17-08-2025

1803CJA101005250007 JM

PART-1 : PHYSICS

SECTION-I

1) The angle between the two vectors and is :-

(A) 0°
(B) 90°
(C) 180°
(D) None of these

2) If s = 2t3 + 3t2 + 2t + 8 then the time at which acceleration is zero, is :-

(A)

(B) t = 2

(C)

(D) Never

3)

(A) 4
(B) –16
(C) 8
(D) 14

4) y = 12x – x3. Find x for which .

(A) –2
(B) –3

(C)

(D) None of these

5) If the resultant of two force of magnitudes P & Q acting at angle of 60° is , then is :
(A)

(B)

(C)

(D)

6) If is a unit vector then c is :-

(A)
(B) 0.2
(C) 0.3
(D)

7) At what angle two forces 2 F and should act, so that the resultant force is ?

(A) 45°
(B) 60°
(C) 120°
(D) 90°

8) The displacement vector of the particle if it moves from A(3, 4, 5) to B(4, 5, 6) is :

(A)
(B)
(C)
(D)

9) Referring to a-t diagram, find the velocity of the particle at t = 20 s. Assume that the particle was
at the origin at t = 0 and was moving with a velocity of 10 m/s in –ve x-direction :-

(A) 20 m/s
(B) 22 m/s
(C) 18 m/s`
(D) 15 m/s

10) Which of the following graph represents particle moving with constant velocity :-
(A) A, B only
(B) A only
(C) C only
(D) A, B, C

11) The displacement - time graphs of two bodies A and B are OP and OQ respectively. If line PO and
QO are making 60° and 45° with time axis respectively, the ratio of the velocity of A to that of B is:

(A)
(B)
(C)
(D) 3 : 1

12) The displacement-time graph of a moving particle is shown in Fig. The instantaneous velocity of

the particle is negative at the point

(A) D
(B) F
(C) C
(D) E

13) Velocity of a particle varies with time as v = 4t. The displacement of particle between t = 2 to t
= 4 sec, is :-

(A) 12 m
(B) 36 m
(C) 24 m
(D) 6 m

14) A body falls freely from rest. It covers as much distance in the last second of its motion as
covered in the first three seconds. The body has fallen for a time of :

(A) 3 s
(B) 5 s
(C) 7 s
(D) 9 s

15) Brakes are applied at t = 0 in a car travelling with a speed of 72 km/hr which produces a
retardation of 5 m/s2. Displacement of car in 0 to 6 seconds is

(A) 30 m
(B) 20 m
(C) 40 m
(D) 50 m

16) A balloon is moving along with constant upward acceleration of 1 m/s2. A stone is thrown from
the balloon downwards with speed 40 m/s with respect to the balloon. At the time of projection
balloon is at height 160 m from the ground and is moving upward with speed 20 m/s. The time

required to fall on the ground by the stone after the projection will be :

(A) 4 sec
(B) 5 sec
(C) 6 sec
(D) None of these

17) A car covers the first half of the distance between two places at 40 km/h and other half at 60
km/h. The average speed of the car is.

(A) 40 km/h
(B) 45 km/h
(C) 48 km/h
(D) 60 km/h

18) A particle starts with an initial velocity of 10.0ms–1 along x-direction and accelerates uniformly at
the rate of 2.0 ms–2. The time taken by the particle to reach the velocity of 60.0 ms–1 is______.

(A) 6s
(B) 3s
(C) 30s
(D) 25s

19) The position of a body with respect to time is given by x = 4t3 – 6t2 + 20t + 12. Acceleration at t
= 0 will be :-

(A) – 12 units
(B) 12 units
(C) 24 units
(D) – 24 units

20) A stone is thrown vertically upward with an initial speed u from the top of a tower, reaches the
ground with a speed 3u. The height of the tower is:

(A) 3 u2/g
(B) 4 u2/g
(C) 6 u2/g
(D) 9 u2/g

SECTION-II

1) If A = 5 units, B = 6 units and , then what is the angle between and (in degree) ?

