28-12-2025

0999DJA161153250008 JA

PART-1 : PHYSICS

SECTION-I

1) The linear density of a non-uniform rod of length 2m is given by λ(x) = a(1 + bx2) where a and b
are constants and 0 ≤ x ≤ 2. The centre of mass of the rod will be at, x =

(A)

(B)

(C)

(D)

2) A rod of length ‘5m’ and mass ‘12 kg’ leans against the wall as shown. If end ‘A’ of rod is moving
with a velocity of 3 m/s and rod makes an angle of 37° with horizontal find kinetic energy of rod at

that instant :-

(A) 50 Joule
(B) 100 Joule
(C) 150 Joule
(D) 200 Joule

3) As shown, a wheel of weight W and radius 0.8 m is placed against a 0.3 m height rectangular
block fixed on the ground. The wheel has an axle of radius 0.1 m. A force F is applied tangentially to
the axle to lift the wheel. The minimum value of F is closest to :-
(A) 1.04 W
(B) 0.86 W
(C) 0.69 W
(D) 0.32 W

4) In the figure, there is a conducting wire having current i and which has a shape of half ellipse

is kept in a uniform magnetic field B as shown. If the mass of wire is m, the

acceleration of wire will be :

(A)

(B)

(C)

(D)

5) A positive charge particle having charge q and mass m has velocity in the magnetic

field at the origin. Its speed as the function of y is :-

(A)
(B)

(C)

(D) None of the above

6) A semicircular loop of radius R is rotated about its straight edge which divides the space into two
region one having a uniform magnetic field B and the other having no field. If initially the plane of
loop is perpendicular to (as shown), and if current flowing from O to A be taken as positive, the

correct plot of induced current v/s time for one time period is :-

(A)

(B)

(C)

(D)
7) A uniform magnetic field exists in circular region of radius R as shown which is decreasing with
time at a constant rate. There is a concentric wooden ring which have uniformly distributed charge
Q and radius 2R and another concentric uncharged copper ring of radius 3R, then select incorrect

alternative. (Assume rings are placed on frictionless surface) :-

(A) There is no induced current in wooden ring.

(B) Induced electric field in wooden ring is more in magnitude then copper ring.
(C) Induced electric field in copper ring is more in magnitude then wooden ring.
(D) Wooden ring will start rotating.

8) An arc lamp requires a direct current of 10 A at 80 V to function. If it is connected to a 220 V

(rms), 50 Hz AC supply, the series inductor needed for it to work is close to –

(A) 80 H
(B) 0.08 H
(C) 0.044 H
(D) 0.065 H

9) In the circuit shown in figure current in the circuit is : (R = 51.5 Ω)

(A) 1.27A
(B) 2.23 A
(C) 4.26 A
(D) 3.87A

10) A copper wire (Y =1 × 1011 N/m2) of length 8 m, and a steel wire (Y= 2 × 1011 N/m2) of length
4m, each of cross-section 0.5 cm2 are fastened end to end and stretched with a tension of 500 [Link]
elastic potential energy of the system is :-

(A) 0.125 J
(B) 0.2 J
(C) 0.25 J
(D) 0.5 J

11) A pendulum clock loses 12 s a day if the temperature is 40°C and gains 4 s a day if the
temperature is 20°C. The temperature at which the clock will show correct time, and the co-efficient
of linear expansion (α) of the metal of the pendulum shaft are respectively :

(A) 25°C; α = 1.85 × 10–5/°C

(B) 60°C; α = 1.85 × 10–4/°C
(C) 30°C; α = 1.85 × 10–3/°C
(D) 55°C; α = 1.85 × 10–2/°C

12) One mole of an ideal monoatomic gas is taken from A to C along the path ABC. The temperature
of the gas at A is 2T0. For the process ABC (where R is gas constant), which of the following is

wrong?

(A) Change in internal energy of gas is 9RT0

(B) Heat absorbed by the gas is 11RT0
(C) Work done by the gas is 2RT0

(D)
Heat absorbed by the gas is

13) Three Carnot engines operate in series between a heat source at a temperature T1 and a heat
sink at temperature T4 (see figure). There are two other reservoirs at temperature T2, and T3, as

shown, with T1 > T2 > T3 > T4 . The three engines are equally efficient if :
(A)

(B)

(C)

(D)

14) In the figure below, P and Q are two equally intense coherent sources emitting radiation of
wavelength 20 m. The separation between P and Q is 5 m and the phase of P is ahead of that of Q by
90°. A, B and C are three distinct points of observation, each equidistant from the midpoint of PQ.

