12-10-2025

0999DJA161151250001 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A light spring of spring constant k is kept compressed between two blocks of masses m and M on
a smooth horizontal surface (figure). When released, the blocks acquire velocities in opposite
directions. The spring loses contact with the blocks when it acquires natural length. If the spring
was initially compressed through a distance x, find the final speed of the M block.

(A)

(B)

(C)

(D)

2) Figure shows a wedge on which a small block is released from rest at A. All the surfaces are
smooth. System comprises of wedge and blocks. Mark the correct statement(s) for interval starting
from releasing the block at A till block attains maximum height on wedge on other side for the first

time

When block attains maximum height, it is below C & both block and wedge are moving towards
(A)
right.
(B) Initially centre of mass of system (block + wedge) moves down and then up.
(C) Centre of mass of wedge moves towards left then right.
When block moves from A to B, acceleration of centre of mass of system (block + wedge) moves
(D)
right.

3) Which of the following is true in an inelastic collision (in the absence of any external force)?

Momentum Kinetic energy Total energy

(1) conserved conserved conserved
(2) conserved not conserved conserved
 (3) conserved conserved not conserved
(4) not conserved not conserved conserved
(A) 1
(B) 2
(C) 3
(D) 4

4) A particle is acted upon by a force for 1 sec whose X component remains constant at Fx = 30 N
but Y and Z components vary with time as shown. The magnitude of change in momentum of the

particle in 1 sec will be :-

(A)
(B)
(C)
(D) 150

SECTION-I (ii)

Common Content for Question No. 1 to 2

Collision may be defined as the impact of one moving body on another body moving or stationary.
Linear momentum is conserved in all type of collision. In elastic collision kinetic energy after
collision is equal to kinetic energy before collision. A nucleus V of mass 2m moving with velocity u
collides inelastically with a stationary nucleus W of mass 10m. After collision the nucleus V travels at
90° with the incident direction while W proceeds at an angle 37° with the incident direction. Answer
the following questions based upon above information.

1) What fraction of the initial kinetic energy is lost in the collision process ?

(A)

(B)

(C)

(D)

2) The speed of V after the collision is-

(A)
(B)

(C)

(D)

Common Content for Question No. 3 to 4

A shell is fired vertically upward with a speed of 60 m/s. When it is at maximum height, it explodes
into large number of fragments. Assume that the fragments fly in every possible direction and all of
them have same initial speed of 25 m/s.

3) The speed of the center of mass of the system after 1 sec of explosion will be :-

(A) 25 m/s
(B)
(C) 10 m/s
(D) Zero

4) The minimum time taken by any one fragment to reach at ground will be :-

(A) 4 sec
(B) 6 sec
(C) 2 sec
(D) 11 sec

SECTION-I (iii)

1) A particle of mass m, kinetic energy K and momentum p collides head on elastically with another
particle of mass 2 m at rest. After collision :

List-I List-II

(P) Momentum of first particle (1) 3/4 p

(Q) Momentum of second particle (2) – p/3

(R) Kinetic energy of first particle (3)

(S) Kinetic energy of second particle (4) None

(A) P → 2;Q → 4;R → 4;S → 3
(B) P → 4;Q → 2;R → 4;S → 3
(C) P → 1;Q → 4;R → 4;S → 3
(D) P → 2;Q → 4;R → 3;S → 1

2) A particle of mass 1kg has velocity and another particle of mass 2 kg has velocity
. Initially particle is at origin.
 List-I List-II

(P) Net force on centre of mass at 2s. (1)

units

(Q) Velocity of centre of mass at 2s. (2) units

(R) Displacement of centre of mass in 2s. (3)

units

(S) x coordinate of centre of mass in 2s. (4)

units
(A) P → 3;Q → 1;R → 3;S → 4
(B) P → 4;Q → 3;R → 3;S → 1
(C) P → 3;Q → 1;R → 4;S → 3
(D) P → 2;Q → 3;R → 1;S → 4

SECTION-II

1) Velocity of a particle of mass 2 kg varies with time t according to the equation .