2) A particle having initial velocity 10 m/s. If particle suffers a constant retardation of 2 m/s2, then in
how much time (in sec) velocity of particle will become zero.

3) A ball is projected with initial velocity of 15 m/s from a tower such that it travels a distance of 30
m in the last second of its motion then the height of the tower is - (Take g = 10 m/s2)

4) Figure shows the graph of speed versus time for a moving truck. What will be the distance

travelled by truck in the last two seconds ?

5) Velocity of a particle moving in x-y plane is given by v = – x3 + 2x2. Find its value of acceleration
at x = 2m :-

PART-2 : CHEMISTRY

SECTION-I

1) XeO3 has

(A) one pπ-pπ & two pπ-dπ bonds

(B) three pπ-pπ bonds
(C) four pπ-dπ bonds
(D) three pπ-dπ bonds

2) Molecule showing exception to lewis octet rule is

H2O,
(A)

(B) CO2, IF
(C) BCl3, XeF4
(D) PCl3, KCl

3) What is the bond ratio for the benzene molecule?

(A) 3
(B) 4

(C)

(D)

4) According to VBT, which of the following overlapping results π-type covalent bond in O2 molecule
formation, when Z-axis is internuclear axis?
(I) 2s – 2s (II) 2px – 2px
(III) 1s – 1s (IV) 2py – 2py
(V) 2pz – 2pz

(A) I, III
(B) II, V
(C) II, IV
(D) IV, V

5) The types of bond present in N2O5(g) are

(A) only covalent

(B) only ionic
(C) ionic and covalent
(D) covalent & coordinate

6) Which of the following molecule has co-ordinate bond in it's Lewis structure.

(A)
(B)
(C)
(D) HCN

7) The compound containing co-ordinate bond is

(A) O3
(B) SO3
(C) H2SO4
(D) All of these

8) One of the resonating structure of is :

Which set of average formal charge on oxygen and bond order is correct ?

(A) –0.5 and 1.5

(B) –1.5 and 3
(C) –2 and 3
(D) –1.5 and 1.5

9) Nitrogen does not form NF5 because :

(A) Nitrogen is member of V group

(B) It contains no empty d-orbital
(C) The bond energy of N ≡ N is very high
(D) Fluorine is highly electronegative

10) Which of the following compound is formed in the second excitation state of sulphur atom ?

(A) SF4
(B) SF6
(C) SF2
(D) None
11) Consider the following statements : I. A sigma (σ) bond is formed when two s-orbitals overlap II.
A pi(π) bond is formed when two p-orbitals axially overlap
III. A σ - bond is weaker than π - bond
Which of the above statements is/are correct ?

(A) I and II
(B) II and III
(C) I alone
(D) II alone

12) Which of the following compounds has four bond pair and one lone pair ?

(A)
(B)
(C)
(D)

13) A molecule which contains same number of σ and π–bonds is:

(A) HNO2
(B) HCN
(C) H2SO4
(D) HC ≡ CH

14) Pick out among the following species isoelectronic with CO2.

–
(A) N3
(B) (CNO)–
(C) (NCN)2–
(D) All of these

15) The maximum covalency is equal to

(A) the number of unpaired p-electrons

(B) the number of paired d-electrons
(C) the number of unpaired s and p-electrons
(D) total number of unpaired electron in ground state or in excited state

16) Calculate the total number of lone pairs in XeO3 molecule.

(A) 5
(B) 6
(C) 7
(D) 8

17) Which of the following statements is not correct ?

(A) Double bonds is shorter than a single bond
(B) σ – bond is weaker than a π bond
(C) Double bond is stronger than a single bond
(D) Covalent bond is stronger than a hydrogen bond

18) The weakest Cl –O bond found in:

(A)

(B)

(C)

(D)

19) Among the following element group number is not equals to valence electrons for :

(A) Na
(B) Ba
(C) Ne
(D) None

20) The number of electrons involved in the bond formation of N2 molecule

(A) 2
(B) 4
(C) 6
(D) 10

SECTION-II

1) The number of resonating structure in is ___.