The intensities of radiation at A, B, C will be in the ratio :-

(A) 0 : 1 : 2
(B) 4 : 1 : 0
(C) 0 : 1 : 4
(D) 2 : 1 : 0

15) In a Young's double slit experiment, the path different, at a certain point on the screen, between

two interfering waves is of wavelength. The ratio of the intensity at this point to that at the
centre of a brigth fringe is close to :-

(A) 0.94
(B) 0.74
(C) 0.85
(D) 0.80

16) The electric conductivity of an intrinsic semiconductor increases when the electromagnetic
waves of wavelength equal or shorter than 2475 nm is incident on it. The charge carrier
concentration of this semiconductor at room temperature is 1.6 × 1016 m–3 and the mobilities of
electrons and holes at the same temperature are 0.4 m2 V–1 s–1 and 0.2 m2 V–1 s–1 respectively. The
band gap of the semiconductor is :-

(A) 0.2 eV
(B) 0.5 eV
(C) 1.0 eV
(D) 1.5 eV

17) A student performs an experiment for determination of g , m, and he commits an

error of Δℓ. For T he takes the time of n oscillations with the stop watch of least count ΔT and he
commits a human error of 0.1 sec. For which of the following data, the measurement of g will be
most accurate?

(A) ΔL = 0.5, ΔT = 0.1, n = 20

(B) ΔL = 0.5, ΔT = 0.1, n = 50
(C) ΔL = 0.5, ΔT = 0.01, n = 20
(D) ΔL = 0.1, ΔT = 0.05, n = 50

18) An electron is constrained to move along the y-axis with a speed of 0.1 c (c is the speed of light)
in the presence of electromagnetic wave, whose electric field is
. The maximum magnetic force experienced by the
electron will be : (given c = 3 × 10 ms and electron charge = 1.6 × 10–19 C)
8 –1

(A) 1.6 × 10–19 N

(B) 4.8 × 10–19 N
(C) 3.2 × 10–18 N
(D) 2.4 × 10–18 N

19) A space 2.5 cm wide between two large plane surfaces is filled with oil. Force required to drag a
very thin plate of area 0.5 m2 just midway the surfaces at a speed of 0.5 m/sec is 1 N. The coefficient

of viscosity in kg-s/m2 is :

(A) 5 × 10–2
(B) 2.5 × 10–2
(C) 1 × 10–2
(D) 7.5 × 10–2

20) A container has two immiscible liquids of densities ρ1 and ρ2. A capillary tube of radius r is
inserted in the liquid so that its bottom reaches upto the denser liquid. The denser liquid rises in the
capillary and attains a height h from the interface of the liquids, which is equal to the column length
of the lighter liquid. Assuming angle of contact to be zero, the surface tension of heavier liquid is -

(A) 2πrρ2gh
(B)

(C)

(D) 2πr (ρ2 – ρ1) gh

SECTION-II

1) The frequency of oscillation of the system shown in the figure is then the value of (α +

β) is :-

2) A particle of mass 9.1 × 10–31 kg travels in a medium with a speed of 106 m/s and a photon of a
radiation of linear momentum 10–27 kg m/s travels in vacuum. The wavelength of photon is _______
times the wavelength of the particle.

3)

A radioactive substance decays to of its initial activity in 80 days. The half life of the
radioactive substance expressed in days is :-

4) An observer can see through a small hole on the side of a jar (radius 15 cm) at a point at height of
15 cm from the bottom (see figure). The hole is at a height of 45 cm. When the jar is filled with a
liquid up to a height of 30 cm the same observer can see the edge at the bottom of the jar. If the
refractive index of the liquid is N/100, where N is an integer, the value of N is :-

5) In a YDSE a parallel beam of light of wavelength 6000Å is incident on slits at angle of incidence
30°. A and B are two thin transparent films each of refractive index 1.5. Thickness of A is 20.4 µm.
Light coming through A and B have intensities I and 4I respectively on the screen. Intensity at point
O which is symmetric relative to the slits is 3I. The central maxima is above O. What is the maximum

thickness of B (in μm)?

PART-2 : CHEMISTRY

SECTION-I

1) SO32– and CO32– can be distinguished by

(A) CaCl2 solution

(B) Acidic KMnO4 solution
(C) H2O2 solution
(D) Both (A) & (B)

2) Which of the following statement is not correct ?

