Q 1. The standard entropies of CO2 (g), C(s) and O 2 (g) are 213.5, 5.690 and 205 JK–1 respectively.

The standard entropy of formation of CO2 (g) is

(A) 1.86 JK–1 (B) 1.96 JK–1 (C) 2.81 JK–1 (D) 2.86 JK–1

Q 2. For a reaction at 25°C enthalpy change and entropy change are – 11.7×103 J mol–1 and
− 105J mol −1K −1 respectively, what is the Gibb's free energy.

(A) 15.05 kJ (B) 19.59 kJ (C) 2.55 kJ (D) 22.55 kJ

1
Q 3. For reaction Ag 2 O(s) → 2Ag(s) + O 2 (g) the value of H = 30.56kJ mol −1 and
2
S = 0.066kJ mol −1 K −1. Temperature at which free energy change for reaction will be zero is

(A) 373 K (B) 413 K (C) 463 K (D) 493 K

Q 4. The free energy change for the following reactions are given below
5
C 2H2 (g) + O 2 (g) → 2CO 2 (g) + H2 O(l) ; Go = −1234kJ
2
1
C(s) + O 2 (g) → CO 2 (g); G o = −394kJ H2 (g) + O 2 (g) → H2 O (l); Go = −237kJ
2
What is the standard free energy change for the reaction H2 (g) + 2C(s) → C2H2 (g)

(A) – 209 kJ (B) – 2259 kJ (C) +2259 kJ (D) 209 kJ

Q 5. Calculate the free energy per mole when liquid water boils against 1 atm pressure
( Hvap = 2.0723 kJ / g)

(A) 0 (B) 0.2 (C) 0.3 (D) 0.4

Q 6. The heat of formations of CO(g) and CO2 (g) are –26.4 kcal and −94.0 kcal respectively. The
heat of combustion of carbon monoxide will be

(A) + 26.4 kcal (B) – 67.6 kcal (C) –120.6 kcal (D) + 52.8 kcal

Q 7. Reaction H2 (g) + I2 (g) → 2HI(g); H = −12.40 kcal . According to this, the heat of formation of HI
will be

(A) 12.4 kcal (B) –12.4 kcal (C) –6.20 kcal (D) 6.20 kcal
Q 8. C(diamond) + O 2 (g) → CO2 (g); H = − 395 kJ C ( graphite) + O 2 (g) → CO 2 (g); H = − 393.5 kJ
From the data, the H when diamond is formed from graphite is

(A) –1.5kJ (B) + 1.5kJ (C) +3.0kJ (D) –3.0kJ

Q 9. The enthalpy of combustion of benzene from the following data will be

(i) 6C(s) + 3H2 (g) → C6H6 (l); H = + 45.9 kJ
1
(ii) H2 (g) + O 2 (g) → H2 O(l); H = −285.9 kJ
2
(iii) C(s) + O2 (g) → CO2 (g); H = − 393.5 kJ

(A) + 3172.8 kJ (B) –1549.2 kJ (C) –3172.8 kJ (D) –3264.6 kJ

Q 10. The enthalpy of formation of H2O(l) is – 285.77 kJ mol–1 and enthalpy of neutralisation of strong
acid and strong base is –56.07 kJ mol–1, what is the enthalpy of formation of OH – ion

(A) + 229.70kJ (B) –229.70kJ (C) +226.70kJ (D) –22.670kJ

Q 11. The heat of combustion of glucose is given by C6H12O6 + 6O2 → 6CO2 + 6H2O ; H = −2840 kJ .
Which of the following energy is required for the production of .18 gm of glucose by the reverse
reaction.

(A) 28.40 kJ (B) 2.84 kJ (C) 5.68 kJ (D) 56.8 kJ

Q 12. One gram sample of NH4NO3 is decomposed in a bomb calorimeter. The temperature of the
calorimeter increases by 6.12K. The heat capacity of the system is 1.23kJ/g/deg. What is the
molar heat of decomposition for NH4NO3 .

