10-08-2025

9610ZJA802322250002 JA

PART 1 : PHYSICS

SECTION-I (i)

1) If where F : force, r : distance, v : velocity and C & k are constants then dimension
of C is :-

(A) Dimensionless
(B) MLT–2
(C) ML2T–3
(D) ML2T–4

2) In an octagon ABCDEFGH of equal side, what is the sum of

if,

(A)
(B)
(C)
(D)

3) Three vectors and are shown in the figure. Let S be any point on the vector . The

distance between the points P and S is . The general relation among vectors and

(A)
(B)
(C)
(D)

4) Let us consider a system of unit in which units of length and force are dimensionless if mass has
dimension M which of the following is incorrect ? (Hint: power = force × velocity, angular
momentum = linear momentum × distance, linear momentum = mass × velocity)

(A) Dimension of velocity is .

(B) Dimension of acceleration is M–1.
(C) Dimension of power is .
(D) Angular momentum is dimensionless.

SECTION-I (ii)

1) The value of can be zero if :–

(A)

(B)

(C)

(D)

2) Let us consider a system of units in which mass and angular momentum are dimensionless. If
length has dimension of L, which of the following statement (s) is/are correct ?

(A) The dimension of force is L–3

(B) The dimension of energy is L–2
(C) The dimension of power is L–5
(D) The dimension of linear momentum is L–1

3) Which of the following is/are true statement?

(A) A vector cannot be divided by another vector.

(B) Dot product of two vectors is a scalar.
(C) Since addition of vectors is commutative therefore vector subtraction is also commutative.
The resultant of two equal forces of magnitude F acting at a point is F if the angle between the
(D)
two forces is 120º.

SECTION-II

1) In a new system of units, mass, acceleration & frequency are taken as fundamental units. If unit of
mass is 100 g, unit of acceleration is 2 m/s2 and unit of frequency is 4 sec–1, in this new system of
units, then the value of 10 J in this new system is K × 100. Fill K.
2) Length of a year on a planet is the duration in which it completes one revolution around the sun.
Assume path of the planet known as orbit to be circular with sun at the centre. The length T of a
year of a planet orbiting around the sun in circular orbit depends on universal gravitational constant
G, mass ms of the sun and radius r of the orbit. If , find value of .

3) The loss of pressure when a fluid flows through a pipe is given by P = k ρa ℓ Vb dc μ where d and ℓ
are diameter and length of the pipe respectively, ρ and μ are the mass density and coefficient of
viscosity of the fluid, V is the mean velocity of flow through the pipe and k is a numerical constant.
Write the value of (a + b – c).

4) According to Maxwell-distribution law, the probability function representing the ratio of

molecules at a particular velocity to the total number of molecules is given by

Where m is the mass of the molecule,

v is the velocity of the molecule,
T is the temperature
k and k1 are constants.
If the dimensional formulae of k1 is LaTbθc then find the value of a + b + c.

5) are vectors each having a unit magnitude. If , then

will be :-

6) If the angle between and is θ (0° < θ < 360°). The value of 'θ' will be
_________°.

SECTION-I (iii)

1) A set of 2 vectors is given in each option of List–I. Match List–I and II.

List-I List-II

(P) (1) Sum of 2 vectors is a unit vector.

(Q) (2) Magnitude of sum of two vectors is .

 (R) (3) Magnitude of difference of two vectors is 5.

The resultant has a positive rectangular component in the

(S) (4)
direction +X.

(5) None of these

(A) P → 3;Q → 4;R → 2;S → 1
(B) P → 2;Q → 3;R → 1;S → 4
(C) P → 1;Q → 4;R → 2;S → 3
(D) P → 4;Q → 1;R → 3;S → 2

2) In a regular hexagon then express all vector in terms of them :

List-I List-II

(P) (1)

(Q) (2)

(R) (3)
(S) (4)

(A) P → 3;Q → 4;R → 1;S → 2

(B) P → 4;Q → 2;R → 1;S → 3
(C) P → 2;Q → 4;R → 1;S → 3
(D) P → 1;Q → 2;R → 3;S → 4

3) If a physical quantity x is given as , where F is force A is area, x is distance and

P is power then match following list.