(A) Lu+3 has the strongest tendency toward complex formation among trivalent lanthanoid ions
(B) Ce has maximum composition in misch metal
0
(C) f-block elements can have electrons from f to f14
(D) Nd, Np and Nb all are f-block elements

3) In the following sequence of reactions ‘Z’ will be :

(A) Acetic acid

(B) Acetone
(C) Methyl amine
(D) Ethyl amine
4) (Q) in following sequence is :

(A)

(B)

(C)

(D)

5) The Difference in wavelength of first and last line of lyman series in emission spectrum of He+
would be :

(A)

(B)

(C)

(D)

6)

Kohlrausch's law states that at :

(A) For strong electrolyte, molar conductane varies linearly with concentration of electrolyte
Infinite dilution, each ion makes definite contribution to molar conductance of an electrolyte
(B)
whatever be the nature of the other ion of the electrolyte.
At all concentration, each ion makes definite contribution to molar conductance of an
(C)
electrolyte whatever be the nature of the other ion of the electrolyte.
(D) Molar conductance increases with decrease in concentration

7) When 'X' (purple colour compound) boiled with strong alkaline solution dark green colour
compound (Y) is formed. Product (Y) on addition of H2O show disproportionation reaction. Which of
the following is correct for 'X' & 'Y' ?
(A) 'Y' is stable in acidic medium
(B) X = MnO2 , Y = KMnO4
(C) During the formation of (Y), O2 is produced.
(D) Disproportionation of 'Y' only 'X' is formed

8)

Which of the following statement is INCORRECT ?

Ferric ions gives brown precipitate with NaOH solution, which is insoluble in excess of NaOH
(A)
solution
2+
(B) Cu ions gives brown ppt. with K4[Fe(CN)6] solution
(C) Ferric ions gives brown colouration with K3[Fe(CN)6] solution
(D) Ferrous ion gives blue ppt with K4[Fe(CN)6] solution

9)
Choose the incorrect option ?

(A) (S) is 4-bromoaniline

(B) (Q) is Acetanilide
(C) Basic strength order is : (Q) > (P) > (R)
(D) Preparation of R from Q is electrophilic substitution

10) E , E is -

(A)

(B)
(C)

(D)

11)

A solution of Pb (NO3)2 is added drop wise to a second solution in which

[Cl–] = [F–] = [I–] = [SO42] = 0.001 M. What is the first precipitate that forms ?

–5
(A) PbCl2(KSP = 1.5 × 10 )
–8
(B) PbF2[KSP = 3.7 × 10 ]
–9
(C) PbI2(Ksp = 8.5 × 10 )
–8
(D) PbSO4(KSP = 1.8 × 10 )

12)

The formation constant of is

(A)
(B)
(C)
(D)

13) A white sodium salt dissolves readily in water to give a solution which is neutral to litmus. When
silver nitrate solution is added to the solution, a white precipitate is obtained which does not
dissolve in dil. HNO3. The anion could be :-

(A)
(B) Cl–
(C)
(D) S2–

14) The compound that does not produce nitrogen gas by the thermal decomposition is

(A) (NH4)2Cr2O7
(B) NH4NO2
(C) (NH4)2SO4
(D) Ba(N3)2

15) Which of the following is an essential Amino acid :

(A) Aspartic acid (Asp)

(B) Glycine (Gly)
(C) Alanine (Ala)
(D) Phenylalanine(Phe)

16) Benzaldehyde and 3-pentanone can be distinguished by :

(A) 2,4 D.N.P.

(B) Fehling solution
(C) I2 + NaOH
(D) NaHSO3

17) In a photoelectric effect experiment photons of energy 5 eV are incident on metal surface. They
liberate electrons which are just stopped by an electrode at a potential of 3.5 V with respect to
metal. The work function of the metal surface in eV is -

(A) 5
(B) 3.5
(C) 1.5
(D) 7

18) Transition elements act as catalyst because -

(A) Their melting points are higher

(B) Their I.P. values are higher
(C) They have high density
(D) They can show variable oxidation states

19)
Choose the correct option ?

