CME110 Introduction to Chemical Engineering
Tutorial #10
(Energy Balances for Reactive Processes)
1) A gas mixture containing 55 mole % methane and the balance oxygen is charged at the rate
of 4500 standard (STP) litres per minute into an evacuated well-insulated reactor at 45 °C.
Formaldehyde will be produced in the following reaction:
𝐶𝐻4(𝑔) + 𝑂2(𝑔) → 𝐻𝐶𝐻𝑂 (𝑔) + 𝐻2𝑂 (𝑔)
A methane conversion of 53 % is achieved and the products emerge from the reactor at
350 °C.
a) Compute the outlet compositions (mole fraction) of the reactor.
b) Compute the amount of heat (kJ/s) that is added or removed from the reactor for the
oxidation process.
2) Ammonia is oxidized in a well-insulated continuous reactor with the following reaction:
4𝑁𝐻3(𝑔) + 5𝑂2(𝑔) → 4𝑁𝑂(𝑔) + 6𝐻2𝑂(𝑔)
The feed stream enters the reactor at 250°C, containing 4 mol/s of NH 3(g) and 6 mol/s of
O2(g). Ammonia completely consumed in the oxidation process.
a) Sketch a completely labelled process flow diagram for the reaction.
b) Compute the molar flow rate of all components (mol/s) in the product stream.
c) If the product stream temperature (Tout) is at 900 °C, interpret whether the cooling
capacity of a cooler at 600 kW in the reactor is sufficient to support the process.