(A) – 7.53 kJ/mole (B) – 398.1kJ / mole (C) −16.1kJ / mole (D) −602 kJ / mole

Q 13. If H0f for H2O2 and H2O are – 188kJ/mole and −286kJ / mole . What will be the enthalpy
change of the reaction 2H2O2 (l) → 2H2O(l) + O2 (g)

(A) −196 kJ / mole (B) 146 kJ / mole (C) −494 kJ / mole (D) −98 kJ / mole

Q 14. The heat of combustion of carbon is –94 kcal at 1 atm pressure. The intrinsic energy of CO2 is

(A) + 94 kcal (B) –94 kcal (C) + 47 kcal (D) –47 kcal

Q 15. If enthalpies of methane and ethane are respectively 320 and 360 calories then the bond energy
of C – C bond is

(a) 80 calories (b) 40 calories (c) 60 calories (d) – 120 calories

Q 16. Given that C(g) + 4H(g) → CH4 (g); H = −166 kJ . The bond energy C − H will be

(A) 208 kJ/mol (B) – 41.5 kJ/mol (C) 832 kJ/mol (D) None of these

Q 17. If at 298K the bond energies of C − H,C − C,C = C and H − H bonds are respectively 414, 347,
615 and 435 kJ mol–1, the value of enthalpy change for the reaction
H2C = CH2 (g) + H2 (g) → H3C − CH3 (g) at 298 K will be

(a) + 250 kJ (b) –250 kJ (c) + 125 kJ (d) – 125 Kj

Q 18. What is enthalpy change of the following reaction

CH2 = CH2 + H2(g) ⎯→ CH3 – CH3

Given, C – H, C – C, C = C, H – H are 414, 347, 615 & 435 kJ mole–1 respectively.

(A) – 100 kJ (B) – 125 kJ

(C) – 150 kJ (D) – 175 kJ

Q 19. What is average S-F bond energy in SF6  given Hf of SF6(g) S(g) & F(g) are – 1100, 275 & 80

kJ mole–1 respectively

(A) 520 kJ (B) 401 kJ (C) 309 kJ (D) 254 kJ

Q 20. The heat of reaction for N2 + 3H2 ⎯→ 2NH3 at 27C is – 91.94 kJ. What will be its value at

50C The molar heat capacities at constant P & 27C for N2, H2 and NH3 are 28.45, 28.32

& 37.07s J respectively.

(A) – 92.843kJ (B) – 47.7723 kJ

(C) –132.5 kJ (D) –176.114 kJ

Q 21. Given Hionisation (HCN) = 45.2 kJ mole–1 & Hionization (CH3CO2H) = 2.1 kJ mole–1 which of the

following statement is correct?

(A) pKa(HCN) = pKa(CH3CO2H) (B) pKa(HCN)  pKa(CH3CO2H)

45.17
(C) pKa(HCN)  pKa(CH3CO2H) (D) pKa(HCN) = pKa(CH3CO2H)
2.07

Q 22. If H2(g) 2H(g) H = 104 kcals the Then heat of atomisation of H2 is

(A) 52 kcals (B) 104kcals

(C) 20 kcals (D) none of these

Q 23. At 298 k in a constant volume calorimeter, 0.01 mole of TNT was detonated when 8180

cals of heat was released. Each mole of TNT gives 6 moles of gaseous products on

detonation. What is H/mole of TNT exploded?

(A) – 714 kcals mole–1 (B) – 814 kcals mole–1

(C) –914 kcals mole–1 (D) none of these

Q 24. The latent heat of vaporisation of Br2 at 59C at 1 atm is 29.2 kJ mole–1. E (energy change

at constant volume) of this process is

(A) 25 kJ (B) 50 kJ (C) 75 kJ (D) none of these

Q 25. The H – H bond energy is 430 kJ mole–1 & Cl – Cl bond energy is 240 kJ mole–1. (H)f for

HCl is – 90kJ. The H – Cl bond energy is about

(A) 425 kJ mole–1 (B) 213 kJ mole–1

(C) 360 kJ mole–1 (D) 180 kJ mole–1

1. 2. 3. 4. 5. 6. 7.

C B C D A A B

8. 9. 10. 11. 12. 13. 14. 15. 16. 17.

B D B B A A B D B D

18. 19. 20.

C B D
21. 22. 23. 24. 25.

B A B D A