05-01-2026

6901CJA10153125MJ017SB JM

PHYSICS

SECTION-I

1) A particle is projected from a horizontal plane (x-z plane) such that its velocity vector at time t is
given by . Its range on the horizontal plane is given by :-

(A)

(B)

(C)

(D) None

2) A student is cleaning a blackboard by moving a light duster up and down on it. The coefficient of
static friction between the duster and the board is µs. The duster will not move, no matter how large

the force is if (ignore gravity) :-

(A) tan β > µs

(B) tan β < µs
tan β >
(C)

tan β <
(D)

3) If velocity of block B in the given figure is 300mm/s towards right. Then velocity of A will be :-

(A) 200 mm/s

(B) 100 mm/s
(C) 450 mm/s
(D) 150 mm/s

4) Find the ratio of work done by gravity on the block under the two conditions. Assume
between block and plane.

(A) 1 : 2
(B) 2 : 1
(C) 1 : 1
(D)

5) The angular velocity of a body moving in a circular path is shown in graph below. What is the

average angular velocity (in rad/s) for the entire motion?

(A) 9
(B) 18
(C) 27
(D) 36

6) A and B are two identical masses and A is moving with speed 5m/s and B is at rest. If A collides

with B elastically, speed of A after collision is :

(A)

(B) 5 m/s
(C) 0 m/s

(D)
7) y-coordinate of COM of given system will be at :-

(A)

(B)

(C)

(D)

8) In an experiment with a beam balance on unknown mass m is balanced by two known masses of
16 kg and 4 kg as shown in figure.

The
value of the unknown mass m is

(A) 10 kg
(B) 6 kg
(C) 8 kg
(D) 12 kg

9) A plank ‘P’ is placed on a solid cylinder S which rolls on a horizontal surface. The two are of equal
mass. There is no slipping at any of the surfaces in contact. The ratio of kinetic energy of ‘P’ to the

kinetic energy of ‘S’ is :-

(A) 1:1
(B) 12:1
(C) 8 :3
(D) 11:8

10) To one end of thread thrown over the pulley we suspended load of mass M = 10kg, made from a
material of specific gravity 2.5. The mass M is suspended in a container with water. By the other
end of the thread we suspended a mass m (see figure). For what minimum value of m (in kg) can

mass M float in liquid in equilibrium? (Friction negligible everywhere)

(A) 2
(B) 4
(C) 6
(D) 8

11) A tank is filled with water up to height H. Water is allowed to come out of a hole P in one of the
walls at a depth D below the surface of water. Express the horizontal distance x in terms of H and D

(A)

(B)

(C)
(D)

12) If the work done in blowing a bubble of volume V is W, then the work done in blowing the bubble
of volume 2V from the same soap solution will be :-

(A) W/2
(B)
(C)
(D)

13) A piece of cork starts from rest at the bottom of a lake and floats up. Its velocity v is plotted
against time t. Taking into account viscosity of water which of the following best represents the
resulting curve?

(A)
(B)

(C)

(D)

14) Two light wires of the same material (Young's modulus Y) and same length L but different radii R
and 2R, as shown in the figure, are joined end to end and supported from a fixed support. A weight

W is suspended from the combination. The elastic potential energy in the system is:

(A)

(B)

(C)

(D)

15) A rod of length 2m rest on smooth horizontal floor. If rod is heated from 0°C to 100°C. Find the
longitudinal strain developed ? (Coefficient of thermal expansion α = 5 × 10–5 /°C) :-

(A) 10–3
(B) 2 × 10–3
(C) Zero
(D) None
16) Work done in converting 1 g of ice at –10°C into steam at 100°C is

(A) 3045 J
(B) 6056 J
(C) 721 J
(D) 6 J

17) Two slabs A and B of different materials but of the same thickness are joined as shown in Fig.
The thermal conductivities of A and B are k1 and k2 respectively. The thermal conductivity of the

composite slab will be

(A) (k1 + k2)

(B)

(C)

(D)

18) The correct order of most probable speed (Vmp), root mean square speed (Vrms) and average speed
(Vav) of molecules in an ideal gas is :