(A) (P) is benzoic acid

(B) (Q) is o-cresol
(C) Formation of (Q) is clemmesen reduction
(D) (P) can reduce Tollen's reagent

20) The final product is : Final product

(A)

(B)

(C)

(D)

SECTION-II

1) When an electric current is passed through acidified water, 112 mL of hydrogen gas at 1 atm &
0°C was collected at the catode in 965 seconds. The current passed, in ampere, is :

2) The specific conductance of 0.0025 M acetic acid is 5 × 10–5 S cm–1 at a certain temperature. The
dissociation constant of acetic acid is _______ × 10–7. (Nearest integer)
Consider limiting molar conductivity of CH3COOH as 400 S cm2 mol–1

3)

Conside the following reactions :

NaCl + K2Cr2O7 + H2SO4(Conc.) → (A) + Side products
(A) + NaOH → (B) + Side product
(B) + H2SO4(dilute) + H2O2 → (C) + Side product
The sum of the total number of atoms in one molecule each of (A), (B) and (C) is

4) In the given reaction The number of sp2 hybridised

carbon present in the product 'X' is _____.

5) Solubility of AgCN(Ksp = 10–12) in buffer of HA & A– having pH = 3 is s1 while in buffer of BOH &

BCl of pH = 13 is s2. Then calculate . [Given : (Kb)A– = 10–9]

PART-3 : MATHEMATICS

SECTION-I

1) If the differential equation representing the family of all circles touching x-axis at the origin is
 = g(x)y, then g(x) equals :

(A) 2x2
(B) 2x

(C)

(D)

2) Solution of differential equation

xdy + ydx = (xdy – ydx) is given by -
(where C is arbitrary constant)

(A)

(B)

(C)

(D)

3) Let for all x ∈ R–{0} such that y(1) = e – 1 then y(2) is equal to

(A) 4e – 7
(B) e2 + 3
(C) 4e + 7
(D) 4e2 – 4

4) Find the radius of circle which passes through three points (–1, 3), (2, 4) and (1, 7).

(A)
(B)
(C)
(D)

5) The range of radius of the circle x2 + y2–6x – 8y – sin2θ = 0 is (where θ ∈ R)

(A) [6,8]

(B)

(C)

(D)

6) Mr. X walk up 16 steps, going up either 1 or 2 steps at a time. There is an explosive material on
the 8th step so he cannot step there. The number of ways in which Mr. X can go up 16 steps is

(A) 441
(B) 420
(C) 462
(D) 400

7) If A and B are two events such that , , then is equal

to -

(A)

(B)

(C)

(D)

8) Sixteen players s1, s2 ,....., s16 play in a tournament. They are divided into eight pairs at random.
From each pair a winner is decided on the basis of a game played between the two players of the
pair. Assume that all the players are of equal strength. The probability that "exactly one of the two
players s1 & s2 is among the eight winners" is :

(A)

(B)

(C)

(D)

9) The relation R is defined on A = {1, 2, 3} by aRb if |a2 – b2| ≤ 5. Which of the following is false ?

(A) R = {(1, 1), (2, 2), (3, 3), (2, 1), (1, 2), (2, 3), (3, 2)}
(B) R–1 = R
(C) Domain of R = {1, 2, 3}
(D) Range of R = {5}

10) Vector equation of the line passing through (–1, 1, 3) and perpendicular to lines

and is :

(A)

(B)
(C)

(D)

11) If (1 + i) (1 + 2 i) (1 + 3 i) ......(1 + n i) = x + iy, then value of (2) (5) (10) ..... (1 + n2) is :

(A) x2 + y2
(B) x2 – y2
(C) x + y
(D) x – y

12) Let z1, z2, z3 are three complex number satisfying |z| = 1 and 4z3 = 3(z1 + z2), then |z1 – z2| is
equal to -

(A)

(B)

(C)

(D)

13) If focus and directrix of a parabola are (3, 5) and x + y = 4, then coordinates of its vertex are -

(A) (1, 3)
(B) (3, 4)
(C) (2, 4)
(D) data insufficient

14) If and then possible value of n is :

(A) 4
(B) 6
(C) 7
(D) 10

15) Two circles of radii 'a' & 'b' touching each other externally, are inscribed in the area bounded by

and the x-axis. If , then 4a is equal to

(A) 1

(B)

(C)
(D)

16) Let y(x) be a solution of . If y(0) = 2, then y equals :

(A) 2

(B)

(C)

(D) 3

17) A(0,2), B and C are points on parabola y2 = x + 4 and such that , then least positive
value of ordinate of C is -

(A) 3
(B) 4
(C) 1
(D) 2

18) The image of the line in the plane 3x – 3y + 10z = 26 is the line :

(A)

(B)

(C)

(D)

19) Let R be a relation defined as a R b if 1 + ab > 0. Then, the relation R is (a, b ∈ R)

(A) Reflexive
(B) Not symmetric
(C) Transitive
(D) None of these

20) The length of projection of the line segment joining the point (1,–1,0) and (–1,0,1) on the plane
2x + y + 6z = 1, is equal to-

(A)

(B)
(C)

(D)

SECTION-II

1) If α – β = π/2, then the chord joining the points whose eccentric angles are α and β of the ellipse

= 1 touches the ellipse where k is equal to ______.

