Saraswati Vidhya Mandir, Gandhinagar

Chapters : 1,2 Std 12 : Chemistry Date : 27/11/25

Total Marks : 49 Unit Test Time : 03 Hour
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [37]
1. The role of a catalyst is to change ..........
(A) Gibbs energy of reaction. (B) enthalpy of reaction.
(C) activation energy of reaction. (D) equilibrium constant.
2. In the presence of a catalyst, the heat evolved or absorbed during the reaction....
(A) increases (B) decreases
(C) remains unchanged (D) may increase or decrease
3. Activation energy of a chemical reaction can be determined by....
(A) determining the rate constant at standard temperature.
(B) determining the rate constants at two temperatures.
(C) determining probability of collision.
(D) using catalyst.
4. Consider figure below and mark the correct option.
(A) Activation energy of forward reaction is E1 + E2 and product
is less stable than reactant.
(B) Activation energy of forward reaction is E1 + E2 and product
is more stable than reactant.
(C) Activation energy of both forward and backward reaction is
E1 + E2 and reactant is more stable than product.
(D) Activation energy of backward reaction is E1 and product is
more stable than reactant.

5. Consider a first order gas phase decomposition reaction given below : A(g) ® B(g) + C(g)
The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total
pressure of the system increased by x units and became ‘pt’. The rate constant k for the reaction is
given as .........
2.303 pi 2.303 pi
(A) k = log (B) k = log
t pi – x t 2pi – pt
2.303 pi 2.303 pi
(C) k = log (D) k = log
t 2pi + pt t pi + x
6. According to Arrhenius equation rate constant k is equal to A e–Ea /RT. Which of the following
1
options represents the graph of ln k vs ?
T

(A) (B) (C) (D)

Wish You - All The Best

7. Consider the Arrhenius equation given below and mark the correct option. k = A e–Ea/RT
(A) Rate constant increases exponentially with increasing activation energy and decreasing
temperature.
(B) Rate constant decreases exponentially with increasing activation energy and decreasing
temperature.
(C) Rate constant increases exponentially with decreasing activation energy and decreasing
temperature.
(D) Rate constant increases exponentially with decreasing activation energy and increasing
temperature.
8. A graph of volume of hydrogen released Vs time for the reaction between zinc and dil. HCl is given in
figure below. On the basis of this mark the correct option.
V3 – V2
(A) Average rate upto 40 seconds is
40
V3 - V2
(B) Average rate upto 40 seconds is 40 - 30

V3
(C) Average rate upto 40 seconds is
40
V3 - V1
(D) Average rate upto 40 seconds is 40 - 20

9. Which of the following statements is not correct about order of a reaction ?

(A) The order of a reaction can be a fractional number.
(B) Order of a reaction is experimentally determined quantity.
(C) The order of a reaction is always equal to the sum of the stoichiometric coefficients of
reactants in the balanced chemical equation for a reaction.
(D) The order of a reaction is the sum of the powers of molar concentration of the reactants in
the rate law expression.
10. Consider the graph given in Figure. Which of the following options does not show instantaneous rate
of reaction at 40 s ?
V5 – V2 V4 – V2
(A) 50 – 30 (B) 50 – 30

V3 – V2 V3 – V1
(C) 40 – 30 (D) 40 – 20

11. Which of the following statements is correct ?

(A) The rate of a reaction decreases with passage of time as the concentration of reactants
decreases.
(B) The rate of a reaction is same at any time during the reaction.
(C) The rate of a reaction is independent of temperature change.
(D) The rate of a reaction decreases with increase in concentration of reactant(s).
12. Which of the following expressions is correct for the rate of reaction given below ?
–
5Br(aq) + BrO–3(aq) + 6H+(aq) ® 3Br2(aq) + 3H2O(l)

D[Br - ] D[H + ] D[Br - ] 6 D[H + ] D[Br - ] 5 D[H + ] D[Br - ] D[H + ]

(A) =5 (B) = (C) = (D) =6
Dt Dt Dt 5 Dt Dt 6 Dt Dt Dt

Wish You - All The Best

13. Which of the following graphs represents exothermic reaction ?

(i) (ii)

(iii)