Here t is in seconds. Find the magnitude of impulse (in N-s) imparted to the particle in the time
interval from t = 0 to t = 2 s.

2) A block of wood of mass 9.8 kg is suspended by a long string. A bullet of mass 200 gm strikes
horizontally with a velocity of 100ms–1 and gets embedded in it. The maximum height (in m) attained
by the block is: (g = 10 ms–2)

3) Four balls A, B, C and D are placed on a smooth horizontal surface. Ball B collides with ball C with
an initial velocity u as shown in figure. If all collisions are elastic, find the total number of collisions

between the balls.

4) A body of mass 2 kg is moving with a speed of 4 m/s. makes an elastic collision with another body
at rest and continues to move in the original direction but with one fourth of its initial speed. The
speed of the centre of mass to two body is x/10 m/s. Then the value of x is :-

5) Two point mass 36 g and 72 g are located at coordinates (2 cm, 0) and (5 cm, 0). The x-coordinate
(in cm) of centre of mass will be at :

6) Two blocks of mass 3 kg and 6 kg respectively are placed on a smooth horizontal surface. They
are connected by a light spring of force constant k = 50 N/m. Initially the spring is unstretched and
the indicated velocities are imparted to the blocks. Find maximum extension of the spring in cm.
 SECTION-IV

1) On the left are statements about the location of the center of mass of the objects depicted on the
right. The objects on the right are symbols constructed out of sticks of equal length and mass. The
location of the center of mass is described using the coordinate system depicted in the sample.

The centre of mass lies at x = 0, y = 0

Column-I Column-II

(A) The center of mass is at x > 0 and y = 0 (P)

(B) The center of mass is at x = 0 and y > 0 (Q)

(C) The center of mass is at x > 0 and y > 0 (R)

(D) The center of mass is at x = 0 and y = 0 (S)

(T)

2) A particle of mass m is projected with velocity v and at an angle θ with horizontal then match the
following columns.
 Column-I Column-II

Change in momentum between point of

(A) projection and point at which it strikes (P) mv cosθ
on horizontal surface

(B) Radius of curvature at highest point (Q) 2mv sinθ

(C) Minimum momentum is (R) mv sinθ

Magnitude of change in momentum

(D) between point of projection and highest (S)
point

(T) None

PART-2 : CHEMISTRY

SECTION-I (i)

1) Identify the non-feasible reaction

(A)
CH3–C ≡ CH + NH2– ⇌
(B) CH3CH2–OH + NaH ⇌ CH3CH2ONa + H2
(C) CH3–OH + NaOH ⇌ CH3ONa + H2O
(D) HC ≡ CH + NaOH ⇌ HC ≡ CNa + H2O

2)
Correct order of basic strength of this compound is

(A) d > b > c > a

(B) c > b > a > d
(C) c > a > b > d
(D) a > d > c > b

3) Correct order of stability :

(A)

(B)
(C)

(D)

4) Select the strongest acid in each of the following sets:

(i)

(ii)

(iii)

(iv)

(A) (i) → b ; (ii) → a ; (iii) → b ; (iv) → b

(B) (i) → a ; (ii) → b ; (iii) → c ; (iv) → b
(C) (i) → c ; (ii) → c ; (iii) → a ; (iv) → a
(D) (i) → d ; (ii) → d ; (iii) → c ; (iv) → d
 SECTION-I (ii)

Common Content for Question No. 1 to 2

Bond length is defined as the internuclear distance between the two atoms. When bond order is
greater, then the bond length is lesser. When double bond character increase, then bond length
decreases and vice versa.