2) Let P be a plane passing through the points (1, 0, 1), (1, –2, 1) and (0, 1, –2). Let a vector
be such that is parallel to the plane P, perpendicular to and

, then (α – β + γ)2 equals _______.

3) The area bounded by the parabola 4y = 3x2 and the straight line 2y = 3x + 12 is __.

4) A plane P passes through a point P(3, – 2, 1) and is perpendicular to the vector .

The distance between the plane P and the plane , equals

5) There are 10 pairs of shoes in a cupboard, from which 4 shoes are picked at random. If p is the
probability that there is at least one pair, find 323p.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A A D C D C D D C A D A D C B D B B C

SECTION-II

Q. 21 22 23 24 25
A. 7 910 20 158 120

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B D C B A B C D C B D A B C D D C D D B

SECTION-II

Q. 46 47 48 49 50
A. 1 66 18 8 1

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A D D D A D C D C A D C D A C B B A B

SECTION-II

Q. 71 72 73 74 75
A. 2 81 27 3 99
 SOLUTIONS

PART-1 : PHYSICS

1)

2)

KE =

IIOR = ICOM + Md2 = = 100

v = ωR
∴ 50 Joule

3)
mgRsinθ = F(0.6)

F = 1.04 W

4)

Clearly F = BIℓ = BI × (2b)

∴a=

5)

Along y

Net speed =

6)
 Emf induced when a loop rotates in a magnetic field is (e = Ns B ω sin ω t), which is a
sinusoidal function. Therefore, induced current will also be sinusoidal as shown :

The curve will be negative, because initially the flux decreases from
t = 0 to T/4

But from t = to , there will be no induced current as there is no field on the right side. Hence,

the current produced will be as shown : Hence (D).

7)

8)

(ωL)2 = 484 – 64 = 420

ωL =

L= = 0.065

9)

10)

T.E. = stress × strain × volume

also
∴T.E. = 0.25 J

11)
by solving
T = 25°C

12) (i) Work done by BC = 0

Work done by AB = PV0 = R(2T0)
(ii) Temperature at A = 2T0
Temperature at B = 4T0
(∵ volume get double)
Temperature at C = 8T0
(∵ pressure get double)
Heat absorbed = Heat absorbed A to B + Heat absorbed B to C
= nCPΔT+ nCVΔT

(iii)

13)

⇒ T2 = =
T3 =

T2 =

14) For (A)

xP – xQ = (d + 2.5) – (d – 2.5) = 5m

Δϕ due to path difference = =

At A, Q is ahead of P by path, as wave emitted by Q reaches before wave emitted by P.
Total phase difference at A
(due to P being ahead of Q by 90°) = 0

(due to P being ahead of Q by 90°) = 0

= 4I
For C
xQ – xP = 5 m
Δϕ due to path difference

Total phase difference at C =

=0
For B
xP – xQ = 0,
(Due to P being ahead of Q by 90°)

= 2I
IA : IB : IC = 4I : 2I : 0
=2:1:0
∴ correct option is (4)

15)

16) Question Explanation: Calculating the energy band gap from wavelength.
Concept: Semiconductor Band Gap
Since conductivity is increasing because of EM waves, energy of photon should be equal to
energy band gap.

Answer : (B)

17) Question Explanation: Find the data set for which the measurement of g will be most
accurate in a simple pendulum experiment.
Concept: Error analysis for simple pendulum

Solution: The formula for g is The fractional error in g is The error

in the time period T is given by For the measurement of g to be

most accurate, the fractional error should be minimum. This is achieved by minimizing the
errors in both length and time.

In option (4) error in Dg is minimum and number of repetition of measurement are maximum.
In this case the error in g is minimum.
Final Answer: The measurement of g will be most accurate for the data in option 4.

18) Question Explanation: Calculating maximum magnetic force on a charge.

