08-06-2025

2401CJA101029250012 JM

PHYSICS

SECTION - I

1) In a winter season (temperature 10°C), take a container and pour 200 gm ice at –20° C and 100
gm water at 40° C in it. What will be the final constituent of water in container if we assume no heat
transfer to atmospher (water equivalent of container is 200 gm, specific heat of ice = sw/2, sw = 1
cal/gm ºC, latent heat of ice = 80 cal/gm):-

(A) 100 gm
(B) 200 gm
(C) 150 gm
(D) 300 gm

2) Among the following four cylindrical rods, in which rod the rate of conduction of heat will be
maximum, if the temperature difference between their ends is same ?

(A) Length 2 m, radius 1 cm

(B) Length 4 m , radius 2 cm
(C) Length 2 m, radius 2 cm
(D) Length 2 m, radius 4 cm

3) A spherical black body with a radius of 12cm radiates 450W power at 500K. If the radius were
halved and the temperature doubled, the power radiated in watt would be :-

(A) 225
(B) 450
(C) 900
(D) 1800

4)
What is the temperature of steel-copper junction at steady state. The length, and area of cross
section of steel is double that of copper and thermal conductivity of copper is nine times that of steel
:-

(A) 10°C
(B) 20°C
(C) 30°C
(D) 40°C

5) If 10 gm ice at 0°C is mixed with 10 gm water at 20°C, the final temperature will be

(A) 50°C
(B) 10°C
(C) 0°C
(D) 15°C

6) If two metallic plates of equal thicknesses, equal areas of cross section and thermal conductivities
K1 and K2 are put together face to face and a common plate is constructed, then the equivalent

thermal conductivity of this plate will be :-

(A)

(B)

(C)

(D)

7) A uniform electric field E = (8m/e) V/m is created between two parallel plates of length 1m as
shown in figure, (where m = mass of electron and e = charge of electron). An electron enters the
field symmetrically between the plates with a speed of 2m/s. The angle of the deviation (q) of the

path of the electron as it comes out of the field will be ……….

(A) tan–1 (4)

(B) tan–1 (2)

(C)

(D) tan–1 (3)

8) Charge Q coulombs is uniformly distributed throughout the volume of a solid hemisphere of

radius R metres. Then the potential at centre O of the hemisphere in volts is
(A)

(B)

(C)

(D)

9) A dipole comprises of two charged particles of identical magnitude q and opposite in nature. The
mass 'm' of the positive charged particle is half of the mass of the negative charged particle. The two
charges are separated by a distance 'ℓ' . If the dipole is placed in a uniform electric field ; such a
way that dipole axis makes a very small angle with the electric field, . The angular frequency of
the oscillations of the dipole when released is given by :

(A)

(B)

(C)

(D)

10) Electric field in a region is found to be . The total energy stored in electric field inside the

cube shown will be

(A)
(B)

(C)

(D) 0
11) In an electric field the potential at a point is given by the following relation V = . The electric
field at is :

(A)
(B)

(C)

(D)

12) The surface density on the copper sphere is σ. The electric field strength on the surface of the
sphere is

(A) σ
(B) σ/2
(C) σ/ε0
(D) σ/2ε0

13) With what angular velocity the earth should spin in order that a body lying at 30° latitude may
become weightless [R is radius of earth and g is acceleration due to gravity on the surface of earth]

(A)

(B)

(C)

(D)

14) A body attains a height equal to the radius of the Earth when projected from Earth' surface. The
velocity of the body with which it was projected is :–

(A)

(B)

(C)

(D)

15)

Calculate energy needed for moving a mass of 4kg from the centre of the earth to its surface. If
radius of the earth is 6400 km and acceleration due to gravity at the surface of the earth is g = 10
m/sec2

(A) 1.28 × 108 J

(B) 1.28 × 106 J
(C) 2.56 × 108 J
(D) 2.56 × 1010 J

16) Time taken by the planet to cover path ABC is t1 & time taken by the planet to cover path C D A

is t2 :-

(A) t1 = t2
(B) t2 > t1
(C) t1 > t2
(D) cannot be determined

17) In the circuit shown below, find the decrease in power dissipated in 2Ω resistance after switch is

closed. The battery is ideal :-

(A) 8.34 W
(B) 21.21 W
(C) 3.68 W
(D) 14.72 W

18) A battery of internal resistance 8Ω is connected to network as shown. In order to deliver

maximum power to network R should be :

