18-01-2026

4001CJA101001250041 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A block of mass m is performing SHM with an amplitude A, on a frictionless surface. When it is at

negative extreme position as shown, a bullet of mass m moving with a velocity v0 collides and gets
embedded into it at time t = 0. The displacement x at any time t will be (mv02 = 2kA2) :

(A)

(B)

(C)

(D)

2) n moles of gas kept in a large tube of length L and cross-sectional area A. The tube is placed in a
horizontal plane. If temperature of tube varies linearly from T1 to T2 (T2 > T1). Then find the pressure

of gas in tube.

(A)

(B)

(C)

(D)

3) A monoatomic ideal gas undergoes a process consists of concentric semi-circles on PV graph,

starting from A(P0, V0) and ending at B(P0, 2V0). The point B is the common centre of the PV semi
circles. Let rn be the magnitude of radius of nth circle. It is given that rn = 2/3 rn–1, n ∈ N. Find the
magnitude of heat gained (or rejected) by the system in undergoing whole process from A to B.

Process is isobaric from (n – 1)th to nth circle.

(A)

(B)

(C)

(D)

4) A uniform rod of mass m and length ℓ remains in equilibrium inside a fixed smooth hemisphere of
radius R. When the rod is slightly displaced and released (neglect the air resistance). The time

period of oscillation for ℓ = R is

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) A model of a CO2 molecule is made of two spheres, each of mass m1, representing oxygen atoms
and a sphere of mass m2, in between, representing the carbon atom. The spheres are interconnected
by springs of force constant k. Such a system can vibrate freely in two ways shown by arrows.

(A)
In case-1, the angular frequency of SHM is
(B) In case-1, the carbon atom always remains at rest.
In case-2, the angular frequency of SHM of carbon is
(C)

(D) In case-2, the phase of oscillation of both oxygen atoms is same.

2) A model for the potential energy of a diatomic molecule is the Morse potential energy

where B, a, and r0 are parameters used to adjust the shape of the potential energy graph and its
depth. Mark the CORRECT statement(s) :

(A) The equilibrium separation of the nuclei is r0

The depth of the potential well, defined as the difference in energy between the potential
(B)
energy's minimum value and its asymptote as r approaches infinity is 'B'
The vibrational period of the diatomic molecule (reduced mass µ) in its ground state is

(C)
, (Assume the potential energy graph is nearly parabolic about the well bottom, use
approximation ex = 1 + x)
The amount of energy needs to be supplied to the ground-state molecule to separate the two
(D)
nuclei to infinity is 'B'.

3) Block m is released from rest when spring is in its natural length (assume pulley is ideal and block

does not strike on ground during it's motion in vertical plane) then :

(A) maximum elongation in spring is 4 mg/k

(B) maximum elongation in spring is 2 mg/k

(C)
maximum speed of block is
(D)
maximum speed of block is

4) Consider an ideal helium gas at a pressure P0 and volume V0 placed in a vertical cylinderical
container as shown in figure. A movable fractionless horizontal piston of mass ‘m’ and cross-section
A compresses the gas leaving the upper section of the container void. There is a vertical spring
attached to the piston and upper wall of the container. Disregard any gas leakage through their
surface contact, and neglect the specific thermal capacities of the container, piston and spring.
Initially the system is in equilibrium and the spring is unstretched. Neglect spring’s mass.

Let the spring constant . All the processes in gas are adiabatic.
Acceleration due to gravity is g. For monoatomic gas (helium). Use replace constant r = 5/3.

The frequency ‘f’ of small oscillation of the piston, when it is slightly displaced from equilibrium
(A)
position is
The frequency ‘f’ of small oscillation of the piston, when it is slightly displaced from equilibrium
(B)
position is

If the piston is pushed down until the gas volume is and released with zero velocity then
(C)

velocity of piston when spring becomes unstreatched first time after release is

If the piston is pushed down until the gas volume is and released with zero velocity of piston
(D)

when spring becomes unstretched first time after release is

5) In the shown figure mass of the pulley is m and radius 2R. A light concentric spool of radius R is
rigidly attached with the pulley. Two blocks A and B having masses m & 4m respectively are
attached with the pulley by means of light strings. Lower surface of the block B is attached to a
spring of stiffness k and block B rests on a smooth inclined plane inclined 30° with horizontal. Other
end of the spring is fixed to the ground. Initially the blocks are held at a height such that spring is in
relaxed position. The block A is stretched a small distance and released. The strings do not slip on
the pulley and spool.