1) Which of the following is correct about the bond length -

(A)

(a > b)
2– –
(B) CO 3 > HCOO (for C–O)

(C)

(a > b)

(D)

(a > b)

2) Incorrect order of the (C–N) bond lengths for the given compound is -

(A) a > b > c > d

(B) d > a > b > c
(C) c > b > a > d
(D) b > c > a > d

Common Content for Question No. 3 to 4

For the given compounds

(I) (II) (III) (IV) (V)

(VI) (VII) (VIII) (IX) (X)

3) Which compound(s) is/are soluble in aqueous NaOH :

(A)

(B)

(C)

(D)

4) Correct order of basic strength is :

(A) IX > VI > VIII > VII

(B) VII > VIII > VI > IX
(C) VIII > VI > VII > IX
(D) VII > IX > VIII > VI

SECTION-I (iii)

1)
 List-I List-II
(Group) (Effect)

(P) –NO (1) +M

(Q) –NO2 (2) –M

(R) (3) +I

(S) –NH2 (4) –I

(A) P → 1,2,4;Q → 2,4;R → 4;S → 1,4
(B) P → 2,3,4;Q → 2,4;R → 4;S → 1,4
(C) P → 1,2,4;Q → 2,3,4;R → 4;S → 1,4
(D) P → 2,4;Q → 2,4;R → 4;S → 1,4

2)

List- I List- II

(P) (1) Aromatic compound

(Q) (2) Acidic hydrogen is present

(R) (3) Cyclic ester (lactone)

(S) (4) Bicyclo compound

The correct option is -

(A) P → 1, 2;Q → 4;R → 2, 3;S → 4
(B) P → 1, 2;Q → 4;R → 2, 3;S → 3
(C) P → 1, 2, 3;Q → 4;R → 2, 3;S → 4
(D) P → 1, 2, 3;Q → 2, 4;R → 2, 3;S → 4

SECTION-II

1) In how many compound lone pair of nitrogen is involved in resonance ?

(1) (2) (3) (4)

(5) (6) (7)

2) How many of the given groups shows e– donating nature in resonance and e– with drawing
inductively when attached to benzene.

(a) –NH2 (b) –OH (c) –OCH3 (d)

(e) –OΘ (f) (g) (h)

(i) –CN (j) –CHO (k) –COCl (ℓ) –F

(m) –NO2 (n) (o)

3) If Number of Aromatic compounds are X.

Number of Non Aromatic compounds are Y.
and number of Anti aromatic compounds are Z.
Then value of (X + 2Y – Z) is :

(a) (b) (c) (d)

(e) (f) (g) (h)

4) Find number of compound which are soluble in NaOH as well as NaHCO3?

(i) (ii) (iii) (iv)

(v) CH3OH (vi) (vii) (viii) CH3 – C ≡ CH

5) How many properties given are correct :

(1) Bond length : b > a

(2) Rotational energy barrier : a > b

(3) C–H bond energy : b > c > a

(4) Acidic strength : 2 > 1

(5) Stability : B > A

(6) Stability 2 > 1 > 3

6) Total number of pairs of resonating structure in which second is more stable than first

(A)

(B)

(C)
(D)

(E)

(F)

SECTION-IV

1)

Match Column-I with Column-II.

Column-I (Facts) Column-II (Reasons)

Resonance stabilisation of conjugate acid of

(A) (P)
Guanidine is strong base.
example of strong base

(B) Carbanion stability (Q) Due to s-character of central atoms

(C) Alkyne is more acidic than alkene (R) Due to d-orbital resonance

(D) (S) Due to formation of aromatic anion

Acidity : <

Stability of conjugate acid / base due to

(T)
more number of identical resonating structure

2) Match Column-I with Column-II.