(A) 8 Ω
(B) 4Ω
(C) 2 Ω
(D) None of these

19) A hollow spherical conductor have inner radius ‘a’ and outer radius ‘b’. A constant potential
difference is applied across inner and outer shell, due to which current flows radially. Select the

correct statement :-

(A) Drift velocity remains constant

(B) Drift velocity increases radially
(C) Drift velocity decreases radially
(D) Potential gradient [electric field] increases radially

20)

‘n’ identical bulbs, each designed to draw a power P from a certain votage supply are joined in series
across the supply. The total power which they will draw is:

(A) P
(B) nP

(C)

(D)

SECTION - II

1) A current of 2A flows through 6Ω resistance shown in figure. The power dissipated in the 2Ω

resistor is :-

2) A particle is projected radially outwards from the surface of a planet with an initial speed of 4.0
km/s. Maximum height attained by the particle is h = 900 km from the planet’s surface. Find the
radius R (in km) of the planet taking g = 10 m/s2 on the surface of the planet. Fill R/900.
3) In the given figure if α > β, then the net electric field will be in the direction :

4) An electric field Vm–1 exists in the space. If potential at the origin is zero then find the
potential at (5m,3m) in volts.

5) Three rods of the same dimensions have thermal conductivities 3 k, 2 k and k. They are arranged
as shown, with their ends at 100°C, 50°C and 0°C. The temperature of their junction in °C is in

nearest integer.

CHEMISTRY

SECTION - I

1) If {–d [A]/ dt} = 2k1 [A]2 [B] – 2k–1 [C]3 [D] – 3k2 [C]2 then the possible reaction steps are :

(A)

(B)

(C)

(D) None of these

2) 1In the reversible reaction 2NO2 N2O4 the rate of disappearance of NO2 is equal to :

(A) [(2k1 / k2) (NO2)2]

(B) 2k1[NO2]2 – 2k2 [N2O4]
(C) 2k1 [NO2]2 – k2 [N2O4]
(D) (2k1 – k2)[NO2]

3) In the given first order reaction NH4NO2(aq.) → N2(g) + 2 H2O(l) the volume of N2 after 20 min
after a long time is 40 ml and 70 ml respectively The value of rate constant is :

(A) (1/20) ln (7/4) min–1

(B) (2.303/1200) log (7/3) sec–1
(C) (1/20) log (7/3) min–1
(D) (2.303/20) log (11/7) min–1

4) The following data were obtained for a gaseous reaction A2 + 2B → 2AB

A2 B –d[A2]/dt
(mole/It) (mole/It) mole lt–1 min–1
0.1 0.01 0.072
0.1 0.04 0.288
0.2 0.01 0.144.
The rate constant and rate of formation of AB, when [A2] = 0.01M and [B] = 0.02 M will be
(A) 72 (mol L–1)–1 min–1, 0.0288 M min–1
(B) 36 (mol L–1)–1 sec–1, 0.0144 M min–1
(C) 36 sec–1, 0.0144 M min–1
(D) 72 (mol L–1)–1 min–1, 0.0144 M min–1

5) In the following questions, two statements are given :

One labelled as Assertion A and the other as Reason R. Examine the two statements carefully and
mark the correct choice (A), (B), (C) and (D) according to the instructions given below
Assertion A : On increasing the temperature, the value of rate constant (k) of an a elementary gas
reaction always increases.
Reason R : On increasing the temperature, the value of equilibrium constant (Keq) of a reaction
always increases.

(A) if both A and R are correct and R is correct explanation of A.

(B) if both A and R are correct but R is not the explanation of A.
(C) if A is correct but R is wrong
(D) if A is wrong but R is correct

6) The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much,
the temperature of reaction B should be increased from 300 K so that rate doubles if activation
energy of the reaction B is twice to that of reaction A :

(A) 2.45 K
(B) 4.92 K
(C) 9.84 K
(D) 19.67 K
7) Select the option in which all parameters are intensive properties of a system :

(A) Entropy, volume, boiling point.