(A) In equilibrium the extension in the spring is zero

(B) In equilibrium the extension in the spring is 2mg/k
The time period of oscillation of block B is T = 2π
(C)

The time period of oscillation of block B is T = 2π

(D)

SECTION-I (iii)

Common Content for Question No. 1 to 2

A container of volume 4V0 made of a perfectly non-conducting material is divided into two equal
parts by a fixed rigid wall whose lower half is non-conducting and upper half is purely conducting.
The right side of the wall is divided into equal parts (initially) by means of a massless non-conducting
piston free to move as shown. Section A contains 2 mol of a gas (γ = 1.5) while the section B and C
contain 1 mol each of the same gas (γ = 1.5) at pressure P0. The heater in left part is switched on till
the final pressure in section C becomes 125/27 P0. (Assuming no heat supplied to C after moving the

piston also).

1) Final temperature in part A and C.

(A)

(B)

(C)

(D)

2) The heat supplied by the heater

(A)

(B)

(C)

(D)

Common Content for Question No. 3 to 4

Consider a sphere filled with liquid inside rolling back and forth at the bottom of a spherical bowl.
That is, the sphere is periodically changing its translational and rotational direction. Assume that the
rigid thin spherical shell of radius r and mass m is fully filled with some liquid substance of mass M.
Liquid has such a unique property that usually it behaves like an ideal liquid (i.e. without any
viscosity), while in response to some special external influence (such as electric field or sudden cold
climate) it transits to solid state immediately with the same volume; and once the applied influence
removed, the liquid state recovers immediately. Besides, this influence does not give rise to any
force or torque exerting on the sphere. This liquid-filled spherical shell (for convenience, called ‘the
sphere’ hereafter) is supposed to roll back and forth at the bottom of a spherical bowl of radius R
without any relative slipping, as shown in the figure. Assume the sphere moves only in the vertical

plane.

3) If the transition of spherical shell of liquid to solid occurs when the shell is at its extreme, Which
of the following statements is correct?

The angular amplitude remains the same, the oscillation energy remains the same and the
(A)
speed at the bottom increases.
The angular amplitude remains the same, the oscillation energy remains the same and the
(B)
speed at the bottom decreases.
The angular amplitude decreases, the oscillation energy increases and the speed at the bottom
(C)
decreases.
(D) The angular amplitude, the oscillation energy and the speed at the bottom all remain same.

4) If the transition of spherical shell of liquid to solid occurs when the shell is at its mean position.
Which of the following statements is correct?

The angular amplitude decreases, the oscillation energy decreases and the speed at the bottom
(A)
decreases.
The angular amplitude remains the same, the oscillation energy decreases and the speed at the
(B)
bottom decreases.
The angular amplitude remains same, the oscillation energy remains same and the speed at the
(C)
bottom remains same.
The angular amplitude decreases, the oscillation energy increases and the speed at the bottom
(D)
decreases.
 SECTION-II

1) Two linear simple harmonic motion of equal amplitude a & frequencies ω & 2ω are impressed on

a particle along x & y axis respectively resultant path followed by particle is given by .

The initial phase difference between them is /. Find n.

2) Two blocks of masses m1 = 1 kg and m2 = 2 kg are connected by a spring of constant k = 100 N/m
and placed over a plank as shown. The coefficient of friction between m2 and plank is 0.5 and there
is no friction between m1 and plank. Initially the whole system, is at rest. The plank is now pulled to
right with constant acceleration a = 2 m/s2. Find the amplitude (in cm) of oscillation of block

m1 relative to plank.