Column-I (Compounds) Column-II (pKa)

(A) (P) 7.15

(B) (Q) 10.14

(C) (R) 9.98

(D) (S) 9.38

(T ) pKa is more than phenol

PART-3 : MATHEMATICS
 SECTION-I (i)

1) If variable line L is passing through a point M(2,3) and intersecting the circle x2 + y2 – 7x – 7y +
22 = 0 at A1, A2, A3, ........, An, ........... then all lines perpendicular to L through A1, A2, A3, ........, An,
....... passes through a fixed point N(x0, y0). The value of (x0 + y0) is equal to

(A) 5
(B) 7
(C) 9
(D) 11

2) Given A and B are fixed points such that AB = a and point P moves on the plane in such a way that

where m ∈ (0,1). If the locus of 'P' is a curve 'C' then maximum distance between any two
points of curve 'C' is -

(A)

(B)

(C)

(D) None of these

3) If a circle of radius R passes through the origin O and intersects the coordinate axes at A and B,
then the locus of the foot of perpendicular from O on AB is :

(A) (x2 + y2)2 = 4Rx2y2

(B) (x2 + y2)(x + y) = R2xy
(C) (x2 + y2)3 = 4R2x2y2
(D) (x2 + y2)2 = 4R2x2y2

4) If the tangents drawn at the point O(0, 0) and on the circle x2 + y2 – 2x – 4y = 0

intersect at the point Q, then the area of the triangle OPQ is equal to

(A)

(B)

(C)

(D)

SECTION-I (ii)
Common Content for Question No. 1 to 2

Consider a circle x2 + y2 = 25 and a point . If tangents drawn from P to the circle

touches at A and B then :

1) If angle bisectors of the angles subtended by the chord AB in the same segment always passes
through the point (a, b) then which can be true ?

(A) a + b = –1
(B) a – b = 7
(C) a – b = –7
(D) a + 2b = 5

2) If angle made by chord AB on the major segment of circle is θ, then

(A)

(B)

(C)

(D)

Common Content for Question No. 3 to 4

Let M = {(x, y) ∈ × : x2 + y2 ≤ r2}, where r > 0. Consider the geometric
progression n = 1, 2, 3, ... . Let S0 = 0 and for n ≥ 1, let Sn denote the sum of the first n terms of
this progression. for n ≥ 1, let Cn denote the circle with centre (Sn–1, 0) and radius an and Dn denote
the circle with center (Sn–1, Sn–1) and radius an.

3) Consider M with . The number of all those circles Dn that are inside M is

(A) 198
(B) 199
(C) 200
(D) 201

4) Consider M with . Let k be the number of all those circles Cn that are inside M. Let ℓ be
the maximum possible number of circles among these k circles such that no two circles intersect.
Then

(A) k + 2ℓ = 22
(B) 2k + ℓ = 26
(C) 2k + 3ℓ = 34
(D) 3k + 2ℓ = 40
 SECTION-I (iii)

1) The circle x2 + y2 = 4 and circle x2 + y2 – 2x – 2y + 1 = 0 intersect at A and B, then match List-I

with List-II and select the correct answer using the code given below the list.

List-I List-II

If ax + 2by = 5 is common chord of given circles then

(P) (1)
the value of is

If θ is acute angle between given circles then the value of

(Q) (2)
cosθ is

(R) Length of common tangent is (3) 1

Diameter of smallest circle which is passing through A &

(S) (4)
B
(A) P → 2;Q → 4;R → 3;S → 1
(B) P → 4;Q → 2;R → 3;S → 1
(C) P → 4;Q → 1;R → 3;S → 2
(D) P → 1;Q → 2;R → 3;S → 4

2) For the circles x2 + y2 = 4 and x2 + y2 – 16x – 16y + 127 = 0.

List-I List-II

(P) Length of direct common tangent is less than (1)

(Q) Length of transverse common tangent is (2)

(R) Point of intersection of direct common tangents is (3) (16, 16)

(S) Point of intersection of transverse common tangent is (4)

(A) P → 2;Q → 3;R → 4;S → 1

(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 4;Q → 1;R → 2;S → 3

SECTION-II

1) Diameter of the circle which passes through the point (–1, 2) and touches the circle x2 + y2 – 8x +
6y = 0 at origin, will be :

2) If a = max{(x + 2)2 + (y – 3)2} and b = min{(x + 2)2 + (y – 3)2} where x, y satisfying x2 + y2 + 8x –

