SOLUTIONS

(After the list of questions, the solution will Start.)

OBJECTIVE TYPE

Question No: 1
The statement "If moles of a gas are dissolved in of water under a pressure of 1
atmosphere, moles will be dissolved under a pressure of 2 atmospheres", illustrates
(a) Dalton's law of partial pressure
(b) Graham's law
(c) Raoult's law
(d) Henry's law
Question No: 2
Which statement is incorrect about osmotic pressure , volume , and temperature
(a) , if is constant.
(b) , if is constant.
(c) , if is constant.
(d) , is constant, if is constant.
Question No: 3
The value of Henry's constant is___________
(a) greater for gases with higher solubility.
(b) greater for gases with lower solubility.
(c) constant for all gases.
(d) not related to the solubility of gases.
Question No: 4
Which one of the following pairs of solution can we expect to be isotonic at the same temperature?
(a) urea and
(b) urea and
(c) and
(d) and
Question No: 5
Colligative properties of the solution depend on
(a) Nature of solute
(b) Nature of solvent
(c) Number of particles present in the solution
(d) Number of moles of solvent only
Question No: 6
What is the normality of a solution of
(a)
(b)
(c)
(d)
Question No: 7
Equal moles of water and urea are taken in a flask. What is mass percentage of urea in the solution?
(a)
(b)
(c)
(d)
Question No: 8
Which of the following units is useful in relating concentration of solution with its vapour pressure?
(a) Mole fraction
(b) Parts per milion
(c) Mass percentage
(d) Molality
Question No: 9
The vapour pressure of a given liquid will decrease if :
(a) surface area of liquid is decreased
(b) the volume of liquid in the container is decreased
(c) the volume of the vapour phase is increased
(d) the temperature is decreased
Question No: 10
An unripe mango placed in a concentrated salt solution to prepare pickle shrivels because.
(a) it gains water due to osmosis
(b) it loses water due to reverse osmosis
(c) it gains water due to reverse osmosis
(d) it loses water due to osmosis
Question No: 11
Pressure cooker reduces cooking time because
(a) the heat is more easily distributed
(b) the higher pressure tenderizes the food
(c) the boiling point of the water inside is elevated
(d) a larger flame is used
Question No: 12
litre solution is mixed with another , 3 litre solution. Then find out the
molarity of resultant solution
(a)
(b)
(c)
(d)
Question No: 13
In comparison to a solution of glucose, the depression freezing point of a
solution is_________
(a) thesame
(b) about twice
(c) about three times
(d) about six times
Question No: 14
When 1 mole of benzene is mixed with 1 mole of toluene The vapour will contain: (Given : vapour
pressure of benzene and vapour pressure of toluene .
(a) equal amount of benzene and toluene as it forms an ideal solution
(b) unequal amount of benzene and toluene as it forms a non ideal solution
(c) higher percentage of benzene
(d) higher percentage of toluene
Question No: 15
The decrease in the vapour pressure of solvent depends on the
(a) quantity of non-volatile solute present in the solution
(b) nature of non-volatile solute present in the solution
(c) molar mass of non-volatile solute present in the solution
(d) physical state of non-volatile solute present in thesolution
Question No: 16
Which one of the following is non-ideal solution
(a) Benzene toluene
(b) -hexane -heptane
(c) Ethyl bromide ethyl iodide
(d)
Question No: 17
A solid dissolves in water exothermically. If its saturated solution at is cooled to , then
(a) some solid seperates out
(b) some ice separates out
(c) both the solid and ice separate
(d) neither the solid nor the ice separates out
Question No: 18
Which will form maximum boiling point azeotrope
(a) solution
(b) solution
(c) solution
(d) None of these
Question No: 19
The solubility of gases in liquids (water) is favoured by
(a) increase in both pressure and temperature
(b) decrease in both pressure and temperature
(c) increase in pressure and decrease in temperature
(d) decrease in pressure and increase in tempeature
Question No: 20
When common salt is dissolved in water
(a) The melting point of the solution increases.
(b) The boiling point of solution decreases.
(c) Both melting point and boiling point decrease.
(d) The boiling point of the solution increases.
Question No: 21
The solubility of in water at and 500 torr partial pressure is . The solubility (in
) at 750 torr partial pressure is :
(a)
(b)
(c)
(d)
Question No: 22
Molarity of liquid HCl will be, if density of solution is
(a)
(b)
(c)
(d)
Question No: 23
Vapour pressure of benzene at is . When of a non volatile solute is dissolved
in of benzene its vapour pressure decreased to . The molecular weight of the
solute (Mo. wt. of solvent
(a)
(b)
(c)
(d)
Question No: 24