3) A solid sphere (radius = R) rolls without slipping in a cylindrical trough (radius = 5R) as shown in
figure. For small displacements from equilibrium perpendicular to the length of the trough, the

sphere executes simple harmonic motion with a period T = then value of n is

4) A rod of mass m and length ℓ is pivoted at a point O in a car whose acceleration towards left is a0.
The rod is free to oscillate in vertical plane. In the equilibrium state the rod remains horizontal when
other end is suspended by a spring of stiffness K. The time period of small oscillations of the rod is

0
given by T = . Find the value of C and fill in OMR sheet. [Given value : K = 20 N/m, a = 10

m/s2, m = 1 kg, l = 1m]

 PART-2 : CHEMISTRY

SECTION-I (i)

1) Calculate the magnitude of net work done in the following cycle for one mol of an ideal gas (in

Calorie), where in process BC, PT = constant. (R = 2cal/mol-K).

(A) 800 cal

(B) 200 cal
(C) 300 cal
(D) 400 cal

2) Calculate the enthalpy change when 50 ml of 0.01 M Ca(OH)2 reacts with 25 ml of 0.01 M HCl.
Given that of strong acid and strong base is –57.1 kJ.
[Assuming that Ca(OH)2 is strong base]

(A) –14.275 kJ
(B) –14.275 J
(C) –14.275 × 103 kJ
(D) –14.375 × 103 J

3) The standard state Gibbs free energies of formation of C(graphite) and C(diamond) at T = 298 K
are ΔfG° [C(graphite)] = 0 kJ mol–1 ΔfG° [C(diamond)] = 2.9 kJ mol–1. The standard state means that
the pressure should be 1 bar, and substance should be pure at a given temperature. The conversion
of graphite [C(graphite)] to diamond [C(diamond)] reduces its volume by 2 × 10–6 m3 mol–1. If
C(graphite) is converted to C(diamond) isothermally at T = 298 K, the pressure at which C(graphite)
is in equilibrium with C(diamond), is
[Useful information : 1 J = 1 kg m2 s–2; 1 Pa = 1 kg m–1 s–2; 1 bar = 105 Pa]

(A) 14501 bar

(B) 29001 bar
(C) 58001 bar
(D) 1450 bar

4) The vapour density of a sample of N2O4(g) is at 4.8 atm at 127°C. The value of Kp (in atm) of
the reaction , at 127°C, is -

(A) 0.6
(B) 0.4
(C) 0.8
(D) 1.5

SECTION-I (ii)

1) One mole of an ideal diatomic gas (Cv = 5 cal) was transformed from initial 25°C and 1 L to the
state when temperature is 100°C and volume 10 L. Then for this process (R = 2 calories / mol / K)

(A) ΔH = 525 cal

(B)
ΔS = (5 ln + 2 ln 10) cal
(C) ΔE = 525 cal
(D) ΔG = 0

2) An ideal gas is expanded from (p1, V1, T1) to (p2, V2, T2) under different conditions. The correct
statement(s) among the following is(are)

The work done on the gas is maximum when it is compressed irreversibly from (p2, V2) to (p1, V1)
(A)
against constant pressure p1.
The work done by the gas is less when it is expanded reversibly from V1 to V2 under adiabatic
(B) conditions as compared to that when expanded reversibly from V1 to V2 under isothermal
conditions.
The change in internal energy of the gas is (i) zero, if it is expanded reversibly with T1 = T2, and
(C)
(ii) positive, if it is expanded reversibly under adiabatic conditions with T1 ≠ T2.
(D) If the expansion is carried out freely, it is simultaneously both isothermal as well as adiabatic.

3) For a general substance A the phase diagram is represented as shown. Identify the option(s)
which is/are correct.

(A) Triple point of the substance is (200 K and 3.8 mm of Hg)

(B) Standard boiling point of the substance should be slightly less than 400 K.
(C) Above 500 K, gas – liquid transition can not occur without change in temperature.
(D) Melting point of the substance will increase with increase in pressure.

4) Which relation of KP and degree of dissociation (α) is correct for the respective reactions in
equilibrium ?
[Assuming α is very small as compared to unity at equilibrium pressure P] Initial moles = 1
(A)

(B)

(C)

(D)

5) If heat of formation of PCl3(g) and PH3(g) are 140 and 8 kJ /mole respectively and heat of
atomisation of phosphorous[P4(s)], chlorine and hydrogen are 320, 120 and 216 kJ/mole respectively
then.

