Refrigerant Oil Basics

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27 July 2022

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By July 27, 2022

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First, here's a quick summary of the role of oil in the refrigerant circuit:

The compressor requires oil for the lubrication of the moving parts in the compressor. We
would keep 100% of the oil in the compressor if we could. However, that is generally
unrealistic. So, we need to utilize oils and oil strategies that will circulate the oil through the
system and return it to the compressor where it belongs regularly and continuously.

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There are components called oil separators that can strip most of the oil from the discharge
gas and return the oil to the compressor; these are often used on larger systems, and they
are still less than 100% effective by themselves.

In VERY large systems, such as chillers, we are beginning to see oilless technologies with
magnetic bearings like TurboCor from Danfoss (shown above), but these are still pretty rare
in the field.

So, we are left with circulating oil through the system and returning it to the compressor as a
regular part of A/C and refrigeration system operation under normal running conditions.

First, let's cover the oil considerations a service tech can easily diagnose and impact.

Technician Considerations

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We are tasked with preventing liquid refrigerant from entering the compressor, which can
cause more rapid and potentially catastrophic oil loss. This condition is called “flooding,” and
it can occur while the system is running when the refrigerant superheat is allowed to stay at
zero as it enters the compressor; zero superheat indicates the presence of liquid refrigerant
mixed with the suction vapor.

A flooded start occurs during startup when liquid refrigerant is allowed to collect in the
compressor, suction line, or even in the evaporator. These conditions can cause oil loss from
the compressor and oil dilution, resulting in rapid compressor wear.

Preventing flooding is a significant part of oil management. It involves setting superheat

Another factor in lubrication is oil breakdown, which can occur at high temperatures. We
should consistently monitor discharge temperatures exiting the compressor to avoid
breakdown. The discharge line temperature shouldn't exceed 225°, equating to around 300°
at the compressor discharge valves (on a reciprocating compressor). Monitoring discharge

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pressures will help ensure that the oil doesn't break down and “carbonize.” Now, that
temperature varies based on the compressor type, system, and oil type. However, 225° is a
generally accepted rule in the absence of a more detailed guideline.

On a properly functioning compressor, the mass flow rate (amount of refrigerant moving
through the compressor) and the suction gas temperature are the primary factors that impact
compressor discharge temperature. Often, high discharge temperatures occur when the
suction pressure is low, superheat is low, and the compression ratio is high (high head
pressure, low suction pressure). It also occurs when there is some combination of those
issues.

Oil Return

Once the oil has left the compressor, it must circulate through the system and return to the
compressor crankcase, and there are a few key factors that impact oil return:

1. Oil/refrigerant miscibility (how well the oil mixes and moves with the refrigerant)
2. Oil viscosity (oil thickness)
3. Refrigerant velocity throughout the circuit

The oil being utilized should be suited to the refrigerant type and of the proper viscosity for
the compressor and the temperature application. Refrigerant velocity should be maintained
according to manufacturer recommendations. Low velocity will primarily be an issue in
evaporator coils and suction lines when the suction pressure is lower than design due to
improper tubing sizing, low evaporator load, metering device underfeeding, or undercharge.

Oil Quantity

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Keep in mind that systems will need more oil when they have longer refrigerant lines and
larger evaporators; more oil will be out in the “circuit,” meaning the system will need to
contain more total oil. Technicians who work in “built-up” systems like market refrigeration
are very aware of this and take an active approach to managing oil. Residential and light
commercial HVAC techs may take the approach that it's the “manufacturer's job” to ship the
system with the correct amount of oil but may fail to read long-line guidelines that call for
more oil to be added.

On the other hand, too much oil can also lead to compressor issues and poor system
performance. That often occurs when a new compressor is installed with a new oil charge on
a system that previously had oil return issues. The new compressor will only add more oil to
the circuit, worsening the situation and leading to a reoccurring failure. That is why
diagnosing fully and finding WHY the old compressor failed is a huge part of the process so
that you can make some oil adjustments if an oil return issue was found and rectified.

Important Oil Terms

Miscibility – The ability of the oil to mix with and move with the refrigerant.