Concept: Lorentz Force
Solution:-
⇒E=

⇒ B ⇒ E/V ⇒
⇒ 10–7 Tesla

⇒ Fmag = = |qVB|
= 1.6 × 10 × 0.1 × 3 × 108 × 10–7
–19

= 4.8 × 10–19 N
Final Answer:- Option (2)

19) Velocity gradient =

as force on the plate due to viscosity is from upper as well as lower portion of the oil, equal
from each part,

Then,

⇒ h = 2.5 × 10–2 kg – sec/m2

20) From A to B,

+ ρ2gh = ρ + ρ1gh ⇒ (ρ2 – ρ1) gh

0 0
P –

= ⇒T=

21)
= k + k + 3k = 5k
 22) For photon

For particle

23)
4 × t1/2 = 80
t1/2 = 20 days

24)

1 sin 45° = µ sin r

N = 100 µ
N = 158.11
So integer value of N = 15800

25)

Path difference = d cos 60°

As given at 0 the Intensity = 3I
3I = I + 4I + cosϕ

⇒ 0.1 × 10–3 + (20.4 – t)10–6

= 2/3 × 6000 × 10–10 = 4 × 10–7
⇒ t = 20.4 – 0.4 + 100 = 120 μm

PART-2 : CHEMISTRY

26) Explain the question : How can be distinguished for and ion.
Concept : This question is based on confirmatory test for .
Solution :
 → (no change)

27) Nb belongs to d - block.

28)

Explanation Question: Question is asking about the final product (Z) in the following
sequence of reaction.
Concept:

A. Oxidation of alcohol with KMnO4

B. Nucleophilic addition elimination reaction
C. Hofmann's bromamide reaction

Solution:

29)

Explanation Question: Question is asking to identify final product (Q) of the given reaction.
Concept: This question is based on carbylamine reaction and reduction by LiAlH4.
Solution:

30)

Explanation Question: Question is asking about difference in wavelength of first and last line
of Lyman series for H+.
Concept: This question is based on atomic line spectrum.
Solution:

Wave length =
Wave number for a line in spectrum

Z = 2 Lyman series n1 = 1
First line n2 = 2, last line n2 = ∞

⇒
So,

31) Kohlrausch's law states that at Infinite dilution, each ion makes definite contribution to
equivalent conductance of an electrolyte whatever be the nature of the other ion of the
electrolyte.

32)

Question Explanation: Analyzing the reactions of potassium permanganate and potassium

manganate.
Concept: Chemistry of Manganese Compounds.
Solution:

A. The purple compound 'X' is potassium permanganate (KMnO4​).

B. When boiled with a strong alkali (KOH), it forms the dark green compound 'Y', which is
potassium manganate (K2​MnO4​). During this reaction, oxygen gas is evolved. 4KMnO4
+4KOH→4K2​MnO4​+O2​+2H2​O

C. Potassium manganate ('Y') is only stable in alkaline solutions. In neutral or acidic water,
it disproportionates to form permanganate ('X') and manganese dioxide (MnO2​).
3K2​MnO4​ + 2H2​O → 2KMnO4​ + MnO2​ + 4KOH

D. Statement (C) is correct as oxygen is produced during the formation of (Y).

33) Question Explanation: Identifying the incorrect statement among qualitative tests for
some metal ions.
Concept: Qualitative Inorganic Analysis.
Ferrous ion gives white ppt with K4[Fe(CN)6]

34)

Explaining the Question :- Question is asking about the incorrect statement for kb order and
products of reaction.
Concept :- This Question is based on
(a) Acylation of aniline
(b) Bromination
(c) Hydrolysis
Solution :-
Basic strength (kb) order ⇒ P > S > Q > R

35)

Explanation Question: Question is asking about the final product (E) in given reaction
sequence.
Concept:

A. Trimerisation of acetylene

B. Friedel craft reaction

C. Electrophilic aromatic substitution (Sulphonation, Bromination and Desulphonation)

Solution:
Three molecules of acetylene trimerise to give benzene; Friedel–Crafts alkylation to give
isopropylbenzene; Sulphonation installs a temporary blocking group (–SO3H) to direct
bromination to the ortho position of isopropyl group; desulphonation then yields
o‑bromoisopropyl benzene.
36)
S S 2S
KSP < [I.P.] for PbSO4

37)

Explain Question:
Calculate formation constant of [(Ag(NH3)2]+
Concept:
Factors affecting equilibrium constant
Solution:
Ag+ + NH3 [Ag (NH3)]+ .....(1)
+
[Ag(NH3)] + NH3 [Ag(NH3)2]+ .....(2)
add eq. (1) and (2)
K = K1 . K2 = 1.6 × 103 × 6.8 × 103
K = 1.08 × 107

38) AgCl insoluble in

39) 1. (NH4)2 Cr2O7 + 4H2O

2. NH4NO2 N2 + 2H2O
3. (NH4)2SO4 2NH3 + H2SO4
4. Ba(N3)2 Ba+3N2
In reaction (3) NH3 is evolved where as in reaction 1, 2 and 4 N2 is evolved.