(A) Bond energy of P–Cl is 63 kJ/mole

(B) Bond energy of P–H is 210 kJ/mole
(C) Heat of formation of isolated gaseous hydrogen atom is 108 kJ/mole
(D) Heat of formation of isolated gaseous chlorine atom is 60 kJ/mole

SECTION-I (iii)

Common Content for Question No. 1 to 2

A diatomic ideal gas containing Avogadro’s number of atoms is subjected to the following expansion

from the initial temperature of 300K. The area of the curve is 100 J

1) The change in the internal energy is:

(A) 125 J
(B) 250 J
(C) – 125 J
(D) – 250 J

2) The final temperature of the gas is (where R = universal gas constant):

(A)

(B)

(C)
(D)

Common Content for Question No. 3 to 4

10 moles of pure PCl5 gas is put into a closed container of volume ‘V’ and temperature ‘T’ allowed to
come at equilibrium, at an equilibrium pressure 20 atm. The pure PCl5 is found to be 50%
dissociated at equilibrium. PCl5 (g) PCl3 (g) + Cl2 (g)

3) If 20 moles of PCl5(g) is added to original equilibrium mixture keeping total pressure constant to
20 atm at same temperature ‘T’, then ratio of new equilibrium volume to the initial volume V will be-

(A) 1.5
(B) 2.0
(C) 1.8
(D) 3.0

4) The partial pressure of PCl5, if equilibrium is established at new equilibrium pressure 35 atm by
changing volume is -

(A) 10 atm
(B) 15 atm
(C) 18 atm
(D) 12 atm

SECTION-II

1) For the reaction : N2H4(g) → N2H2 (g) + H2(g) ; ΔrH° = 109 kJ /mol
Calculate the bond enthalpy of N = N.
Given : B.E. (N – N ) = 163 kJ/mol, B.E. (N–H) = 391 kJ/mol, B.E. (H–H) = 436 kJ/mol

2) In a hypothetical elementary reaction X → Y at 500 K. and .

0
Assume that catalyst is used and it lowers the activation energy by 20% then what is |ΔG | for the

reaction after use of catalyst (in kJ mol–1) is:

3) For the reaction , the concentration and time is shown as:

 Calculate the value of KC for the reaction 2Y 2X

4) One mole of an ideal gas at 300 K and 5 atm is expanded adiabatically to a final
pressure of 2 atm against a constant pressure of 2 atm. Then final temperature of the gas (in nearest
integer) is :

PART-3 : MATHEMATICS

SECTION-I (i)

1) Consider the circle |z – 5i| = 3 and two points z1 and z2 on it such that |z2| > |z1| and arg(z1) =

arg(z2) = . A tangent is drawn at z2 to the circle which cut real axis at z3, then |z3| is equal to :

(A) 3
(B)
(C)
(D) 4

2) The equations of the perpendicular bisectors of the sides AB & AC of a triangle ABC are x – y + 5
= 0 & x + 2y = 0, respectively. If the point A is (1, –2) find the equation of the line BC.

(A) 14x + 23y = 20

(B) 14x + 23y = 40
(C) 23x – 14y = 40
(D) 40x + 23y = 14

3) If z1, z2, z3 are vertices of a triangle such that then argument of

is _____

(A)

(B) 0
(C)

(D)

4) The number of seven letter word that can be formed by using the letter of the word SUCCESS
such that no two C and no two S are together is :

(A) 120
(B) 96
(C) 48
(D) 72

SECTION-I (ii)

1) These are two circles in a parallelogram, one of them of radius 3 is inscribed in parallelogram and
the other touches two sides of a parallelogram and first circle. The distance between points of
tangency which lie on same side of parallelogram is equal to 3, then :

(A)
Radius of other circle is
Area of parallelogram is equal to
(B)

(C) d1d2 = 75
(D) d1d2 = 95 (d1, d2 length of diagonal of parallelogram)

2) A circle is tangent to line at (1, 1) and is normal to line 2x + y – 5 = 0. Choose

correct options :

(A) Length of tangent to circle from (–1, 1) is 4 units

(B) Length of perpendicular from centre of circle to x-axis is 3 units
(C) x-intercept of director circle of given circle is
x-intersect of director circle of given circle is
(D)

3) Pairs of lines and ;

intersect to form a quadrilateral of area Ak .