2) Which of the following overlapping result π-bond when z is considered as internuclear axis.
(s – pz), (px – dxy), (pz – pz), (dxy – dxy), (dyz – dyz)

3) Total number of pπ-pπ and pπ-dπ bonds present in XeO4 is x and y respectively. Find (10x + y).

4) How many of the following species is/are superoctet molecule ? AlCl3, CH4, NH3, SF6, ClF3, BrF5,
XeO3, XeF2, ICl3, PCl3, SiCl4

5) The sum of σ-bonds, π-bonds and lone pairs (on S and O) in SO3-2 is ___.
 PART-3 : MATHEMATICS

SECTION-I

1) Given quadratic equation mx2 + (2m – 1)x + m – 1 = 0 has real roots of opposite sign, then range
of 'm' is -

(A) m ∈ ϕ
(B) m ∈ R
(C) –1 < m < 0
(D) 0 < m < 1

2)

Graph of y = ax2 + bx + c is given in the adjacent figure, then which of the following is correct -

(where α,β are the zeros of ax2 + bx + c)

(A) α + β > 0, αβ < 0
(B) b < 0, D < 0
(C) b > 0, D > 0
(D) α + β < 0, αβ < 0

3) If the equations x2 – 4x + 3 = 0 & x2 – (3k – 2)x + (k + 1) = 0 have a root common, then k is equal
to -

(A) 1 or 2
(B) 2 or 3
(C) 2
(D) 1

4) The complete set of values of k for which the roots of (k2 – k – 2)x2 – kx + 3 = 0 lie on either side of
unity is -

(A)
(B) (–1,2) – {1}
(C) [–1, 2]
(D) [–2, 1]

5) Number of real root of the equation x2 – 3|x| + 2 = 0 is/are –

(A) 1
(B) 2
(C) 3
(D) 4

6) If equation ax2 + bx + c = 0 ; (a, b, c ∈ R) and 2x2 + 3x + 4 = 0 have a common root then –

(A) a = 2 and b = 3 and c = 4

(B) a : b : c = 2 : 3 : 4
(C) a : b : c = 1 : : 1 : 1
(D) a + b + c = 9

7) The number of positive integral solutions of , is -

(A) 3
(B) 2
(C) 4
(D) 0

8) The value of a for which one root of the equation x2 – (a + 1) x + a2 + a – 8 = 0 exceeds 2 and
other is less than 2, is given by :

(A) 3 < a < 10

(B) a ≥ 10
(C) –2 < a < 3
(D) a ≤ – 2

9) The expression lies in the interval, (x ∈ R) :

(A) [– 1, 0]
(B) (– ∞, 0] ∪ [1, ∞)
(C) [0, 1)
(D) [0, 1]

10) Roots of the equation x2 + bx + c = 0,

where b > 0, c < 0 :

(A) Both roots are positive

(B) Both roots are negative
(C) One root is positive, other is negative and negative root has greater magnitude
(D) One root is positive, other negative and positive root has greater magnitude
11) If one root of the quadratic equation is then equation will be :

(A) x2 – 4x – 1 = 0
(B) x2 + 4x – 1 = 0
(C) x2 + 4x + 1 = 0
(D) None of these

12) The set of possible values of λ for which x2 – (λ2 – 5λ + 5) + (2λ2 – 3λ – 4) = 0 has roots, whose
sum and product are both less than 1, is

(A)

(B) (1, 4)

(C)

(D)

13) Sum of integral value(s) of 'm' for which both roots of x2 – 2mx + m2 – 1 = 0 will lie between –2
and 4

(A) 5
(B) 4
(C) 6
(D) 3

14) If , then

(A) x ∈ [2, 3]
(B) x ∈ ϕ
(C) x ∈ R
(D) x ∈ [–1, 0]

15) If α,β,γ are roots of the cubic equation x3 + 2x – 1 = 0 then value of (α + β) (β + γ) (γ + α) is

