IV → S

3)

Match Column-I with Column-II and select the correct answer using the code given below the list.

Column-I Column-II

(P) ƒ : R → R ; ƒ(x) = x + [x] (1) Injective Mapping

ƒ : R → (0,∞)
(Q) (2) Surjective Mapping

(R) (3) Non injective mapping

ƒ(x) = x3 – 2x2 + 2x + log x

ƒ : [–3,0] → [cos3,1]
(S) (4) Non surjective mapping
ƒ(x) = cosx

(5) Invertible function

(A) P → 1;Q → 4;R → 2;S → 1;T → 5;U → 2;V → 5
(B) P → 1;Q → 4;R → 2;S → 3;T → 1;U → 2;V → 5;W → 1;X → 2;Y → 5
(C) P → 3;Q → 4;R → 2;S → 3;T → 1;U → 5;V → 2
(D) P → 1;Q → 2;R → 5;S → 1;T → 3;U → 2;V → 5

4) Match the function mentioned in List-I with the respective classification given in List-II. (where [.]
and {.} denote greatest integer function and fractional part function respectively)

List-I List-II
 (P) f: → ; f(x) = (e[x])(e{x}) (1) one-one and onto

(Q) f : (–∞, –2) ∪ (0, ∞) → ; f(x) = ℓn(x2 + 2x) (2) one-one and into

(R) f : [–1, 1] → [–1, 1] ; f(x) = sinx (3) many-one and onto

(S) f: → ; f(x) = x3 – 3x2 + 3x – 7 (4) many-one and into

(5) not a function

Match each entry in List-I to the correct entries in List-II.
The correct option is :
(A) P → 1;Q → 3;R → 5;S → 4
(B) P → 1;Q → 3;R → 2;S → 1
(C) P → 2;Q → 4;R → 5;S → 1
(D) P → 2;Q → 3;R → 5;S → 4
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-II

Q. 1 2 3 4 5 6 7 8
A. 2.00 2.00 7.00 1.50 -1.00 6.00 6.00 3.00

SECTION-I (i)

Q. 9 10 11 12 13 14
A. B,C A,B C A,C,D A C

SECTION-I (ii)

Q. 15 16 17 18
A. A C C A

PART 2 : CHEMISTRY

SECTION-II

Q. 19 20 21 22 23 24 25 26
A. 1680.00 6.75 37.80 5.35 6.00 4.00 40.00 0.50

SECTION-I (i)

Q. 27 28 29 30 31 32
A. A,C A,C,D A,B A,B,D B,C,D A,C,D

SECTION-I (ii)

Q. 33 34 35 36
A. D A D A

PART 3 : MATHEMATICS

SECTION-II

Q. 37 38 39 40 41 42 43 44
A. 3.00 1.00 4.00 6.00 2.80 4.00 9.00 3.00

SECTION-I (i)

Q. 45 46 47 48 49 50
A. A,B,C,D A,B,C B,C B,D A,B A,B,D
 SECTION-I (ii)

Q. 51 52 53 54
A. B D B B
 SOLUTIONS

PART 1 : PHYSICS

1)

Magnitude of force on charge q at origin =

N=2

2) mg = qE

3)

The neutral point is where the net electric field due to both charges is zero.
The electric field due to a point charge at a distance r is given by :

E=
At the neutral point, the fields due to both charges must cancel each other out.

cancelling k, we solve for x.

2(4 – x)2 = 8x2

dividing by 2 :
(4 – x)2 = 4x2
Taking the square root on both sides :
4 – x = 2x
solving for x :
4 = 3x
x=

since the neutral point is found at x = and comparing with , we get α = 4 and β = 3.
α+β=4+3=7

Correct answer is 7

4)

a=0
a + b = 1⇒ b = 1
–2a – 2b + c = 0
0–2+c=0
c=2

5) [Y] =[Va Ab Fe-]

[Y] = [M1L-1T-2]
[VaAbFc] = [L1T-1][L1T-2]b[M1L1T-2]c
= [L1T-a][LbT-2b][McLcT-2c]
= [M1L-1T-2] = [McLa+b+cT-a-2b-2c]
c = 1 ....... (1)
a + b + c = -1 .....(2)
-a - 2b - 2c = -2 ....(3)
a + b + 1 = -1 a+b=-2 -2b + b = -2
-a - 2b - 2 = - 2 -a - 2b = 0 -b = -2
a = -2b b=2
a + b + c = -4 + 2 + 1 = -1 a = -2 × 2 = -4

6) 102 = A2 +

100 =
A=6

7) W =
Now

∴
∴ W= =
= 15 – 12 + 3 = 6 J

8)

Fe = mg

9 × 109 = 0.9 × 10–3 × 10

⇒ q = 3 × 10–6 C
= 3 µC

9) (initially) ∴ mg = fair

(finally) ∴ QE = mg + fair = 2mg

∴ charge is –ve, so electric field 'E' is directed downwards.