Which of the following aqueous solutions should have the highest boiling point?
(a)
(b)
(c)
(d)
Question No: 25
Which of the following statements is incorrect?
(a) A solution in which no more solute can be dissolved at the same temperature and pressure is
called a saturated solution.
(b) An unsaturated solution is one in which more solute can be dissolved at the same temperature.
(c) The solution which is in dynamic equilibrium with undissolved solute is the saturated solution,
(d) The minimum amount of solute dissolved in a given amount of solvent is its solubility.
Question No: 26
The vapour pressure of an aqueous solution of sucrose at is found to be . The
molality of the solution at the same temperature will be :
(a)
(b)
(c)
(d)
Question No: 27
Osmotic pressure of urea solution is and that of came sugar is atin.
When the above two solutions are mixed, the osmotic pressure of the resulting solution is ;
(a)
(b)
(c)
(d)
Question No: 28
A solution of sucrose (molar mass ) has been prepared by dissolving of
sucrose in of water. The freezing point of the solution obtained will be for water
.
(a)
(b)
(d)
(d)
Question No: 29
A beaker contains a solution of substance ' '. Precipitation of substance ' ' takes place when
small amount of ' ' is added to the solution. The solution is ............
(a) saturated
(b) supersaturated
(c) unsaturated
(d) concentrated
Question No: 30
Molarity of is . Its density is . Hence molality is
(a) 36
(b) 200
(c) 500
(d) 18
Question No: 31
Molarity of liquid HCl will be, if density of solution is
(a)
(b)
(c)
(d)
Question No: 32
The osmotic pressures of solutions of KI and of sucrose are atm and
respectively. The van't Hoff factor for KI is :
(a)
(b)
(c)
(d)
Question No: 33
If and are vapour pressures of solvent and its solution, respectively, and are mole
fractions of solvent and solute, respectively, then
(a)
(b)
(c)
(d)
Question No: 34
Low concentration of oxygen in the blood and tissues of people living at high altitude is due to
...............
(a) low temperature
(b) low atmospheric pressure
(c) high atmospheric pressure
(d) Both low temperature and high atmospheric pressure
Question No: 35
How many grams of concentrated nitric acid solution should be used to prepare of
? The concentrated acid is
(a) conc.
(b) conc.
(c) conc.
(d) conc.
Question No: 36
If the elevation in boiling point of a solution of of solute (mol. wt. = 100 ) in of water is
, the ebullioscopic constant of water is
(a) 10
(b)
(c)
(d)
Question No: 37
When solid is added to an aqueous solution of , the
(a) vapour pressure is lowered
(b) vapour pressure is raised
(c) osmotic pressure is increased
(d) boiling point is raised
Question No: 38
What is the normality of a solution of
(a)
(b)
(c)
(d)
Question No: 39
A solution of urea (mol. mass ) boils at at the atmospheric pressure. If and
for water are and respectively, the above solution will freeze at
(a)
(b)
(c)
(d)
Question No: 40
On mixing of acetone with of chloroform, the total volume of the solution is
(a)
(b)
(c)
(d) Cannot be predicted
Question No: 41
An azeotropic mixture of two liquids has a boiling point higher than either of them when it:
(a) shows positive deviation from Raoult's law
(b) shows negative deviation from Raoult's law
(c) shows ideal behaviour
(d) is saturated
Question No: 42
The boiling point of a solution of of a substance in of ether was found to be
than that of pure ether. The molecular weight of the substance will be
(a) 148
(b) 158
(c) 168
(d) 178
Question No: 43
On dissolving sugar in water at room temperature solution feels cools to touch. Under which of the
following cases dissolution of sugar will be most rapid?
(a) Sugar crystals in cold water
(b) Sugar crystals in hot water
(c) Powdered sugar in cold water
(d) Powdered sugar in hot water
Question No: 44
The vapour pressure of two liquids ' ' and ' ' are 80 and 60 torr, respectively. The total vapour
pressure of solution obtained by mixing 3 mole of and 2 mole of would be
(a) 72 torr
(b) 140 torr
(c) 68 torr
(d) 20 torr
Question No: 45
The normal boiling point of water is . Vapour pressure of water at temperature is
. If enthalpy of vaporisation is , then temperature would be Use
:
(a)
(b)
(c)
(d)
Question No: 46
A solution is prepared by dissolving in of a solvent of density . The
molality of the solution in is
(a)
(b)
(c)
(d)
Question No: 47
The mole fraction of component A in vapour phase is and mole fraction of component A in liquid
mixture is vapour pressure of pure A; vapour pressure of pure B). Then total
vapour pressure of the liquid mixture is
(a)
(b)
(c)
(d)
Question No: 48
A solution of sucrose (molar mass ) has been prepared by dissolving of
sucrose in of water. The freezing point of the solution obtained will be ( for water