(A) 1
(B) –1
(C) 2
(D) –2

16) If sum of the roots of the equation (a + 1)x2 + (2a + 3)x + (3a + 4) = 0 is – 3, then the product of
the roots is

(A) 1
(B) 4
(C) 2
(D) – 2

17) If α β, but α2 = 5α – 3 and β2 = 5β – 3, then the equation whose roots are α/β and β/α is

(A) 3x2 – 25x + 3 = 0

(B) x2 + 5x – 3 = 0
(C) x2 – 5x + 3 = 0
(D) 3x2 – 19x + 3 = 0

18) If roots of quadratic equation ax2 + bx + c = 0 are non-real and 4a + c < 2b, then which of the
following is the graph of f(x)= ax2 + bx + c

(A)

(B)

(C)

(D)

19) For what values of p, the equation (p + 2)(p – 1)x2 + (p – 1) (2p + 1)x + p2 – 1 = 0 has more than
two roots.

(A) 1
(B) 2
(C) 3
(D) -5

20) Solution set of |x + 3| + |2x – 1| – |3x + 2| = 0

(A) x ∈ (–∞, –3) ∪ [1/2, ∞)

(B) x ∈ (–∞, –3) ∪ (1/2, ∞)
(C) x ∈ (–∞, –3] ∪ (1/2, ∞)
(D) x ∈ (–∞, –3] ∪ [1/2, ∞)

SECTION-II
1) Find the number of integral values of λ such that (λ2 + λ – 2)x2 + (λ + 2)x < 1 for all x ∈ R.

2) Find the number of integral values of x satisfying .

3) The values of λ such that sum of the squares of the roots of the quadratic equation,
x2 + (3 – λ) x + 2 = λ has the least value is :

4) If n(U) = 600, n(A) = 100, n(B) = 200 and n(A ∩ B) = 50, then is -
(U is universal set and A and B are subsets of U)

5) In a survey of 700 students in a college, 180 were listed as drinking Limca, 275 as drinking
Mirinda and 95 were listed as both drinking Limca as well as Mirinda. Find how many students
drinking neither Limca nor Mirinda?
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B D D A D D A C B B B D C B C A C D A B

SECTION-II

Q. 21 22 23 24 25
A. 60 5 50 20 0

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D C B C D B D A B B C C B D D C B C C C

SECTION-II

Q. 46 47 48 49 50
A. 4 1 4 6 13

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D D C B D B B C C C B D D B B B D D A D

SECTION-II

Q. 71 72 73 74 75
A. 2 3 2 350 340
 SOLUTIONS

PART-1 : PHYSICS

1) θ = cos–1 0, so θ = 90°

2)
a = 12t + 6 = 0

not (possible)

3)

4) y = 12x – x3

Hence points are (2,16) and (–2, –16).

5) R2 = P2 + Q2 + 2PQ cos 60

4x2 + 4x – 3 = 0
in solving, we get

x=

6) =1C=
7)

θ = 45°

8) Position vector of
Position vector of
Displacement vector

9)

Area of a-t graph = ΔV = Vf – Vi

32 = Vf – (– 10)
Vf = 22 m/s

10)

Slope of (x – t) graph in (A) is constant.

11) Tangent of displacement time graph gives velocity.

12) Tangent of displacement time graph gives velocity and slope is negative at point E.

13) ∵

= = = 2 (4)2 – 2 (2)2
= 32 – 8 = 24 m

14) u = 0
9 = 2t – 1
10 = 2t
t = 5 sec

15) 02 = (20)2 – 2(5)d7

d = 40 m

16) astone = –10 m/s2

ustone = –40 + 20 = –20 m/s2
x = –160 m

⇒ –160 = –20t – × 10t2

⇒ 32 = 4t + t2
t2 + 4t – 32 = 0
t2 + 8t – 4t – 32 = 0
⇒ t(t + 8) – 4(t + 8) = 0
t = 4 sec.