(A) Vav > Vmp > Vrms

(B) Vrms > Vmp > Vav
(C) Vmp > Vrms > Vav
(D) Vrms > Vav > Vmp

19) Certain perfect gas is found to obey PV3/2 = constant during an adiabatic process. If such a gas at
initial temperature T is adiabatically compressed to half the initial volume, its final temperature will
be :-

(A) T
(B) 2T
(C) 2 T
(D) 4T

20) A particle is moving along a straight line parallel to x-axis with constant velocity. Its angular
momentum about the origin :

(A) Decreases with time

(B) Increases with time
(C) Remains constant
(D) Is zero
 SECTION-II

1) The vertical displacement of block A in meter is given by y = t2/4 where t is in second. Calculate

the downward acceleration aB of block B. (in m/s2)

2) Four uniform rods of equal length ℓ and mass m are rigidly joined together at their ends to form a
square framework ABCD. The framework is free to rotate in a vertical plane about a fixed smooth
horizontal axis passing through A. The framework is slightly displaced from its position of unstable
equilibrium. If the maximum angular velocity reached in subsequent motion if its centre moves in its

own plane is given by . Fill the value of x.

3) A capillary glass tube of height 2h is just dipped in water. In effect, the water rises to a height h
as shown in the figure. Let p1 be the pressure at height h/3 as shown inside the tube. The entire
system is put in an elevator moving up with a constant acceleration of 'g'. Let the new pressure at
the same point be p2. If 'Δp' = p1 – p2 be change in pressure at a height 'h/3' inside the tube. Find

4) A swimmer can swim in still water with a speed of m/s. While crossing a river his speed is 3
m/s with respect to ground. If he crosses the river in the shortest possible time, what is the speed of
flow of water (in m/s) ?

5) In the atmosphere of a planet there are only two gases Helium and oxygen in the mass ratio 1 : 4
respectively. The value of = CP/CV of the mixture is given by = 1 + K/11. Find the value of K

CHEMISTRY

SECTION-I

1) bond is formed when two dx 2

– y2 orbital

(A) x-axis
(B) y-axis
(C) z-axis
(D) Both (A) & (B)

2) In the reaction,
xZn + yHNO3(dil) → aZn(NO3)2 + bH2O + cNH4NO3,
upon balancing with simplest whole number coefficients, select the correct option(s) :

(A) The sum of the coefficients (a + b + c) is 8.

(B) Whole of HNO3 is oxidized to in above reaction.
(C) Zn acts as oxidant.
(D) HNO3 acts as reductant.

3) Which of the following is least stable (or unstable) resonating structure of following carbocation?

(A)

(B)
(C)

(D)

4) The quantum number of four elelctron ore given below :-

(I) n = 4, ℓ = 2, mℓ = –2, ms =–1/2
(II) n = 3, ℓ = 2, mℓ = 1, ms = +1/2
(III) n = 3, ℓ = 1, mℓ = 0, ms = +1/2
(IV) n = 4, ℓ = 1, mℓ = 0, ms = +1/2
Correct order of increasing energy is :-

(A) I < IV < III < II

(B) III < IV < II < I
(C) III < II < IV < I
(D) II < IV < III < I

5) What is the end product of following reaction

(A)

(B)

(C)

(D) CH4

6) Isomers of hexane, based on their branching, can be divided into three distinct classes as shown

in the figure. (I) and (II) and

 (III)
The correct order of their boiling point is

(A) I > II > III

(B) III > II > I
(C) II > III > I
(D) III > I > II

7) Arrange stability of the given carbocations in decreasing order :

(A) i > ii > iii > iv

(B) iii > ii > i > iv
(C) iv > i > ii > iii
(D) ii > iii > i > iv

8) Which of the following does not repesent major product of that reaction ?

(A)

(B)

(C)

(D)
9)

Select the correct statement for following structure

(A) Degree of unsaturation for above compound is 2

(B) Number of carbon atom in parent carbon chain is 1
(C) Number of carbon atom in parent carbon chain is 6
(D) Number of carbon atom in parent carbon chain is 7

10) Which of the following compounds does not have plane of symmetry ?