(a)
(b)
(d)
(d)
Question No: 49
An ideal solution is formed when its components
(a) have no volume change on mixing
(b) have no enthalpy change on mixing
(c) have both the above characteristics
(d) have high solubility.
Question No: 50
Blood has been found to be isotonic with
(a) Normal saline solution
(b) Saturated solution
(c) Saturated solution
(d) Saturated solution of a mixture of and
Question No: 51
At a given temperature, osmotic pressure of a concentrated solution of a substance .............
(a) is higher than that of a dilute solution
(b) is lower than that of a dilute solution
(c) is same as that of a dilute solution
(d) cannot be compared with osmotic pressure of dilute solution
Question No: 52
The correct order of osmotic pressure of aqueous solution of the following is
(a) Sucrose
(b) Sucrose
(c) Sucrose
(d) Sucrose
Question No: 53
Osmotic pressure of blood is , at . Number of moles of glucose to be used per litre for
an intravenous injection that is to have same osmotic pressure of blood is:
(a)
(b)
(c)
(d)
Question No: 54
At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is ........
(a) less than the rate of crystallisation
(b) greater than the rate of crystallisation
(c) equal to the rate of crystallisation
(d) zero
Question No: 55
Maximum amount of a solid solute that can he dissolved in a specified amount of a given liquid
solvent does not depend upon ...............
(a) temperature
(b) nature of solute
(c) pressure
(d) nature of solvent
Question No: 56
The volume of and required to make 1 litre of are
(a) litre of and litre of
(b) litre of and litre of
(c) litre of and litre of
(d) litre of and litre of
Question No: 57
For a dilute solution, Raoult's law states that:
(a) the lowering of vapour pressure is equal to the mole fraction of solute
(b) the relative lowering of vapour pressure is equal to the mole fraction of solute
(c) the relative lowering of vapour pressure is proportional to the amount of solute in solution
(d) the vapour pressure of the solution is equal to the mole fraction of solvent
Question No: 58
Each pair forms ideal solution except
(a) and
(b) and
(c) and
(d) and
Question No: 59
An molal solution of a compound in benzene has mole fraction of solute equal to . The value of
is
(a) 14
(b)
(c)
(d) 2