17)

18) v = u + at
60 = 10 + 2t
t = 25 sec.
Correct option (4)

19) V =

a= = 24t – 12
t = 0 ; a = –12 m/s2

20)
 21) AB sin θ = 15

sinθ =
θ = 30°

22) v = u + at
0 = 10 – 2 × t
t=5

23)

–45 = –5(2n – 1)
2n – 1 = 9
n = 5 sec

–h = 75 – 125
h = 50 m

24)

distance is area under v-t curve

25)

a= | at x = 2
=0

PART-2 : CHEMISTRY
26)

Question is Asking About :-

We have to find correct statement regarding XeO3.

Concept :-
Electronic configuration of Xe → 5S25b6

In Excited state →

3 pπ – d π bond

Hence, option (4) is correct.

27)

28)

29)
If Pz is INA then Bond formed by 2Pz -2Pz is sigma and remaining
2Px - 2Px & 2Py - 2Py
can either one form π-Bond.

30) In N₂O₅ (g), both covalent and coordinate covalent bonds are present. Specifically,
nitrogen and oxygen atoms are connected by covalent bonds, and there is also a coordinate
(dative) bond where one atom provides both electrons for the bond

31)

32) Co-ordinate bond is a special type of covalent bond which is formed by sharing of electrons
between two atoms, where both the electrons of the shared pair are contributed by one atom.
Since this type of sharing of electrons exits in O3, SO3 and H2SO4. Therefore all these contains
coordinate bond

33)
Charge on each oxygen = –0.5, because –2 charge is distributed on 4 oxygen.

34) Nitrogen does not contain vacant d-orbitals.

35)

36)

(I) Correct : Two s - orbitals on overlapping form σ – bond.

(II) Incorrect : Because axial overlap of two pi - orbitals form σ - bond.
(III) Incorrect : Because σ-bond is stronger than π - bond.

37)
38) (A) is incorrect because has 3 σ and 1 π bond.
(B) is correct beacause H — C ≡ N has 2 σ and 2 π bonds.

(C) is incorrect because has 6 σ and 2 π bonds.

(D) is incorrect because H — C ≡ C — H has 3 σ and 2 π bonds.

39) N3–, (CNO)– and (NCN)2– all have same number of electrons i.e., 22; So, all are isoelectronic
with CO2 which also has 22 electrons.

40) The covalency is decided according to number of unpaired electrons that are present in
ground state or can be created in excited state.

41)

42)

σ bonds are stronger than π bonds because of effective orbital overlapping along the
internuclear axis.
So, option (B) is incorrect.

43) Bond strength α Bond order

(C) → has smallest bond order so, (C) has weakest Cl — O bond.

44) Neon, valence electron 8, group number is 18.

45) In N2 molecule each Nitrogen atom contribute so total no. of electron’s are 6.
 46)

47)

If Z is internuclear axis then

Overlapping Type of bond
s – pz σ
px – dxy — (No overlapping)
pz – pz σ
dxy – dxy δ
dyz – dyz π

48)

49) AlCl3 = 6e– ; BrF5 = 12e–

CH4 = 8e–; XeO3 = 14e–
NH3 = 8e–; XeF2 = 10e–
SF6 = 12e–; ICl3 = 10e–
ClF3 = 10e–; PCl3 = 8e–
–
SiCl4 = 8e

50)
σ bonds = 3
π bonds = 1
lone pair = 8 +1
Total = 13

PART-3 : MATHEMATICS
 51)

Required condition is
m.ƒ(0) < 0, where ƒ(x) = mx2 + (2m–1)x + m–1
⇒ m(m – 1) < 0 ⇒ 0 < m < 1

52) It is obvious from figure that roots are of opposite sign but –ve root has greater magnitude

53)

x2 – 4x + 3 = 0 ...(1)
2
x – (3k – 2)x + (k + 1) = 0 ...(2)
subtracting (2) from (1)
(–6 + 3k)x + 2 – k = 0
(3x – 1) (k – 2) = 0

⇒ k = 2, (rejected)

if we put k = 2, we will get a root common.