& QE = 2 mg

10)

Make components of all forces along & perpendicular to the plane

 Now balance forces perpendicular to plane
(N + qE sin θ) – Mg cos θ = m a sin θ
(N + qE sin θ) = (Mg cos θ+ m a sin θ)
Now balance forces along the plane
(mg sin θ) + (qE0) cos θ = ma cos θ

11)
Net electric field due to dq charge placed symmetrically about y-axis at O

ENet =

= [pR = L]

12) For stable equilibrium

13)

Electric field due to 1 wire E =

14)

Enet =
=

15)
At centre field is due to charge at D. The field of other charfes cancel-out. If B is removed field
at centre is due to D & E.

16) Apply the following tests :-

(1) Electric field will be zero in between the charges only if the charges are of same nature.
(2) E.F. will be zero in between the charges, closer to the smaller charge
(3) E.F. may be zero on outer side of charges (on the line joining them), if they are unequal,
closer to the smaller charge.

17)

(P)

∴
(Q)
(R)
(S)

18) (P) Energy density = Energy/volume

= Dyne × cm/cm3 = Dyne/cm2
Energy density = Joule/m3 = N × m/m3
= N/m2 = Pascal

Energy density =
= ML–1T–2
(Q) K = F/Δl = Dyne/cm
= Dyne × cm/(cm × cm) = Erg/cm2
 Force constant k of spring
f = kx

(R) Pressure = Force/Area = Dyne/cm2

= Newton/m2 = Pascal

Pressure =
(S) F = 6πηrv

⇒
η = ML–1 T –1

(1)
(2) kgm–1s–1 = ML–1T–1

(3) Erg/cm2

(4) Pascal ⇒
(5) kg m–2s–1 ⇒ ML–2 T –1

PART 2 : CHEMISTRY

19) 0.04 = K[A]10 ⇒

0.03 = K[A]22

min–1 = 0.025 min–1

20)

r = k [A]x[B]y[C]z : from table x = 1; y = 0, z = 1

r = k[A] [C]
from1st experiment 6 × 10–5 = k × 0.2 × 0.1
k = 3 × 10–3
r = (3 × 10–3) × 0.15 × 0.15 = 6.75 × 10–5 mol dm–3 s–1

21)

∴ x = 37.80
22) If EA = f(T) then

∴ ℓn K2 – ℓnK1 =

⇒
K2 =
=
= 105.3478
= 105.35

23) Mole of BaO =

Mole of CaO
∴ Mole of HCl = 0.008 + 0.01 = 0.018
∴ Vol. of HCl = 6 ml

24)

Eq. of Mn(NO3)2 · 6H2O

= Eq. of Na4XeO6
x × 5 = 62.5 × 0.04 × 8
x=4

25) Applying formula for elevation in boiling point;

ΔTb = Tb' – Tb = Kb × molality;
Tb' = boiling point of solution;
Tb' = boiling point of pure solvent
Kb = molal elevation constant
Substituting values;

moles of solute =

molality =

⇒ (101.36 – 100) k =
⇒ ⇒ formula = C40H80O40
26) Given:

i = 1 + (y – 1) α =
Applying formula of depression in freezing point;
ΔTf = kf × molality × i ; where
Tf' = freezing point of the solution;
Tf = freezing point of pure solvent
Kf = molal depression constant;
molality = molality of solution
i = Van't Hoff factor = 1 + (y – 1)α.
α = degree of dissociation;
y = no. of moles of product per mole of reactant
Substituting values;

0.768K =

⇒ = 0.75 ⇒ α = 0.5

27)

→ solution showing positive deviation from Raoult's law

∴ L-M interactions are weaker than L-L & M-M interactions.

28)

π = iCRT

i = 1 + (n – 1)α

⇒ n = 2, hence, formula of compound is [Co(NH3)4 Cl2] Cl

(A) [Co(NH3)4 Cl2]Cl + AgNO3 —→ AgCl + [Co(NH3)4Cl2]+ + NO3–

2M, 1liter 1M, 2liter
0 0 2mole = 287 gm 2mole 2 mole

(B) Osmotic pressure of final solution which contains 2mol of [Co(NH3)4Cl2]NO3

π = i CRT =

29)

We know, Kexp / Kcollison =

the experimentally determined value of the frequency factor is higher than that predicted by
the Arrhenius equation.
option A is correct and C is incorrect.

Since in this equation Ea is not changed, option B is correct.

Since Kexp > K, there is no need for an effective catalyst to reduce activation energy so that
Kexp increases.
option D is also not correct.

30)

A→B

2(A)1/2 = –kt + C
Condition
A = A0 at t = 0

31)

P, V, T same.
∴ Moles same & molecules same.
∴ NH3 will have more number of atoms.