10y – 40 = 0, then value of is

3) If ax + by = 10 is chord of minimum length of circle (x – 10)2 + (y – 20)2 = 729 & chord passes
through (5, 15) then value of ab is equal to (Here a,b ∈ R)

4) If A is the area formed by the positive x-axis, the normal and tangent to the circle x2 + y2 = 4 at

then A is :

5) Let P be a point on the circle C1 : and Q be a point on the curve C2 : x + y = 4. Both P

and Q lie in the first quadrant. If 'd' denotes the minimum distance between P and Q then value of 'd'
is equal to

6) The line x + y + 3 = 0 intersects the circle x2 + y2 – 4x – 3y – 27 = 0 at A and B. If locus of a point

C such that AC is perpendicular to BC is x2 + y2 + 2gx + 2ƒy + c = 0, then the value of is

SECTION-IV

1) Match Column-I with Column-II and select the correct answer.

Column-I Column-II

Circle passing through distinct points

(A) (t2, 1), (1, t), (2, 2t + 1) ∀ t ∈ R (P) 1
passes through a fixed point (a, b), then a + b is

Tangent AB, AC are drawn from A to

x2 + y2 – 2x + 4y + 1 = 0 meeting circle at B and C.
(B) (Q) 3
If equation of circumcircle of ΔABC is
x2 + y2 – x + y – 2 = 0 such that A is (a, b), then a + b is

(C) (R) 5
The value of is

Radius of a circle which is orthogonal to line pair

(D) xy – 3x + 2y – 6 = 0 and touches the line (S) 2
x – 2y + 3 = 0 is r then r2 is

(T) 7

2)

Column-I Column-II

If point of intersection and number of common tangents of two circles

(A) x2 + y2 – 2x – 6y + 9 = 0 and x2 + y2 + 6x – 2y + 1 = 0 (P) µ–λ=3
are λ and µ respectively, then

If point of intersection and number of tangents of two circles

(B) x2 + y2 – 6x = 0 and x2 + y2 + 2x = 0 (Q) µ+λ=5
are λ and µ respectively, then
 If the straight line y = mx ∀ m ∈ I touches or lies outside the circle
(C) x2 + y2 – 20y + 90 = 0 and the maximum and minimum values of (R) µ–λ=4
|m| are µ & λ respectively then

If two circle x2 + y2 + px + py – 7 = 0 and

(D) x2 + y2 – 10x + 2py + 1 = 0 (S) µ+λ=4
cut orthogonally and the value of p are λ & µ respectively then

(T) µ+λ=8
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A B B C

SECTION-I (ii)

Q. 5 6 7 8
A. B A C A

SECTION-I (iii)

Q. 9 10
A. A D

SECTION-II

Q. 11 12 13 14 15 16
A. 8.00 0.20 3.00 25.00 4.00 60.00

SECTION-IV

Q. 17 18
A. A->P,B->S,C->QR,D->T A->Q,B->S,C->P,D->R

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22
A. D B D A

SECTION-I (ii)

Q. 23 24 25 26
A. B,C,D A,B,D A,B,C,D C

SECTION-I (iii)

Q. 27 28
A. A A

SECTION-II

Q. 29 30 31 32 33 34
A. 4.00 6.00 7.00 4.00 5.00 4.00
 SECTION-IV

Q. 35 36
A. A->PT,B->R,C->Q,D->ST A->R,B->S,C->P,D->QT

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40
A. C B C C

SECTION-I (ii)

Q. 41 42 43 44
A. A,B,C,D A,B B D

SECTION-I (iii)

Q. 45 46
A. B B

SECTION-II

Q. 47 48 49 50 51 52
A. 2.50 1.41 0.25 3.46 1.41 0.25

SECTION-IV

Q. 53 54
A. A->Q,B->P,C->S,D->R A->RS,B->S,C->P,D->Q
 SOLUTIONS

PART-1 : PHYSICS

1) Consider the two blocks plus the spring to be the system. No external force acts on this
system in horizontal direction. Hence, the linear momentum will remain constant. As the
spring is light, it has no linear momentum. Suppose the block of mass M moves with a speed V
and the other block with a speed V after losing contact with the spring. As the blocks are
released from rest, the initial momentum is zero. The final momentum is MV – mv towards
right. Thus,

MV – mv = 0 or, V = ........ (i)

Initially, the energy of the system =

Finally, the energy of the system =

As there is no friction,

.......(ii)
Using (i) and (ii),

or, and

2) There is no external force on system in x-direction. Just after leaving block at A, COM is
coming downward and at B, COM has no velocity in x and y direction.