List-I List-II

(P) Dimension of β is (1) M1/2L–1/2T–1/2

If y is velocity then 0 0
(Q) (2) M L1T
dimension of ω is

If y is velocity then
(R) (3) M–3/2L1/2T7/2
dimension of α is
 If ω is dimensionless 0
(S) (4) M1L T–2
then dimension of y is
(A) P → 2;Q → 1;R → 4;S → 3
(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 1;Q → 3;R → 2;S → 4
(D) P → 4;Q → 2;R → 3;S → 1

PART 2 : CHEMISTRY

SECTION-I (i)

1)

280 mL of sulphur vapour (Sx) at 1 atm, 273 K weighs 1.6 gm. Determine the molecular formula of
sulphur vapour?

(A) S
(B) S4
(C) S6
(D) S8

2) The degree of dissociation of A is 10% then find molecular weight of A for given reaction when
vapour density of mixture is 60
A(g) B(g) + C(g)

(A) 120
(B) 132
(C) 60
(D) 40

3)

A certain dye absorbs light of λ = 4000 Å and then fluorescence light of λ = 5000 Å. Assuming that
under given conditions 50% of the absorbed energy is re-emitted out as fluorescence, calculate the
ratio of the number of quanta emitted out to the number of quanta absorbed:

(A)

(B)

(C)

(D)

4) A photon of wavelength 155 nm is fallen on the metal surface (work function = 64 × 10–20J). The
electron ejected from the metal surface with maximum kinetic energy is absorbed by Hg vapours
and emitted radiation by loosing its kinetic energy. The wavelength of emitted radiation is:

(A) 155 nm
(B) 165 nm
(C) 310 nm
(D) 620 nm

SECTION-I (ii)

1) Which is / are correct statement.

The difference in angular momentum associated with the electron present in consecutive orbits
(A)
of H-atom is (n–1) .
Energy difference between energy levels will be changed if, P.E. at infinity assigned value other
(B)
than zero.
(C) Frequency of spectral line in a H-atom is in the order of (2 → 1) < (3 → 1) < (4 → 1).
(D) On moving away from the nucleus, kinetic energy of electron decreases.

2) Which of the following orbital (s) has/have 3 peaks in the radial probability distribution plot ?

(A) 2s
(B) 4p
(C) 3d
(D) 6f

3) 1 g atom of nitrogen (N) is present in.

23
(A) 6.02 × 10 N2 molecules
(B) 22.4 litre of N2 at 1 atm, 273 K
(C) 11.2 litre of N2 at 1 atm, 273 K
(D) 14 g of nitrogen

SECTION-II

1) The ionisation potential of a hydrogen like species is 36 volt. What is the value of excitation
energy from ground state to 1st excited state. (in eV)
(Fill your answer as sum of digit)

2) By a sample of ground state atomic hydrogen, UV light of energy is absorbed.

How many different wavelengths will be observed in Balmer region of hydrogen spectrum ?

3) The number of photons emitted by a monochromatic (single frequency) infrared range finder of
power 1 mW and wavelength of 1000 nm, in 0.1 second is x × 1013. The value of x is _____. (Nearest
integer)
(h = 6.63 × 10–34 Js, c = 3.00 × 108 ms–1)

4) Considering Bohr model to be valid, the time period of revolution of electron revolving in nth orbit

in H-like species (atomic number = z) is proportional to . Find value of p + q

5) Density of ozone relative to methane under the same temperature & pressure conditions is :

6) A gaseous mixture contains SO3(g) & C2H6(g) in a 16 :15 ratio by mass. The ratio of total number
of atoms present in C2H6(g) & SO3(g) is

SECTION-I (iii)

1) Match the list:

List-I List-II

Electron moving in 2nd orbit in He+ Radius of orbit in which electron is moving is 0.529
(P) (1)
ion Å

Electron moving in 3rd orbit in H-

(Q) (2) Total energy of electron is (–)13.6 × 9eV
atom

Electron moving in 1st orbit in Li+2

(R) (3)
ion Velocity of electron is m/sec

Electron moving in 2nd orbit in Be+3

(S) (4)
ion de-Broglie wavelength of electron is Å

Radius of orbit in which electron moving is 0.529 ×

(5)
9
Correct code is:
(A) P → 4;Q → 5;R → 1;S → 2
(B) P → 4;Q → 3;R → 2;S → 1
(C) P → 4;Q → 3;R → 1;S → 2
(D) P → 4;Q → 5;R → 3;S → 2

2) Match List-I with List-II and select the correct answer using the codes given below in the lists (n,
and m are respectively the principal, azimuthal and magnetic quantum no.)

List-I List-II

Number of value of for

(P) (1) 0, 1, 2, ....... (n - 1)
an energy level(n)

Values of for a particular

(Q) (2) + to – through zero
type of orbit
 Number of value of m for
(R) (3) 5
=2

Values of 'm' for a

(S) (4) n
particular type of orbital

(5) n - 1
(A) P → 4;Q → 1;R → 3;S → 2
(B) P → 4;Q → 5;R → 3;S → 2
(C) P → 5;Q → 1;R → 1;S → 2
(D) P → 5;Q → 1;R → 2;S → 4

3) Match the quantities given in list-I with equivalent amount in list-II.

List-I List-II

(P) 0.4 mol CO2 (1) 45g

(Q) 2.5 mol H2O (2) 32g

(R) 3.01 × 1023 molecules of SO2 (3) 6g

(S) 4.48L of C2H6(g) at 1 atm, 0°C (4) 17.6 g

(5) 35.2 g
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 4;Q → 1;R → 2;S → 3
(C) P → 1;Q → 2;R → 4;S → 3
(D) P → 1;Q → 4;R → 2;S → 3

PART 3 : MATHEMATICS

SECTION-I (i)

1) ≤0

(A) (–1, 1] ∪ [2, 3] ∪ [4, ∞)

(B) (–∞, –1] ∪ [1, 2] ∪ [3, 4]
(C) (–1, 1] ∪ [3, ∞] ∪ {2}
(D) None

2) Solve

(A) x = 0, 3, 4
(B) x = 3, 4, 5
(C)

(D)

3) Number of non-negative integral values of x satisfying the inequality

is

(A) 4
(B) 3
(C) 5
(D) 7

4)

Solve for x :
then

(A) (0, 3)
(B)
(C)
(D)

SECTION-I (ii)

1) If complete solution set of the inequality (x2 + x – 2)(x2 + x – 16) + 40 ≥ 0 is x ∈ (–∞, –4] ∪ [a, b] ∪
[c, ∞) then value of a + b + c is equal to

(A) 4
(B) 3
(C) 2
(D) 7

2) If positive p, q, r satisfy pqr = 1, then for equation , x equals

(A) p + q + r
(B) 1
(C) Independent of p, q & r

(D)

3) If a3 + b3 + 3ab = 1, then which of the following can be true

(A) a + b = 1
(B) a + b = –2
(C) a = 3b
(D) 3a = b

SECTION-II

1) Given that , if the value of the expression is λ, then find the

value of

2) If number of points common between | |x| – |y| | = 1 and 2a |x| |y| + 1 = 2|x| + a|y| are 8 then
value of 3a (where a < 1) is

3)

If P(x) is 3 degree polynomial & P(1) = 2, P(2) = 3, P(3) = 4 and P(4) = 17 then value of P(5) is

4) Find product of all real values of x satisfying = 10

5)

If then value of is where P and Q are positive integers.