(A)
Range of

(B)
Quadrilateral is rhombus
(C) Range of

(D)
Quadrilateral is kite
4) If one vertex of an equilateral triangle of side 2 lies at the origin and other lies on the line
, then the coordinates of the third vertex are

(A) (0, 2)

(B)

(C) (2, 0)

(D)

5) If , then which of following is correct (where ω is the complex

(non real) cube root of unity and a, b, c ∈ R and k ∈ N)

(A) Total number of factor of k is 8

(B) Number of positive integral solution of xyz = k is 27
(C) Number of integral solution of xyz = k is 81
(D) Remainder obtained when k100 is divided by 7 is 2

SECTION-I (iii)

Common Content for Question No. 1 to 2

The centres of two circles C1 and C2 of radii 4 and 9 respectively are at a distance of 15 units from
each other. Let L1 be one direct common tangent to these circles.

1) There are n circles which touches both the circles C1 and C2 and also the line L1 then n is :

(A) 2
(B) 4
(C) 3
(D) 8

2) Let r1, r2, …..rn be the radii of these circles then find max (r1, r2 …..rn) ?

(A)

(B)

(C) 50
(D) 1

Common Content for Question No. 3 to 4

Consider all the permutation of the word ‘MAHAKUMBH’

3) Number of permutation of the word in which vowels are in alphabetical order is :

(A) 2520
(B) 7560
(C) 3024
(D) 15120

4) Number of permutation of the word if no two alike letters are together is:

(A) 22560
(B) 21960
(C) 7560
(D) 33840

SECTION-II

1) Let be the vertices of a regular polygon of n sides in a circle of radius unity and

then is equal to

2) Circle C1 and C2 touches externally and circles C1 and C2 touches internally to the circle C3. The
radii of C1 and C2 are 4 and 10 respectively and the centres of the three circles are collinear. A chord

of C3 is also a common transverse tangent of C1 and C2. Given that the length of the chord is ,,
where m, n and p are positive integers, m and p are relatively prime and n is not divisible by the

square of any prime, then find the value of :

3) Let z1, z2, z3 be complex numbers such that and

then the value of is :

4) The number of sets of three different numbers that can be chosen from numbers lying between 0
and 90, so that their average is 30, is_______
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A C D B

SECTION-I (ii)

Q. 5 6 7 8 9
A. A,B,C,D A,B,C,D A,C A,D A,C

SECTION-I (iii)

Q. 10 11 12 13
A. A A B A

SECTION-II

Q. 14 15 16 17
A. 2 2 28 5

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. A B A C

SECTION-I (ii)

Q. 22 23 24 25 26
A. A,B A,B,D A,B,C A,B,C C,D

SECTION-I (iii)

Q. 27 28 29 30
A. B C D B

SECTION-II

Q. 31 32 33 34
A. 400 45 9 249

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. C B C B

SECTION-I (ii)

Q. 39 40 41 42 43
A. A,B,C A,B C,D A,D A,B,D

SECTION-I (iii)

Q. 44 45 46 47
A. B C D B

SECTION-II

Q. 48 49 50 51
A. 2 1 8 1110
 SOLUTIONS

PART-1 : PHYSICS

1)

mv0 = 2mv

2) We have,

we have PV = nRT

\(\eqalign{ & \Rightarrow \frac{1}{P} = \frac{{AL}}{{nR\left( {{T_2} - {T_1}} \right)}}\left|

{\ell n\frac{{{T_1} + \left( {{T_2} - {T_1}} \right)x}}{L}} \right|_0^L \cr & =
\frac{{AL}}{{nR\left( {{T_2} - {T_1}} \right)}}\ell n\left( {\frac{{{T_2}}}{{{T_1}}}} \right)
\cr}\)

3)

Change in the internal energy of from A to B is

ΔU = nCv ΔT =

and

∴ Heat exchanged
= ΔU + W

4) ℓ=R

5)

In the first case, the two oxygen atoms vibrate with the same frequency with the carbon atom
remaining motionless.