(A)

(B)

(C)

(D)

11)

Which of the following pairs of compounds are enantiomers :-

(A)

(B)

(C)

(D)

12) The ratio of circumference of 3rd and 2nd orbits of He+ ion is -

(A) 3 : 2
(B) 2 : 3
(C) 9 : 4
(D) 4 : 9

13) AB dissociates as 2AB (g) ⇌ 2A (g) + B2 (g)

When the initial pressure of AB is 500 mm, the total pressure becomes 625 mm when the
equilibrium is attained. Calculate KP for the reaction assuming volume remains constant.

(A) 500
(B) 125
(C) 750
(D) 375

14)
Which of the following statement is not correct for above elements ?

(A) P is the metal which form halide of the formula MX

(B) S is the least reactive non metal
(C) T is the least reactive element
(D) Q is a non-metal and does not form binary halide of the formula MX2

15) 2.5 mL of weak monoacidic base (Kb = 1 × 10–12 at 25°C) is titrated with M HCl in water
at 25°C. The concentration of H⊕ at equivalence point is
(Kw = 1 × 10–14 at 25°C)

(A) 3.7 × 10–13 M

(B) 3.2 × 10–7 M
(C) 3.2 × 10–2 M
(D) 2.7 × 10–2 M

16) One mole of an ideal gas expanded from 1 litre to 4 litre against constant pressure of 2 atm and
constant temperature 300 K, then heat absorbed by gas is : (1 lit-atm = 100 J)

(A) 600 J
(B) 800 J
(C) –600 J
(D) –800 J

17) 2 moles of H2S and 11.2 L SO2 at STP react to form x moles of S in the following reaction,
2H2S + SO2 → 3S + 2H2O
Thus, x is

(A) 1.5
(B) 3.0
(C) 11.2
(D) 6.0

18) Which of the following compounds has four bond pair and one lone pair ?

(A)
(B)
(C)
(D)

19) For which reaction at 298 K, the value of is maximum and minimum respectively:-
(a) N2O4 ⇌ 2NO2
(b) 2SO2 + O2 ⇌ 2SO3
(c) X + Y ⇌ 4Z
(d) A + 3B ⇌ 7C

(A) d, c
(B) d, b
(C) c, b
(D) d, a

20) If S is the solubility of a sparingly soluble salt M2X3, its solubility product is equal to

(A) 9 s4
(B) 27 s3
(C) 6 s2
(D) 108 s5

SECTION-II

1) How many of the following have standard heat of formation is zero.

(i) Br2(l) (ii) CO2(g) (iii) C(graphite)
(iv) Cl2(l) (v) Cl2(g) (vi) F2(g)
(vii) F2(l) (viii) F(g) (ix) S(monoclinic)
(x) N2(g) (xi) P(Black) (xii) P(red)
(xiii) CH4(g)

2) The oxidation states of iron atoms in compounds (A), (B) and (C), respectively, are x, y and z. The
sum of x,y and z is ____.
3)

Calculate the total number of stereoisomers for the given compound :

4) How many 'sp' hybrid orbitals are present in allene H2C = C = CH2 ?

5) How many of the following graphical representations are correct for ideal gas?

(a) (isotherm)

(b) (isotherm)

(c) (isotherm)

(d) (isobar)
(e) (isotherm)

(f) (isobar)

MATHEMATICS

SECTION-I

1) The equation of normal to curve x + y = xy where it cuts the x-axis is equal to

(A) y = –2x + 2
(B) y = 3x – 3
(C) y = x – 1
(D) 2y = x – 1

2) Let P(x) be a polynomial of degree 5 having extremum at x = – 1, 1 and

If M and m are the maximum and minimum value of the function y = on the set

A = {x | x2 + 6 ≤ 5x} then Find

(A) – 6
(B) 18
(C) 6

(D)

3) If curve and intersect orthogonally then the value of a is -

(A)

(B)

(C) 2
(D) 3
4) Given p,q,r are three distinct real numbers such that

, then roots of above equation are-

(A)

(B)

(C)

(D) roots depends on values of p,q,r

5) The number of real solutions of the equation is -

(A) 2
(B) 1
(C) 4
(D) 0

6) If m2 – n2 = 2010 then number of ordered pairs (m,n) satisfying equation is :- (where m & n are
natural numbers)

(A) 1
(B) 2
(C) 0
(D) 3

7) is non-differentiable at :

(A) Two points.