(B) Molar enthalpy, heat capacity, molarity
(C) Temperature, molarity, melting point
(D) Mass, pressure, molar entropy

8) Match the lists:

List-I List-II

(P) A process carried out infinitesimally slowly (1) Adiabatic

A process in which no heat enters or leaves

(Q) (2) ΔU = 0
the system

A process carried out at constant

(R) (3) Reversible
temperature

(S) Cyclic process (4) Isothermal

(5) Irreversible
(A) P → 3;Q → 1;R → 4;S → 2
(B) P → 5;Q → 4;R → 1;S → 3
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 5;Q → 1;R → 4;S → 3

9) In the redox reaction –

10FeC2O4 + x KMnO4 + 24H2SO4 → 5Fe2 (SO4)3 + 20CO2 + y MnSO4 + 3 K2SO4 + 24H2O.
The values of x and y are respectively –

(A) 6, 3
(B) 3, 6
(C) 3, 3
(D) 6, 6

10)

Column-II
('n' factor of
Column-I
underlined
(Chemical reactions)
specie in the
given chemical
redox
reactions)

(A) (P) 4

(B) (Q) 1

(C) (R) 2
 (D) (S) 3

(T) 6
(A) A-Q, B-T, C-P, D-S
(B) A-T, B-T, C-P, D-Q
(C) A-Q, B-P, C-T, D-T
(D) A-T, B-Q, C-P, D-T

11) How many mililiters of 0.1 M H2SO4 must be added to 50 ml of 0.1 M NaOH to give a solution
that has a concentration of 0.05 M in H2SO4.

(A) 40 ml
(B) 50 ml
(C) 200 ml
(D) 100 ml

12) Arrange in decreasing order of reactivity with HCl

(A) IV > III > II > I

(B) III > IV > II > I
(C) IV > II > III > I
(D) III > II > I > IV

13)

Reaction of one molecule of HBr with one molecule of 1, 3-butadiene at 40°C gives predominantly:

(A) 1-Bromo-2-butene under kinetically controlled conditions

(B) 3-Bromobutene under thermodynamically controlled conditions
(C) 1-Bromo-2-butene under thermodynamically controlled conditions
(D) 3-Bromobutene under kinetically controlled conditions

14)

A is:

Product A
(A)

(B)

(C)

(D)

15) The major product in the following reaction

(A)

(B)

(C)

(D)

16) Which of the following compound do not undergo substituion by SN1 as well as SN2 mechanism
(A)

(B)

(C) CH3–O–CH2–Cl

(D)

17) Which of the following is/are incorrect?

(A)
(Rate of SN1)

(B)
(Rate of SN2)

(C)
(Rate of electrophilic addition reaction)

(D)

(Rate of dehydration of alcohol)

18) An SN2 reaction at an asymmetrical carbon of a compound always gives :

(A) enantiomer of the substrate

(B) a product with opposite optical rotation
(C) a mixture of diastereomeres
(D) a single stereo isomers

19) reactivity of the following halides. (i)

(ii)
(iii)
(iv) will be in the order

(A) i > iv > ii > iii

(B) ii > i > iii > iv
(C) i > iii > ii > iv
(D) iii > ii > i > iv

20) Identify correct nucleophilicity order in PPS

(A) (i) > (ii) > (iii)

(B) (ii) > (iii) > (i)
(C) (i) > (iii) > (ii)
(D) (iii) > (ii) > (i)

SECTION - II

1) Given :
X(g) —→ 3Y(g)
Pt = 400 mmHg : Total pressure after time 70 min
P∞ = 600 mmHg : Total pressure after completion
t0.75 = 2 × t0.5
Calculate rate constant of appearance of Y in minute–1 -
given ln2 = 0.7

2)

For reaction A→B, the rate constant and for the reaction X→Y, the rate constant
. If A1 = 109, A2 = 1010, = 1200 cal/mol and = 1800 cal/mol, then

temperature at which k1 = k2 is K. Find . (Given : R = 2 cal/K-mol)

3) How many 1, 2 shift of carbocation intermediate involved during the reaction :

4) How many of the following can decolourize bromine water

5) Number of grams of bromine that will completely react with 5.0g of pent-1-ene is _______ × 10–2g.
(Atomic mass of Br = 80 g/mol) [Nearest Integer)