(A) only (i) (B) only (ii) (C) only (iii) (D) (i) and (ii)
14. Rate law for the reaction A + 2B ® C is found to be Rate = k [A][B] Concentration of reactant
‘B’ is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be...
(A) the same (B) doubled (C) quadrupled (D) halved
15. Which of the following statements is incorrect about the collision theory of chemical reaction ?
(A) It considers reacting molecules or atoms to be hard spheres and ignores their structural
features.
(B) Number of effective collisions determines the rate of reaction.
(C) Collision of atoms or molecules possessing sufficient threshold energy results into the product
formation.
(D) Molecules should collide with sufficient threshold energy and proper orientation for the
collision to be effective.
16. A first order reaction is 50% completed in 1.26 × 1014 s. How much time would it take for 100%
completion ?
(A) 1.26 × 1015 s (B) 2.52 × 1014 s (C) 2.52 × 1028 s (D) infinite
17. Compounds ‘A’ and ‘B’ react according to the following chemical equation.
A(g) + 2B(g) ® 2C(g)
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants
constant and rates were measured as a function of initial concentration. Following results were
obtained. Choose the correct option for the rate equations for thisreaction.

Experiment Initial Initial Initial

concentration concentration oncentration
of [A] of [B] of [C]
mol L–1 mol L–1 mol L–1 s–1
1 0.30 0.30 0.10
2 0.30 0.60 0.40
3 0.60 0.30

(A) Rate = k [A]2[B] (B) Rate = k [A][B]2 (C) Rate = k [A][B] (D) Rate = [k][A]2[B]0
18. Which of the following statement is not correct for the catalyst ?
(A) It catalyses the forward and backward reaction to the same extent.
(B) It alters DG of the reaction.
(C) It is a substance that does not change the equilibrium constant of a reaction.
Wish You - All The Best
(D) It provides an alternate mechanism by reducing activation energy between reactants and
products.
 (A) It catalyses the forward and backward reaction to the same extent.
(B) It alters DG of the reaction.
(C) It is a substance that does not change the equilibrium constant of a reaction.
(D) It provides an alternate mechanism by reducing activation energy between reactants and
products.
19. The value of rate constant of a pseudo first order reaction...
(A) depends on the concentration of reactants present in small amount.
(B) depends on the concentration of reactants present in excess.
(C) is independent of the concentration of reactants.
(D) depends only on temperature.
20. Consider the reaction A ® B. The concentration of both the reactants and the products varies
exponentially with time. Which of the following figures correctly describes the change in concentration
of reactants and products with time ?

(A) (B)

(C) (D)

21. Rate law cannot be determined from balanced chemical equation if ..........
(A) reverse reaction is involved. (B) it is an elementary reaction.
(C) it is a sequence of elementary reactions. (D) any of the reactants is in excess.
22. Which of the following statements are applicable to a balanced chemical equation of an
elementary reaction ?
(A) Order is same as molecularity. (B) Order is less than the molecularity.
(C) Order is greater than the molecularity. (D) Molecularity can never be zero.
23. In any unimolecular reaction ..........
(A) only one reacting species is involved in the rate determining step.
(B) the order and the molecularity of slowest step are equal to one.
(C) the molecularity of the reaction is one and order is zero.
(D) both molecularity and order of the reaction are one.
24. For a complex reaction ..........
(A) order of overall reaction is same as molecularity of the slowest step.
(B) order of overall reaction is less than the molecularity of the slowest step.
(C) order of overall reaction is greater than molecularity of the slowest step.
(D) molecularity of the slowest step is never zero or non integer.
1130 K
25. At high pressure the following reaction is zero order. 2NH3(g)  → N + 3H
Platinum catalyst 2(g) 2(g)

Which of the following options are correct for this reaction ?

Wish You - All The Best
(A) Rate of reaction = Rate constant
(B) Rate of the reaction depends on concentration of ammonia.
 1130 K
At high pressure the following reaction is zero order. 2NH3(g)  → N + 3H
Platinum catalyst 2(g) 2(g)

Which of the following options are correct for this reaction ?