(B) One point
(C) Three points.
(D) More than three points.

8) If , then the value of is

equal to

(A)
(B)
(C)
(D) None of these

9) Let f : [0, ∞) → [0, 3] be a function defined by

Then which of the following is true?

(A) f is continuous everywhere but not differentiable at one point in (0, ∞)

(B) f is differentiable everywhere in (0, ∞)
(C) f is not continuous at two points in (0, ∞)
(D) f is continuous everywhere but not differentiable at two points in (0, ∞)

10) If f is twice differentiable such that and If h(x) is a twice differentiable

2 2
function such that h'(x) = (f(x)) + (g(x)) .
If h(0) = 2, h(1) = 4 then the equation y = h(x) represents :

(A) An exponential curve

(B) A logarithmic curve
(C) A straight line
(D) A sinusoidal curve

11) Let ƒ(x) = x3 + x2 + 6x – 22, and g(x) be inverse function of ƒ(x), then is equal to

(A) 23
(B) 32
(C) 33
(D) 22

12)

If an invertible function ƒ(x) satisfies x + |ƒ(x)| = 2ƒ(x), then ƒ–1(x) satisfies

(A) 3x + |ƒ–1(x)| = 2ƒ–1(x)

(B) x + |ƒ–1(x)| = 2ƒ–1(x)
(C) ƒ–1(x) – |x| = 2x
(D) 3x – |ƒ–1(x)| = 2ƒ–1(x)

13)

If ƒ(x) = x11 + sin3(35x) + 111x, then the value of

is equal to -

(A)

(B)

(C)
(D)
14) is equal to-

(A) e

(B)

(C)

(D)

15) Let a variable line is given as y = mx + c, where m is constant and c is variable. The locus of foot
of perpendicular from origin on this variable line is a straight line whose equation is -

(A)

(B) y + mx = 0
(C) m2y = x
(D) my + x = 0

16)

Equation of the angle bisector of the angle between lines 3x + 4y – 4 = 0 and 4x + 3y + 6 = 0 in

which point (1,1) lies is -

(A) x – y + 10 = 0
(B) 7x + 7y + 2 = 0
(C) x + y – 10 = 0
(D) 7x – 7y + 2 = 0

17) If ∠A = 90° in ΔABC ; then = (where the notations have

usual meaning)

(A) 0
(B) 1

(C)

(D)

18) Let ΔABC be a right angled triangle with right angle at C. Also, sinA & sinB are the roots of
quadratic equation (5n + 8)x2 – (7n – 20)x + 120 = 0
(n ∈ Z), then sum of all possible value(s) of n is

(A) –1
(B) 65
(C) 66
(D) 67
19) Number of solutions of equation in [–2π,2π] is equal to-

(A) 2
(B) 4
(C) 8
(D) none of these

20) Let the area of ΔABC is sq. units, b = 2, and c = . If ∠A is acute then the
measure of angle C is (where notations have usual meaning)

(A)

(B)

(C)

(D)

SECTION-II

1) Let , then the value of

2
(ƒ(25°) + ƒ(65°)) (1 + sin50°) is

2) The base of an isosceles triangle is the intercept made by the line x + 2y = 4 with the coordinate
axes. If the equations of equal sides be x = 4 and y = mx + c , then (8m + c) is equal to

3) The sum of abscissa and ordinate of the point on the curve xy = 8 which is closest to the point
(3,0) is equal to

4) The total number of local extrema of the function

f(x) = cos (πx + 3π) + sin (πx + 3π),

where 0 < x < 4 is equal to

5) Number of integers in the domain of is (where {.} denotes fractional part

function)
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C A C A A A C C C C D A C C A D D A C

SECTION-II

Q. 21 22 23 24 25
A. 4 5 3 2 6

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D A C C A B B D B D B C B D D A A C B D

SECTION-II

Q. 46 47 48 49 50
A. 5 5 8 2 3

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C C B B D C C A B C A D D C D A C C D D