3) Question Explanation: The question asks about the characteristics of an inelastic collision
in the absences of external forces.

Concept: This question is based on inelastic collision.

Solution: In an inelastic collision (when net external force is zero) momentum and total
energy is conserved but kinetic energy is not conserved.

Final Answer: Option (2)

4) Change in momentum = Impulse =

∴ Change in momentum in x-direction
= Fx × t
ΔPx = 30 × 1
For the change in momentum in
z and y-direction = Area of F-t curve with time axis

∴ ΔPy =
and ΔPz = × 1 × 40 = 20
∴
=
=
=

5) Applying momentum conservation in x & y directions

2mu = 10 mv2 cos37°;

0 = 2mv1 – 10mv2sin 37°

⇒
Energy lost in collision

Fractional loss in

KE =

6) Applying momentum conservation in x & y directions

2mu = 10 mv2 cos37°;

0 = 2mv1 – 10mv2sin 37°

⇒
Energy lost in collision

Fractional loss in

KE =
7) Maximum height =
At the time of explosion velocity of centre of mass will be zero.
So the speed after 1 sec equals to 10 m/s down wards.
for minimum time : Any one fragment which has initial velocity 25 m/s downwards will take
minimum time to reach at ground, so

∴ –180 = –25t –
t = 4 sec

8) Maximum height =
At the time of explosion velocity of centre of mass will be zero.
So the speed after 1 sec equals to 10 m/s down wards.
for minimum time : Any one fragment which has initial velocity 25 m/s downwards will take
minimum time to reach at ground, so

∴ –180 = –25t –
t = 4 sec

9)
By COLM
V = V1 + 2V2 …..(i)

e=1= …..(ii)

and V1 = –V/3

10)

At t = 2 sec
 In x-direction

Displacement =

11)
impulse =
=

12)
Just Before collision
Using conservation of Linear momentum
0.2 × 100 + 0 = 10 v ⇒ v = 2 m/s

maximum height attained =

13)

I collision : between B and C.

II collision : between C and D.
(After that vC = 0)
III collision : between B and A.

(After that vB = 0)

14) pi = pf
2 × 4 = 2 × 1 + m2 × v2
m2v2 = 6 ....(i)
by coefficient of restitution
by (i)
m2 × 5 = 6
m2 = 1.2 kg

x = 25

15) Co-ordinates of com

16) Apply momentum conservation and energy conservation.

17)

Concept : Center of mass shift towards higher mass.

18) (I)

(P-2)

(II) At highest point :

vp = vcosθ & a = g

(Q-4)
(III) At highest point velocity of particle becomes minimum, hence momentum becomes
minimum
Thus, at highest point : vp = vcosθ
P = mv
Pmin = mvcosθ (R-3)
 (IV)

= mvcosθ – (mvcosθ + mvsinθ )

ΔP = –mvsinθ
|ΔP| = mvsinθ (S-3)

PART-2 : CHEMISTRY

19)
products formed are strong. So, reaction is not feasible.

20)

The correct answer option is (B)

21) on the basis of resonance and hyperconjugation

22) Question Explanation:

(i) to (iv) four sets are given and we have to select strongest acid in each set.

Concept:
This question is based on effect of I.E., M.E. and hyper conjugation on acidic strength.