Then P + Q is

6)

If are the roots of the equation and consider

. Then the value of is

SECTION-I (iii)

1) Given, ƒ(x) = (x – 1), g(x) = (x2 – 1)(x + 2) & h(x) = (x2 + 3)(x – 4)

If , then

List-I List-II

(P) Largest integral solution of x (1) 2

(Q) Product of positive integral solution of x (2) 3

(R) Sum of all positive integral solution of x (3) 4

(S) Number of non-negative integer solution of x (4) 5

(5) 6
The correct option is
(A) P → 2;Q → 5;R → 5;S → 3
(B) P → 3;Q → 2;R → 1;S → 4
(C) P → 2;Q → 5;R → 5;S → 2
(D) P → 3;Q → 1;R → 5;S → 4

2) Correct match from list I to List II is

List I List II

(P) The number of real solutions of is (1) 0

(Q) The number of real solutions of (2) 1

(R) The number of real solutions of is (3) 2

(S) The number of real solutions of is (4) 3

(5) 4
(A) P → 5;Q → 3;R → 2;S → 4
(B) P → 5;Q → 3;R → 2;S → 1
(C) P → 5;Q → 3;R → 4;S → 2
(D) P → 5;Q → 2;R → 3;S → 4

3) X = Minimum value of
Let Polynomial f(x) = x4 + ax3 + bx2 + cx + d has roots 1, 2, 3 & 4 then
Y = sum of value of (a + b + c + d), Z = a + d, W = d – c + b – a
Match each entry in List-I to the correct entries in List-II

List-I List-II

(P) X (1) –1

(Q) Y (2) 119

(R) Z (3) –5

(S) W (4) 14

(5) 8

The correct option is :

(A) P → 2;Q → 4;R → 5;S → 1
(B) P → 5;Q → 4;R → 3;S → 1
(C) P → 2;Q → 1;R → 3;S → 2
(D) P → 5;Q → 1;R → 4;S → 2
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. D B C D

SECTION-I (ii)

Q. 5 6 7
A. B,D A,B,D A,B,D

SECTION-II

Q. 8 9 10 11 12 13
A. 4.00 2.00 3.00 1.50 -1.50 180.00

SECTION-I (iii)

Q. 14 15 16
A. C A B

PART 2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. B B A C

SECTION-I (ii)

Q. 21 22 23
A. C,D B,D C,D

SECTION-II

Q. 24 25 26 27 28 29
A. 9.00 5.00 50.00 5.00 3.00 5.00

SECTION-I (iii)

Q. 30 31 32
A. B A B

PART 3 : MATHEMATICS
 SECTION-I (i)

Q. 33 34 35 36
A. C D B B

SECTION-I (ii)

Q. 37 38 39
A. C C,D A,B

SECTION-II

Q. 40 41 42 43 44 45
A. 331.05 2.00 54.00 8.00 18.00 6.00

SECTION-I (iii)

Q. 46 47 48
A. A B D
 SOLUTIONS

PART 1 : PHYSICS

1)
[C] = [M1L2T–4]

2) We know,

By triangle law of vector addition, we can write

;
;
;

Now
=

=
=
= =
=

3) Let vector from point P to point S be

⇒ = = =
From triangle rule of vector addition

⇒ .

0 0
4) [F] = [M1L1T–2], [F ] = [M1L T–2]
⇒ M1T–2 = 1 ⇒ T =
(A) [V] = [L1T–1],

(B) [a] = [LT–2],

(C) [P] = [M1L2T–3],

(D) [L] = [M1L2T–1],

5) can not be zero if sum of magnitude of three smallest vectors is less than the
magnitude of bigger vector.