SECTION-II

Q. 71 72 73 74 75
A. 4 8 6 2 3
 SOLUTIONS

PHYSICS

1)

vx = a
vy = b – ct
uy = b ux = a
ay = c

2)

Explain question : A force is applied at angle β on a duster against a board; we must find the
condition under which the duster doesn't slide, ignoring gravity.
Concept : This question is based on Friction prevents sliding; the force component
perpendicular to the board generates normal force.
Explanation :

Duster will not move

If fL ≥ F cos β
⇒ µsN = µsF sin β ≥ F cos β

tan β ≥
Final answer :- (3)

3)

Question Explanation:
This problem asks the velocity of A in the arrangement for given velocity of B.

Concept:
This question is based on constraint motion .
Solution:
The virtual work done by the tension in the system will be zero i.e.

suppose tension in string is T

3T⋅VA – 2TVB = 0

VA =

=
VA = 200 mm/s (Towards Right)

Final Answer: The correct option is (1)

4) Work done by gravity will depend only upon the height ‘h’ and not on the length of inclined
plane. So work done in both the vases = mgh only.
ratio = 1 : 1.

5)

Explain Question : We need to find the average angular velocity (in rad/s) for the entire
motion depicted in the graph.
Concept : This question is based on average angular velocity, kinematics.
Solution :

ωavg =
Angular displacement is represented by the area under the angular velocity-time graph.
Area under the graph = A1 + A2 + A3

= × 16 × 12 + (41 – 16) × 12 + (50 – 41) × 12

= 96 + 300 + 54
= 450 rad

ωavg = = 9 rad/s
Final answer : option 1

6)
 Velocity perpendicular to impact will not change

7) Explain question : Half ring and half disc arranged as shown. Find the Y-coordinate of the
system.
Concept : This question is based on calculation of center of mass.
Solution : The system is symmetrical about the Y axis.

Final answer : 1

8)

9)

10)

Explanation Question: Two blocks are connected with string passing over a pully out of
which one block is in air and other is in liquid. This system is in equilibrium.
Concept: This question is based on buoyant force
Solution:

Mg = mg + B

Mg = mg + p2 × g

M = m = 6 kg

Final Answer
The correct option is (3)

11)
12)

Work done to from a soap bubble

W = 8πR2T [As V ∝ R2 ∴ R ∝ V1/3]
∴ W ∝ V2/3

= (2)2/3 ⇒ W2 = (4)1/3 W

13) As the cork moves up, the force due to buoyancy remains constant. As its speed increases,
the retarding force due to viscosity increases, being proportional to the speed. Thus the
acceleration gradually decreases. The acceleration is variable, and hence the relation between
velocity and time is not linear.

14)

15)

No detorming force
Stress = zero
Strain = zero

16)
+

→ 725 calorie

17)

Req = R1 + R2 =
Req

18) Question Explanation:

The question asks for the correct order of most probable speed (Vmp), root mean square speed
(Vrms) and average speed (Vav) of molecules in an ideal gas.

Concept:
This question is based on most probable speed, root mean square speed, average speed.

Solution:

∴ Vrms > Vav > Vmp

Final Answer:
The correct option is (4)

19) PV3/2 = constant and PV = nRT

⇒ V1/2T = const.
⇒ V1/2T = const.

⇒ T1 = const.
⇒ T1 =

20)

Explanation Question: Particle moving along a straight line and we have to find its angular
momentum.
Concept: This question is based on conservation of angular momentum.
Solution:

Since the particle is moving with constant velocity, let it be at a distance y from the origin.
Then its angular momentum will be equal to mvy. Since it is moving parallel to x -axis,
therefore y remains constant and in turn the angular momentum (mvr) of the particle remains
constant.

Final Answer
 The correct option is (3)

21)

Question Explanation: The problem involves a system of two blocks A and B connected by
strings and pulleys. The vertical displacement of block A is described by a function of time y =
t2/4 and we need to find the acceleration of block B.

Concept: This question is based on constrained motion and differentiation .