Let x1 be the instantaneous leftward displacement of the right hand oxygen atom,
x2 (rightward) of the carbon atom and x3 (leftward) of the left oxygen atom. Since the system is
free from external force, its centre of mass remains stationary.

ℓ0 = natural length of each spring.

or m1x1 = m2x2 – m1x3
or m1(x1 + x3) = m2x2.
Let us consider motion of m2.
Force on carbon atom m2 to the right

= – k(x1 + x2) – k(x2 + x3)

Hence motion is simple harmonic and its ω is given by

6)

at equilibrium, F = 0 ⇒ r = r0
Umin = 0
 =B
Assuming potential is nearly parabolic about the well minimum.
U = B [–a(r – r0)]2 [ ex = 1 + x]
U = Ba2 (r – r0)2

7)

By energy conservation 1/2 kx2 = mg (2x)

⇒ (maximum elongation)

8)

Fact based .

9)
In equilibrium net torque on the pulley is zero.
⇒ 2T1R - T2R = 0
⇒ 2T1 = T2 (1)
Also T1 = mg
and T2 = 4mg sin ϕ + kx0
⇒ 2mg = 4mg sin ϕ + kx0 ⇒ x0 = 0
Hence the spring is relaxed.
As total energy is always constant .

Differentiating w.r.t. time,

Hence ω2 =

Hence T =
10)

Q = ΔU

11)

Q = ΔU

12)
θ0 = amplitude
→ same.
ΔU = oscillation energy
→ same
13) At bottom, sphere is rolling.

I suddenly increases.

0 0 0 0
Li = mV R + I ω = mV R + I0

Lafter = mvR + Iω =

τ about point of contact is zero.

⇒ v↓

⇒K=

⇒ K↓

14) Here x = a sin ωt

y = a sin (2ωt + ϕ)

Since

15)

Tviewed from fram of plank

 [Initial condition]

[at the time of maximum compression]

2m1a + m2a = 8N and fmax = μN = 10N
⇒ Friction is static

kA = m1a ⇒

16) The kinetic energy of the ball is K = , where Ω is the rotation rate of the ball
about its centre of mass. Since the centre of the ball moves along a circle of radius 4R, its

displacement from equilibrium is s = (4R)θ and its speed is v = . Also, since the

ball rolls without slipping. So Ω =

The kinetic energy is then

K=
When the ball has an angular displacement θ, its centre is distance h = 4R(1 – cosθ) higher
than when at the equilibrium position. Thus, the potential energy is Ug = mgh = 4mgR(1 –

cosθ). For small angles, .

2
Hence Ug ≈ 2mgRθ , and the total energy is

E = K + Ug = .

Since E = constant in time,

This reduces to , or .
Withe the angular acceleration equal to a negative constant times the angular position, this is

in the defining form of a simple harmonic motion equation with ω = .

 The period of the simple harmonic motion is then T =

17)
In equilibrium, taking moments of the forces about O,
mg (ℓ/2) = Keℓ
e = (mg/2K)
e = (mg / 2K)
e ⇒ initial extension in the spring
During small oscillations, let the angular displacement be θ
In the reference of car.
Restoring torque about O.

Substituting values T =

PART-2 : CHEMISTRY

18) wtotal=wAB + wBC + wCA

wAB = 0 (isochoric)

wBC = (Polytropic PV1/2= constant)

 = –2400 Cal
wCA = –nRΔT (isobaric)
= –1 × 2 × –800 = 1600 Cal
wtotal=0 – 2400 + 1600 = –800 Cal

19) Number of meq of Ca(OH)2 = 50 × 2 × 0.01 = 1.00

Number of meq. of HCl = 25 × 0.01 = 0.25
0.25 meq. of HCl will be neutralized by 0.25 meq of Ca(OH)2
1 eq of acid neutralizes 1 eq of Ca(OH)2 to give 57.1 kJ.
0.25 meq of acid neutralizes 0.25 meq of base to give =

20) C(graphite) – C(diamond)

ΔG° = 2.9 kJ
If 'P' represents the pressure at which eq. exist then ΔGP = 0 ⇒ Also ΔGP – ΔG° = (ΔV)dP
⇒ 0 + 2.9 × 103 = + 2 × 10–6 × (P – 1)

∴ P = 14500 + 1 = 14501 bar

21)

22)

ΔH = nCP . ΔT = 1 × 7 × 75 = 525 cal

ΔS = nCv ln + nR ln

= 1 × 5 cal × ln + R ln (10).