0 0 0
6) Mass = M L T
0 0 0
MVr = M L T

L2 = T1 ...(1)
1 1 –2
Force = M L T (in SI)
0 1 –4
=M L L (In new system from equation (1))
= L–3
Energy = M1L2T–2 (In SI)
0
= M L2L–4 (In new system from equation (1))
–2
=L

Power =
= M1L2T–3 (in SI)
0
= M L2L–6 (In new system from equation (1))
= L–4
Linear momentum = M1L1T–1 (in SI)
0
= M L1L–2 (In new system from equation (1))
–1
=L

7) 1. vector cannot be divided by vector 2. Ang. displacement is scalar

3. If two equal forces acting at 120° then their resultant

resultant

8) [Energy] = ML2T–2 =
n1v1 = n2v2

n2 = 10

= 10 × 10 × × 16
n2 = 400

9)
 0 0
M L T = [M–1L3T–2]
[M]b[L]c = Mb–aL3a+cT–2a

, ,
⇒a+b+2c=2

10) P = kPaℓVbdcµ ⇒ [P] = [P]a [ℓ] [V]b [d]c [µ]

⇒ ML–1T–2 = (ML–3)a(L)(LT–1)b(L)c(ML–1T–1)
a+1=1⇒a=0
–b – 1 = –2 ⇒ b = 1
–3a + 1 + b + c –1 = –1
⇒ b + c = –1 ⇒ c = –2

11) (exp. function are dimensionless)

[k1] = [LT–1θ3/2]

a+b+c= = 1.5

12) (given)
⇒ (given)

13)
PQ sin θ = –PQ sin θ
⇒ sin θ = 0
⇒ θ = 0, 180, 360…….
Given 0° < θ < 360°
⇒ θ = 180°

14)
 (P)

∴
(Q)
(R)
(S)

15)

16)

(Q)
ω = M1/2L–1/2T–1/2

(R)

PART 2 : CHEMISTRY

17)

Mol of sulphur =
wt. of Sx
⇒

18)

α=

⇒ 0.1 =
⇒ 12 = MA –120
⇒ MA = 132

19)

20) = ϕ + K.E.

E(photon) =

w=
K.E. of electron = 8 – 4 = 4eV

λ=

21)

(A) Angular momentum =

For successive orbit it will be & so difference will be hence A wrong.

(B) energy of orbit will change but difference remains same.
(C) ΔE = hv, more ΔE, more v as 'n' increases ΔE increases
so ΔE4–1 > ΔE3–1 > ΔE2–1
so v4→1 > v3→1 > v2→1

(D) as 'n' increases K.E. decreases.

22)

No of spherical (radial) nodes = n – – 1; for s.p, d, f values of = 0, 1, 2, 3 respectively.

For 3 peeks, there are 2 radial nodes.
(A) 2 – 0 – 1 = 1
(B) 4 – 1 – 1 = 2
(C) 3 – 2 – 1 = 0
(D) 6 – 3 – 1 = 2

23)

1 g atom of nitrogen means 1 mole atoms of nitrogen or NA atoms of nitrogen

(A) 6.02 × 1023 N2 molecule = 2 × 6.02 × 1023 atoms of nitrogen

(B) Moles = 1 mole N2 = 6.02 × 1023 N2 molecule =2 × 6.02 × 1023 atoms of nitrogen

(C) Moles = 0.5 moles N2 = 3.01 × 1023 N2 molecule =2 × 3.01 × 1023 atoms of
nitrogen = 6.02 × 1023 atoms of nitrogen

(D) Moles of N2 = = 0.5 moles N2 = 3.01 × 1023 N2 molecule =2 × 3.01 × 1023 atoms of
nitrogen = 6.02 × 1023 atoms of nitrogen

24) ΔE = q.ΔV

E=–

ΔE = I.P. = 36 × = 27 eV

25)

n1 = 1 & n2 = 7

26) Total energy = 1 mw = 10–3 J in 1 sec

= 10–4 J in 0.1 second

energy of one photon = (λ = 1000 nm)

so, number of photones =

Hence

27)
p = 3, q = 2
p+q=5
28) Relative density =

29)

Mass of SO3 = 16 x gm
Mass of C2H6 = 15 x gm

Moles of SO3 =

Moles of C2H6 =

Number of atoms in SO3 = × NA × 4

Number of atoms in C2H6 = × NA × 8

Ratio = 5

30) (P) K.E. = –T.E. =

For e– moving in 2nd orbit for He+ ion

K.E. = ...(1)
–
and K.E. of e = e × V ...(2)
From equation (1) and (2)
V = 13.6 V

de-Broglie wavelength of e– = Å

Å
(Q) z = 1, n = 3

Velocity =

(R) n = 1, z = 3 (for Li2+)

T.E. =
(S) n = 2, z = 4

r=

31)

Number of values of = total number of subshells = n.