Solution:

(i)

⇒ Acidic strength ∝
⇒ Most acidic = (b)
⇒ Power :– M > H > I
(ii)

⇒ Acidic strength ∝
⇒ Most acidic = (a)
⇒ –I order –NO2 > – F

(iii)

⇒ Acidic strength ∝
⇒ Most acidic = (b)

(iv)

⇒ Acidic strength ∝
⇒ Most acidic = (b)
⇒ Power :– More -M groups, more -M effect

Final Answer:
The correct option is (1).

23)

The correct answer option is (B), (C), (D)

24) In the compound

In (c) minimum double bond character due to (SIR)
In (b) Double bond character due to resonance
In (a) Pure double bond
In (d) Pure triple bond
Bond Length = c > b > a > d

25) Compound which is more acidic then H2O is soluble in aq. NaOH.

26) Basic strength of the given aniline & its derivatives

27)

(P) is +M, –M, –I

(Q) is –M, –I
(R) is –I
(S) is +M, –I

28)

(P) is Aromatic compound, Acidic hydrogen is present

(Q) is Bicyclo compound
(R) is Acidic hydrogen is present ,Cyclic ester (lactone)
(S) is Bicyclo compound

29)

(1, 2, 5, 7)

30) The group which show +M and –I are –

(a) –NH2 (b) –OH (c) –OCH3

(d) (ℓ) –F (o)

 31)

Aromatic ⇒ a, c, d ⇒ x = 3
Non-aromatic ⇒ b, e, g ⇒ y = 3
Anti-aromatic ⇒ f, h ⇒ z=2
∴ x + 2y – z = 3 + 2 × 3 – 2
=9–2
=7

32)

(iii), (iv), (vi), (vii)

33)

1, 2, 3, 5, 6

34) A, C, D, E

35)

(A) is Resonance stabilisation of conjugate acid of strong base. Stability of conjugate acid due
to more number of identical resonating structure
(B) is Due to d-orbital resonance
(C) is Due to s-character of central atoms
(D) is Due to formation of aromatic anion, Stability of conjugate base due to more number of
identical resonating structure

36)

(A) is 9.98
(B) is 9.38
(C) is 7.15
(D) is 10.14, pKa is more than phenol

PART-3 : MATHEMATICS

37) The point M(2,3) lies on circle x2 + y2 – 7x – 7y + 22 = 0. So, every line L passing through
other end of the diameter M(2,3) whose coordinates are N(5,4). So, (x0 + y0) = 5 + 4 = 9

38) Take A = (0, 0), B = (a, 0) & P = (x, y)

∵ PA2 = m2.PB2
⇒ x2 + y2 = m2[(x – a)2 + y2]
⇒ x2(1 – m2) + y2(1 – m2) + 2am2x – a2m2 = 0
which is a circle of radius =

∴ required maximum distance = diameter

39) Slope of AB =
Equation of AB is hx + ky = h + k2
2

,B
AB = 2R
⇒ (h2 + k2)3 = 4R2h2k2
⇒ (x2 + y2)3 = 4R2x2y2

40)

Tangent at O
–(x + 0) –2 (y + 0) = 0
⇒
Tangent at P
x(1 + ) + y.2 – (x + 1 + ) – 2 (y + 2 = 0)
Put x = –2y
–2y(1 + ) + 2y + 2y – 1 – – 2y – 4 = 0

–2 y=5+ ⇒y

Length of tangent OQ =

Area =
=

41)
⇒ P lies on circle which also on
perpendicular bisector of AB
⇒ Perpendicular bisector of AB is
4x + 3y = 0
Hence point be intersection point of circle and line
⇒ (3, –4) & (–3, 4)

42)
Equation of AB : T = O

⇒
⇒ 3x – 4y = 24

OD = , OB = 5

⇒ ⇒

43)
∴ nmax = 199

44)

n = 1, 2, 3, ... 10

∴ k = 10

45) (P) common chord is S1 – S2 = 0

⇒ 2x + 2y – 5 = 0
⇒ 2x + 2y = 5
∴ a = 2, b = 1

(Q) ,
d is distance between centres

(R) These circles have two direct common

tangents

(S)
Equation of AB is 2x + 2y – 5 = 0
AB is diameter of smallest circle
⇒ diameter = length of AB

46) Let A and B be centres of circles and P and Q be intersection

of direct and transverse common tangent.