(A) Rate of reaction = Rate constant
(B) Rate of the reaction depends on concentration of ammonia.
(C) Rate of decomposition of ammonia will remain constant until ammonia disappears
completely.
(D) Further increase in pressure will change the rate of reaction.
26. During decomposition of an activated complex ..........
(A) energy is always released (B) energy is always absorbed
(C) energy does not change (D) reactants may be formed
27. According to Maxwell, Boltzmann distribution of energy .........
(A) the fraction of molecules with most probable kinetic energy decreases at higher temperatures.
(B) the fraction of molecules with most probable kinetic energy increases at higher temperatures.
(C) most probable kinetic energy increases at higher temperatures.
(D) most probable kinetic energy decreases at higher temperatures.
28. In the graph showing Maxwell, Boltzman distribution of energy, .........
(A) area under the curve must not change with increase in temperature.
(B) area under the curve increases with increase in temperature.
(C) area under the curve decreases with increase in temperature.
(D) with increase in temperature curve broadens and shifts to the right hand side.
29. Which of the following statements are in accordance with the Arrhenius equation ?
(A) Rate of a reaction increases with increase in temperature.
(B) Rate of a reaction increases with decrease in activation energy.
(C) Rate constant decreases exponentially with increase in temperature.
(D) Rate of reaction decreases with decrease in activation energy.
30. Mark the incorrect statements.
(A) Catalyst provides an alternative pathway to reaction mechanism.
(B) Catalyst raises the activation energy.
(C) Catalyst lowers the activation energy.
(D) Catalyst alters enthalpy change of the reaction.
31. Which of the following graphs is correct for a zero order reaction ?

(A) (A)

(C) (D)

32. Which of the following graphs is correct for a first order reaction ?

Wish You - All The Best

(A) (B)
 Which of the following graphs is correct for a first order reaction ?

(A) (B)

(C) (D)

33. Assertion [A] : Order and molecularity are same.

Reason [R] : Order is determined experimentally and molecularity is the sum of the stoichiometric
coefficient of rate determining elementary step.

(A) Both assertion [A] and reason [R] are correct and the reason [R] is correct explanation of
assertion [A].
(B) Both assertion [A] and reason [R] are correct but reason [R] does not explain assertion [A].
(C) Assertion [A] is incorrect but reason [R] is correct.
(D) Both assertion [A] and reason [R] are incorrect.
(E) Assertion[A] is correct but reason [R] is incorrect.
34. Assertion [A] : Order of the reaction can be zero or fractional.

Reason [R] : We cannot determine order from balanced chemical equation.

(A) Both assertion [A] and reason [R] are correct and the reason [R] is correct explanation of
assertion [A].
(B) Both assertion [A] and reason [R] are correct but reason [R] does not explain assertion [A].
(C) Assertion[A] is correct but reason [R] is incorrect.
(D) Both assertion [A] and reason [R] are incorrect.

(E) Assertion [A] is incorrect but reason [R] is correct.

35. Assertion [A] : The enthalpy of reaction remains constant in the presence of a catalyst.

Reason [R] : A catalyst participating in the reaction, forms different activated complex and lowers
down the activation energy but the difference in energy of reactant and product remains the
same.

(A) Both assertion [A] and reason [R] are correct and the reason [R] is correct explanation of
assertion [A].
(B) Both assertion [A] and reason [R] are correct but reason [R] does not explain assertion [A].
(C) Assertion[A] is correct but reason [R] is incorrect.
(D) Both assertion [A] and reason [R] are incorrect.
(E) Assertion [A] is incorrect but reason [R] is correct.
36. Assertion [A] : Rate constants determined from Arrhenius equation are fairly accurate for simple
as well as complex molecules.

Reason [R] : Reactant molecules undergo chemical change irrespective of their orientation during
collision. Wish You - All The Best
(A) Both assertion [A] and reason [R] are correct and the reason [R] is correct explanation of
 Assertion [A] : Rate constants determined from Arrhenius equation are fairly accurate for simple
as well as complex molecules.

Reason [R] : Reactant molecules undergo chemical change irrespective of their orientation during
collision.

(A) Both assertion [A] and reason [R] are correct and the reason [R] is correct explanation of
assertion [A].
(B) Both assertion [A] and reason [R] are correct but reason [R] does not explain assertion [A].
(C) Assertion[A] is correct but reason [R] is incorrect.
(D) Both assertion [A] and reason [R] are incorrect.

(E) Assertion [A] is incorrect but reason [R] is correct.

37. Assertion [A] : All collision of reactant molecules lead to product formation.

Reason [R] : Only those collisions in which molecules have correct orientation and sufficient
kinetic energy lead to compound formation.