MATHEMATICS

SECTION - I

1) tan–1 =

(A)

(B)

(C)

(D) does not exist

2) is equal to

(A) 1
(B) –1
(C) 0
(D) does not exist

3) =, where [.] denotes the greatest integer function

(A) 0
(B) 1
(C) 2
(D) 3

4) =

(A)

(B) 1
(C) –1
(D) 2

5)
If , then x is equal to

(A) 1
(B) 0

(C)

(D)

6) is equal to

(A) e
(B) e2
(C) e–1
(D) e–2

7) is equal to

(A) 1
(B) 2
(C) e2
(D) e

8) is equal to

(A) e4
(B) e–4
(C) e2
(D) none of these

9) is equal to

(A) 1
(B) –1
(C) 2
(D) 0

10) is
(A) 0
(B) does not exist
(C) 1
(D) –1

11) The range of the function ƒ(x) = sin–1(log2(–x2 + 2x + 3)) is -

(A)

(B)

(C)

(D) [–1, 1]

12) If then x is equal to

(A) 1
(B) -1

(C)

(D)
–

13) The value of is

(A) 1
(B) -1
(C) 0
(D) None of these

14) If x takes negative permissible value, then

(A)
(B)
(C)
(D)

15) has the value equal to

(A) 1
(B) -1
(C)

(D) 0

16) The value of is :-

(A)

(B)

(C)

(D)

17) The expression simplifies to -

(A) (1 + cos2 x)
(B) sin2 x
(C) – (1 + cos2 x)
(D) cos2x

18) If and then:

(A) A + B = 0
(B) 2A + B = 0
(C) A + 2B = 0
(D) A = B

19) Range of function is:

(A)

(B)

(C)

(D)

20)
If in a triangle ABC, (usual notation) (a + b + c)(b + c – a) = k. b c, then :

(A) k < 0
(B) k > 6
(C) 0 < k < 4
(D) k > 4

SECTION - II

1) In a ΔABC if medians from B and C are perpendicular then the minimum value of 3(cotB + cotC) is

2) In a ΔABC, if a, b, c are in arithmetic progression and sin2C + sin2B + sin2A + sin2B = 2,

then the value of cosecB is equal to (Note : All symbols have usual meaning for ΔABC)

3)

Value of is then k is

4) If the sum of the series is equal

to

a2cosec2ax – ,a∈ , then the value of 'a' is

5) is equal to ____.
 ANSWER KEYS

PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C D D C C B B D C C B C D A A C D B C D

SECTION - II

Q. 21 22 23 24 25
A. 72.00 8.00 2.00 90.00 67.00

CHEMISTRY

SECTION - I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B B A C B C A D A D B C B A D A D D D

SECTION - II

Q. 46 47 48 49 50
A. 0.03 3.00 3.00 4.00 1143.00

MATHEMATICS

SECTION - I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D B A B D C C A A A A D A B B D B D C C

SECTION - II

Q. 71 72 73 74 75
A. 2.00 2.00 3.00 2.00 1.00
 SOLUTIONS

PHYSICS

1) Heat given by container and water = heat gained by Ice

100 × 1 × 40 + 200 × 1 × 10

= 200 × × 20 + m × 80
(Let 'm' gm ice melts)
m = 50 gm
∴ Total water = 150 gm

2) r =
one having lowest 'r' have highest conduction.

3) = σAT4 = σ.4πR2.T4

4) New Ans. (D) By Hemant Sahu Sir

5)

to dissolve all ice we need latent heat = mL = 10 × 80

= 800
but water can give = msΔt amount if energy = 10 × 20 × 1
= 200
so all ice cannot dissolve and final temperature is 0°C

6)

7)

sx = uxt
1=2×t
vy = uy + ayt

vy = 0 + 8 ×
vy = 4 m/s

8) The potential at centre of sphere in which q charge is uniformly distributed throughout the

volume is by symmetry the potential at centre due to half sphere will be half of
the complete sphere.