32)

(A, C, D) In acidic medium KMnO4 n factor is 5

33)

⇒ Disproportionation of P2H4

(nf) of P2H4 = ⇒
⇒ Disproportionation of I2

(nf) of I2 = ⇒
⇒ Comproportination of KmnO4

(nf) of KMnO4 = ⇒

(nf) of KMnO4 = 5 ⇒
 34)

(P)

(Q)

(R)

(S)

35)

36) (P) K = =

0
r = K[A] =
= 6.93 × 10–3 M/s

(Q) rA =

r=
(R) r = K[A]

=
= 3.465 × 10–4 M/s

(S) KA =

r= × (0.008)2 = 10–6 M/s

PART 3 : MATHEMATICS

37) |2 – |x|| = 2–x

38) ⇒ x ∈ [–1 0) ∪ [1, ∞)

9 – [x]2 ≥ 0 ⇒ –3 ≤ [x] ≤ 3 ⇒ –3 ≤ x < 4
There are 4 integers in [–1, 0) ∪ [1, 4)
–1, 1, 2, 3
But tanx is negative for x = –1, 2 & 3.
Therefore there is only one integer in the domain.

39) | 2x – [x]| = 4
⇒ |[x] + 2 {x}| = 4
Let if {x} = 0, then
[x]= ± 4
⇒ x = 4, – 4

If {x} = , then
|[x] + 1| = ± 4
⇒ [x ] = –5, 3

⇒ x=
So, number of solution = 4

40) or ...(1)
...(2)

No. of integral values of x are 6.

i.e. –5, –4, –3, 3, 4, 5.

41)

5x = 7[x] ⇒ 5x = 7x – 7{x}

∴ ⇒
∀ x ∈ [0,1) : [x] = 1 ⇒ 5x = 7 × 0 ⇒ x = 0
∀ x ∈ [1,2) : [x] = 1 ⇒ 5x = 7 × 1 ⇒ x = 7/5
∀ x ∈ [2,3) : [x] = 2 ⇒ 5x = 7 × 2 ⇒ x = 14/5
∀ x ∈ [3,7/2) : [x] = 3 ⇒ 5x = 7 × 3 ⇒ x = 21/5 (Reject)
largest x = 14/5

42)
⇒
⇒
⇒
⇒
⇒
⇒
⇒

43) (x2 – 3x – 4)(x2 + 2x – 3) < 0

(x – 4)(x + 1)(x + 3)(x – 1) < 0
⇒

44) Clearly

Therefore possible integral values of k are

–2, –1, 0, 1, 2, 3.

45)
⇒3–x≥0 & x≥0
⇒0≤x≤3
~(A ∪ B ∪ C) = 20 + x
⇒ 20 ≤ 20 + x ≤ 23

46) Take

47) Let there be x families in the town

n(P) = , n(C) =

n(P′ ∩ C′) = , n(P ∩ C) = 2000

n(P′ ∩ C′) = n(P ∩ C)′

= total – n(P ∪ C)

= x – {n(P) + n(C) – n(P ∩ C)}

x = 40000
48) Assume
p(x) = (x3 – 6x2 + 11x – 6)Q(x) + ax2 + bx + c
Put x = 1, p(1) = 2
x = 2, p(2) = 3
x = 3, p(3) = 4

49)

Graph of y=|x+2|–|x+1|+|x–1|

for two solutions K∈(1, 2) ∪ (3, ∞)

50)

(A) –1 ≤ sinx ≤ 1 ⇒ 5 + 7sinx ∈ [–2, 12]

(B) 0 ≤ sin2x ≤ 1 ⇒ 5 + 7sin2x ∈ [5, 12]
(C) f(x) = sin2x – 3sinx + 8
Range [7, 12]

(D)

51) LHS : y = ||x| – 10| RHS : y = k

(I) For n = 0 ; k ∈ (–∞, 0)

(II) For n = 2 ; k ∈ (10, ∞) ∪ {0}
(III) For n = 3 ; k ∈ {10}
(IV) For n = 4 ; k ∈ (0, 10)
52)

(I)
(II) y = (cosx – 2)2 ∈ [1, 9]

(III)

(IV)
y ∈ [0, ∞)

53) (P) f(x) = x + [x] =

f(x) is injective but not surjective

(Q) f : R → (0, ∞)

Non injective surjective

(R) f : (0, ∞) → R
f(x) = x3 – 2x2 + 2x + logx

⇒ f'(x) > 0
∴ Always +ve
∴ f(x) is increasing ⇒ one one
Also Range of f(x) is R
∴ f(x) is one one onto
(S) f : [–3, 0] → [cos3, 1]
 f(x) = cosx
one one onto

54) (P) f : R → R+, f(x) = e[x]. e{x}

f(x) = e[x] + {x} = ex
∴ f(x) is one-one, onto
(Q) f : (–∞,–2) ∪ (0,∞) → R,
f(x) = ℓn (x2 + 2x)
x2 + 2x ∈ (0,∞)
∴ ℓn (x2 + 2x) ∈ (–∞,∞)
∴ f(x) is many-one, onto
(R) f : [–1,1] → [–1,1], f(x) = sinx
f(x) ∈ [– sin1, sin1]
∴ f(x) is one-one, into
(S) f : R → R, f(x) = x3 – 3x2 + 3x – 7
f'(x) = 3(x – 1)2 > 0 → ∴ f(x) is one-one, onto