Assertion-Reason Question
Question No: 60
Assertion : A non volatile solute is added in liquid solvent then freezing point of mixture decreases.
Reason : Vapour pressure decreases by addition of non volatile solute, so equilibrium point where
V.P. of solid and V.P. of liquid are equal can reach at lower temp.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 61
Assertion : Molarity of a solution in liquid state changes with temperature.
Reason: The volume of a solution changes with change in temperature.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 62
Assertion : When a solution is separated from the pure solvent by a semipermeable membrane, the
solvent molecules pass through it from pure solvent side to the solution side.
Reason : Diffusion of solvent occurs from a region of high concentration solution to a region of low
concentration solution.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 63
Assertion : Azeotropic mixtures are formed onlyby non-ideal solutions and they may have boiling
points either greater than both the components or less than both the components. Reason : The
composition of the vapour phase is same as that of the liquid phase of an azeotropic mixture.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 64
Assertion : One molal aqueous solution of glucose contains of glucose in of water.
Reason : Solution containing one mole of solute in solvent is called one molal solution.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 65
Assertion : Homogeneous mixture of two or more nonreacting substances is known as solution.
Reason : State of solutions can be solid only,
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 66
Assertion: When one solvent is mixed with other solvent, vapour pressure of one increases and other
decreases.
Reason: When any solute is added into solvent, vapour pressure of solvent decreases.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 67
Assertion : Molarity of a solution in liquid state changes with temperature.
Reason : The volume of a solution changes with change in temperature.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 68
Assertion : If one component of a solution obeys Raoult's law over a certain range of composition,
the other component will not obey Henry's law in that range.
Reason : Raoult's law is a special case of Henry's law.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 69
Assertion : When methyl alcohol is added to water, boiling point of water increases.
Reason : When a volatile solute is added to a volatile solvent elevation in boiling point is observed.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 70
Assertion : If red blood cells were removed from the body and placed in pure water, pressure inside
the cells increases
Reason: The concentration of salt content in the cells increases.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 71
Assertion: Nitric acid and water form maximum boiling azeotrope.
Reason: Azeotropes are binary mixtures having the same composition in liquid and vapour phase.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 72
Assertion: Aquatic species are more comfortable in cold waters rather than in warm waters.
Reason: Different gases have different values at the same temperature
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
Question No: 73
Assertion : People taking a lot of salt or salty food experience edema which is a condition of swelling
or puffiness in body.
Reason : It is a caused by water retention in tissue cells and in the intercellular spaces because of
osmosis.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect but the Reason is correct.
 CASE STUDY QUESTIONS