40) Explanation Question: Question is asking about essential amino acid.

Concept: This question is based on classification of amino acids.
Solution:
Essential amino acids are those that the human body cannot synthesize on its own and must be
obtained through diet. There are ten essential amino acids: Arginine, histidine, isoleucine,
leucine, lysine, methionine, phenylalanine. threonine, tryptophan and valine. These amino
acids are crucial for various bodily functions, including protein synthesis.
Phenylalanine(Phe) is the essential amino acid among the given options.

41) Question Explanation:

Distinction between Benzaldehyde & 3-Pentanone
Concept:
 Different behaviour of substrate with reagent.
Solution:

PhCHO H5C2–CO–C2H5
Reagent
Benzaldehyde 3-Pentanone

1. 2,4-DNP ✔ ✔

2. Fehling solution ✖ ✖

3. I2 + NaOH ✖ ✖

4. NaHSO3 ✔ ✖
NaHSO3 can be use to distinguish aldehyde and ethyl ketone, because both show different behaviour
with NaHSO3.

42)

Explanation Question:
Question is asking about work function of metal surface.
Concept:
This question is based on photo electric effect.
Solution:
E = W + KE
E = 5 eV
K.E. = stopping potential X charge
= (3.5 V) X (e)
= 3.5 eV
W = 5 – 3.5
=1.5 eV

43) Question Explanation: Explaining why transition elements are effective catalysts.
Concept: Catalysis by Transition Metals.
Solution: Transition metals are excellent catalysts primarily due to two properties:
Transition metals are effective catalyst because they can easily give and
take electrons from other molecules (Show’s variable oxidation state).
This is due to presence of incomplete (n – 1)d orbital.

44)
formation of Q is wolf-kishner reduction.

45)
46)

Concept - Faraday's law

Level - Easy
Cathode :

Number of moles of H2 gas

I=?
1 mole H2 gas produced 2 × 96500 C charge

mole H2 gas produced C charge

= 965 C charge
Q = It
965 = I × 965
I=1A

47)
Given k = 5 × 10–5 S cm–1
C = 0.0025 M

= 20 S cm2 mol–1

= 66 × 10–7

48) Question Explanation: Question is asking to find the total number of atoms in three
compounds formed in the chromyl chloride test sequence.
Concept: Chromyl Chloride Test and Stoichiometry.
Solution:
4NaCl + K2Cr2O7 + 6H2SO4
↓
2CrO2Cl2 + 4NaHSO4 + 2KHSO4 + 3H2O
(A)
CrO2Cl2 + 4 NaOH → Na2CrO4 + 2NaCl + 2H2O
(B)
Na2CrO4 + 2H2SO4 + 2H2O2
 ↓
CrO5 + 2NaHSO4 + 3H2O
(C)
A = CrO2Cl2
B = Na2CrO4
C = CrO5
Total atoms = 5+7+6=18.

49)

50)

s1 = 10–5M

PART-3 : MATHEMATICS

51) x2 + y2 + 2gx + 2fy + c = 0

It touches the x-axis at origin
⇒ c=0

⇒
⇒ g=0
x + y2 + 2fy = 0
2
... (1)
Differentiate w.r.t. x
2x + 2yy′ + 2fy′ = 0

(by using (1))

y′(x2 – y2) = 2xy

 ⇒ g(x) = 2x

52)

53)

put x = 1, y = e – 1 ⇒ c = 0
y = x2(ex – 1)

54) Points form a right angled triangle at (2, 4)

hence hypotaneous is (–1, 3) and (1, 7) ; length of diameter = = ; radius =

55)

56) No. of 1 steps = x, No. of 2 steps = y

x + 2y = 7

1,2,2,2, =
Total = 21 steps
Again from 9th to 16th steps
(total = 7 steps) we have
x + 2y = 7 (No. of ways = 21)
Total = 21 × 21 = 441

57) Given ,

∵
 Þ

∴ P(only A) , P(only B) = .