(A) Both assertion [A] and reason [R] are correct and the reason [R] is correct explanation of
assertion [A].
(B) Both assertion [A] and reason [R] are correct but reason [R] does not explain assertion [A].
(C) Assertion[A] is correct but reason [R] is incorrect.
(D) Assertion [A] is incorrect but reason [R] is correct.

(E) Both assertion [A] and reason [R] are incorrect.

Section B
//X
• Write the answer of the following questions. [Each carries 1 Mark] [4]
42.1) For a general reaction A ® B, plot of concentration of A vs time is given in figure. Answer the following
1.
question on the basis of this graph.
What is the order of the reaction ?

42.2) For a general reaction A ® B, plot of concentration of A vs time is given in figure. Answer the following
2.
question on the basis of this graph.
What is the slope of the curve ?

42.3) For a general reaction A ® B, plot of concentration of A vs time is given in figure. Answer the following
3.
question on the basis of this graph.
What are the units of rate constant ?

Wish You - All The Best

4. Match the items of Column-I and Column-II.

Column - I Column - II
(A) Mathematical expression rate of (1) rate constantfor
reaction
(B) Rate of reaction for zero reaction is (2) rate laworder
equal to
(C) Units of rate constant for order (3) order ofzero
reaction is same that of slowest stepas
(D) Order of a complex reaction (4) rate of ais
determined by reaction

Section C
//X
• Write the answer of the following questions. [Each carries 2 Marks] [8]
5. Match the items of Column-I and Column-II.
Column - I Column - II
(A) Diamond (1) short interval of time
(B) Instantaneous rate (2) ordinarily rate of conversion is
imperceptible
(C) Average rate (3) long duration of tim

6. Match the statements given in Column-I and Column-II.

Column-I Column-II
(A) Catalyst alters the rate of (1) cannot be fraction or
reaction. zero.
(B) Molecularity (2) proper orientation is
not there.
(C) Second half life of first (3) by lowering the
order reaction activation energy.
Ea
(D) e – RT (4) is same as the first.
(E) Energetically favourable reactions (5) total probability is one.
are some-times slow
(F) Area under the Maxwell (6) refers to the fraction of
Boltzman curve is constant molecules with energy
equal to or greater than
activation energy

7. Match the graph given in column - I with the order of reaction given in column - II. More than one
item in column-I may link to the same item of column-II.

Column-I Column-II

(A)

(B) (1) 1st order

Wish You - All The Best

(C) (2) Zero order

 Match the graph given in column - I with the order of reaction given in column - II. More than one
item in column-I may link to the same item of column-II.

Column-I Column-II

(A)

(B) (1) 1st order

(C) (2) Zero order

(D)

8. For a general reaction A ® B, plot of concentration of A vs time is given in figure. Answer the following
question on the basis of this graph.
(i) What is the order of the reaction ?
(ii) What is the slope of the curve ?
(iii) What are the units of rate constant ?

Wish You - All The Best

 Saraswati Vidhya Mandir, Gandhinagar
Chapters : 1,2 Std 12 : Chemistry Date : 27/11/25
Total Marks : 49 Unit Test Time : 03 Hour
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [37]
1.

2.

3.

4.

Welcome To Future - Quantum Paper

5.

6.

Welcome To Future - Quantum Paper

7.

8.

9.

Welcome To Future - Quantum Paper

10.

11.

Welcome To Future - Quantum Paper

12.

13.

Welcome To Future - Quantum Paper

14.

15.

16.

17.

Welcome To Future - Quantum Paper

18.

19.

20.

Welcome To Future - Quantum Paper

21.

22.

23.

24.

Welcome To Future - Quantum Paper

25.

26.

27.

Welcome To Future - Quantum Paper

28.

29.

Welcome To Future - Quantum Paper

30.

31.

32.

Welcome To Future - Quantum Paper

33.

34.

Welcome To Future - Quantum Paper

35.

36.

37.

Welcome To Future - Quantum Paper

 Section B
//X
• Write the answer of the following questions. [Each carries 1 Mark] [4]
1.

2.

3.

4.

Welcome To Future - Quantum Paper

 Section C
//X
• Write the answer of the following questions. [Each carries 2 Marks] [8]
5.

6.

7.

Welcome To Future - Quantum Paper

8.

Welcome To Future - Quantum Paper

Welcome To Future - Quantum Paper