Question No: 74
Boiling point or freezing point of liquid solution would be affected by the dissolved solids in the
liquid phase. A soluble solid in solution has the effect of raising its boiling point and depressing its
freezing point. The addition of non-volatile substances to a solvent decreases the vapor pressure and
the added solute particles affect the formation of pure solvent crystals. According to many
researches the decrease in freezing point directly correlated to the concentration of solutes
dissolved in the solvent. This phenomenon is expressed as freezing point depression and it is useful
for several applications such as freeze concentration of liquid food and to find the molar mass of an
unknown solute in the solution. Freeze concentration is a high quality liquid food concentration
method where water is removed by forming ice crystals. This is done by cooling the liquid food
below the freezing point of the solution. The freezing point depression is referred as a colligative
property and it is proportional to the molar concentration of the solution (m), along with vapor
pressure lowering, boiling point elevation, and osmotic pressure. These are physical characteristics
of solutions that depend only on the identity of the solvent and the concentration of the solute. The
characters are not depending on the solute's identity. (Jayawardena, J. A. E. C., Vanniarachchi, M. P.
G., \& Wansapala, M. A. J. (2017). Freezing point depression of different Sucrose solutions and
coconut water.)
[Link] a non volatile solid is added to pure water it will:
(a) boil above and freeze above
(b) boil below and freeze above
(c) boil above and freeze below
(d) boil below and freeze below
[Link] properties are:
(a) dependent only on the concentration of the solute and independent of the solvent's and solute's
identity,
(b) dependent only on the identity of the solute and the concentration of the solute and independent
of the solvent's identity.
(c) dependent on the identity of the solvent and solute and thus on the concentration of the solute.
(d) dependent only on the identity of the solvent and the concentration of the solute and independent
of the solute's identity.
[Link] three samples of juices A, B and C have glucose as the only sugar present in them. The
concentration of sample A, B and C are and respectively. Freezing point will be
highest for the fruit juice:
(a) A
(b)
(c)
(d) All have same freezing point
[Link] which of the following is a colligative property:
(a) freezing point
(b) boiling point
(c) osmotic pressure
(d) all of the above
a)c,d,a,c b)a,d,a,c c)b,d,a,c d)c,c,c,b
Question No: 75
The word "colligative" has been adapted or taken from the Latin word "colligatus" which translates
to "bound together". A colligative property is a property of a solution that is dependent on the ratio
between the total number of solute particles (in the solution) to the total number of solvent particles.
Colligative properties are not dependent on the chcmical naturc of the solution's componcnts. Dilute
solution containing non-volatile solute exhibit some properties which depend only on the number of
solute particles present and not on the type of solute present. These properties are called colligative
properties. These properties are mostly seen in dilute solutions. There are different types of
colligative properties of a solution. These include, vapour pressure lowering, boiling point elevation,
freezing point depression and osmotic pressure.
[Link] one of the following is a colligative property?
(a) Boiling point
(b) Vapour pressure
(c) Osmotic pressure
(d) Freezing point
[Link] relative lowering of the vapour pressure is equal to the ratio between the number of
(a) solute molecules to the solvent molecules
(b) solute molecules to the total molecules in the solution
(c) solvent molecules to the total molecules in the solution
(d) solvent molecules to the total number of ions of the solute.
[Link] has added a non electrolyte solid to the pure liquid but forgot that among which of the
two beakers he has added that solid. This problem can be solved by checking
(a) relative lower in vapour pressure
(b) elevation in boiling point
(c) depression in Freezing point
(d) all above
4. of a non-volatile solute dissolved in of water produces the relative lowering of vapour
pressure of . The molecular mass of the solute is
(a) 80
(b) 60
(c) 20
(d) 40
[Link] freezing point of solution of lead nitrate in water will be
(a)
(b)
(c)
(d) below
a)c,b,d,b,d b)c,a,d,c,d c)c,b,a,c,d d)c,b,d,c,d
 SOLUTIONS

Answer Key

1 2 3 4 5 6 7 8

d a b d c d c a

9 10 11 12 13 14 15 16

d d c c c c a d

17 18 19 20 21 22 23 24

d a c d d b a b

25 26 27 28 29 30 31 32

d c d a b c b a

33 34 35 36 37 38 39 40

b b d c b d b a

41 42 43 44 45 46 47 48

b b d a b a a a

49 50 51 52 53 54 55 56

c a a d a c c c

57 58 59 60 61 62 63 64

b d b a a b b a

65 66 67 68 69 70 71 72

c b a b d c b b

73 74 75

a a d
 SOLUTIONS

Question No: 1
(d) Henry's law
Question No: 2
(a) , and not .
Question No: 3
(b)
Question No: 4
(d) Solutions having same no. of ions are isotonic

Question No: 5
(c) Colligative properties of dilute solution containing non volatile solute depends upon the number
of particles of the solute present in the solution.
Question No: 6
(d) is tribasic so,
Question No: 7
(c) If mole
Mass of mole of
Then urea mole
Mass of mole of
Total mass of the solution .
Mass \% of urea
Question No: 8
(a) According to Henry's law partial pressure of a gas in the solution is proportional to the mole
fraction of gas in the solution.

