Thermochemistry
Chemistry for
Engineers
Module II
Prof. Florderliza O. Babat
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Introduction
Our discussion will utilize the concepts of energy and heat. Although these terms are
somewhat familiar to us, we will need to have some definitions for our discussion. We
will focus on the basic principles of heat flow, calorimetry, enthalpy, thermochemical
equations, and bond energy.
Throughout the discussion, self-assessment questions (SAQ) are given for you
to monitor yourself if you understood the concept. Be sure to try answering them before
looking at the answer to self-assessment question (ASAQ) which is provided at the
last part of the module.
Objectives
At the end of this module, you should be able to:
1. Understand the basic principles of heat flow.
2. Discuss how enthalpy affects reaction.
3. Explain the use of calorimeter.
4. Write a thermochemical equation.
5. Solve problems on heat capacity, enthalpy and bond energy.
6. Analyze the heat effects in the bond breaking and bond formation.
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Table of Contents
Page No.
TITLE PAGE
INTRODUCTION i
OBJECTIVES i
TABLE OF CONTENTS ii
DISCUSSION 1
Thermochemistry 1
Direction and Sign of Heat Flow 2
Magnitude of Heat Flow 2
Measurement of Heat Flow; Calorimetry 5
Enthalpy 8
Thermochemical Equations 9
Bond Energy 10
Table: Average Bond Energies 12
SUMMARY 15
REFERENCES 16
ANSWER OF SELF-ASSESSMENT QUESTIONS (ASAQ) 17
MASTERY TEST 18
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