9) Note: Dipole will rotate about COM but no option is matching with this calculation.
If we assume dipole to oscillate about midpoint

10)

Energy stored
Energy stored

11)

12)

13) g' = g – ω2Rcos230° = 0

14) By applying conservation of energy

KEi + PEi = KEf + PEf

15)

4E =

16)

From kepler's 2nd law

= constant
Thus ABC, area concept is more ⇒ more time

0
17) i =
P0 = 50 W

iT =

i2 = 7 × = 4.2 A
P = 4.22 × 2 = 35.28 W. ΔP = 14.72 W

18) Wheatstone bridge

2R = 8
⇒ R = 4Ω

19)

i = ne AVd

20)

Let resistance of each bulb is R

In 1st case, power consumed =

In 2nd case,

So, power consumed by all bulb =

21)

22)

(R + 900 × 103) × 8 × 106 = 10 × R × 900 × 103

R = 72 × 105 m ⇒ 7200 km

23)

Since α > β, field due to upper part of the line charge will be greater than field due to lower
part. So vertical component will be in – direction and horizontal component for both the parts
is in ( ) direction. So resultant will be in direction.
 24) = 30dx – 20dy

⇒V = (30x)05–(20y)03 = 150 – 60 = 90 volt

25)
T = 66.67°C

CHEMISTRY

29)

Ans. (A)
A is the correct answer

30)

Ans. (C)
C is the correct answer

31)

T2 = 304.92 K
(T2 – T1)B = 4.92 K

33)

(P) A process carried out infinitesimally slowly is called reversible process

(Q) A process in which no heat enters or leaves the system is called adiabatic process
(R) A process carried out at constant temperature is called isothermal process
(S) In a cyclic process, state function have no change in their value. So, ΔU = 0

34)

K : x=3×2 =6
Mn : x=y=6
35)

Ans. (A)
A is the correct answer

36) H2SO4 + 2NaOH → Na2SO4 + 2H2O

0.1 × V 50 × 0.1 – –
0.1 × V – 2.5 5 – 5 2.5 5

= 0.05
0.1 V – 2.5 = 0.05 V + 0.05 × 50
(0.1 – 0.05)V = 2.5 + 2.5

V= = 100 ml

37) Reaction is taking place at alkene double bond in all the cases because alkene double bond
is more reactive than aromatic ring. If a (+ M) group is attached to alkene double bond, then
reactivity increases whereas if a (–M) group is attached, then reactivity decreases. Hence,
order is III > IV > II > I.

38)

Ans. (C)
C is the correct answer

39)

Ans. (B)
B is the correct answer

40)
Oxymercuration – Demercuration
Addition of H2O
Markovnikov’s addition without rearrangement

41)

Ans. (D)
D is the correct answer

42)

Ans. (A)
A is the correct answer
43)

Ans. (D)
D is the correct answer

44)

Ans. (D)
D is the correct answer

45)
In group top to bottom nucleophilicity increase.
So (D) (iii) > (ii) > (i)

46)

Reaction belongs to first order kinitcs

X(g) —→ 3Y(g)
0
P 0
0
P –P 3P Pt
0 0
3P = 600 ⇒ P = 200
0
P – P + 3P = Pt = 100

Kx =
KY = 3 × Kx = 3 × 0.01 = 0.03 min–1

48)

49)

Ans. (4.00)
 50)
moles of Br2 = moles of C5H10

= 11.428 g

MATHEMATICS

52)

apply L' Hopital :

53)
= [sin1] = 0

55)

56)

57)

58)

Do Yourself.

59)
Ans. (A)
A is the correct answer

61) ⇒

62)

Ans. (D)
D is the correct answer

63)

64) takes -ive permissible value.

65)

66)

Ans. (D)
D is the correct answer

67)

68)
Ans. (D)
D is the correct answer

69)

Ans. (C)
C is the correct answer

70)

∵ (a + b + c) (b + c – a) = kbc
⇒ (b + c)2 – a2 = kbc
b2 + c2 – a2 = (k – 2)bc

∵ In a ∆ABC
–1 < cos A < 1

0 < k < 4.

71)

tanB = tan(B1 + B2)

tanB

Similarly

72) 2b = a + c (Given)
73)

Ans. (3.00)

74) Use tanθ = cotθ – 2 cot2θ

Now differentiate w.r.t x

= 4 cosec22x –
⇒a=2

75)