Solution :

∵ Net work done by tension is zero

∴
(aA) (8T) – (aB) (T) = 0
aB = 8 a A

The downward acceleration of block B is aB = 4 m/s2

Final Answer : 4

22)

Explain Question : The problem describes a square frame work made of four uniform rods,
each of length l find mass m. It rotates in a vertical plane about a fixed horizontal axis passing
through point A. The frame work is lightly displaced from its unstable equilibrium we need to

find the value of x in the expression for the maximum angular velocity w = .
 Concept : Conservation of mechanic energy
Solution :

Final answer : Therefore the value of x is 5.

23) p1 = p2 – ...(1)

0
p2 = p – ...(3)

24)
vr = 2 m/s

25)
Now,

CHEMISTRY

26)

dx -y found on x and y axis to facial overlap they approach by z-axis

2 2

27) Balance the equation by any method

4Zn + 10HNO3 → 4Zn(NO3)2 + 3H2O + NH4NO3
∴a+b+c=4+3+1=8

28)

Structure (C) violates the stability rules most severely by placing a positive charge and an
incomplete octet on the highly electronegative Oxygen atom. Therefore, it is the least stable
(or unstable) resonating structure.

29)

Higher the value of n+l higher will be energy of orbital. If n+l are equal then higher the value
of n higher will be energy
I.
II.
III.
IV.
order is III < II < IV < I.

30)

Explaining the Question :-

End product of given reaction sequence.
Concept:-
This question is based on
(1) Hydrolysis of carbide
(2) Monohalogenation photochemical of alkene.
(3) Corey house synthesis
Solution :-
Hydrolysis of aluminium carbide gives methane.

(B) to (C) is corey house synthesis.

Final Answer :- (1)

31)

Explain the question: Asking about the boiling point order of 3 set of isomers of hexane.
Concept: This question is based on Boiling point of isomeric alkanes is inversely proportional
to branching.
Solution:
Boiling point of isomeric hydrocarbon decreases with increasing branching because more
branched molecules have a smaller surface area, leading to weaker intermolecular forces,
which require less energy to overcome during boiling.
• Hence correct order of boiling points for the isomers of hexane is: III > II > I.
Final Answer: 2

32)

Explaining the Question :-

Stability order of given carbocation.
Concept:-
This question is based on carbocation or intermediate stability
Solution :-
Carbocations are stabilized by electron.
donating groups
stability ∝ + M
∝+I
∝ delocalization of charge

Stability ∝

+M of –NH2 > –OH.

So stability order is III > II > I > IV
Final Answer :- (2)

33)

34) Question Explanation:

Select the correct statements.

Concept:
This question is based on IUPAC nomenclature.

Solution:

Du = 3

Final Answer:
The correct option is (2)

35) Explanation: Asking about the molecule that does not have plane of symmetry.
Concept: This question is based on plane of symmetry (POS).
Solution: Plane of symmetry (also called a mirror plane) is an imaginary plane that divides a
molecule or object into two halves so that they are mirror images of each other.
option (1), (2) and (3) have plane of symmetry.
option (4) does not have plane of symmetry.
(4)

Find answer: option (4).

36) Explain Question: Question is Asking about the pair of enantiomers.

Concept: This question is based on relationship in steroisomers.
Solution: Enantiomers are a pair of molecules that are non -superimposable mirror images of
each other
In enantiomers configuration of all chiral centers are opposite
option (1) Diastereomers (Not mirror image stereoisomers)
option (2) Enantiomers (non-superimposable mirror images)
option (3) Diastereomers (Not mirror image stereoisomers)
option (4) Diastereomers (Not mirror image stereoisomers)

option (2)
(Pair of Enantiomers)
Final answer: option 2

37)

Explanation Question: Question is asking about circumference ration for 3rd and 2nd orbits of
He+
Concept: This question is based on Bohr model.
Solution:
Circumference = 2πr

r = 0.529 ×
So, for same atom

⇒ 9:4
The correct option is (3)

38)

Question Explanation:
Question is asking about value of KP for the reaction.
Concept:
This question is based on KP.

Solution:
2AB(g) = 2A(g) + B2(g)
t=0 p 0 0

t=t P–x x

PTotal = P – x + x + = (P + )

Given P = 500 mm &

So PAB = P – x = 250 ; PA(g) = x = 250

PB2 = = 125

Final Answer: The correct option is (2).