Now, (internally)
∴

(Externally)

∴ P(16,16)
Let d = distance between centres

length of direct common tangent

Length of transverse tangent

47) Tangent at origin on circle will be 4x – 3y = 0

∴ required circle is x2 + y2 + λ (4x – 3y) = 0
(–1, 2 ) is on it
∴ 1 + 4 + λ (–4 –6) = 0

⇒λ=

∴ Circle is : x2 + y2 + (4x – 3y) = 0

Radius =

∴ diameter =

48) Given circle is : (x + 4)2 + (y – 5)2 = 92

point (–2, 3) lies inside the circle.
∴ a1/2 = max distance of (–2, 3) from given circle

a = 89 +
b1/2 = min distance of (–2, 3) from given circle

49) AAFor chord of minimum length, (5, 15) must be the mid point of chord & equation of
chord will be
T = S1

50)

Equation of tangent
Q ≡ (4, 0)

51)

C1 : ; C2 : x + y = 4

Let P is (x1, y1) at P

⇒ x12 = 2 – x12
⇒ x1 = 1, y1 = 1 (first quadrant)
∴ from (1, 1) min. distance

52) Circle through A & B

x2 + y2 + (λ – 4)x + (λ – 3)y + 3λ – 27 = 0

Centre lies on x + y + 3 = 0

53)
Let A(t2, 1), B(1, t), C(2, 2t+1)

(A) , mBC = t + 1
 ⇒ AB ⊥ BC
Equation is
(x – t2)(x – 2) + (y – 1)(y – 2t – 1) = 0
⇒ Clearly x = 2, y = 1 ∀ t ∈ R
a+b=3
(B) S1 : x2 + y2 – 2x + 4y + 1 = 0
S2 : x2 + y2 – x + y – 2 = 0
BC : Radical axis x – 3y – 3 = 0 ...(1)
⇒ Equation of BC is
T=0
ax + by – (x + a) + 2(y + b) + 1 = 0,
(a – 1)x + (b + 2)y – a + 2b + 1 = 0 ...(2)
(1) and (2) are identical

⇒
⇒ a = 0, b = 1

(C)
(D) xy – 3x + 2y – 6 = 0 are diameters
(x + 2)(y – 3) = 0
Center is (–2, 3)
radius = 5

54) (A) S1 ≡ x2 + y2 – 2x – 6y + 9 = 0 c1 ≡ (1, 3) r1 = 1

S2 ≡ x2 + y2 + 6x – 2y + 1 = 0 c2 ≡ (–3, 1) r2 = 3
c1 c2 = r1 + r2 = 4
c1 c2 > r1 + r2
λ=0 μ=4
Option (r) & (s) are correct match. (B) S1 ≡ x2 + y2 – 6x = 0 c1 ≡ (3, 0) r1 = 3
S2 ≡ x2 + y2 + 2x = 0 c2 ≡ (–1, 0) r2 = 1
c1 c2 = 4 r1 + r2 = 4
c1 c2 = r1 + r2
μ=3 λ=1
Option (s) is correct match. (C) L ≡ y = mx ∀ m ∈ I
S1 ≡ x2 + y2 – 20y + 90 = 0 c1 ≡ (0, 10)

⇒
⇒
1 + m2 ≤ 10
m2 ≤ 9 ⇒ m = ± 3
|m| ∈ [0, 3]
μ=3 λ=0
Option (p) is correct match.
(D) S1 ≡ x2 + y2 + px + py – 7 = 0
S2 ≡ x2 + y2 – 10x + 2py + 1 = 0 c2 = (5, –p)
condition of orthogonality
2g1g2 + 2f1f2 = c1 + c2

p2 – 5p = –6; p2 – 5p + 6 = 0
⇒ (p – 3) (p – 2) = 0
option (q) is correct match.