Now,

58) 7 players (leaving S1 & S2) out of 14 can be selected in 14C7 and the 8th player can be
chosen in two ways i.e. either s1 or s2. Hence the total ways = 14C7. 2

Therefore p =
Alternatively :
Let
E1 : S1 and S2 are in the same group
E2 : S1 and S2 are in the different group
E : exactly one of the two players S1 & S2 is among the eight winners.
E = (E∩E1) + (E∩E2)
P(E) = P(E∩E1) + P(E∩E2)
P(E) = P(E1).P(E/E1) + p(E2).P(E/E2) ....(1)

Now P(E1) = ;

P(E2) =

P(E) = ·P
(exactly one of either S1 & S2 wins)

59) Let a = 1
∴ |a2 – b2| ≤ 5 ⇒ |b2 – 1| ≤ 5 ⇒ b = 1, 2
Let a = 2
∴ |a2 – b2| ≤ 5 ⇒ |4 – b2| ≤ 5 ⇒ |b2 – 4| ≤ 5
⇒ b = 1, 2, 3
Let a = 3
∴ |a2 – b2| ≤ 5 ⇒ |9 – b2| ≤ 5 ⇒ |b2 – 9| ≤ 5
⇒ b = 2, 3
∴ R = {(1, 1), (1, 2), (2, 1), (2, 2), (2, 3), (3, 2), (3, 3)}
R–1 = {(y, x) : (x,y) ∈ R}
= {(1, 1), (2, 1), (1, 2), (2, 2), (3, 2), (2, 3), (3, 3)} = R
Domain or R = {x : (x, y) ∈ R} = {1, 2, 3}
Range of R = {y : (x, y) ∈ R} = {1, 2, 3}

60) dr of line

=
Hence vector equation of line is

61) (1 + i) (1 + 2i) (1 + 3i) ...... (1 + ni) = x + iy

So, (1 – i) (1 – 2i) (1 – 3i) ...... (1 – ni)
= x – iy Multiply both,
(1 + i) (1 – i) (1 + 2i) (1 – 2i) (1 + 3i)
(1 – 3i) ...... = x2 + y2
(2) (5) (10)......(1 + n2) = x2 + y2
So, (1) is correct

62)

63)
axis x – y = 1
x – y = –2
now foot of directrix z

x = 1, y = 3
v is mid point of x & z
so v(2, 4)

64)

= =

65)

C1C2 = a + b =

C1 is

C2 is now calculate.

66)

IF =
2 + sinx = t
cos x dx = dt

= e–ln t

2 cosec x + 1 = t
–2 cosec x cot x dx = dt
 =

y=
y(0) = 2
⇒ c=1

y=

67)

⇒
⇒ (t2 + 2)2 – 4(2t2 + 1) ≥ 0 (∵ t1 is real)
⇒
least positive value of t2 is 4.

68) (x, y, z) = (9λ + 1, –λ + 2, –3λ – 3)

(x, y, z) = (9λ + 4, –λ –1, 7 – 3λ)

69) Here solution R is reflexive since 1 + a × a > 0 ∀ real numbers a. It is symmetric since 1 +

ab > 0 ⇒ 1 + ba > 0. However R is not transitive : consider three real numbers and

–2. We have and Hence,

 But since 1 + 2(–2)

70)

AC = AB sin θ ,

71) The chord joining α and β is

= cos

= cos =

If =θ
then the equation of the chord is

cosθ + sinθ = 1
Hence, the chord touches the ellipse

=1

or =
Therefore, k = 2

72)

⇒ 3x – z – 2 = 0
 || to 3x – z – 2 = 0
⇒ .....(1)

⇒ α + 2β + 38 = 0 ..... (2)

⇒ α + β + 28 = 2 ..... (3)
on solving 1, 2 & 3
α = 1, β = –5, 8 = 3
So (α – β + 8) =

73)
The line intersects the parabola 4y = 3x2 in the points (–2, 3) and (4,12) (see fig.). Therefore

required area =

= + –

= (16 – 4) + 6(4 + 2) – (64 + 8)

74) Equation of the plane passing through the point P(3, – 2, 1) is

A(x – 3) + B(y + 2) + C(z – 1) = 0 ....(1)
equation (1) is perpendicular to

hence A = 4; B = 7 and C = – 4
hence equation of the plane is
4x + 7y – 4z + 6 = 0 ....(1)
given 4x + 7y – 4z + 33 = 0 ....(3)
∴ Distance between (2) and (3)

= = =3

75) That total number of ways of choosing 4 shoes (in order) out of 10 pairs (or 20 shoes) is 20
× 19 × 18 × 17. The number of ways in which no pair is selected is 20 × 18 × 16 × 14. Thus,
the probability of not getting a pair is:

Hence, the probability of getting at least one pair is :