Value of = 0, 1, 2 ........ (n – 1).
 = 2 ⇒ m = –2, –1, 0, +1, +2 (5 values)
m = – to + through zero.

32)

(P) 0.4 mole CO2

W = 0.4 × 44 = 17.6 = n × MW
(Q) = 2.5 × 18 = 45.0 gram (n × MW)

(R) = 0.5 mole SO2

= 0.5 × 64 = 32.0 g

(S)
W=6g

PART 3 : MATHEMATICS

33)

x ∈ (–1, 1] ∪ [3, ∞) ∪ {2}

34)

Put x + =t

So, x2 + = t2 – 2
⇒ 2(t2 – 2) – 9(t) + 14 = 0
2t2 – 9t + 10 = 0
(2t – 5) (t – 2) = 0

t= or t = 2

x+ = or x + =2

⇒ x = 2, , 1

35)
 , x ≠ –1 ⇒

x ∈ (–∞, –1) ∪ (–1, 2]

required value of x = {0, 1, 2}.

36)

Here

So

So

37)

Let x2 + x – 2 = t
t2 – 14t + 40 ≥ 0
(t – 4)(t – 10) ≥ 0
t≤4 or t ≥ 10
2
x +x–2≤4 x2 + x – 2 ≥ 10
x2 + x – 6 ≤ 0 x2 + x – 12 ≥ 0
(x + 3)(x – 2) ≤ 0 (x + 4)(x – 3) ≥ 0
x ∈ [–3, 2] x ∈ (–∞, –4] ∪ [3, ∞)
x ∈ (–∞, –4] ∪ [–3, 2] ∪ [3, ∞)

38) Given pqr = 1

Put 1 = pqr

⇒
39) a3 + b3 – 1 + 3ab = 0
a3 + b3 + (–1)3 – 3ab(–1) = 0
⇒ (a + b – 1) (a2 + b2 + 1 – ab + b + c) = 0
⇒ a + b – 1 = 0 or a2 + b2 + 1 – ab + b + c = 0
⇒ a + b – 1 = 0 or a = b = –1

40)

41)

2a|x||y| + 1 = 2|x| + a|y|

1 – 2|x| = a|y| – 2a|x| |y|
(1 –2|x|) = a|y|(1 – 2|x|)

∴ |x| = or |y| = and a < 1

||x| – |y|| = 1 ||x| – |y|| = 1

– |y| = ±1 |x| – = ±1

∴ |y| = |x| =

|x| = or |x| =
Now, a < 1

x= ∴ both are positive,

4 solution so one solution should be common

42)
43)

⇒ = 10 ⇒ t2 – 10t + 1 = 0

t= ⇒ = or

⇒ x2 – 3 = 1 or x2 – 3 = –1

⇒ x = 2 or –2 or or
Product 8

44)

45)

46)

Integral solution = 3, 2, 1, 0, –1, –2, –3, ...

• Largest integral solution = 3
• Product of +ve integral solution = 3.2.1 = 6
• Sum of +ve integral solution = 3 + 2 + 1 = 6
• Number of non-negative integral solution
=4

47) P)

Q)

R)
(rejected)

48) Value of
f(x) = (x – 1) (x – 2) (x – 3) (x – 4)
= x4 – 10x3 + 35x2 – 50x + 24
∴ a = –10, b = 35, c = –50, d = 24
Y = –10 + 35 – 50 + 24 = –1
Z = 14
W = 24 + 50 + 35 + 10 = 119