39)

Q has lowest IE1 amongest all elements given in the table and therefore Q is a metal.

40) BOH + HCl → BCl + H2O

At eq. point volume of HCl req.

2.5 × = ×V
V = 7.5 ml
BOH + HCl → BCl + H2O
1 mmoles 1 mmoles 1 mmoles

× × Conc. = = 0.1
B⊕ + H2O ⇌ BOH + H⊕
0.1
0.1–0.1h 0.1h 0.1h

Kh =

∴ 10–2 =
⇒ 10–2 – 10–2 h = 10–1h2
On solving quadratic
h = 0.2701
⇒ [H⊕] = 2.7×10–2 M.

41)
Conceptual

42)

Conceptual

43) Explanation the Question : Find species with 4 BP and 1 LP.

Concept : This question is based on VSEPR & Steric Number

Final answer : Option (3)

44) Question Explanation:

Find maximum and minimum value of for given equilibrium.

Concept:
This question is based on relation between KP and KC.

Solution:
KP = KC(RT)Δng

∴ = (RT)Δn g

If Δng maximum then maximum

If Δng minimum then minimum

(a) N2O4 ⇌ 2NO2 Δng = 2 – 1 = 1
(b) 2SO2 + O2 ⇌ 2SO3 Δng = 2 – 2 – 1 = –1 (min.)
(c) X + Y ⇌ 4Z Δng = 4 – 1 – 1 = 2
(d) A + 3B ⇌ 7C Δng = 7 – 1 – 3 = 4 (max.)

Final Answer:
The correct option is (2).

45)
Explain question : Calculate ksp of M2X3
Concept : This question is based on The solubility of a sparingly soluble salt is determined by
its solubility products (Ksp) value
Solution :-

Solution :
At equilibrium;
Ksp = [M+3]2 [X–2]3 = (2s)2 (3s)3 = 108 S5
Final answer :- 4

46)

Elements in their standard or reference state have zero standard heat of formation.

47)

(A)
(+1)4 + x + (–1)6 = 0

(B)
(+1)3 + y + (–1)6 = 0

(C)
2z + 0 × 9 = 0

so (x + y + z) = +2 + 3 + 0 = 5

48)
⇒ n = 3 & unsymmetrical
⇒ Total stereoisomers = 2n = 23 = 8

49)

H2C = C = CH2

Sp (Two sp hybrid orbitals).

50) c, d, e are correct representation.

MATHEMATICS

51) x + y = eyℓnx

and given curve cuts x-axis at (1,0).

52)
Consider P(x) = ax5 + bx4 + 6x3
⇒ = 5 ax4 + 4bx3 + 18x2
Now = 0 ⇒ 5a – 4b = – 18
& = 0 ⇒ 5a + 4b = – 18
⇒ a = – 18/5, b = 0

Hence p(x) =
⇒ p'(x) = – 18x4 + 18x2 = 18(x2 – x4)
⇒ p''(x) = 18(2x – 4x3)
⇒ p''(x) = 36(x – 2x3)
⇒ p''(x) = 36x (1 – 2x2)
Also A = {x | x2 + 6 – 5x ≤ 0}
gives x ∈ [2, 3]
Clearly
So, y = (x) is decreasing fxn. in [2, 3]
∴M= Max.(x = 2) = 18 (4 – 16) = – 18 × 12

and m = min. (x = 3) = 18 (9 – 81) = – 18 × 72

Hence

53)

Two curves intersec orthogonally if

Now eliminating y from the given equations we have

Eliminating from (i) and (ii) we get

54) Let
∴ ƒ(p) = p2, ƒ(q) = q2, ƒ(r) = r2
consider an equation ƒ(x) = x2 ....(1)
equation has roots p,q,r
but equation (1) is quadratic equation and it has more than two roots so equation (1) is an
identity.
hence in order to solve ƒ(x) = x + 1 it is sufficient to solve

x2 = x + 1 ⇒ x2 – x – 1 = 0 ⇒

55)

Explanation of Question:
We have to find number of solution of given equation.