23) (A)
|w| = Pext [V2 – V1]
∴ if Pext = P1 ∴ Maximum work.
∴ (A) is correct.
(B)
∴ |w|Iso. > |w|adia.
∴ (B) is correct.

24) Triple point is (200 K, 5 × 10–3 atm)

(200 K, 5 × 10–3 × 760 mm of Hg)
(200 K, 3.8 mm of Hg)
Boiling point slightly less than 400 K
Above 500 K, gas – liquid transition can not occur without change in temperature as 500 K is
critical point.

25) (A)

(B)

(C)

(D)

26) ; ΔH = 140

140 =

(B–E)P–Cl =

; ΔH = 8

8=
(B–E)P–H = 132 kJ/mole

H2 → 2H ; ΔH = 216 ∴ (ΔHf)H =

Cl2 → 2Cl ; ΔH = 120 ∴ (ΔHf)Cl =

27) The area of the curve = 100 = nRΔT

 ΔE = n ΔT = 250 J

28) Since, nRΔT = 100

ΔT = 100/nR = 200/R (n = 0.5 mol)

Thus, T(final) =

29)

3.0

30)

15 atm

31) 400 kJ/mole

0
32) ΔrH = Eaf – Eab = 15 – 10 = 5 kg mol–1
0
ΔrS = 150 – 50 = 100 Jk–1
0 0 0
ΔG = ΔH – TΔS
= 5 – 500 × 100 × 10–3
= – 45 KJ mol–1.

33)

34)

⇒ T2 = 248.5 K

PART-3 : MATHEMATICS
35)

AD = 6 and OD = 5
|z3| = OA =

36)
Equation of SE : x – y + 5 = 0 …(i)
Equation of SF : x + 2y = 0 …(ii)

Point B is the reflection of point A w.r.t line SE

x2 = –7 y2 = 6
∴ B(–7, 6) Point C is the reflection of point A w.r.t line SF

&

∴
∴ Equation of line BC

37) and z1, z2, z3 are vertices of a triangle

∴ triangle is isosceles triangle
38) Number of word in which no two S are together – Cases where both C are together

39)

ABCD is a rhombus with side

Area of ABCD =

40)
⇒

41)

at
at k = 4

42)
The equation of line x – y = 0 in parametric form is

= =r ⇒

Put r = ± 2, we get and

Case-1 : Consider two vertices of an equilateral triangle of side 2 as (0, 0) and .

∴ Equation of line which is perpendicular bisector of (0, 0) and is

Put r1 = ± (As altitude = )

∴
⇒

∴ Third vertex can be (0, 2) and

Case-2 : Consider two vertices of an equilateral triangle of side 2 as (0, 0) and

∴ Equation of line which is perpendicular bisector of (0, 0) and is

= = r2 (let)
Put r2 = ± (As altitude = )

∴ x= ;y=

⇒ x= ; y=

∴ Third vertex can be and (0, –2)

Note : Number of possible equilateral triangles are four.

43) We know that

and

44)
option (1) is correct answer

45)
AC – BC = AB

Option (2) is correct answer

46)
= 126 × 120

47) P : A are together

Q : M are together
R : H are together

48)

=2(n – 1) – 2 Real part of

= 2(n –1) – 2(–1)
∴
Also
=
=
Since are the roots of

⇒
Substituting z = 1, we have

49)
⇒ r = 14
Now, PC3 = x = 14 – 8 = 6

∴ m = 8, n = 10, p =1
∴ m + n + p =19

50)

Given
∴ Triangle is isosceles

θ ≠ π because z2 ≠ z3

51)
(i) a ∈ [0, 29], b ∈ [0, 29], c > 30
Number of ways = 30 × 29
(ii) a = 30, b + c = 60
Number of ways = 30
(iii) a ∈ [31, 45], b ∈ [31, 45], c < 30
Number of ways = 210