Viscosity – A measure of the oil’s flow resistance (how thick it is). Two units of measure are
used with refrigeration oil. The older measure is Saybolt Universal Seconds (SUS); the
newer is ISO viscosity grade number (ISO VG). In both cases, a higher number is a thicker
oil; just don't mix up the two standards.

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Hygroscopic – Many modern oils are hygroscopic, which means they attract and hold
moisture. It is very important to keep moisture away from hygroscopic oils to keep them from
becoming contaminated.

Hydrolysis – Decomposition due to a reaction with water. For example, POE oil
decomposes into acids and alcohol in the presence of water. Once it decomposes, it cannot
be reconstituted with line driers or evacuation.

Oil Types

Mineral – A product of gasoline production. Naphthene-based mineral oils are suitable for
refrigeration systems using CFC or HCFC refrigerants and have been the standard oils used
for generations. Mineral oil worked well with refrigerants that contained chlorine, but it's not
miscible with modern HFC and HFO refrigerants.

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Alkylbenzene (AB) – A synthetic oil suitable for refrigeration systems using CFC or HCFC
refrigerants. It is compatible with mineral oil. It has improved refrigerant miscibility at low-
temperature conditions compared to mineral oil, so it was often used with HCFC refrigerants
in commercial refrigeration.

Polyolester (POE) – The most common oil utilized in refrigeration and air conditioning
systems using HFC/HFO refrigerants. It is also suitable for systems using CFC or HCFC
refrigerants.

Polyvinyl Ether (PVE) – A synthetic oil used as an alternative to POE oil; it is very common
in ductless and VRF systems. It is more hygroscopic than POE oil, but PVE oil does not
undergo hydrolysis in the presence of water. While PVE will grab water more easily, it is
capable of being dehydrated again, unlike POE.

Polyalkylene Glycol (PAG) – A synthetic oil primarily used in automotive air conditioning
systems. It is more hygroscopic than either POE or PVE oils, but like PVE, it does not
undergo hydrolysis in the presence of water.

Refrigerant Piping for Oil Return

When oil does not return properly to the compressor, it can cause compressor wear and
decrease system performance by coating the inside of the evaporator tubing walls and
inhibiting heat transfer. It can even cause restrictions.

Especially with mineral and AB oils, it was very important to employ proper trapping
strategies according to the manufacturers and industry guidelines, such as THIS ONE FROM
RSES.

With newer oils like POE and PVE, these trapping and oil return strategies have become less
critical in high and medium-temperature applications due to the strong miscibility of the oil in
the refrigerant. As always, read and follow manufacturers' piping guidelines; the lower the
velocity, the more likely the oil is to have issues returning, especially in retrofit applications
where some mineral or AB may still be present with the POE or PVE oils.

One good practice to use when running long runs of horizontal piping is to pitch it back
towards the compressors. This is a common-sense practice, no matter the oil, refrigerant, or
application whenever possible.

Oil Mixing

When POE oils first gained common use, it was widely rumored that mixing POE and mineral
oil would result in “sludge.” This has been proven to be a myth. To some extent,
manufacturers of retrofit refrigerants have been suggesting adding small amounts of POE to

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mineral oil to help carry it through the system. It is always better to move to POE or PVE oils
from mineral oil when retrofitting to an HFC refrigerant, but small amounts of mineral oil have
proven to be rather inconsequential in most cases.

New Oil Considerations

One thing that has become clear with the advent of POE oil is the importance of proper
brazing practices (flowing nitrogen), proper deep evacuation, and keeping the oil away from
air and moisture during storage. Many poor practices that techs could get away with when
CFC/HCFC and mineral oil were in common use can result in DISASTER with modern
refrigerants and oils.

Keep the system clean and dry, and use the correct oil in the correct amounts. Keep the oil
from overheating, and keep the compressor from “throwing” oil by preventing flooding.
Maintain proper oil return through proper pipe sizing, pitching, and trapping (as required) and
by maintaining the appropriate design velocity of the refrigerant.

Easy.

—Bryan

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