54) (k2 – k – 2)ƒ(1) < 0

(k2 – k – 2)(k2 – 2k + 1) < 0
(k – 2)(k + 1)(k – 1)2 < 0

55) Let |x| = t

t2 – 3t + 2 = 0
⇒ t = 1 or t = 2
|x| = 1 or |x| = 2
⇒ x=±1 x=±2 No. of solution = 4

56) Root of 2x2 + 3x + 4 = 0 are imaginary (D < 0)

so both roots are same of both equations
so a : b : c = 2 : 3 : 4

57)

x = 0, 1, 3

58) As the roots are real and distinct

(a +1)2 – 4(a2 + a – 8) > 0
3a2 + 2a – 33 < 0
⇒ (3a + 11) (a – 3) < 0
⇒– <a<3 ...(1)

Also, for
22 – 2(a + 1) + a2 + a – 8 < 0
⇒ a2 – a – 6 < 0
⇒ (a – 3) (a + 2) < 0
⇒ –2 < a < 3 ...(2)
From (1) and (2), we get –2 < a < 3.

59) Let

⇒ y ∈ [0, 1)

60) Sum of roots = – b is –ve

and product of roots = c is –ve
so one root is +ve other is –ve & –ve root has greater magnitude.

61)

Hence,
= x2 + 4x – 1 = 0

62)

Sum of roots < 1

⇒ λ2 – 5λ + 5 < 1 ⇒ (λ – 1) (λ – 4) < 0 ⇒ 1 < λ < 4 ...(1)
2
⇒ Product of roots < 1 ⇒ 2λ – 3λ – 4 < 1

⇒ 2λ2 – 3λ – 5 < 0 ⇒ (2λ – 5) (λ + 1) < 0 ⇒ –1 < λ < ...(2)

(1) & (2) ⇒ 1 < λ < .

63) (x – m)2 = 1 ⇒ x = m ± 1

⇒ m ∈ (–1, 3)
64)

65) x3 + 0.x2 + 2x – 1 = 0
*α+β+γ=0 ....(1)
* αβγ = 1 ...(2)
∴ (α + β) (β + γ) (γ + α)
= (–γ) (–α) (–β) = –αβγ = –1

66)

α+β=–3

Hence, a = 0
Therefore, αβ = 4

67)

Hence, quadratic equation

x2 – 5x + 3 has root α & β

68)

f(x) = ax2 + bx + c
f(–2) < 0 and D < 0

69)

(p + 2)(p – 1)x2 + (p – 1) (2p + 1)x + p2 – 1 = 0 has more than two roots so

∵a=b=c=0

(p + 2)(p – 1) = 0 ⇒ p = –2, 1

(p – 1)(2p + 1) = 0 ⇒ p = 1, –
(p2 – 1) = 0 ⇒ p = 1, –1

70)

|a| + |b| = |a + b|
(x + 3) (2x – 1) ≥ 0

x ∈ (–∞, –3] ∪ [1/2, ∞]

71) and D < 0 for (λ2 + λ – 2)x2 + (λ + 2)x – 1 < 0 for all x ∈ R.
λ2 + λ – 2 < 0 ⇒ (–2, 1)

D<0⇒

Intersection of the above is

Therefore, – 1, 0 are the integer values.

72) and
and
Therefore, the inequality is valid for .
SOBS
– x2 + 10x – 16 < x2 + 4 – 4x
Hence,
The integers which satisfies the above inequalities is 6, 7, 8.

73) α + β = λ – 3
αβ = 2 – λ
α2 + β2 = (α + β)2 – 2αβ = (λ – 3)2 – 2(2 – λ)
= λ2 + 9 – 6λ – 4 + 2λ
= λ2 – 4λ + 5
= (λ – 2)2 + 1
∴ λ=2

74)
= n(u) – n(A ∪ B)
= 600 – (n(A) + n(B) – n(A ∩ B))
= 600 – 100 – 200 + 50
= 350

75)

n(L) = 180
n(M) = 275
Therefore,
= 700 – 360 = 340