Concept: “This question is based on log equation”

If N = logab then
(i) N > 0 if a and b both side of '1'.
(ii) N < 0 if a and b opposite side of '1'.

Solution:

L.H.S. =
here x2 + 7 and 10 both are greater then '1'
⇒ L.H.S. gives positive value.

R.H.S. =

here x2 + 7 > 1 but

⇒ L.H.S. ≠ R.H.S.
∴ No solution
Number of solution = 0

Final Answer:
The correct option is (4)

56) m2 – n2 = 2010
m2 – n2 = 2 × 3 × 5 × 67
(m – n) (m + n) = 2 × 3 × 5 × 67
If m & n both odd then m – n, m + n both even
⇒ (m – n) × (m + n) ≠ even × even ≠ 2010
If m, n both even then m – n, m + n both even then (m + n), (m + n) = even × even ≠ 2010
If m,n one is odd & one is
even than (m + n) (m – n) = odd × odd ≠ 2010

57)
Non-differentiable at x = –1, 0, 1

58)
so
i.e. | x | = 3
so

59) Graph of max{ sin t : } in

& graph of 2 + cos x for

So graph of

f(x) is differentiable everywhere in

60) f"(x) = –f'(x) ....(i)

f'(x) = g(x) ....(ii)
h'(x) = (f(x))2 + (g(x))2 .....(iii)
Differentiating equation (iii) w.r.t.
h"(x) = 2f(x) . f'(x) + 2g(x), g'(x)
= 2f(x) . f'(x) – 2f'(x) . f(x) = 0
⇒ h'(x) is constant
 ⇒ h(x) is linear function

61)

ƒ(x) = x3 + x2 + 6x – 22
⇒ ƒ(2) = 2 ⇒ g(2) = 2

Now ƒ(g(x)) = x ⇒

⇒ ⇒ ƒ'(2).g'(2) = 1

62)

Given x + |ƒ(x)| = 2ƒ(x) ...(1)

If ƒ(x) ≥ 0, then (1) ⇒ ƒ(x) = x
⇒ ƒ–1(x) = x is x ≥ 0 ...(3)

if ƒ(x) < 0, then (1) ⇒

⇒ ƒ–1(x) = 3x is x < 0 ...(4)
∴ Now option (4) satisfies both (3), (4)

63) ∵ 'f' is odd ƒ–1 is also odd

f–1(x) + f–1(–x) = 0
⇒ sum = 0

64)

65) Explanation of Question: In this question we have given a variable line and we have to
find locus of foot of perpendicular form origin on this line.
Concept: “This question is based on point and line”
Solution: Given variable line is y = mx + c
where m - constant
c- variable
If the lines are perpendicular then m1m2 = –1

(m) =
⇒ h + km = 0 for hour h→x
k→y
So, required locus is x + my = 0
Final Answer: The correct option is (4)

66)
The required bisector of the angle in which origin does not lie.

67)

( ∵ a2 = b2 + c2)

68)

∴ ...(1)

...(2)
∴ C = 90°
⇒ A + B = 90°
⇒ B = 90° – A
⇒ sinB = cosA

(1) ⇒
⇒ n2 – 65n – 66 = 0 ⇒ (n – 66) (n + 1) = 0
⇒ n = 66 or –1.
but n ≠ –1 by equation (1) otherwise sinA + cosA is negative
∴ n = 66

69)

Given equation is tan(3x – 2x) = 1

⇒ tanx = 1 ⇒
but at this value tan2x is underfined, hence there is no solution.

70)

B – C = 120°
B + C = 150°

∴C=

71)

72)

Slope of
So, line AB will be
(y –2) =

73)

∴ Equation of normal at (x1, y1) is ,

As (3, 0) lies on it, so (x1 = 4, y1 = 2).

74)

f '(x) = (2 – x) sin (πx)

∴ Local maximum at x = 1 and local minimum at x = 3.

75) {x2} – x2 + 3 > 0

⇒ –[x2] + 3 > 0
⇒ [x2] < 3 ⇒ [x2] = 0,1,2
⇒ x2 ∈ [0,3)

⇒
⇒ x = –1,0,1