Question No: 9
(d) liquid vapour, of liq,

Question No: 10
(d) When an unripe mango is placed in a concentrated salt solution to prepare pickle then mango
loose water due to osmosis and get shrivel.
Question No: 11
(c) The boiling point of water inside the cooker increases above due to accumulation of steam
and increase in pressure. Thus making it possible to cook food faster.
Question No: 12
(c) From molarity equation
Question No: 13
(c) As we know depression in freezing point is directly related to van't Hoff factor according to
which greater the value of greater will he the depression in freezing point

Hence, depression in freezing point of glucose is about 3 times of glucose.

Question No: 14
(c) Vapour pressure of benzene is higher than the vapour pressure of toluene.
Question No: 15
(a) For example, decrease in the vapour pressure of water by adding of sucrose to one of
water is nearly similar to that produced by adding of urea to the same quantity of water at
the same temperature.
Question No: 16
(d) is non-polar and is polar.
Question No: 17
(d) In case of exothermic dissolution, the solubility of the solid increases on lowering the
temperature. On cooling, the solution becomes unsaturated and solid solute does not separate. At
, water in the solution does not freeze.
Question No: 18
(a) The solutions (liquid mixture) which boils at constant temperature and can distil as such without
any change in composition are called azeotropes.
Solution of and will form maximum boiling point azeotrope. Maximum boiling
azeotropes show negative deviation from Raoult's law.

Boiling point of the azeotrope of these two solutions is

Question No: 19
(c) Dissolution of gases in liquids is generally an exothernic process accompanied by a large
decrease in volume. Follow Le chatelier's principle.
Question No: 20
(d) Addition of a solute increases the boiling point of solution.
Question No: 21
(d) According to Henry's law

Question No: 22
(b) Density (Given) As
Volume Mass
Molarity
-
Question No: 23
(a) Given vapour pressure of pure solvent ; Weight of solute
Weight of solvent ; Vapour pressure of solution and Molecular
weight of solvent
From Raoult's law

or
Question No: 24
(b) As we know greater the value of van't Hoff factor higher will be the elevation in boiling point and
hence higher will be the boiling point of solution.

Hence, has highest value of boiling point.

Question No: 25
(d) The maximum amount of solute dissolved in a given amount of solvent is its solubility.
Question No: 26
(c) Given
is boiling point of water.
Thus,

Question No: 27
(d) Osmotic pressure is a colligative property. Hence resulting osmotic pressure of the solution is
given by

Question No: 28
(a)

Question No: 29
(b) When solute is added to the solution three cases may arise
(i) It dissolves into solution then solution is unsaturated.
(ii) It does not dissolve in the solution then solution is known as saturated.
(iii) When solute get precipitated solution is known as supersaturated solution.
Question No: 30
(c) Molality (m)
Question No: 31
(b) Density (Given) As volume mass Molarity
-
Question No: 32

(a)

Question No: 33

(b) Mole fraction of solute

Question No: 34
(b) Low concentration of oxygen in the blood and tissues of people living at high altitude is due to
low atmospheric pressure. Because at high altitude, the partial pressure of oxygen is less than at the
ground level. This decreased atmospheric pressure causes release of oxygen from blood.
Question No: 35

(d) Molarity wt. of acid

Question No: 36
(c)

Question No: 37
(b)

The number of ions decreases in the ratio of 4 to 3 , and so also the colligative property.
Question No: 38
(d) is tribasic so
Question No: 39
(b) As
Hence, we have

or

As the freezing point of pure water is ,

Thus the freezing point of solution will be .

Question No: 40
(a) The interparticle forces in between and acetone increase due to H-bonding and thus
 becomes negative.
Question No: 41
(b) Show negative deviation from Raoult's law.
Question No: 42

(b)

Question No: 43
(d) Dissolution of sugar in water will be most rapid when powdered sugar is dissolved in hot water
because powder form can easily insert in the vacancies of liquid particles. Further dissolution of
sugar in water in an endothermic process. Hence, high temperature will favour the dissolution of
sugar in water.
Question No: 44
(a) Given torr torr

torr
Question No: 45
(b) Given

Applying Clausius-Clapeyron's equation

on solving, we get
Question No: 46
(a) Given Mol. mass Weight of solvent
Molality
Question No: 47

(a)

Question No: 48
(a)

Question No: 49
(c) For ideal solution,
and
Question No: 50
(a) Normal saline is solution.
Question No: 51
(a) According to definition of osmotic pressure we know that . For concentrated solution
has higher value that dilute solution.
Hence, as concentration of solution increases osmotic pressure will also increase.
Question No: 52
(d) Osmotic pressure is directly proportional to the number of particles in the solution. will
dissociate completely in the solution, while and sucrose are weak electrolyte. Hence
correct order will be :

Question No: 53
(a)
Question No: 54
(c) equal to the rate of crystallisation
Question No: 55
(c) Maximum amount of solid that can be dissolved in a specified amount of a given solvent does not
depend upon pressure. This is because solid and liquid are highly incompressible and practically
remain unaffected by change in pressure.
Question No: 56
(c) Thus litre of

litre of
Question No: 57

Question No: 58
(d) show H-bonding as well as polarity both
Question No: 59
(b) Let total moles in solution , Moles of solute ,
Moles of solvent , Mass of solvent .
Molality
Question No: 60
(a) Vapour pressure of liquid and solid are equal at freezing point. Reduction in V.P. occurs when
solute is added.
Question No: 61
(a) Assertion and reason both are correct statements and reason is the correct explanation of
assertion.
Volume of solutions is a function of temperature which varies with temperature. Hence, molarity of
solution in liquid state changes with temperature.

Question No: 62
(b) Assertion and reason both are correct statements but reason is not the correct explanation of
assertion.
When a solution is separation from the pure solvent by a semipermeable membrane, the solvent
molecules pass through it from pure solvent side to the solution side. Solvent molecules always flow
from lower concentration to higher concentration of solution.
Question No: 63
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
Question No: 64
(a) Molar mass of glucose
Number of moles = Given mass/Molar mass
Molality Number of moles of solute/Mass of solvent molal
Question No: 65
(c) State of solution can be solid, liquid or gas.
Question No: 66
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
Question No: 67
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
Question No: 68
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
Question No: 69
(d) Assertion is wrong statement but reason is correct statement. When methyl alcohol is added to
water, boiling point of water decreases because when a volatile solute is added to a volatile solvent
elevantion in boiling point is observed.
Question No: 70
(c) The pressure inside the cell increases due to osmosis. Water enters into the cell due to higher
concentration inside the cell. This results in lowering of concentration of salt content inside the cell.
Question No: 71
(b) Mixture of nitric acid and water shows negative deviation from raoult's law
Question No: 72
(b) Aquatic species are more comfortable in cold water than in warm water because the solubility of
oxygen in water increases with decrease in temperature.
Question No: 73
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
Question No: 74
(c) When non-volatile solid is added to pure solvent the boiling point of solution increases and
freezing point of solution decreases.
(d) dependent only on the identity of the solvent and the concentration of the solute and independent
of the solute's identity.
(a) Since the concentration of sample A is less, so it will show less depression in freezing point.
Consequently, its freezing point will be higher than other solutions.
(c) Elevation in boiling point, freezing point depression and osmotic pressure are colligative presents
Question No: 75
(c) Osmotic pressure is a colligative property.
(b) According to Raoult's law, the relative lowering in vapour pressure of a dilute solution is equal to
the mole fraction of the solute present in the solution.

(d) All are colligative properties.

(c)

(d) Addition of solute to water decreases the freezing point of water (pure solvent).
When lead nitrate (solute) is added to water, the freezing point of water will be below .